Distinct Regimes Research Articles

On the continuous nature of phase change in near-critical carbon dioxide

Unique boiling behavior at near-critical conditions can leverage the large heat transfer coefficients associated with flow boiling while mitigating some of the disadvantages encountered in two-phase flows, presenting opportunities for enhancing the stability and effectiveness of cooling systems. Contemporary understanding treats subcritical boiling and supercritical heat transfer as two distinct regimes, separated by the critical point. Recent studies investigating microchannel flow boiling near the critical point challenge this notion, suggesting a significant alteration in subcritical phase change heat transfer mechanisms, predominantly driven by variations in thermophysical properties near the critical point. However, a generalized understanding of heat transfer behavior and the phase change physics near the critical point is lacking. The current work presents a new perspective to elucidate underlying fluid phenomena associated with near-critical (0.85<PR<1.02) microscale (Dh=500μm) phase change over parameterized experimental conditions (G=100−1000kgm−2s−1; q″=2−100Wcm−2). Through high-speed (8000fps) side-view microscopic imaging and simultaneous heat transfer measurements, unique flow behavior was discovered at PR>0.95, including supercritical-like phenomena and evidence of homogeneous nucleation which form the physical basis for altered heat transfer behavior. The visualized flow physics and heat transfer behavior suggest a continuous transition from subcritical phase change to supercritical mechanisms near the critical point. As homogeneous nucleation becomes the dominant phase change mechanism, the near-wall heat transfer condition transitions from nucleate boiling to single-phase vapor convection. However, due to significant thermophysical property variations near the critical point, this single-phase convection condition exhibits fluid physics and heat transfer behavior virtually indistinguishable from supercritical conditions. These insights significantly disrupt the conventional understanding of a sharp transition in fluid behavior at the critical point. The gradual change in flow boiling mechanisms near the critical point presents opportunities for application-specific tuning of heat transfer performance through pressure variation alone.

Extreme risk spillovers between US and Chinese agricultural futures markets in crises: A dependence-switching copula-CoVaR model.

The linkages between the US and China, the world's two major agricultural powers, have brought great uncertainty to the global food markets. Inspired by these, this paper examines the extreme risk spillovers between US and Chinese agricultural futures markets during significant crises. We use a copula-conditional value at risk (CoVaR) model with Markov-switching regimes to capture the tail dependence in their pair markets. The study covers the period from January 2006 to December 2022 and identifies two distinct dependence regimes (stable and crisis periods). Moreover, we find significant and asymmetric upside/downside extreme risk spillovers between the US and Chinese markets, which are highly volatile in crises. Additionally, the impact of international capital flows (the financial channel) on risk spillovers is particularly pronounced during the global financial crisis. During the period of the COVID-19 pandemic and the Russia-Ukraine 2022 war, the impact of supply chain disruptions (the non-financial channel) is highlighted. Our findings provide a theoretical reference for monitoring the co-movements in agricultural futures markets and practical insights for managing investment portfolios and enhancing food market stability during crises.

Boosting the production of sterile neutrino dark matter with self-interactions

Sterile neutrinos are well-motivated and simple dark matter (DM) candidates. However, sterile neutrino DM produced through oscillations by the Dodelson-Widrow mechanism is excluded by current X-ray observations and bounds from structure formation. One minimal extension, that preserves the attractive features of this scenario, is self-interactions among sterile neutrinos. In this work, we analyze how sterile neutrino self-interactions mediated by a scalar affect the production of keV sterile neutrinos for a wide range of mediator masses. We find four distinct regimes of production characterized by different phenomena, including partial thermalization for low and intermediate masses and resonant production for heavier mediators. We show that significant new regions of parameter space become available which provide a target for future observations.

