Doped Nanocrystalline Phosphors Research Articles

Synthesis and Structural Features of Tunable Emitting Single- Phased Eu3+/ Tb3+ Co- Doped LaAlO3 Nanophosphors

In the prevailing study, single- phased color- tunable La1-x-yEuxTbyAlO3 co- doped nanocrystalline phosphors have been synthesized via the most simplistic and low cost urea- aided solution combustion synthetic route. This was done by adjusting the doping concentration of Eu3+ (x = 0.01, 0.03, 0.05, 0.07 mol) and Tb3+ (y = 0.03 mol) ions in the LaAlO3 host lattice. The X- ray powder diffraction (XRD) and Rietveld refinement analysis confirmed the formation of single- phased La0.97-xAlO3: xEu3+/ 0.03Tb3+ (x = 0.07), co- doped nanophosphor at 800°C. The synthesized nanophosphors were crystallized in cubic crystal system having Pm3̄m space group with 221 space group number. The morphological studies i.e., field emission scanning electron microscopy (FE- SEM), and transmission electron microscope (TEM) images depicted the agglomerated clusters of distinct spherical shaped particles of La0.97-xAlO3: xEu3+/ 0.03Tb3+ in nano- regime. Energy dispersive X- ray analysis (EDAX) was employed to ascertain the real elemental mapping of the fabricated phosphors. Through diffuse reflectance (DR) spectroscopy measurements, the optical band gap value for La0.92Eu0.05Tb0.03AlO3 nanocrystalline phosphor was determined to be 5.26 eV. The photoluminescent excitation (PLE) and photoluminescent emission (PL) spectra were studied in detail as a function of Eu3+ ion contents and La1-x-0.03AlO3: xEu3+/ 0.03Tb3+ (x = 0.05 mol) co- doped sample exhibits strongest emission and over the 0.05 Eu3+ ions doping concentration, the emission intensity falls as a consequence of the quenching phenomenon. The concentration quenching in directed co- doped nanophosphors was attributed to the dipole - dipole interactions. With the exploitation of photoluminescent data, Commission International de I'Eclairage 1931 (CIE) color coordinates (x, y) of co- doped samples have been calculated from the emission spectra, which revealed the color could be tuned i.e., from orange to red region in La0.97-xAlO3: xEu3+/ 0.03Tb3+ samples with divergences in the Eu3+ and other significant photometric assets viz. correlated color temperature (CCT), color purity (CP) of the synthesized La1-x-yAlO3: xEu3+, yTb3+ co- doped nanocrystalline photoluminescent materials were also determined. The studies outcomes suggested that Eu3+/ Tb3+ co- doped LaAlO3 phosphors have great potential as color- tunable luminescent material in solid- state lighting and display technologies.

Size dependent luminescence of nanocrystalline Y2O3:Eu and connection to temperature stimulus

In the emission spectra of nanocrystalline Y2O3:Eu with decreasing the particle size, the 5D0–7F0 transition of Eu3+ shifts towards blue. This size effect is explained by lattice expansion of the nanocrystallines, more precisely, by larger Eu–O distance. Meanwhile, increasing temperature also expands the lattice constant and shifts the emission peak to blue. Then nephelauxetic effect is employed to organize the size effect and temperature dependence. It is also introduced to indicate the change of Eu3+ coordination number in the nanosized phosphor. Based on the experimental results, possible applications of temperature sensing and stress mapping with Eu3+ doped nanocrystalline phosphors are proposed.

Rare-Earth Doped Nanocrystalline Phosphors for Field Emission Displays

The cathodoluminescence properties of rare-earth (RE = Ce, Eu, Tb) doped nanocrystalline phosphors (Y2O3,Y3Al5O12) were investigated. Their structure and morphology were determined and correlated with optical properties. The effect of grain sizes on emission yield of RE doped nanophosphors has been investigated. A possibility of application of RE doped nanophosphors for efficient field emission display (FED) devices has been discussed.