Gas Droplet Research Articles

Evaporation characteristics of single free-falling liquefied natural gas droplet under different ambient conditions based on the VOF method

The evaporation characteristics of droplets is a fundamental issue for accurate depictions of moving liquefied natural gas (LNG) droplets and constantly changing ambient environment owing to intense heat, mass transfer, and momentum exchanges. In this study, a modified droplet evaporation model is developed to investigate the evaporation behavior of a single free-falling LNG droplet under various ambient conditions. The proposed model captures the droplet interface and calculates the mass transfer rate through the vapor concentration gradient using the volume of fluid method integrated with a smooth function. Evaporation experiments were conducted on a single free-falling LNG droplet to capture the evaporation process. The results indicate that it is acceptable to ignore the effect of the Stefan flow of a single free-falling LNG droplet. This study also examined the impact of different ambient conditions on evaporation characteristics. The results indicate that the evolution of the droplet diameter is mainly influenced by the ambient temperature because it affects the thermal properties of the surrounding gas and the distribution of the boundary layer. The temporal characteristics of the Nu and Sh numbers generally stabilize after a period of rapid decline. This study provides a theoretical basis for understanding the evaporation mechanisms of LNG droplets.

Experimental and numerical studies of the processes of spraying coal-water slurries with pneumatic nozzle

The article presents the results of spraying tests of highly viscous coal-water slurries with a pneumatic nozzle and numerical studies of the structure of the gas-drop jet. An increase in the viscosity of coal-water slurries was ensured by introducing a third component into its composition – industrial waste (pyrogenetic liquid). The moderate effect of the slurry viscosity on the average droplet size of coal-water slurries in the jet is due to the high efficiency of the aerodynamic characteristics of the pneumatic nozzle. Introduction of pyrogenetic liquid in the amount of 20 % by weight into the composition of coal-water slurry significantly increases its viscosity. The value of the surface tension of such a slurry is more than doubled. The increase in the average droplet size was no more than 25 % when pyrogenetic liquid content in the composition of coal-water slurry was over 10 % by weight. The average droplet size of coal-water slurries varied in the range from 180 to 210 microns in the study area of gas droplet jet. The results of experimental and numerical studies have shown good convergence. High air velocities at short distances from the nozzle ensure high crushing efficiency of the jet of coal-water slurry. The breakdown of the boundary layer of the liquid from the periphery of the droplets of coal-water slurries and its subsequent destruction was observed at short distances from the nozzle. The values of the Weber number were 100<We<350. At considerable distances from the nozzle (more than 0.5 m), droplets of coal-water slurries were subjected to vibrational crushing (We<50).

Quantum liquid in lower dimensions: From the perspective of surface tension

We analyze the surface tension in ultra-cold atomic gases in a quasi one-dimensional and one-dimensional geometry. In recent years, experimental observations have confirmed the “clustering of atoms” to form droplets in ultra-cold atomic gases and the emergence of this new phase is attributed to the beyond mean-field interaction. However, two decades earlier, liquid formation was predicted due to the competition of two-body and three-body interactions. Here, we review both propositions and comment on the role of beyond mean-field and three-body interaction in liquid formation by calculating the surface tension.

Multi-scale numerical analysis of Ca-based desulfurizer dynamics characteristics and SO2 absorption processes in industrial-scale SDA-FGD reactor