Experimental and numerical study of mixed convection heat transfer in a vented cavity partially filled with a porous medium: Effects of reynolds and rayleigh numbers on Nusselt number and flow regimes

This article presents a comprehensive investigation of mixed convection flow and heat transfer within a vented, partially side-heated cubical cavity, incorporating a porous medium with low-conductivity square-shaped inclusions. The study encompasses an extensive range of Rayleigh numbers (106 < Ra < 6 × 106) and Reynolds numbers (200 < Re < 4000) while maintaining a fixed Prandtl number of Pr = 0.71. This investigation spans over three decades in Richardson numbers (Ri = Ra/(Re2 Pr)), aiming to discern the interplay between the Nusselt number, Nu, and the Richardson number. Our understanding of Nusselt number dependencies is enhanced by combining PIV measurements of heat transfer and velocity fields with temperature field data. The study uses both experimental and numerical PIV data, incorporating porous media representation to reveal heat transfer scaling with both Reynolds and Rayleigh numbers. Computational Fluid Dynamics (CFD) methods are used to explore the complex physical behavior under different flow conditions. Three distinct flow and heat transfer regimes have been identified, predicated upon the Richardson number. For Ri < 25, the flow structure and Nusselt number exhibit similarities with pure forced convection, where the Nusselt number scales as Nu ∼ Re0.6, independent of the Rayleigh number. Conversely, for Ri > 70, natural convection dominates the vicinity of the heating wall, rendering the Nusselt number less sensitive to Reynolds number variations and predominantly dictated by the Rayleigh number. Notably, the intermediate regime, ranging from 25 < Ri < 70, witnesses a competition between upward-directed natural convection flow at the heating wall and downward-directed forced flow, culminating in a minimum effective Nusselt number.

Do natural resources rents reduce income inequality? A finite mixture of regressions approach

The World Bank report (2023) highlights that almost all types of natural capital, the global stock of resources and services provided by nature, are in decline while inequalities persist. Based on this context, the objective of this article is to analyze the effect of natural resources on income inequality in 73 developing countries over the period 2005–2020. Unlike previous works, this article examines the possibility that countries follow different inequality regimes and test the hypothesis that whether natural resources, reduce or increase income inequality depending on the inequality regime to which countries belong. We used a finite mixture regression model, and we found that our sample is best described by a model with five regimes of countries. The results show that the effect of natural resource rents on income inequality varies across five distinct regimes of countries. In regimes 1 and 2, natural resources have a positive effect on inequality, while in regimes 3 and 4, they have a negative effect on inequality. In regime 5, the effect is not significant. Furthermore, our analysis shows that countries that have low levels of political risk are likely to be in the regime where the dependence of natural resources decreases income inequality. These results clearly emphasize that for countries with abundant natural resources to fully benefit from reduced inequality, they must undertake strong reforms to reduce political risk. These reforms include improving the quality of the judicial system, intensifying the fight against corruption, and reducing investment risks.

Voltage waveform tailoring for high aspect ratio plasma etching of SiO2 using Ar/CF4/O2 mixtures: Consequences of low fundamental frequency biases

The use of non-sinusoidal waveforms in low pressure capacitively coupled plasmas intended for microelectronics fabrication has the goal of customizing ion and electron energy and angular distributions to the wafer. One such non-sinusoidal waveform uses the sum of consecutive harmonics of a fundamental sinusoidal frequency, f0, having a variable phase offset between the fundamental and even harmonics. In this paper, we discuss results from a computational investigation of the relation between ion energy and DC self-bias when varying the fundamental frequency f0 for capacitively coupled plasmas sustained in Ar/CF4/O2 and how those trends translate to a high aspect ratio etching of trenches in SiO2. The fundamental frequency, f0, was varied from 1 to 10 MHz and the relative phase from 0° to 180°. Two distinct regimes were identified. Average ion energy onto the wafer is strongly correlated with the DC self-bias at high f0, with there being a maximum at φ = 0° and minimum at φ = 180°. In the low frequency regime, this correlation is weak. Average ion energy onto the wafer is instead dominated by dynamic transients in the applied voltage waveforms, with a maximum at φ = 180° and minimum at φ = 0°. The trends in ion energy translate to etch properties. In both, the high and low frequency regimes, higher ion energies translate to higher etch rates and generally preferable final features, though behaving differently with phase angle.

