Drying Shrinkage Behavior Research Articles

Developing greener concretes from spent bleaching earth and sugarcane bagasse ash

Concrete is by far the most widely utilized construction material due to its excellent mechanical and durability properties. However, the concrete industries are notorious for their anthropogenic activities that contribute to climate change. Cement production alone consumes immense amounts of energy and trails a significant CO2 footprint. One solution that researchers have deemed promising over the last couple of decades is the substitution of cement with agricultural waste products, which subsequently serves to alleviate waste disposal problems. This study investigates the suitability of spent bleaching earth (SBE) and sugarcane bagasse ash (SCBA) as partial replacement of ordinary Portland cement (OPC) in increments of 0, 5, 10 and 15% by mass. Tests were conducted in accordance to British Standards to assess the consistence, compressive strength, split tensile strength and drying shrinkage strain of SBE and SCBA based concretes. Results indicated that while these concretes displayed similar degrees of consistency, the SCBA concretes exhibited superior compressive and tensile strengths. Optimum SCBA dosages were revealed to be about 5-10%, yielding a 7-12% and 3-8% increase in compressive and tensile strengths, respectively, as compared to OPC concrete. Drying shrinkage behavior was also improved in the SCBA concretes. Further, comparisons of the mechanical and durability performances of the concretes with British and American codes suggest that up to 10% replacement of cement with SCBA may be a viable approach to developing sustainable materials for the concrete industry.

Study on the dry shrinkage characteristics and size effect of swell-shrink characteristic soil.

Swell-shrink characteristic soils exhibit a high susceptibility to cracking during the drying process, which poses a significant risk of various geological disasters. Among these, the occurrence of drying shrinkage acts as a prerequisite for the cracking phenomenon. Therefore, it is of utmost importance to comprehend the specific characteristics associated with the drying shrinkage mechanism. To investigate the drying shrinkage behavior of swell-shrink characteristic soils, a series of drying shrinkage experiments were conducted on long strip samples of red clay and expansive soil. Utilizing three-dimensional digital image correlation (DIC) technology, the surface displacement, strain, and anisotropic shrinkage rates of the soil samples during the drying process were obtained, and the size effect on the drying shrinkage of swell-shrink characteristic soil were analyzed. The research findings are as follows: The displacement development of the soil samples in the X and Y directions can be divided into two stages: a linear growth stage and a stable displacement stage. In the Z direction, the soil surface deformation can be divided into three stages: soil surface arching, vertical shrinkage, and shrinkage stabilization. The drying shrinkage of swell-shrink characteristic soil exhibits anisotropy, with the vertical shrinkage rate being the largest, followed by the longitudinal and then the transverse directions. Additionally, the soil sample shrinkage exhibits a size effect, whereby the shrinkage rates in all directions increase with increasing sample width and thickness. During the drying shrinkage process, the stress state on the soil surface evolves from initial tensile strain to subsequent compressive strain. The strain at different positions and times within the soil sample is not uniform, resulting in the non-uniformity and anisotropy of the sample shrinkage. This study provides important insights into the cracking mechanism of swell-shrink characteristic soils and serves as a valuable reference for related laboratory experiments, which will contribute to better prediction and control the geological hazards caused by the drying shrinkage of swell-shrink characteristic soils.

An evaluation on the shrinkage deformation characteristics of Chinese yam during multiphase microwave drying based on digital image processing