Spray dry absorption flue gas desulfurization technology is widely employed to control sulfur dioxide emissions from industrial pollutant gases. This study employs the multiphase particle-in-cell method to numerically simulate gas–solid heat transfer, SO2 removal processes, and the effect of operating conditions in the SDA reactor. The flue gas desulfurization model used has been experimentally validated. The results indicate that flue gas and slurry droplets exhibit swirling flow along the reactor walls, forming gas vortices at the top and near the outlet. The temperature and Reynolds number of slurry droplets show minimal variation when particle size is below 43 μm. The heat transfer coefficient of slurry droplets is notably higher at the reactor top and increases with the slip velocity of the droplets. Furthermore, the CaSO3 volume fraction increases with longer residence times of the slurry droplets in the reactor. When the height and diameter of the main reaction area are lower than 14 m and 8.5 m, respectively, the SO2 mass fraction in the central area undergoes significant changes. The SO2 inlet concentration is negatively correlated with desulfurization efficiency, whereas the slurry injection speed, along with the diameter and height of the main reaction region, are positively correlated with desulfurization efficiency. Among these factors, the SO2 inlet concentration and the height of the main reaction region have the most substantial impact on desulfurization efficiency.

Dynamic evaporation characteristics of liquefied natural gas droplets

To delve into the intricate evaporation and dispersion mechanisms of dense droplets formed in the vicinity of liquefied natural gas (LNG) accidental releases, it is imperative to first examine the evaporation dynamics of individual moving LNG droplets. This paper presents a visual experimental setup designed to scrutinize the temporal evolution of diameter and displacement of single free-falling LNG droplets. Additionally, eight typical drag force models used for droplet motion state calculations were assessed. The optimal drag force models were selected to accurately predict the displacement of LNG droplets in the wide range of 100 &amp;lt; Re &amp;lt; 10 000. Moreover, eight typical gas phase models applied to predict heat and mass transfer were evaluated, revealing that none accurately capture the dynamic evaporation of free-falling LNG droplets. Subsequently, a new gas phase model suitable for predicting LNG droplet evaporation behavior is proposed. Furthermore, the periodic oscillation behavior of LNG droplet shape during the falling process is uncovered. The oscillation amplitude and dominant frequency of droplets are quantitatively investigated using the aspect ratio of droplets. Finally, an in-house program is developed to comprehensively analyze the evaporation characteristics of LNG droplets under different initial droplet diameters, velocities, and ambient temperatures. Based on gray relational analysis, the relative importance of three impacting factors on the evaporation coefficient is ranked.

Measurement report: Cloud and environmental properties associated with aggregated shallow marine cumulus and cumulus congestus

Abstract. Mesoscale organization of marine convective clouds into linear or clustered states is prevalent across the tropical and subtropical oceans, and its investigation served as a guiding focus for a series of process study flights conducted as part of the Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment (ACTIVATE) during summer 2020, 2021, and 2022. These select ACTIVATE flights involved a novel strategy for coordinating two aircraft, with respective remote sensing and in situ sampling payloads, to probe regions of organized shallow convection for several hours. The main purpose of this measurement report is to summarize the aircraft sampling approach, describe the characteristics and evolution of the cases, and provide an overview of the datasets that can serve as a starting point for more detailed modeling and analysis studies. Six flights are described, involving a total of 80 dropsonde profiles that capture the environment surrounding clustered shallow convection. The flights include detailed observations of the vertical structure of cloud systems, comprising up to 20 in situ sampling levels. Four cases involved deepening convection rooted in the marine boundary layer that developed vertically to 2–5 km with varying precipitation amounts, while two cases captured more complex and developed cumulus congestus systems extending above 5 km. In addition to the thermodynamic and dynamic characterization afforded by dropsonde and in situ measurements, the datasets include cloud and aerosol microphysics, trace gas concentrations, aerosol and droplet composition, and cloud and aerosol remote sensing from high-spectral-resolution lidar and polarimetry.