Effects of the applied fields' strength on the plasma behavior and processes in E × B plasma discharges of various propellants. II. Magnetic field

The effects of magnetic field intensity on the properties of the plasma discharge and on the underlying phenomena are studied for different propellants' ion mass. The plasma setup represents a 2D radial–azimuthal configuration with perpendicular electric and magnetic fields. The electric field is along the axial direction, and the magnetic field is along the radial direction. The magnetic field intensity is changed from 5 to 30 mT, with 5 mT increments. The studied propellant gases are xenon, krypton, and argon. The simulations are carried out using a reduced-order particle-in-cell code. It is shown that, for all the propellants, the change in the magnetic field intensity yields two distinct plasma regimes, where either the modified two-stream instability (MTSI) or the electron cyclotron drift instability (ECDI) are dominant. A third plasma regime is also observed for cases with moderate values of the magnetic field (15 and 20 mT), where the ECDI and the MTSI co-exist with comparable amplitudes. This described variation of plasma regime becomes clearly reflected in the radial distribution of the axial electron current density and the electron temperature anisotropy. At the relatively low-magnetic-field intensities (5 and 10 mT), the MTSI is mitigated. At relatively high magnitudes of the magnetic field (25 and 30 mT), the MTSI becomes strongly present, a long-wavelength wave mode develops, and the ECDI becomes suppressed. An exception to this latter observation was noticed for xenon, for which the ECDI was observed to be detectable with a notable strength up to the magnetic field value of 25 mT.

Fire severity drives understory community dynamics and the recovery of culturally significant plants

AbstractAnthropogenic influences are altering fire regimes worldwide, resulting in an increase in the size and severity of wildfires. Simultaneously, throughout western North America, there is increasing recognition of the important role of Indigenous fire stewardship in shaping historical fire regimes and fire‐adapted ecosystems. However, there is limited understanding of how ecosystems are affected by or recover from contemporary “megafires,” particularly in terms of understory plant communities that are critical to both biodiversity and Indigenous cultures. To address this gap, our collaborative study, in partnership with Secwépemc First Nations, examined understory community recovery following a large, mixed‐severity wildfire that burned in the dry and mesic conifer forests of British Columbia, Canada, with a focus on plants of high cultural significance to Secwépemc communities. To measure the effect of a continuous gradient of fire severity across forest types, we conducted field assessments of fire severity and sampled understory plants 4 years postfire. We found that native species richness and richness of species of high cultural significance were lowest in areas that burned at high severity, with distinct compositional differences between unburned areas and those that burned at high severity. These findings were consistent across forest types characterized by distinct historical fire regimes. In contrast, richness of exotic species increased with increasing fire severity in the dominant montane interior Douglas‐fir forests, with exotic species closely associated with areas that burned at high severity. Our study indicates that recent megafires may be pushing ecosystems outside their historical range of variability, with negative implications for ecosystem recovery and cultural use across these fire‐affected landscapes. We also found consistently higher plant diversity, and both native and cultural species richness, in subalpine forests. Collectively, our results provide strong evidence of the ecological and cultural significance of low‐ to moderate‐severity fire and subalpine forests, and the longstanding and ongoing role of Indigenous peoples in shaping these landscapes. As wildfires continue to impact ecosystems and human communities, this study offers novel insights into the recovery of important ecological and cultural values, while highlighting the need to support ethical research collaborations with Indigenous communities and Indigenous‐led revitalization of fire and plant stewardship.

A numerical study of natural convection through a vertical heated channel with a confined circular cylinder

This study examines thermal flow structures and heat transfer through a vertical heated channel with an adiabatic circular cylinder symmetrically positioned between lateral walls. A two-dimensional numerical simulation is conducted covering a range of parameters including Rayleigh numbers Ra = 8.9 × 106–8.9 × 108, cylinder positions relative to the channel height h = 0–0.50, and blockage ratios (the ratio of cylinder diameter to channel width) β = 0.25–0.75. Three distinct flow regimes are observed at different Rayleigh numbers and blockage ratios, including steady symmetric, unsteady periodic, and unsteady asymmetric flow regimes. The steady symmetric and unsteady periodic flows are observed at all blockage ratios, while the unsteady asymmetric flow is only observed at the highest blockage ratio of β = 0.75 for Rayleigh numbers above 8.9 × 107. It is found that the presence of the cylinder significantly enhances mixing and turbulence in the channel, which in turn enhances heat transfer through the channel. A 64.3% enhancement of heat transfer is achieved at β = 0.50 and h = 0.05 for Ra = 8.9 × 108.