The deformation characteristics of Chinese yam during multiphase microwave drying (MMD) was evaluated by image processing, and the effects of MMD on the drying characteristics, physical properties, shrinkage behavior, and microstructure of the samples were also investigated. The drying time was significantly reduced by increasing microwave power density. Compared with Scheme I, the time of Scheme V was shortened by 22.22%. The moisture content at the transition point from sublimation to evaporation drying stages (TPS-E) significantly affected the shrinkage of the samples. In Scheme I, the lowest moisture content at TPS-E of 0.354 g. g−1 was found, and the dried products with the shrinkage ratio and bulk density closest to those of FD. The deformation of Chinese yam mainly appeared in the evaporation drying stage. At this stage, the rate of change in cross-sectional area of dried samples ranged from 9.74% to 26.76% for Schemes II to Scheme V, compared to 2.03% for Scheme I. Similarly, the shrinkage ratio of the dried samples in Schemes II, III, IV, and V increased from 16.82% to 21.12% at TPS-E to 29.23% to 51.28% at the end of drying, respectively. Additionally, the shrinkage caused by the pores collapse of the samples because of the high moisture content at TPS-E (Scheme III, IV, and V) during the evaporation drying stage resulted in increases of bulk density. The present study can provide valuable insights for rational control of shrinkage and deformation of fruits and vegetables in MMD. Industrial relevanceChinese yam is a widely used food and medicinal resource in China due to its rich nutritional and medicinal values. Since the moisture content of Chinese yam can reach as high as 70–80%, drying serves as an effective method to broaden its application. However, shrinkage and deformation of materials during drying are common forms of appearance deterioration that can directly impact consumer acceptability. MMD has proven to be a promising drying technology. Nevertheless, improper drying parameter settings may lead to a deterioration of the appearance quality of MMD products. Therefore, comprehending the information of shrinkage and deformation of Chinese yam during MMD and effectively regulating these processes is essential. Mastering these aspects is critical for enhancing the economic value and consumer acceptance of dried Chinese yam products.

Long-Term Drying Shrinkage Strain of Engineered Cementitious Composite Concrete Contains Polymeric Fibers

The lack of concrete tensile stress endurance led to the invention of engineered cementitious composite. However, the absence of gravel from the mixture in addition to the high binder content may lead to high shrinkage strain. Therefore, a radical solution to this problem is worth to be anticipated. The importance of this research lies in investigating the long-term drying shrinkage strain of the engineered cementitious composite since there is a lack of information regarding this behavior. Mixes of 30 and 60 MPa strengths were produced with polyvinyl alcohol fibers PVA-ECC and polypropylene fibers PP-ECC. The drying shrinkage strain of PVA-ECC mixes has been compared to PP-ECC mixes for both short term (0–28 days) and long term (0–360 days). Results indicated that all PVA-ECC mixes exhibited lower drying shrinkage strains than PP-ECC mixes. The ultimate drying shrinkage strain was recorded to be 1200 microstrain at 28 days. The increment in drying shrinkage strain after 28 days was 5.6% in PVA-ECC mixes when compared to that in PP-ECC mixes which was 6.77%. For high strength levels, the drying shrinkage strain at the age of 360 days declared a reduction of 3.5% for PVA-ECC compared to PP-ECC mixes. Also, it was lower for mixes with 60 MPa (6.3%) than for mixes with 30 MPa (7.6%). Therefore, despite the higher cement content for mixes with 60 MPa strength, the higher fiber volume fraction and the higher PVA solution percentage restricted the drying shrinkage strain increment. The research also addresses some mechanical tests of engineered cementitious composite concrete such as compressive strength, flexural strength, and strain capacity that may provide a strong relation to the drying shrinkage behavior of the different mixes. The scanning electron microscope images were involved in this research to declare the impact of fiber types on the microstructure of the ECC mixes.

Investigation of Drying Shrinkage Characteristics in Lightweight Engineered Cementitious Composites

Lightweight engineered cementitious composites (LW-ECCs) not only offer comparable mechanical strengths compared with conventional concrete, but also increase the tensile strain of the composite and exhibit strain-hardening behavior, and can be utilized in weight-critical structures such as buildings in seismically active areas. Hollow glass microsphere is a type of ultra-lightweight inorganic non-metallic hollow sphere and it has been deemed as one of the potential sustainable fillers of cement composites. This study aims to investigate the drying shrinkage behavior of LW-ECCs mix designs incorporating different types of hollow glass microspheres (HGMs). Eight types of HGMs with different densities (0.2–0.6 g/cm3) and particle size distributions were incorporated to replace fly ash at 80 and 100 vol% with HGMs. Drying shrinkage was measured from the age of 2 days and up to 91 days. The results demonstrate that all LW-ECCs at 91 days showed greater shrinkage than the control mix, deformation ranged from 1140–1877 µε; 80% replacement ratio of HGMs was regarded as the optimum due to less shrinkage than 100% HGM mixes; the mix incorporating 80% H60 type of HGMs was the relatively most desired mix which had the least shrinkage at 91 days compared to other LW-ECCs, and the strains of the mix using H60 were 1140 and 1385 µε at 91 days for 80% and 100% replacement, respectively.

