Dissolution Of Carbonate Sediments Research Articles

Constraining oceanic carbonate chemistry evolution during the Cretaceous-Paleogene transition: Combined benthic and planktonic calcium isotope records from the equatorial Pacific Ocean

The Mesozoic-Cenozoic transition is a period of biogeochemical cycle perturbations. The strongest of them is the Cretaceous-Paleogene boundary (K-Pg) crisis, characterized by one of the most important extinctions of planktonic marine calcifiers in Earth's history. One of the primary drivers of this biocalcification crisis is thought to be the increase in atmospheric CO2 concentration and ocean acidification triggered by the Chicxulub Impact, and/or Deccan volcanism. Because it reflects changes of the calcium cycle and/or depends on parameters of the carbonate system, the Ca isotope composition of carbonate minerals precipitated from seawater (δ44/40Ca) offers the potential to reconstruct some of the environmental changes that occurred. Here we present new high-resolution planktonic and benthic foraminiferal δ44/40Ca, δ18O, δ13C, and Sr/Ca records across the K-Pg transition from Shatsky rise (Leg 198; ODP Site 1209, Hole C). The δ44/40Ca record displays a succession of rapid shifts of ca. −0.4‰ across the K-Pg transition. They are similar though not identical between the planktonic and benthic records. These shifts took place on a timescale significantly shorter than the residence time of Ca in the oceans and are therefore unlikely to result from global disequilibrium in the oceanic Ca budget. Instead, changes in the fractionation factor between carbonate minerals and seawater in response to changes in precipitation rates may explain the observed δ44/40Ca and Sr/Ca record. The benthic and planktonic δ44/40Ca records show a late Maastrichtian and an early Danian negative excursions best explained by a succession of episodes of ocean alkalinity increase related to increased continental weathering caused by CO2 emissions from Deccan volcanism and the aftermath of the K-Pg biocalcification crisis. Carbonate compensation via carbonate sediment dissolution, biological carbonate compensation via reduction of biocalcification, and/or an increase in continental weathering must have occurred to offset the excess CO2, ultimately resulting in rapid changes in ocean carbonate chemistry, in combination with reduced surface alkalinity export in response to the early Paleogene planktonic biomineralization crisis.

A Unique Diel Pattern in Carbonate Chemistry in the Seagrass Meadows of Dongsha Island: The Enhancement of Metabolic Carbonate Dissolution in a Semienclosed Lagoon

In contrast to other seagrass meadows where seawater carbonate chemistry generally shows strong diel variations with higher pH but lower partial pressure of CO2 (pCO2) during the daytime and lower pH but higher pCO2 during nighttime due to the alternation in photosynthesis and respiration, the seagrass meadows of the inner lagoon (IL) on Dongsha Island had a unique diel pattern with extremely high pH and low pCO2 across a diel cycle. We suggest that this distinct diel pattern in pH and pCO2 could be associated with the enhancement of total alkalinity (TA) production coupled to carbonate sediment dissolution in a semienclosed lagoon. The confinement of the IL may hamper water exchange and seagrass detritus export to the adjacent open ocean, which may result in higher organic matter loading to the sediments, and longer residence time of the water in the IL, accompanied by microbial respiration (both aerobic and anaerobic) that may reduce carbonate saturation level to drive carbonate dissolution and thus TA elevation, thereby forming such a unique diel pattern in carbonate chemistry. This finding further highlights the importance of considering TA production through metabolic carbonate dissolution when evaluating the potential of coastal blue carbon ecosystems to buffer ocean acidification and to absorb atmospheric CO2, in particular in a semienclosed setting.