Intermittent random walks under stochastic resetting.

We analyze a one-dimensional intermittent random walk on an unbounded domain in the presence of stochastic resetting. In this process, the walker alternates between local intensive search, diffusion, and rapid ballistic relocations in which it does not react to the target. We demonstrate that Poissonian resetting leads to the existence of a non-equilibrium steady state. We calculate the distribution of the first arrival time to a target along with its mean and show the existence of an optimal reset rate. In particular, we prove that the initial condition of the walker, i.e., either starting diffusely or relocating, can significantly affect the long-time properties of the search process. Moreover, we demonstrate the presence of distinct parameter regimes for the global optimization of the mean first arrival time when ballistic and diffusive movements are in direct competition.

Unified and vector theory of Raman scattering in gas-filled hollow-core fiber across temporal regimes.

Raman scattering has found renewed interest owing to the development of gas-filled hollow-core fibers, which constitute a unique platform for exploration of novel ultrafast nonlinear phenomena beyond conventional solid-core-fiber and free-space systems. Much progress has been made through models for particular interaction regimes, which are delineated by the relation of the excitation pulse duration to the time scales of the Raman response. However, current experimental settings are not limited to one regime, prompting the need for tools spanning multiple regimes. Here, we present a theoretical framework that accomplishes this goal. The theory allows us to review recent progress with a fresh perspective, makes new connections between distinct temporal regimes of Raman scattering, and reveals new degrees of freedom for controlling Raman physics. Specific topics that are addressed include transient Raman gain, the interplay of electronic and Raman nonlinearities in short-pulse propagation, and interactions of short pulses mediated by phonon waves. The theoretical model also accommodates vector effects, which have been largely neglected in prior works on Raman scattering in gases. The polarization dependence of transient Raman gain and vector effects on pulse interactions via phonon waves is investigated with the model. Throughout this Perspective, theoretical results are compared to the results of realistic numerical simulations. The numerical code that implements the new theory is freely available. We hope that the unified theoretical framework and numerical tool described here will accelerate the exploration of new Raman-scattering phenomena and enable new applications.

Three-body encounters in black hole discs around a supermassive black hole

Context. Dynamical encounters of stellar-mass black holes (BHs) in a disc of compact objects around a supermassive BH (SMBH) can accelerate the formation and coalescence of BH binaries. It has been proposed that binary–single encounters among BHs in such discs can lead to an excess of highly eccentric BH mergers. However, previous studies have neglected how the disc velocity dispersion and the SMBH’s tidal field affect the three-body dynamics. Aims. We investigate the outcomes of binary–single encounters considering different values of the disc velocity dispersion, and examine the role of the SMBH’s tidal field. We then demonstrate how their inclusion affects the properties of merging BH binaries. Methods. We performed simulations of four-body encounters (i.e. with the SMBH as the fourth particle) using the highly accurate, regularised code TSUNAMI, which includes post-Newtonian corrections up to order 3.5PN. To isolate the effect of the SMBH’s tidal field, we compared these simulations with those of three-body encounters in isolation. Results. The disc velocity dispersion controls how orbits in the disc are aligned and circular, and determines the relative velocity of the binary–single pair before the encounter. As the velocity dispersion decreases, the eccentricity of post-encounter binaries transitions from thermal to superthermal, and binaries experience enhanced hardening. The transition between these two regimes happens at disc eccentricities and inclinations of order e ∼ i ∼ 10−4. These distinct regimes correspond to a disc dominated by random motions (e ∼ i ≳ 10−4) and one dominated by the Keplerian shear (e ∼ i ≲ 10−4). The effect of the SMBH’s tidal field depends on the velocity dispersion of the disc. When the velocity dispersion is low, the resulting binaries are less eccentric compared to isolated encounters. Conversely, binaries become less eccentric compared to isolated encounters at high velocity dispersion. This also affects the number of BH mergers. Conclusions. The inclusion of the SMBH’s tidal field and the disc velocity dispersion can significantly affect the number of GW mergers, and especially the number of highly eccentric inspirals. These can be up to ∼2 times higher at low velocity dispersion, and ∼12 times lower at high velocity dispersions. The spin–orbit alignment is influenced by the tidal field exclusively at high velocity dispersions, effectively inhibiting the formation of anti-aligned binary BHs. Nonetheless, encounters in random-motion-dominated discs around a SMBH are still more effective in producing GW mergers compared to those occurring in spherically symmetric nuclear star clusters without an SMBH.