Three-dimensional isotropic droplets in Rydberg-dressed Bose gases

We predict a scheme for the creation of isotropic three-dimensional quantum droplets in Rydbeg-dressed Bose gases, which contain both repulsive contact interactions and attractive soft-core interactions. Via manipulating laser detuning, the droplet size and particle number density could be engineered. Quantum fluctuation induced Lee-Huang-Yang (LHY) correction should be considered to stabilize droplets when LHY energy is comparable to the mean-field energy. Self-trapped droplets possess flat-top density distribution for a large particle number, and the collective excitations are calculated to determine the self-evaporation threshold. We further distinguish quantum droplets from solitons according to condensate compressibility. Finally, the dynamic stability of droplets is examined by pairwise-droplet collision. Our system could realize the most dilute quantum droplets, and establish a promising platform for further simulating topological nontrivial droplets. Published by the American Physical Society 2024

Interaction of Acoustic Waves with a Layer of Multifractional Polydispersed Vapor–Gas–Droplet Mixture with Account of Phase Transitions

Interaction of Acoustic Waves with a Layer of Multifractional Polydispersed Vapor–Gas–Droplet Mixture with Account of Phase Transitions

Membrane supported liquid-liquid oxygenation for use in extracorporeal life support – Proof of principle

Chronic respiratory diseases are the third most frequent cause of death worldwide. However, the limited availability of transplantable organs led to an increased research effort in artificial lung systems. Current artificial lung systems use hollow fibre membrane-based oxygenators. Historic oxygenators using a direct liquid-gas or liquid-liquid interface outperformed todays hollow-fibre technology in terms of gas-transfer. However, these approaches were no longer pursued due to risk of embolization by gas or liquid droplet formation in the blood stream. The herein presented approach of a membrane-supported liquid-liquid oxygenator combines todays hollow-fibre technology with historic liquid-liquid approaches to achieve a stable interface without the risk of embolization but with the advantages of a higher gas-transfer and a decreasing foreign membrane surface of the oxygenator. Perfluoro-n-hexane was chosen as a hemocompatible carrier fluid for the presented liquid-liquid approach. In the proof-of-principle oxygenator, O2 and CO2 gas-transfers were measured to be 1.83 mmolO2 and 1.34 mmolCO2, respectively. No Perfluoro-n-hexane droplets were detected in the blood after the experiment. This study demonstrates the proof of principle of a new membrane-supported liquid-liquid oxygenator.

A lattice Boltzmann model for incompressible gas and liquid two-phase flows combined with free-surface method

A novel lattice Boltzmann (LB) model is proposed to study the gas and liquid two-phase flows with large density and viscosity ratios. In the model, both the gas and liquid phases are considered as viscous incompressible fluids, which are governed separately by the two-relaxation-time LB equations. They are coupled by a momentum exchange method at the interface. The interaction between the gas and liquid phases is explicitly described and naturally involved in the model. The interfacial conditions in the model are validated by the benchmarks of the layered Poiseuille flow and the Laplace law. The feasibility of combining this model with the bubble model and the wetting scheme is proven through transient flow problems of single bubble rising and capillary intrusion. The validity of this model is confirmed by more complex flows including solid–liquid–gas coupling and droplet breaking problems by simulating shearing a droplet on a substrate and a droplet falling on a liquid film. The results demonstrate that the present model can be used to describe both the gas and the liquid flows. This work provides a solution to model the simulation of the dynamical behaviors of multi-phase flows.

Effect of impinging behavior annular jet shielding gas and printing substrate on metal droplet stable ejection

Using coaxial shielding gas for low-oxygen protection in metal droplet-based 3D printing helps to promote flexible production and lightweight manufacturing. However, the presence of the printing substrate causes the shielding gas to exhibit complex annular impinging jet characteristics, making the stability of droplet ejection unpredictable. In the present work, the mechanisms of airflow pattern evolution on droplet formation and metal jet deflection were first revealed by incorporating shielding gas simulations, hydrodynamic modeling, and droplet ejection experiments. An innovative airflow disturbance suppression strategy for metal droplet ejection was proposed, which can remarkably reduce the shielding gas disturbance on droplet printing. Results show that the change in deposition distance leads to a transition between two typical airflow patterns, thus affecting the droplet ejection behavior. When the deposition distance exceeds 2.5 mm, metal jets would be stretched even to a secondary break under airflow pattern 1, accelerating droplets. For the deposition distance below 2.5 mm, metal jet shortening and droplet deceleration would occur under airflow pattern 2, deflecting jet trajectory. The negative airflow effect on droplet ejection could be avoided by controlling the deposition distance to the transition region of two airflow patterns. Furthermore, a ball grid array (BGA) chip ball-mounting and two thin-wall tube printing were realized based on metal droplet ejection in annular impinging jet shielding gas. This work provides theoretical and technical guidance for the stable ejection and accurate printing of metal droplets in an opening low-oxygen environment.