Ocean Acidification and Short‐Term Organic Matter Enrichment Alter Coral Reef Sediment Metabolism Through Different Pathways

AbstractOcean acidification (OA) and organic matter (OM) enrichment (due to coastal eutrophication) could act in concert to shift coral reef carbonate sediments from a present state of net calcification to a future state of net dissolution, but no studies have examined the combined effect of these stressors on sediment metabolism and dissolution. This study used 22‐h incubations in flume aquaria with captive sediment communities to measure the combined effect of elevated pCO2 (representing Ocean Acidification) and particulate organic carbon (representing coastal eutrophication) on coral reef sediment gross primary productivity (GPP), respiration (R), and net calcification (Gnet). Relative to control sediment communities, both OA (pCO2 ~ 1,000 μatm) and OM enrichment (~ +40 μmol C L−1) significantly decreased rates of sediment Gnet by 1.16 and 0.18 mmol CaCO3 m−2 h−1, respectively, but the mechanism behind this decrease differed. The OA‐mediated transition to net dissolution was physiochemical, as rates of GPP and R remained unaffected and dissolution was solely enhanced by a decline in the aragonite saturation state (Ωarg) of the overlying water column and the physical factors governing the pore water exchange rate with this overlying water column. In contrast, the OM‐mediated decline in Gnet was due to a decline in the overlying seawater Ωarg due to the increased respiratory addition of CO2. The decrease in Gnet in response to a combination of both stressors was additive (−0.09 mmol CaCO3 m−2 h−1 relative to OA alone), but this decrease did not significantly differ from the individual effect of either stressor. In this study OA was the primary driver of future carbonate sediment dissolution, but longer‐term experiments with chronic organic matter enrichment are required.

Carbonate-Associated Organic Matter Is a Detectable Dissolved Organic Matter Source in a Subtropical Seagrass Meadow

Seagrasses can enhance carbonate sediment dissolution on diel timescales through oxidation of the rhizosphere and production of acidic exudates of dissolved organic matter (DOM). Carbonates can also associate with DOM either from biogenesis or later adsorption. However, the impact of mineral dissolution on the release of carbonate-associated DOM and on surface water DOM quantity and quality is unclear. We analyzed sub-daily changes in EEMS-PARAFAC components (excitation-emission matrices with parallel factor analysis), fluorescence, and absorbance properties of surface waters over adjacent low- and high-density (LD and HD) Thalassia testudinum seagrass meadows in Florida Bay, USA. We compared fluorescent DOM characteristics of seagrass leaves, acidified (dissolved) sediment leachates, and surface water samples collected from the HD and LD sites with surface water from a nearby mangrove island. The HD site was higher in humic-like PARAFAC components, specific ultraviolet absorbance, and humification index. We did not observe changes in EEMs indices or PARAFAC components with cumulative photosynthetically active radiation, indicating that photodegradation was unlikely to contribute to temporal variability in DOM. Similarities among DOM optical properties from acidified sediment leachates and surface waters at both sites suggest the importance of carbonate dissolution/reprecipitation for DOM cycling, while seagrass leaf leachates were markedly dissimilar to surface waters. We observed similarities among the acidified sediment leachate, surface water, and porewater elsewhere in Florida Bay, indicating dynamic coupling between these DOM pools. From this short study, Florida Bay DOM cycling appears to be more sensitive to carbonate dissolution than to additional photodegradation or authigenic seagrass leaching.

Total alkalinity production in a mangrove ecosystem reveals an overlooked Blue Carbon component

AbstractMangroves have the capacity to sequester organic carbon (Corg) in their sediments permanently. However, the carbon budget of mangroves is also affected by the total alkalinity (TA) budget. Principally, TA emitted from carbonate sediment dissolution is a perennial sink of atmospheric CO2. The assessment of the TA budget of mangrove carbonate sediments in the Red Sea revealed a large TA emission of 403 ± 17 mmol m−2 d−1, independent of light, seasons, or the presence of pneumatophores, compared to −36 ± 10 mmol m−2 d−1 in lagoon sediment. We estimate the TA emission from carbonate dissolution in Red Sea mangroves supported a CO2 uptake of 345 ± 15 gC m−2 yr−1, 23‐fold the Corg burial rate of 15 gC m−2 yr−1. The focus on Corg burial in sediments may substantially underestimate the role of mangroves in CO2 removal. Quantifying the role of mangroves in climate change mitigation requires carbonate dissolution to be included in assessments.