Inflation-Economic Growth Nexus in Nigeria: New Evidence on Threshold Effects

Purpose: The aim of this study is to analyze the influence of inflation on the economic growth of Nigeria from 1990 to 2021. Specifically, it aims to identify a threshold, if it exists, at which the impact of inflation on economic growth begins to shift.&#x0D; Methodology: To assess the inflation threshold and its impact on economic growth, this study employed a novel method, the endogenous sample-splitting and threshold model developed by Hansen (2000).&#x0D; Findings: The study reveals a non-linear relationship between inflation and economic growth in Nigeria, with a single inflation threshold of 12.88%. When inflation is below this threshold, it positively impacts economic growth, while exceeding it negatively impacts economic growth. Furthermore, higher trade openness negatively affects economic growth, and population growth positively impacts growth across all inflation regimes. Investments contribute to economic growth in the linear model, but their influence is statistically insignificant across the threshold regimes. Financial deepening impedes growth above the inflation threshold.&#x0D; Unique Contribution to Theory, Practice and Policy: The study expands upon the current body of research on estimating the inflation threshold for Nigeria using the Hansen (2000) sample splitting technique. To our knowledge, this is the first study that has adopted this technique to estimate inflation threshold for Nigeria. The Hansen (2000) threshold technique offers more flexibility in model specification. It allows for the estimation of parameters separately for different regimes, typically above and below the threshold. This flexibility can help in identifying distinct regimes, such as low and high inflation regimes, and capturing their unique characteristics. The research findings are crucial for shaping monetary policy in Nigeria, providing policymakers with valuable insights for establishing an inflation target that is in line with Nigeria's overarching goal of attaining sustained economic growth.

Impacts of Marine Heatwaves on Subsurface Temperatures and Dissolved Oxygen in the Chesapeake Bay

AbstractSubsurface impacts associated with Marine Heatwaves (MHWs) in estuaries are not well understood, largely due to data scarcity. Using over three decades (1986–2021) of observations from several monitoring programs, this study investigates subsurface temperature and dissolved oxygen (DO) anomalies associated with surface MHWs in the Chesapeake Bay (CB). Seasonal variability in temperature anomalies followed a simple 1‐D response to surface heating with downward heat transport and diffusion controlled by seasonally variable stratification and mixing. Two distinct temperature regimes were found: a thermally stratified spring‐summer regime, when positive temperature anomalies were confined to the surface mixed layer (SML); and a homogeneous fall‐winter regime. Additionally, surface (subsurface) temperatures were elevated for months (days to weeks) before and after MHWs, indicating individual events were shorter than the timescales of elevated temperatures. A simple 1‐D SML heat budget identified air‐estuary heat flux changes as the leading driver of MHW onsets and declines, with latent heat flux being the dominant term. DO anomaly patterns were more complex, with considerable along‐channel gradients. Notable DO decreases (1–4 mg L−1) primarily occurred in the winter/spring below the SML, and the hypoxic zone expanded from spring through fall. Only a small fraction of these DO anomalies could be attributed to MHW temperature‐induced solubility changes, demonstrating that other physical and/or biogeochemical processes dominate changes in DO during these events. In CB, concurrent low DO and persistent high temperatures could compound the impacts of MHWs on this valuable ecosystem, with MHW event impacts likely to be exacerbated by climate change.