Effect of Glass Powder on the Compressive Strength and Drying Shrinkage Behavior of OPC‐ and LC3‐50‐Based Cementitious Composites of Various Strengths

This study assesses the compressive strength and drying shrinkage behavior of cement and LC3‐50‐based cementitious composites containing glass powder. A total of four, i.e., 20, 35, 50, and 60 MPa, strengths of cementitious composites were targeted by varying the mix composition and water‐to‐cement ratios. In all four composite mix types, locally available glass powder was used as 0, 5, 10, and 15% added as a partial replacement of cement and LC3‐50. The novelty of this research is the addition of waste glass powder as an alternative to silica fume, especially in a high‐strength composite (including 50 and 60 MPa). The aim was to investigate the efficiency of waste glass powder in providing eco‐friendly composites. The compressive strength was determined following ASTM C 109 standard and the drying shrinkage test followed ASTM C 157 standard. The results of compressive strength in the enhancement using up to 10% waste glass powder are beneficial in enhancing strength and reducing drying shrinkage. Furthermore, the use of LC3‐50 initially reduced compressive strength up to 14 days while increased at 28 days compared to OPC. Contrariwise, the initial drying shrinkage was higher in LC3‐50 specimens and lower at later ages compared to OPC. A detailed investigation of existing shrinkage models for mortar/composite is assessed, and limitations are also discussed.

Drying shrinkage inhibition effect and mechanism of polyol shrinkagex reducing admixture on the metakaolin-based geopolymer

Geopolymers, environmentally friendly materials, face application limitations due to their high drying shrinkage and propensity for cracking. The shrinkage reducing admixture (SRA) has shown promise in mitigating drying shrinkage in cement-based materials, yet its impact and mechanism in geopolymers remain uncertain. This study examines the influence of the small molecule polyol SRA-2-methyl-2,4-pentanediol on metakaolin-based geopolymer (MKG) properties and its multiscale structural development, aiming to understand the drying shrinkage behavior. The findings reveal that SRA significantly curbs the drying shrinkage of MKG while also reducing its mechanical properties. Analyses of macroscopic and microscopic properties indicate that while SRA does not alter the hydration products of MKG, it can impede the hydration process, particularly in the early stages. Specifically, SRA inhibits the formation of N-A-S-H gel, thereby reducing shrinkage caused by late-stage polycondensation. Furthermore, the alkaline environment in MKG aids SRA in lowering pore solution surface tension and increasing its contact angle, reducing drying shrinkage forces. Additionally, SRA modifies MKG's micro-structure, decreasing pore volume, particularly in the 10–50 nm range, further mitigating shrinkage due to surface tension.

A numerical model for predicting the drying shrinkage behavior of concrete under ultra-low relative humidity

The drying shrinkage caused by rapid water loss will pose a great threat to the safety of concrete structures, especially for those serviced in an extremely dry environment. However, the majority of reported research primarily focuses on drying shrinkage behavior of concrete under relative humidity (RH) ranging from 50% to 100%, and the corresponding drying shrinkage prediction models have poor applicability, leading to an unclear understanding of it under ultra-low RH (RH<40%). In this study, a numerical model, finite element model with cohesive elements, was proposed to better predict the drying shrinkage behavior of concrete, even under the RH of 20%. Initially, geometric models of concrete with varying coarse aggregate size ranges and volume fractions were established. Subsequently, based on the relationship between RH and humidity diffusion coefficient of concrete with different water-cement ratio (w/c), a drying shrinkage model was proposed to examine the corresponding shrinkage strain of concrete even under ultra-low RH conditions, and its validity was verified through comparison with reported experimental research. Utilizing the developed model, the effects of size range and volume fraction of coarse aggregate, and the w/c, on the drying shrinkage of concrete across a wide range of RH levels were systematically investigated. The results indicated that increasing the aggregate size range can only slightly inhibit drying shrinkage, while there is a marked inhibition effect on it (decrease by about 45% at most) for increasing the aggregate vol% or reducing w/c, even under ultra-low RH of 20%. Finally, grey relation analysis was employed to assess the inhibition weight of each parameter on the drying shrinkage, following this sequence in order: RH > w/c > coarse aggregate vol% > coarse aggregate range size. We also envision that the proposed model could provide feasible guidelines for the inhibition of concrete in ultra-dry regions.

