Recent trends in portfolio management emphasize the importance of reducing carbon footprints and aligning investments with sustainable practices. This paper introduces SensitivityVaR (SensitivityVaR), an advanced distortion risk measure that combines Value-at-Risk (VaR) and Expected Shortfall (ES) with the Cornish–Fisher expansion. SensitivityVaR provides a more robust framework for managing risk, particularly under extreme market conditions. By incorporating first- and second-order distorted stochastic dominance criteria, we enhance portfolio decarbonization strategies, aligning financial objectives with environmental targets such as the Paris Agreement’s goal of a 7% annual reduction in carbon intensity from 2019 to 2050. Our empirical analysis evaluates the impact of integrating carbon intensity data—including Scope 1, Scope 2, and Scope 3 emissions—on portfolio optimization, focusing on key sectors like technology, energy, and consumer goods. The results demonstrate the effectiveness of SensitivityVaR in managing both risk and environmental impact. The methodology led to significant reductions in carbon intensity across different portfolio configurations, while preserving competitive risk-adjusted returns. By optimizing tail risks and limiting exposure to carbon-intensive assets, this approach produced more balanced and efficient portfolios that aligned with both financial and sustainability goals. These findings offer valuable insights for institutional investors and asset managers aiming to integrate climate considerations into their investment strategies without compromising financial performance.