Synthesis of granulated Li1.33Mn1.67O4via two antisolvent methods for lithium adsorption from gas-produced water

Gas produced water is an accompanying wastewater in the natural gas extraction process, and it’s a potential liquid lithium resource contains a considerable amount of lithium. This paper investigated the feasibility of using manganese-based ion sieves to adsorb and extract lithium from gas produced water. And we focused on the applicability of two different granulation methods and extrusion and droplet in gas produced water systems. Two types of H1.33Mn1.67O4 particles were prepared by extrusion method (EHMO), and by droplet method (DHMO). The porosity of DHMO was much higher than that of EHMO, and the adsorption performance of DHMO increased with the decrease of binder concentration. DHMO prepared with binder concentration of 0.14 g·ml−1 exhibited the best adsorption performance in gas produced water, and the Li+ adsorption capacity could reach 25.14 mg·g−1. In gas produced water, the adsorption equilibrium of DHMO only took 9 hours, and the adsorption process conformed to the Langmuir model and pseudo-second-order kinetic model. The pore diffusion model (PDM) could well describe its adsorption process. Besides, DHMO showed a great selectivity to Li+, and the selectivity order of DHMO in gas produced water was Li+>Ba2+>>Mg2+, Ca2+, Sr2+>>Na+>>K+, and after 20 cycles, the Li+ adsorption capacity was still higher than 17.30 mg·g−1, and the rate of manganese dissolution was less than 1%.

Experimental study on the freezing process of water droplets for ice air jet technology

Ice air jet technology is one non-destructive, residue-free and environmentally friendly machining process. It is an efficient method to form ice particles by atomizing water droplets in ultra-low temperature environment. The freezing characteristics of water droplets in cryogenic gas and liquid nitrogen environment are visually analyzed, and the effects of droplet volume, ambient temperature are also studied. The results show that when water droplets freeze in a cryogenic gas environment, four distinct stages are observed, namely pre-cooling stage, recalescence stage, solidification stage, and deep cooling stage. However, when water droplets freeze in liquid nitrogen, the recalescence stage cannot be observed. For a 5 µl water droplet, it takes 68 s for water droplets to freeze into ice particles at − 20.36 °C, while it takes only 1.7 s in liquid nitrogen. During the freezing process, the water droplets form an ice shell outside and freeze inwardly. Ice particles may break up due to differences in solubility and density. With the increase of volume the time spent on pre-cooling stage and freezing stage both increases. For the large latent heat of water phase transformation, the solidification stage time is greatly affected by the volume of water droplets. When the ambient temperature drops from − 10.67 °C to − 24.68 °C, the freezing time of 5 µl water droplets decreases by 45.5%, indicating that the ambient temperature has a great influence on the freezing time. The results of the study can significantly contribute to the development of ice air jet technology.