Formulation of inexpensive and green reactive powder concrete by using milled-waste-glass and micro calcium-carbonate – A multi-criteria optimization approach

In view of its high strength and durability, reactive powder concrete (RPC) is a promising construction material. The replacement of cement and silica fume with sustainable alternatives to RPC may provide significant benefits, however, there are challenges to overcome. In this study, calcium carbonate and ground waste glass powder were introduced as mineral mixtures to develop an environmentally friendly and cost-effective RPC mixture. The best flowability, proper compressive strength, and reduced cement content were achieved using a multi-objective simultaneous optimization approach based on the Derringer & Suich methodology. As a result of the study, 603 kg/m3 of cement was determined as the most suitable dosage for RPC. Additionally, the optimized mix contained 368 kg/m3 of waste glass and 118 kg/m3 of calcium carbonate, which had a beneficial impact on both cost and environmental considerations. As a result of numerous experimental tests, including compressive strength, elasticity modulus, chloride ion penetration, and drying shrinkage, the developed RPC's properties were validated and were comparable to the control mixture while showing superior drying shrinkage behavior. A further benefit of adding these admixtures was the reduction of superplasticizer dosage. Despite the optimized RPC's lower mechanical and chloride ion penetration performance at early ages, the performance discrepancy diminished over time due to the pozzolanic properties of waste glass powder. A significant characteristic of the optimized RPC was its superior drying shrinkage behavior throughout the testing period resulting from its reduced water dosage. Ultimately, the study highlights the potential of the addition of calcium carbonate and waste glass powder to RPC for sustainable concrete production at a low cost.

In-situ shrinkage measurement of alkali-activated materials using focused ion beam combined with environmental scanning electron microscopy

Drying shrinkage of alkali-activated slag (AAS) has gained significant attention since the volumetric instability of this material can generate premature cracking and degrade the long-term durability of concrete structures. The unique shrinkage behavior of AAS originates mainly from the particular characteristics of its main hydrated products. However, few studies have even at-tempted to investigate the shrinkage behavior of hydrated products in AAS materials. This paper presented a new method of investigating drying shrinkage behavior of AAS using focused ion beam (FIB) combined with environmental scanning electron microscopy (ESEM). This innovative experimental method allowed the in-situ measurement of phase-specific shrinkage. The results showed FIB/ESEM technique can be successfully implemented to cementitious material to prepare phase-specific samples. Furthermore, object-oriented finite element method (OOF2) has been utilized to compute the shrinkage behavior of AAS concrete using a proposed multi-scale scheme. The computations can be made at multi-scales which highlight the effect of hydration products on shrinkage behaviors. OOF2 calculation at the micro-length scale predicted an increase in the shrinkage due to the well-dispersed hydration products inside the matrix. At larger scale, the decrease in the overall shrinkage is related to the extremely low shrinkage value by aggregates. The findings reveal OOF2 offers the capability to accurately measure local stress and strain distribution within heterogeneous materials, a feature notably absent in conventional numerical homogenization approaches. The importance of this benefit is highlighted particularly in the context of free-restrained shrinkage prediction, as conventional homogenization methods fail to account for stress.

Factors affecting the drying shrinkage of alkali-activated slag/fly ash mortars

Climate change associated with carbon emissions is driving a demand for low-carbon cements. One of the most promising low-carbon alternatives is alkali-activated binder systems consisting of fly ash and ground granulated blast furnace slag. However, there are some issues related to their drying shrinkage which can be problematic when upscaling these binders to produce full size construction products. This study found that modifying the curing regime can reduce the drying shrinkage of alkali-activated mortars by up to 60%. The proportion of slag and fly ash employed also influences drying shrinkage behaviour but is less significant than the curing temperature and curing duration before drying is initiated. The drying shrinkage performance appears to be linked to the maturity and strength of the different mixes when drying begins.Graphical abstract

New Experimental Evidence for Drying Shrinkage of Alkali-Activated Slag with Sodium Hydroxide.