Sensitivity improvement of subharmonic-based pressure measurement using phospholipid-coated monodisperse microbubbles

The use of the subharmonic signal from microbubbles exposed to ultrasound is a promising safe and cost-effective approach for the non-invasive measurement of blood pressure. Achieving a high sensitivity of the subharmonic amplitude to the ambient overpressure is crucial for clinical applications. However, currently used microbubbles have a wide size distribution and diverse shell properties. This causes uncertainty in the response of the subharmonic amplitude to changes in ambient pressure, which limits the sensitivity. The aim of this study was to use monodisperse microbubbles to improve the sensitivity of subharmonic-based pressure measurements. With the same shell materials and gas core, we used a flow-focusing microfluidic chip and a mechanical agitation method to fabricate monodisperse (∼2.45-µm mean radius and 4.7 % polydisperse index) and polydisperse microbubbles (∼1.51-µm mean radius and 48.4 % polydisperse index), respectively. We varied the ultrasound parameters (i.e., the frequency, peak negative pressure (PNP) and pulse length), and found that there was an optimal excitation frequency (2.8 MHz) for achieving maximal subharmonic emission for monodisperse microbubbles, but not for polydisperse microbubbles. Three distinct regimes (occurrence, growth, and saturation) were identified in the response of the subharmonic amplitude to increasing PNP for both monodisperse and polydisperse microbubbles. For the polydisperse microbubbles, the subharmonic amplitude decreased either monotonically or non-monotonically with ambient overpressure, depending on the PNP. By contrast, for the monodisperse microbubbles, there was only a monotonic decrease at all PNPs. The maximum sensitivity (1.18 dB/kPa, R2 = 0.97) of the subharmonic amplitude to ambient overpressure for the monodisperse microbubbles was ∼6.5 times higher than that for the polydisperse microbubbles (0.18 dB/kPa, R2 = 0.88). These results show that monodisperse microbubbles can achieve a more consistent response of the subharmonic signal to changes in ambient overpressure and greatly improve the measurement sensitivity.

Control of the Colloidal and Adsorption Behaviors of Chitin Nanocrystals and an Oppositely Charged Surfactant at Solid, Liquid, and Gas Interfaces.

Chitin has a unique hierarchical structure, spanning the macro- and nanoscales, and presents chemical characteristics that make it a suitable component of multiphase systems. Herein, we elucidate the colloidal interactions between partially deacetylated chitin nanocrystals (cationic ChNC) and an anionic surfactant, sodium dodecyl sulfate (SDS). We investigate charge neutralization and association (electrophoretic mobility, surface tensiometry, and quartz crystal microgravimetry) and their role in the stabilization of Pickering emulsions. We find SDS adsorption and association with ChNC under distinctive regimes: At low SDS concentration, submonolayer assemblies form on ChNC, driven by the hydrophobic effect and electrostatic interactions. With the increased SDS concentration, bilayers or patchy bilayers form, followed by adsorbed hemimicelles and micelles. We further suggested the role of hydrophobic effects in the observed colloidal transitions and complex conformations. At the highest SDS concentration tested, charge neutralization and SDS/ChNC flocculation take place. Remarkably, at given concentrations, adsorbed SDS endows the chitin nanoparticles with an effective hydrophobicity that opens the opportunity to achieve tailorable Pickering stabilization. Hence, a facile route is proposed by in situ modification by SDS physisorption, which extends the potential of renewable nanoparticles in the formulation of complex fluids, for instance, those relevant to household and healthcare products.

Water vapour transit ambiguities for habitable M-Earths

ABSTRACT We have shown in a recent study, using 3D climate simulations, that dayside land cover has a substantial impact on the climate of a synchronously rotating temperate rocky planet such as Proxima Centauri b. Building on that result, we generate synthetic transit spectra from our simulations to assess the impact of these land-induced climate uncertainties on water vapour transit signals. We find that distinct climate regimes will likely be very difficult to differentiate in transit spectra, even under the more favourable conditions of smaller planets orbiting ultracool dwarfs. Further, we show that additional climate ambiguities arise when both land cover and atmosphere mass are unknown, as is likely to be the case for transiting planets. While water vapour may be detectable under favourable conditions, it may be nearly impossible to infer a rocky planet’s surface conditions or climate state from its transit spectrum due to the interdependent effects of land cover and atmosphere mass on surface temperature, humidity, and terminator cloud cover.