Characteristics of granule solidification in gas atomization of molten beryllium

Experimental and analytical studies on gas atomization of the molten beryllium and the production of beryllium granules are presented. The impact of various factors, including the choice of gas (nitrogen or helium), the cooling gas flow rate (ranging from 300 to 650 m/s), melt temperature, and droplet size (&lt;500 µm), on the cooling rate and granule properties, is demonstrated. It has been determined that the solidification of beryllium granules can occur through two distinct mechanisms depending on the atomization process. These mechanisms include crystallization and amorphization (glass transition). When beryllium melt is atomized with nitrogen, granules with diameters less than 100 µm solidify via the amorphization mechanism (glass transition), while those with diameters exceeding 300 µm solidify through crystallization. In such cases, a portion of granules with sizes ranging from 100 to 300 µm undergoes a mixed mechanism solidification. In this process, the surface becomes amorphous, while the central part crystallizes, resulting in the formation of a “shell” on the surface, marking the transition from the glass transition mechanism to the crystallization mechanism. The thickness of this “shell” depends on the granule diameter, measuring 10–15 µm for 300 µm granules and 20–25 µm for 100 µm granules. The findings from this research align well with the hypothesis of a glass-crystalline mechanism of beryllium granule solidification, which leads to their separation at the interfacial boundary. Such solidification through a mixed mechanism results in the creation of a removable “crust” on the granule, which is typically more contaminated with impurities. Understanding this effect opens up possibilities for practical applications in the production of specialized materials from beryllium. The ability to separate the “crust” from the “core” provides the conditions for obtaining specialized sintered beryllium grades suitable for use in nuclear reactors and foil production, where a beryllium microstructure with “clean” boundaries is essential.

Formation of a Spray of Conducting Liquid under High Voltage and Electrical Discharge Plasma

The joint impact of an electrical discharge and a gas–droplet flow of a conducting liquid created by a centrifugal nozzle is studied. In the experiment, the electrical parameters of the discharge are recorded, and the local characteristics of the spray, namely, the droplet diameter distributions of the number of droplets and the components of their velocity vector are measured. The measurements are carried out using double shadow microphotography. The effect of a spray of a conducting liquid on the time-averaged electrical parameters of the discharge, as well as changes in the properties of the spray under the influence of high voltage and current, are studied. Additionally, the spray characteristics are measured when a high voltage of pre-breakdown value is applied. High-speed photography of a discharge in the presence of droplets of conducting liquid is carried out.

Particle coating growth behaviors in a spray fluidized bed based on Gas-Liquid-Solid Quasi-Three-phase DEM numerical simulation

Wet granulation processes are widely used in chemical, food, pharmaceutical, and various other industrial processes. During the process of particle coating growth, particle fluidization state and liquid characteristics have an impact on the layer's thickness and homogeneity. In this study, discrete element, liquid bridge, and droplet motion models were combined to investigate the impact of injection gas velocity, droplet diameter and injection liquid viscosity on the particle growth ratio and coating thickness distribution, and the particle growth mechanism was investigated. The particle growth area, which is the area where the number of coated particles exceeds 0, was significantly expanded by decreasing the droplet diameter and increasing the gas velocity at appropriate ranges. The frequency of droplet and particle collisions increased, and average relative liquid content decreased with increasing particle growth area. By accelerating the injection of gas and reducing the viscosity of the injected liquid, the fluidization condition of the particles, which primarily affected the particle cycle frequency, could be enhanced. The improvement of particle growth area and particle cycle frequency allowed more particles to participate in growth and improved the quality of the grown particles. The proportion of small particles dramatically grew while the proportion of large particles reduced. The standard deviation of particle diameter decreased, and particle growth became more uniform.

Wetting Behavior of CO2 Droplets on Smooth Solid Surface: Molecular Simulation Perspective