Contamination and ecological risk assessment of heavy metals pollution from the Shalateen coastal sediments, Red Sea, Egypt

To assess the contamination and ecological risk assessment of the Shalateen coastal sediments, Red Sea, Egypt, 35 samples were collected to analyze Cu, Sr, Zn, Cd, Pb, Fe, Co, Ni, Mn, and total organic matter with an atomic absorption spectrophotometer. Several indices were calculated to estimate the contamination levels. The results indicated the following order of metal concentrations: Fe > Sr > Mn > Zn > Ni > Pb > Cu > Co > Cd, and revealed that the investigated sediments are highly enriched and contaminated with Sr, Cd, Pb and Zn. Statistical analyses subdivided the elements into Fe and Mn from natural sources, Sr, Cd, Pb and Zn from anthropogenic sources, and Ni, Cu and Co from combined natural and anthropogenic sources. The average Pb and Cd concentrations are considerably higher compared to the Caspian Sea, Indian Ocean, northern Red Sea, background shale, and continental crust. Possible sources of pollutants are fishing operations, antifouling paints, runoff, desalination plants, industries and dissolution of carbonate sediments.

A fundamental paradigm for coral reef carbonate sediment dissolution

The long-term success of coral reefs depends on a positive balance of calcium carbonate production exceeding dissolution, erosion, and material export. As a result of ocean acidification, coral reefs could transition from net accretion to net erosion owing to decreasing rates of calcification and increasing rates of chemical dissolution and bioerosion. Here, I present a fundamental paradigm that aims to explain the main driver of carbonate sediment dissolution on coral reefs based on theory and a new empirical dataset of pore water carbonate chemistry from the Bermuda coral reef platform. The paradigm shows that carbonate sediment dissolution is most strongly controlled by the extent of organic matter decomposition in the sediments, but that the magnitude of dissolution is influenced by how much decomposition is required to reach pore water undersaturation with respect to the most soluble bulk carbonate mineral phase present in the sediments, a condition defined as the Carbonate Critical Threshold (CCT). Decomposition of organic matter beyond the CCT under aerobic conditions results in stoichiometric proportional dissolution of carbonate sediments. As ocean acidification proceeds over the next several decades, the extent of organic matter decomposition required to reach the CCT will decrease, carbonate dissolution will increase, and subsequently the accumulation of carbonate sediments will decrease. Since drastic reductions in anthropogenic CO2 emission are unlikely in the foreseeable future, the paradigm shows that active controls and reduction of organic matter input to coral reefs at the local scale might be an effective mitigation strategy to prevent or delay coral reefs transitioning to a state of net dissolution.

Effects of lower surface ocean pH upon the stability of shallow water carbonate sediments

It is predicted that surface ocean pH will reach 7.9, possibly 7.8 by the end of this century due to increased carbon dioxide (CO 2) in the atmosphere and in the surface ocean. While aragonite-rich sediments don't begin to dissolve until a threshold pH of ~ 7.8 is reached, dissolution from high-Mg calcites is evident with any drop in pH. Indeed, it is high-Mg calcite that dominates the reaction of carbonate sediments with increased CO 2, which undergoes a rapid neomorphism process to a more stable, low-Mg calcite. This has major implications for the future of the high-Mg calcite producing organisms within coral reef ecosystems. In order to understand any potential buffering system offered by the dissolution of carbonate sediments under a lower oceanic pH, this process of high-Mg calcite dissolution in the reef environment must be further elucidated.