Mechanical alloying of AlCoCrFe and AlCoCrFeNi: Design and experimental evaluation of medium- and high-entropy alloy particles for cold spraying

The manufacturability of equiatomic high-entropy alloy (HEA) particles with single- and dual-phase crystal structures using the high-energy mechanical alloying (HE-MA) method was explored in this study. Following a material design-of-experiment (DoE) curriculum, particles were synthesized in a planetary mill. Milling times varied while operating under two distinct HE-MA manufacturing regimes: the conventional approach (simultaneous milling of constituent elements) and the sequential method (progressive milling with the introduction of elements in a specific order). Within the conventional regime, equiatomic AlCoCrFe and AlCoCrFeNi blends were milled, focusing on the influence of incorporating nickel (Ni) as a transient element into the base composition. This led to an equivalent particle size distribution ranging from 5 to 100 μm. Notably, the presence of Ni resulted in an increased fraction of the face-centered cubic (FCC) phase, coupled with a simultaneous reduction in grain and crystallite sizes, thereby enhancing the overall material strength. This knowledge was applied to the design and synthesis of a target equiatomic FeNiCoCrAl HEA system. In this context, individual elements were added to the starting/milled Fe + Ni alloy at four-hour intervals, in line with the sequential milling regimen. The results showed an interesting evolution: the conventionally milled AlCoCrFeNi particles exhibited a dual-phase body-centered cubic (BCC) and FCC structure, with a composition of 55% BCC and 45% FCC phase fractions, while the sequentially milled FeNiCoCrAl particles demonstrated a single-phase BCC structure after 24 h of milling.

Ultrafast-laser-inscribed multiscan type-I mid-infrared waveguides and beamsplitters in IG2.

This study reports the fabrication and characterization of various configurations of mid-infrared waveguides and beamsplitters within the chalcogenide glass IG2 using ultrafast laser inscription (ULI). Our investigation reveals two distinct regimes of ULI modification: weak and strong. The strong regime, marked by higher pulse energies, presents darker and prominent waveguide morphology, enabling efficient light guiding at 4.55 µm, but with higher scattering losses at shorter wavelengths. In the weak regime, we observed a significant enhancement in the mode confinement and a reduction in the propagation loss within the multilayer structures. We have investigated key geometric and inscription parameters such as inscription pulse energy and number of layers, as well as arm separation and splitting angles for beamsplitters. We have successfully fabricated beamsplitters with configurations ranging from 1 × 2 to 1 × 8, achieving a uniform splitting ratio over 96% and a splitting loss as low as 0.4 dB at 4.55 µm. These findings highlight the significant potential of ULI-based IG2 waveguides and beamsplitters for mid-infrared photonics.

Highly tailorable thermomechanical properties of nanograined silicon: Importance of grain size and grain anisotropy

Nanocrystalline silicon can have unique thermal transport and mechanical properties governed by its constituent grain microstructure. Here, we use phonon ray-tracing and molecular dynamics simulations to demonstrate the largely tunable thermomechanical behaviors with varying grain sizes (a0) and aspect ratios (ξ). Our work shows that, by selectively increasing the grain size along the heat transfer direction while keeping the grain area constant, the in-plane lattice thermal conductivity (kx) increases more significantly than the cross-plane lattice thermal conductivity (ky) due to anisotropic phonon–grain boundary scattering. While kx generally increases with increasing ξ, a critical value exists for ξ at which kx reaches its maximum. Beyond this transition point, further increases in ξ result in a decrease in kx due to substantial scattering of low-frequency phonons with anisotropic grain boundaries. Moreover, we observe reductions in the elastic and shear modulus with decreasing grain size, and this lattice softening leads to significant reductions in phonon group velocity and thermal conductivity. By considering both thermal and mechanical size effects, we identify two distinct regimes of thermal transport, in which anisotropic phonon–grain boundary scattering becomes more appreciable at low temperatures and lattice softening becomes more pronounced at high temperatures. Through phonon spectral analysis, we attribute the significant thermal conductivity anisotropy in nanograined silicon to grain boundary scattering of low-frequency phonons and the softening-driven thermal conductivity reduction to Umklapp scattering of high-frequency phonons. These findings offer insights into the manipulation of thermomechanical properties of nanocrystalline silicon via microstructure engineering, carrying profound implications for the development of future nanomaterials.