Alkali-activated slag (AAS) is emerging as a possible and more sustainable alternative to Ordinary Portland Cement (OPC) in the construction industry, thanks to its good mechanical and chemical properties. Conversely, the effects of its high drying shrinkage are still a concern for its long-term durability. This study aims to investigate the drying shrinkage behaviour of six AAS/sodium hydroxide mortar compositions and the main phenomena affecting their drying shrinkage behaviour. Specifically, the molarity, solution-to-binder ratio (s/b), autogenous shrinkage, creep compliance, microcracking, and carbonation are considered as possible causes of the differences between AAS and OPC. The results show that it is not possible to correlate the shrinkage magnitude with the molarity of the activating solution, while an increase in the s/b increases the drying shrinkage. Concerning the other factors, autogenous deformation remains significant even after a period of 112 days, while the creep compliance is definitely affected by the drying process but does not seem to affect the shrinkage magnitude. Furthermore, the presence of microcracks caused by the drying process definitely influences the drying shrinkage. Finally, carbonation depends on the molarity of the activating solution, even though its effects on the material are still unclear.

Mechanical, tidal erosion, and drying shrinkage behaviour of high performance seawater concrete incorporating the high volume of GGBS and polypropylene fibre

Utilization of seawater as a mixing water can reduce demand for freshwater and lowers the carbon footprint of concrete production, making it an environmentally significant solution. This study explored the effect of incorporating polypropylene fibre (PPF) and a high volume of ground granulated blast furnace slag (GGBS) (as a 50% replacement of ordinary Portalnd cement) on the strength and durability parameters of high-performance concrete (HPC). According to the results, the use of seawater has an enhancing effect on the early-stage strength of HPC made with or without GGBS, as it accelerates the hardening process. In long term (over 28 days), the strength properties of seawater concrete produced with 100% OPC were slightly reduced as compared to corresponding freshwater concrete. However, for seawater mixes made with GGBS, strength properties improved with the age, and these mixes achieved high later strength than the seawater mixes made with 100% OPC. The inclusion of seawater and PPF yield a positive effect on the early-stage strength of GGBS-containing mixes. The drying shrinkage strain increased with the use of seawater, and it further increased due to the incorporation of GGBS. However, PPF reinforcement drastically reduced the shrinkage problem of the seawater mix. The wetting-drying cycle-induced erosion was significantly reduced by the inclusion of both GGBS and PPF, indicating their benefit in controlling the degradation of seawater mix in a tidal environment.

Drying shrinkage of geopolymeric recycled aggregate concrete

In this work, the drying shrinkage behavior of geopolymeric recycled aggregate concrete (GRAC) was studied with attention devoted to the mass loss, drying shrinkage strain, and sensitivity of drying shrinkage to water loss. The GRACs were prepared based on different fly ash/slag ratios and various dosages of recycled aggregate. Also, two types of curing regimes were employed, including ambient and heat curing. Additionally, the drying shrinkage strain development of GRACs was fast in the first 28 days and then slowed down with time. Recycled aggregate dosage increased the dry shrinkage strain while increasing the slag content and curing temperature reduced the drying shrinkage strain. Analogously, the sensitivity of drying shrinkage to the mass loss was raised under high recycled aggregate replacement ratios, whereas decreased when the slag content increased or heat curing was employed. Based on the test results, a prediction model was established for the drying shrinkage of GRACs, in which the factors of recycled aggregate replacement ratio, slag content, and curing regime were involved.

Prediction Model and Mechanism for Drying Shrinkage of High-Strength Lightweight Concrete with Graphene Oxide.

The excellent performance of graphene oxide (GO) in terms of mechanical properties and durability has stimulated its application potential in high-strength lightweight concrete (HSLWC). However, more attention needs to be paid to the long-term drying shrinkage of HSLWC. This work aims to investigate the compressive strength and drying shrinkage behavior of HSLWC incorporating low GO content (0.00-0.05%), focusing on the prediction and mechanism of drying shrinkage. Results indicate the following: (1) GO can acceptably reduce slump and significantly increase specific strength by 18.6%. (2) Drying shrinkage increased by 8.6% with the addition of GO. A modified ACI209 model with a GO content factor was demonstrated to have high accuracy based on the comparison of typical prediction models. (3) GO not only refines the pores but also forms flower-like crystals, which results in the increased drying shrinkage of HSLWC. These findings provide support for the prevention of cracking in HSLWC.