An extraterrestrial 3He-based timescale for the Paleocene–Eocene thermal maximum (PETM) from Walvis Ridge, IODP Site 1266

In the deep-sea, the Paleocene–Eocene Thermal Maximum (PETM) is often marked by clay-rich condensed intervals caused by dissolution of carbonate sediments, capped by a carbonate-rich interval. Constraining the duration of both the dissolution and subsequent cap-carbonate intervals is essential to computing marine carbon fluxes and thus testing hypotheses for the origin of this event. To this end, we provide new high-resolution helium isotope records spanning the Paleocene–Eocene boundary at ODP Site 1266 in the South Atlantic. The extraterrestrial 3He, 3He ET, concentrations replicate trends observed at ODP Site 690 by Farley and Eltgroth (2003). By assuming a constant flux of 3He ET we constrain relative changes in accumulation rates of sediment across the PETM and construct a new age model for the event. In this new chronology the zero carbonate layer represents 35 kyr, some of which reflects clay produced by dissolution of Paleocene (pre-PETM) sediments. Above this layer, carbonate concentrations increase for ∼165 kyr and remain higher than in the latest Paleocene until 234 +48/ −34 kyr above the base of the clay. The new chronology indicates that minimum δ 13C values persisted for a maximum of 134 +27/ −19 kyr and the inflection point previously chosen to designate the end of the CIE recovery occurs at 217 +44/ −31 kyr. This allocation of time differs from that of the cycle-based age model of Röhl et al. (2007) in that it assigns more time to the clay layer followed by a more gradual recovery of carbonate-rich sedimentation. The new model also suggests a longer sustained δ 13C excursion followed by a more rapid recovery to pre-PETM δ 13C values. These differences have important implications for constraining the source(s) of carbon and mechanisms for its subsequent sequestration, favoring models that include a sustained release of carbon after an initial pulse.

Regional estimates of reef carbonate dynamics and productivity using Landsat 7 ETM+, and potential impacts from ocean acidification

MEPS Marine Ecology Progress Series Contact the journal Facebook Twitter RSS Mailing List Subscribe to our mailing list via Mailchimp HomeLatest VolumeAbout the JournalEditorsTheme Sections MEPS 380:103-115 (2009) - DOI: https://doi.org/10.3354/meps07920 Regional estimates of reef carbonate dynamics and productivity using Landsat 7 ETM+, and potential impacts from ocean acidification Christopher S. Moses1,3,*, Serge Andréfouët2, Christine J. Kranenburg1, Frank E. Muller-Karger1,4 1University of South Florida, Institute for Marine Remote Sensing, 140 7th Avenue South, St. Petersburg, Florida 33701, USA 2Institut de Recherche pour le Développement (IRD), BP A5—98848 Nouméa cedex, New Caledonia 3Present address: Jacobs Technology, USGS/FISC, 600 Fourth Street South, St. Petersburg, Florida 33701, USA 4Present address: Univ. of Massachusetts Dartmouth, School for Marine Science and Technology (SMAST), 706 South Rodney French Blvd, New Bedford, Massachusetts 02744-1221, USA *Email: cmoses@usgs.gov ABSTRACT: Using imagery at 30 m spatial resolution from the most recent Landsat satellite, the Landsat 7 Enhanced Thematic Mapper Plus (ETM+), we scale up reef metabolic productivity and calcification from local habitat-scale (10–1 to 100 km2) measurements to regional scales (103 to 104 km2). Distribution and spatial extent of the North Florida Reef Tract (NFRT) habitats come from supervised classification of the Landsat imagery within independent Landsat-derived Millennium Coral Reef Map geomorphologic classes. This system minimizes the depth range and variability of benthic habitat characteristics found in the area of supervised classification and limits misclassification. Classification of Landsat imagery into 5 biotopes (sand, dense live cover, sparse live cover, seagrass, and sparse seagrass) by geomorphologic class is >73% accurate at regional scales. Based on recently published habitat-scale in situ metabolic measurements, gross production (P = 3.01 × 109 kg C yr–1), excess production (E = –5.70 × 108 kg C yr–1), and calcification (G = –1.68 × 106 kg CaCO3 yr–1) are estimated over 2711 km2 of the NFRT. Simple models suggest sensitivity of these values to ocean acidification, which will increase local dissolution of carbonate sediments. Similar approaches could be applied over large areas with poorly constrained bathymetry or water column properties and minimal metabolic sampling. This tool has potential applications for modeling and monitoring large-scale environmental impacts on reef productivity, such as the influence of ocean acidification on coral reef environments. KEY WORDS: Remote sensing · Corals · Carbon cycle · Millennium Coral Reef Map Full text in pdf format PreviousNextCite this article as: Moses CS, Andréfouët S, Kranenburg CJ, Muller-Karger FE (2009) Regional estimates of reef carbonate dynamics and productivity using Landsat 7 ETM+, and potential impacts from ocean acidification. Mar Ecol Prog Ser 380:103-115. https://doi.org/10.3354/meps07920 Export citation RSS - Facebook - Tweet - linkedIn Cited by Published in MEPS Vol. 380. Online publication date: April 07, 2009 Print ISSN: 0171-8630; Online ISSN: 1616-1599 Copyright © 2009 Inter-Research.