The wettability of droplets on solid surfaces is important for accurately revealing the microscopic mechanisms of gas condensation nucleation and droplet growth. During the contact condensation of CO2 gas on the heat exchanger surface in the pressurized liquefied natural gas technology, the wettability of CO2 droplets on the heat exchanger surface directly affects the heat transfer thermal resistance of the heat exchanger, which then affects the heat transfer efficiency of methane and ethane in the heat exchanger. Therefore, molecular dynamics simulations were used to study the spreading process and wetting patterns of nanoscale CO2 droplets on different energy surfaces. The results show that as the potential well depth ε of the wall atoms increases, the intensity of the solid-liquid interaction increases and the corresponding surface energy increases accordingly, showing different droplet spreading rates and wetting characteristics. Unlike the interfacial characteristics of macroscopic droplets, there are significant fluctuations at the gas-liquid interface of droplets on the molecular scale, but microdroplets can still form a specific contact angle after spreading on different energy surfaces in a statistical sense, and this contact angle decreases with increasing intensity of solid-liquid interaction. The low-energy surface at potential well depths ε less than 266 J·mol-1 exhibits a CO2-phobicity, and the surface becomes CO2-philic as the potential well depth continues to increase. The trend of the contact angle of CO2 droplets affected by temperature is the same as that of the center-of-mass height, which characterizes the spreading morphology of CO2 droplets. As the temperature increases, the contact angle decreases due to the further spreading and wetting of droplets on different energy surfaces. As the CO2-philicity of the surface gets higher, the contact angle decreases to a greater extent.

Gas–droplet–liquid transitions and fluctuations in soft nano-confinement

One permanent characteristic of the thermodynamics of small systems is environment-dependence, also known as ensemble-dependence. Fluid molecules in soft (deformable) nano-confinement offer a special ensemble that acts as a bridge between classical isobaric (NPT) and isochoric (NVT) ensembles. Here, we discuss the gas–liquid transition taking place in a soft nano-confinement where the cell volume is not fixed but changes when the system pressure is changed. The free energy of the system is calculated as a function of the size of the liquid droplet that appears in the gas phase. We discuss how the phase behavior changes when the condition of the confinement changes from rigid confinement to very soft confinement. For the simple fluid model studied, the coexistence and critical phase behaviors are found to be uniquely determined by αK (αK is the dimensionless elasticity constant of the wall of confined space and is proportional to its ability to resist deformation), and the confinement with moderate softness exhibits richer phase behavior. We then study the fluctuations of pressure, volume, and droplet size for fluid in soft confined spaces, which is again closely related to the wall softness. Under moderate softness, large fluctuations in both fluid pressure and volume are seen in the transition region where fluid pressure increases with volume expansion, accompanied by the strengthened fluctuation of droplet size.

An Inexpensive, Portable Shield to Improve Healthcare Worker Safety During Intubation Procedures.

Healthcare workers (HCW) are exposed to risk of infection during intubation procedures, in particular, in the prehospital setting. Here, we demonstrate a novel shield that can be used during intubation to block aerosols and droplets from reaching the HCW. The device is mounted on the patient's head and provides a barrier between patient and HCW. It incorporates a self-sealing port through which an endotracheal tube can be inserted. The port "floats" in the plane of the shield to facilitate maneuvering of the endotracheal tube. The shield is fabricated from transparent materials to enable the HCW to visualize the procedure. Using two complementary imaging methods, background oriented Schlieren imaging and laser sheet droplet imaging, we show that the device prevents detectable transmission of gas flow and droplets through the shield both before and after endotracheal tube insertion.Clinical Relevance- This device has the potential to protect HCWs from infections during intubation procedures, especially in the prehospital setting.

Cooling-driven coagulation

ABSTRACT Astrophysical gases such as the interstellar-, circumgalactic-, or intracluster-medium are commonly multiphase, which poses the question of the structure of these systems. While there are many known processes leading to fragmentation of cold gas embedded in a (turbulent) hot medium, in this work, we focus on the reverse process: coagulation. This is often seen in wind-tunnel and shearing layer simulations, where cold gas fragments spontaneously coalesce. Using 2D and 3D hydrodynamical simulations, we find that sufficiently large (≫cstcool), perturbed cold gas clouds develop pulsations which ensure cold gas mass growth over an extended period of time (≫r/cs). This mass growth efficiently accelerates hot gas which in turn can entrain cold droplets, leading to coagulation. The attractive inverse square force between cold gas droplets has interesting parallels with gravity; the ‘monopole’ is surface area rather than mass. We develop a simple analytic model which reproduces our numerical findings.