Characterization of high-performance concrete using limestone powder and supplementary fillers in binary and ternary blends under different curing regimes

Although the dumping of waste generated by industries in the environment poses a hazard, it is feasible to use waste and unused materials to manufacture high-performance concrete. By recycling these wastes in binary and ternary blends, sustainable and durable concrete mixtures can be created, resulting in the development of sustainable concrete structures. Therefore, a research project was undertaken to develop high-performance concrete (HPC) using available supplementary and waste materials, such as fly ash (FA), silica fume (SF), Quartz filler (QF), and limestone powder (LSP), as partial replacements for cement in binary and ternary blends under various curing conditions. Different percentages (5, 8, 10, 15, 20%) of the supplementary materials were mixed in binary and ternary combinations to determine the optimal dosage for high-performance concrete. The fresh and hardened properties of the concrete were evaluated using various tests, including slump, compressive strength, rapid chloride ion permeability, porosity, and drying shrinkage tests. The prepared concrete specimens were tested using various concentrations of binder replacement in binary, ternary, and quaternary combinations. The results showed that incorporating quartz filler as a partial replacement of cement up to 8% yielded positive results regarding mechanical properties. However, all mixtures containing different dosages of SF, QF, FA, and LSP demonstrated significant improvement in durability-related properties under normal and high-temperature curing conditions. Interestingly, the porosity of mixtures incorporating fly ash and LSP showed a slight increase compared to identical specimens under normal curing conditions. Moreover, the drying shrinkage behavior of ultrafine fillers (QF, SF, LSP, FA) indicated that their incorporation led to an increase in the shrinkage of high-performance mixtures under normal and high-temperature curing conditions. Binary and ternary blends incorporating QF, LSP, and SF showed an increase of around 5–8% in shrinkage under high-temperature curing compared to identical specimens under normal curing conditions. Therefore, it can be concluded that QF, LSP, SF, and FA can be efficiently used to produce high-performance cementitious composites, leading to sustainable concrete material.

Understanding the changes in engineering behaviors and microstructure of FA-GBFS based geopolymer paste with addition of silica fume

Geopolymers are attracting attention as a new green cementitious material. However, the severe early drying shrinkage deformation of geopolymers limits the use of geopolymer materials in construction projects. Therefore, this study investigates the effect of silica fume (SF) on the drying shrinkage behavior of geopolymer composite. Fly ash (FA) and granulated blast furnace slag (GBFS) were activated by a combination of sodium hydroxide and water glass solutions to produce geopolymer paste. The modification mechanism of SF content on the drying shrinkage and mechanical properties of FA-GBFS geopolymer paste was studied, as well as the important effect of SF on the internal geopolymerization process of geopolymer composite. The results indicate that the SF changes the binding energy and relative content of Si–O-T (T: Si or Al) structure and tetrahedral coordinated Al–OH bond in FA-GBFS geopolymer composite, delaying the early geopolymerization and calcium silicate hydration reaction in the geopolymer. It diminishes the polymerization degree of gel structure in the geopolymer, which also lowers the early strength of the geopolymer paste. In addition, when the SF content reaches 20%, it not only improves the 28d compressive strength of FA-GBFS geopolymer, but also greatly reduces the relative content of harmful pores inside the geopolymer, which reduces the early drying shrinkage strain by about 50%.

Drying shrinkage behavior of cement mortar under low vacuum conditions

In this work, the time-dependent drying shrinkage behaviors of cement mortar under low vacuum and standard drying conditions were tested and compared, in which the specimens were prepared based on various mixtures. Also, a series of microscopic tests were conducted to investigate the hydration and microstructure of the prepared specimens, and thus, to explain the drying shrinkage behavior of different specimens. The results showed that compared with standard drying condition, the specimens under the low vacuum condition exhibited higher drying shrinkage and mass loss, but lower sensitivity of drying shrinkage to mass loss. Under both conditions, the incorporation of fly ash and silica fume or shrinkage-reducing agent could greatly decrease the drying shrinkage, with the better performance identified in the case of fly ash and shrinkage-reducing agent; while the addition of sulphoaluminate cement had no inhibiting effect on the drying shrinkage deformation. Although the specimen solely based on sulphoaluminate cement showed the lowest drying shrinkage under standard drying condition, it exhibited greater drying shrinkage than the Portland cement specimens under low vacuum conditions. The microscopic test results suggested that low vacuum treatment could decrease the hydration degree while the decomposition of ettringite in the sulphoaluminate cement could be observed under low vacuum conditions. Besides, the gel pore volume fractions decreased while the cumulative total pore volume increased after low vacuum treatment, which resulted in a loose and porous microstructure with high vulnerability to drying shrinkage.