Stable isotope ratios and nodular limestone of the Proterozoic Rohtas Limestone: Vindhyan basin, India

The Proterozoic Rohtas Limestone succession in the Vindhyan basin, central India depicts a transition from outer shelf to inner shelf depositional setting. The succession comprises of seven facies viz., black shale, crinkly-laminated limestone, nodular limestone, thinly-laminated heterolithic, grey shale, plane-laminated limestone and wavy-laminated limestone. From field and petrographic features the nodular limestone is identified as early diagenetic product of crinkly-laminated limestone. δ13C and δ18O values of the limestone bear essentially the ‘primary’ seawater composition of late Paleoproterozoic to early Mesoproterozoic time and rules out any postdepositional resetting. δ13C and δ18O compositions of the nodular and non-nodular portions when analysed separately reveals that the nodular portions are invariably enriched in heavier oxygen and carbon isotopes. Enrichment in oxygen and carbon isotope values in the same nodular limestone, although negligible, suggest preferential cementation within the nodular portion. Nodules were possibly generated by dissolution of carbonate sediments and subsequent reprecipitation of carbonate cements close to the sea floor.

CO<sub>3</sub><sup>2−</sup> concentration and pCO<sub>2</sub> thresholds for calcification and dissolution on the Molokai reef flat, Hawaii

Abstract. The severity of the impact of elevated atmospheric pCO2 to coral reef ecosystems depends, in part, on how seawater pCO2 affects the balance between calcification and dissolution of carbonate sediments. Presently, there are insufficient published data that relate concentrations of pCO2 and CO32− to in situ rates of reef calcification in natural settings to accurately predict the impact of elevated atmospheric pCO2 on calcification and dissolution processes. Rates of net calcification and dissolution, CO32− concentrations, and pCO2 were measured, in situ, on patch reefs, bare sand, and coral rubble on the Molokai reef flat in Hawaii. Rates of calcification ranged from 0.03 to 2.30 mmol CaCO3 m−2 h−1 and dissolution ranged from –0.05 to –3.3 mmol CaCO3 m−2 h−1. Calcification and dissolution varied diurnally with net calcification primarily occurring during the day and net dissolution occurring at night. These data were used to calculate threshold values for pCO2 and CO32− at which rates of calcification and dissolution are equivalent. Results indicate that calcification and dissolution are linearly correlated with both CO32− and pCO2. Threshold pCO2 and CO32− values for individual substrate types showed considerable variation. The average pCO2 threshold value for all substrate types was 654±195 μatm and ranged from 467 to 1003 μatm. The average CO32− threshold value was 152±24 μmol kg−1, ranging from 113 to 184 μmol kg−1. Ambient seawater measurements of pCO2 and CO32− indicate that CO32− and pCO2 threshold values for all substrate types were both exceeded, simultaneously, 13% of the time at present day atmospheric pCO2 concentrations. It is predicted that atmospheric pCO2 will exceed the average pCO2 threshold value for calcification and dissolution on the Molokai reef flat by the year 2100.

