Cities are key areas for carbon control and reduction. The study of the decoupling between CO2 emissions and gross domestic product (GDP) and the drivers of CO2 emissions in cities facilitates the reduction of CO2 emissions to safeguard the development of the economy. This paper first calculates the CO2 emissions in Tianjin, China, from 2005 to 2022, then uses the Tapio decoupling index to quantify the decoupling status, and, finally, explores the energy-CO2-emission drivers through the Logarithmic Mean Divisia Index (LMDI) model. The findings indicate that (1) the decrease in CO2 emissions from industrial products and transport is the main reason for the decline. (2) During the period under investigation, the predominant condition observed was a state of weak decoupling. (3) Given the economic-output effect is the primary and substantial driver of energy CO2 emissions, it is essential to harmonize the interplay between economic-development approach and CO2 emissions to foster sustainable development in Tianjin. The industrial structure plays the most critical role in hindering the reduction of CO2 emissions; therefore, optimizing industrial structure can help achieve carbon reduction and control targets. These findings enrich the study of CO2 emission factors and can also interest urban policymakers.
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