Drying shrinkage behavior of geopolymer mortar based on kaolinitic coal gangue

The coal industry generated tons of waste over the years of mineral extraction, and the waste disposal leads to soil and air pollution caused by acid mine drainage and spontaneous combustion. Seeking environmental sustainability, this paper investigated the valorization of coal tailings as a primary precursor in geopolymer mortar. The effect of Portland cement as a hardened admixture was evaluated on the mechanical and physical properties of geopolymer mortar, by replacing the coal tailings with a lower amount of Portland cement. Six mortars were characterized by several standard tests besides ultrasonic pulse velocity, mercury porosimetry (MIP), and drying shrinkage, the microstructure was evaluated by SEM/EDS analysis and X-Ray diffraction. The workability was slightly higher for geopolymer mortars with calcium by almost 5%, and the addition of sugarcane molasses and flue gas desulfurization increased the fluidity, reaching 220 mm. The Portland cement improved the early strength of geopolymer mortar by almost 10 MPa at 7 days, due to the acceleration of chemical reaction yielding a denser and heterogeneous matrix. The SEM/EDS analysis evidenced the co-existence of the polymeric matrix and C-A-S-H gel. The compressive strength at 28 days was higher than 20 MPa for all geopolymer mortars. A higher reaction rate provided by calcium addition leads to higher densification of the aluminosilicate matrix at early ages. The ultrasonic pulse velocity (UPV) confirmed denser matrix formation, and the geopolymer with 05 wt% of Portland cement presented UPV of 2700 m/s at 07 days, while the non-calcium geopolymer showed 2000 m/s. The denser matrix formed limited the water loss, decreased the open porosity, and improved the stiffness of geopolymer mortars, yielding a drying shrinkage almost 50% lower than for geopolymer without calcium addition. Finally, this paper established the lower replacement (5 wt%) of coal tailings for Portland cement produced efficient geopolymer mortar, with excellent physical and mechanical properties for in situ application without a thermal cure.

Application of Fractal to Evaluate the Drying Shrinkage Behavior of Soil Composites from Recycled Waste Clay Brick

Soil drying cracking is the most common natural phenomenon affecting soil stability. Due to the complexity of the geometric shapes of soil cracks during the cracking process, it has become a major problem in engineering science. The extremely irregular and complex crack networks formed in civil engineering materials can be quantitatively investigated using fractal theory. In this paper, fractal dimension is proposed to characterize the drying cracking characteristics of composite soil by adding recycled waste brick micro-powder. At the same time, the concept of the probability entropy of cracking is introduced to quantify the ordered state of crack development. Correspondingly, the endpoint value of probability entropy was solved mathematically, and the meaning of the probability entropy of cracking was clarified. In this study, the fracture fractal characteristics of composite soil mixed with different materials were first investigated. Then, five groups of composite soil-saturated muds with added recycled waste brick micro-powder of different contents were prepared in the laboratory. Using the evaporation test under constant temperature and humidity, the change rules of the fractal dimensions, probability entropy, crack ratios, and water contents of cracks during the cracking process of the soil samples were obtained. The results show that: (1) on the whole, the fractal dimensions of the soil samples added with recycled waste brick micro-powder of different contents increased over time, and the fractal dimensions of the soil samples without recycled waste brick micro-powder were obviously larger than those of the soil samples with recycled waste brick micro-powder. With the increase in the content of recycled waste brick micro-powder, the maximum fractal dimension decreased in turn. The maximum fractal dimensions of the five groups of soil samples were 1.74, 1.68, 1.62, 1.57, and 1.45. (2) The change trends of the probability entropy and fractal dimensions were similar; both of them showed an upward trend over time, and the probability entropy of the soil samples without recycled waste brick micro-powder was greater than that of the soil samples with recycled waste brick micro-powder. With the increase in the contents of recycled waste brick micro-powder, the probability entropy decreased in turn. The maximum values of the crack probability entropy of the five groups of soil samples were 0.99, 0.92, 0.87, 0.83, and 0.80. (3) Under the action of continuous evaporation, the moisture contents of the soil samples gradually decreased over time, while the crack ratios increased over time. To sum up, both from the perspective of the development process of the cracks of the soil samples and from the perspective of the final stable crack networks of the soil samples, the geometric shapes of the cracks of the soil samples without recycled waste brick micro-powder were the most complex. With the increase in the content of recycled waste brick micro-powder, the fractal characteristics of the cracks gradually changed from complex to simple.