Diurnal variation in rates of calcification and carbonate sediment dissolution in Florida Bay

Water quality and criculation in Florida Bay (a shallow, subtropical estuary in south Florida) are highly dependent upon the development and evolution of carbonate mud banks distributed throughout the Bay. Predicting the effect of natural and anthropogenic perturbations on carbonate sedimentation requires an understanding of annual, seasonal, and daily variations in the biogenic and inorganic processes affecting carbonate sediment precipitation and dissolution. In this study, net calcification rates were measured over diurnal cycles on 27 d during summer and winter from 1999 to 2003 on mud banks and four representative substrate types located within basins between mud banks. Substrate types that were measured in basins include seagrass beds of sparse and intermediate densityThalassia sp., mud bottom, and hard bottom communities. Changes in total alkalinity were used as a proxy for calcification and dissolution. On 22 d (81%), diurnal variation in rates of net calcification was observed. The highest rates of net carbonate sediment production (or lowest rates of net dissolution) generally occurred during daylight hours and ranged from 2.900 to −0.410 g CaCO3 m−2d−1. The lowest rates of carbonate sediment production (or net sediment dissolution) occurred at night and ranged from 0.210 to −1.900 g CaCO3 m−2 night−1. During typical diurnal cycles, dissolution during the night consumed an average of 29% of sediment produced during the day on banks and 68% of sediment produced during the day in basins. Net sediment dissolution also occurred during daylight, but only when there was total cloud cover, high turbidity, or hypersalinity. Diurnal variation in calcification and dissolution in surface waters and surface sediments of Florida Bay is linked to cycling of carbon dioxide through photosynthesis and respiration. Estimation of long-term sediment accumulation rates from diurnal rates of carbonate sediment production measured in this study indicates an overall average accumulation rate for Florida Bay of 8.7 cm 1000 yr−1 and suggests that sediment dissolution plays a more important role than sediment transport in loss of sediment from Florida Bay.

An Uncompromised Carbonate Record

PALEOCEANOGRAPHY The strong dependence of atmospheric partial pressure of CO2 ( p CO2) on the carbonate ion content of the deep ocean has made reconstruction of the temporal evolution of deep-water carbonate chemistry over glacial cycles an important goal for paleoceanographers. Past variations of deep-ocean CO32− concentrations are recorded in many marine sediments, but most records are compromised by problems such as low sedimentation rates, chemical erosion, and bioturbation. Hodell et al. demonstrate that the carbonate record from a single site in the deep South Atlantic (Ocean Drilling Program Site 1089) represents a qualitative, high-resolution record of the temporal evolution of the carbonate saturation state of the deep sea. From the phase relations between the site 1089 carbonate signal and benthic δ18O, seawater Sr/Ca, and p CO2, they conclude that sea level helps control carbonate compensation (the accumulation or dissolution of carbonate sediments in response to changes in the distribution of alkalinity and dissolved inorganic carbon) in the deep sea, and that carbonate compensation plays an important role in amplifying p CO2 variations caused by other mechanisms. Additional measurements of dissolution indices as a function of depth may make it possible to determine quantitatively deep-sea carbonate ion changes and to evaluate their impact on p CO2 variability over glacial cycles.— HJS Earth Planet. Sci. Lett. 192 , 109 (2001).

