The SW-NE directed wide-angle reflection-refraction (WARR) SHIELD’21 profile crosses entire width of Ukraine. It targeted the structure of the crust and uppermost mantle in the southwestern part of the East European Craton (EEC), between Carpathians and Voronezh Massif, across Ukrainian Shield and Dnieper-Donets Basin. The ∼660 km-long profile is an extension of the RomUkrSeis profile in Romania and Ukraine. SHIELD’21 experiment, using TEXAN and DATA-CUBE short-period seismic stations, provided high-quality seismic sections from 10 shot points. This allowed construction of a ray-tracing P-wave velocity model, supplemented by Vp/Vs ratio, for the upper part of the lithosphere in the Sarmatia segment of the EEC and constraining geodynamic processes that led to the formation of the Ukrainian Shield and its margins since Archean times.The velocity distribution in the crystalline crust indicates a rather uniform structure, with velocity changing from 6.0 km/s near the surface to 6.8 km/s at the Moho. The entire section shows the lack of a high-velocity lower crust (Vp > 6.8 km/s), presumably resulting from delamination of the primitive mafic lower crust during early evolution of a juvenile continental crust. The seismic boundaries in the upper crust reflect a Paleoproterozoic extensional detachment system below the SW flank of Dnieper-Donets rift basin, initiated in the Devonian. At larger depths, a wide dome of the lower crust with velocities of 6.5–6.8 km/s in the SW-central segment of the profile, probably represents an enormous Palaeoproterozoic(?) granitoid batholith. In the southwesternmost part of the profile, the crystalline crust shows exclusively low velocities. The prominent Moho is undulating and varies in depth between 32 and 50 km. It is underlain by high-velocity bodies (Vp: 8.36–8.40 km/s), against the background of 8.16–8.25 km/s in the mantle. The velocity model corresponds with the anomalies of potential fields and zones of high electric conductivity.
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