Late Quaternary CaCO3 production and preservation in the Southern Ocean: Implications for oceanic and atmospheric carbon cycling

Recent geochemical models invoke ocean alkalinity changes, particularly in the surface Southern Ocean, to explain glacial age pCO2 reduction. In such models, alkalinity increases in glacial periods are driven by reductions in North Atlantic Deep Water (NADW) supply, which lead to increases in deep‐water nutrients and dissolution of carbonate sediments, and to increased alkalinity of Circumpolar Deep Water upwelling in the surface Southern Ocean. We use cores from the Southeast Indian Ridge and from the deep Cape Basin in the South Atlantic to show that carbonate dissolution was enhanced during glacial stages in areas now bathed by Circumpolar Deep Water. This suggests that deep Southern Ocean carbonate ion concentrations were lower in glacial stages than in interglacials, rather than higher as suggested by the polar alkalinity model [Broecker and Peng, 1989]. Our observations show that changes in Southern Ocean CaCO3 preservation are coherent with changes in the relative flux of NADW, suggesting that Southern Ocean carbonate chemistry is closely linked to changes in deepwater circulation. The pattern of enhanced dissolution in glacials is consistent with a reduction in the supply of nutrient‐depleted water (NADW) to the Southern Ocean and with an increase of nutrients in deep water masses. Carbonate mass accumulation rates on the Southeast Indian Ridge (3200–3800 m), and in relatively shallow cores (<3000 m) from the Kerguelen Plateau and the South Pacific were significantly reduced during glacial stages, by about 50%. The reduced carbonate mass accumulation rates and enhanced dissolution during glacials may be partly due to decreases in CaCO3:Corg flux ratios, acting as another mechanism which would raise the alkalinity of Southern Ocean surface waters. The polar alkalinity model assumes that the ratio of organic carbon to carbonate production on surface alkalinity is constant. Even if overall productivity in the Southern Ocean were held constant, a decrease in the CaCO3:Corg ratio would result in increased alkalinity and reduced pCO2 in Southern Ocean surface waters during glacials. This ecologically driven surface alkalinity change may enhance deepwater‐mediated changes in alkalinity, and amplify rapid changes in pCO2.

Projected impact of deep ocean carbon dioxide discharge on atmospheric CO2 concentrations

An evaluation of oceanic containment strategies for anthropogenic carbon dioxide is presented. Energy conservation is also addressed through an input hydrocarbon-fuel consumption function. The effectiveness of the proposed countermeasures is determined from atmospheric CO2 concentration predictions. A previous box model with a diffusive deep ocean is adapted and applied to the concept of fractional CO2 injection in 500 m deep waters. Next, the contributions of oceanic calcium carbonate sediment dissolution, and of deep seawater renewal, are included. Numerical results show that for CO2 direct removal measures to be effective, large fractions of anthropogenic carbon dioxide have to be processed. This point favors fuel pre-processing concepts. The global model also indicates that energy conservation, i.e. a hydrocarbon-fuel consumption slowdown, remains the most effective way to mitigate the greenhouse effect, because it offers mankind a substantial time delay to implement new energy production alternatives.

A global assessment of the oceanic discharge of anthropogenic carbon dioxide in mitigating the greenhouse effect

An evaluation of oceanic containment strategies for anthropogenic carbon dioxide is presented. Energy conservation is also addressed through an input hydrocarbon-fuel consumption function. The effectiveness of these countermeasures is determined from atmospheric CO 2 concentration predictions. A previous box model with a diffusive deep ocean is adapted and applied to the concept of fractional CO 2 injection in 500 m deep waters. The contributions of deep seawater renewal and calcium carbonate sediment dissolution are included. Numerical results show that for CO 2 direct removal measures to be effective, large fractions of anthropogenic carbon dioxide have to be processed. This point favors fuel pre-processing concepts. The global model also indicates that energy conservation, i. e. a hydrocarbon-fuel consumption slowdown, remains the most effective way to mitigate the greenhouse effect, because it offers mankind a substantial time delay to implement new energy production alternatives.

A comparison of acoustic and rock-magnetic properties of equatorial Atlantic deep-sea sediments: paleoceanographic implications

Compressional-wave (P-wave) velocities and magnetic susceptibilities were measured on gravity (GGC) and piston cores (PC) and Ocean Drilling Program (ODP) Leg 108 advanced piston cores (APC) from the equatorial Atlantic to test our hypothesis that climatically driven changes in terrigenous and biogenic fluxes, and in carbonate dissolution control the interrelationships between the two signals. In Pleistocene sediments deposited above the calcium compensation depth (CCD) we observed changes in P-wave velocity and magnetic susceptibility that are (1) inversely correlated, and (2) coherent to changes in glacial-interglacial climate. Glacials show low P-wave velocities and relatively high magnetic susceptibilities. In contrast, interglacials show high P-wave velocities and relatively low magnetic susceptibilities. These temporal changes in P-wave velocity and magnetic susceptibility reflect the climatic history recorded in the sediments and are related to: (1) the production of biogenic carbonate, mainly planktonic foraminifera, and (2) the terrigenous sediment supply that contains magnetic minerals. Below the CCD this pattern disappears and consistently low P-wave velocities and distinctly higher magnetic susceptibilities prevail. The distinct decrease of large P-wave velocity fluctuations is due to the dissolution of carbonate sediments which cause a distinct decrease in sand grain sizes and a consistently low carbonate content (< 10%). Dilution of magnetic material by the carbonate fraction is minor and the high magnetic susceptibility values and the relatively high amplitude variations in magnetic susceptibility are due to changes in the magnetic mineral concentration of the terrigenous (non-carbonate) fraction. In early Pliocene sediments we also observed covarying velocity and magnetic susceptibility signals that may reflect a predominatly terrigenous control on sedimentation. Our preliminary results demonstrate that a combined use of non-destructive measurements of acoustic and rock-magnetic signals provides a potential paleoceanographic tool for characterizing: (1) glacial-interglacial pelagic sedimentation, (2) pelagic sedimentation above the CCD, (3) increases in carbonate dissolution, and (4) areas below the CCD. Furthermore, rock magnetic fluctuations in sediments below the CCD may provide an important stratigraphic tool for the deep carbonate-free basins of the world's oceans.

Sonostratigraphic records from equatorial Atlantic deep-sea carbonates: Paleoceanographic and climatic relationships

Paleoceanographic and stratigraphic methods, based on high-resolution compressional wave ( p-wave) velocity measurements, have been applied to the studies of late Quaternary deep-sea carbonates in the western and eastern equatorial Atlantic. The measurements provide sonostratigraphic records in which changes in p-wave velocity parallel the changes from a glacial to an interglacial climate: Maxima in p-wave velocity (greater than 1540 m/s) occur during interglacial oxygen isotope stages 1, 5 and 7. Minima (1490 m/s) occur during glacial oxygen isotope stages 2, 4 and 6. Changes in p-wave velocity parallel past changes in carbonate accumulation and sediment coarse fraction, and allow a detailed core to core correlation. From these results two main patterns emerge: (1) In cores from shallower than 4300 m and from well above the present lysocline, large temporal changes in p-wave velocity parallel the production of planktonic foraminifera and the climatic history recorded in the sediments, and (2) below 4300 m, the position of the foraminiferal lysocline in the western equatorial Atlantic, large downcore p-wave velocity fluctuations gradually disappear due to dissolution of carbonate sediments. Dissolution also causes a distinct decrease in p-wave velocity and acoustic reflectivity in surface sediments across the present foraminiferal lysocline. Thus, past changes in the position of the foraminiferal lysocline or calcite compensation depth that caused distinct changes in reflectivity of sediments should lead to distinct reflectors within sediment columns. Their distribution can be utilized to map paleowater masses with different degrees of carbonate saturation.

Rate of Dissolution of Carbonate Sediments by Microboring Organisms, Davies Reef, Australia

ABSTRACT Skeletal carbonate sediments on the lagoon floor of Davies Reef (Great Barrier Reef, Australia) are subject to intense attack by microboring organisms, principally algae. The rate at which this microboring process dissolves carbonate was measured experimentally. Fresh, unbored, molluscan sand samples placed in the shallow lagoon (5 m water depth) experienced a weight loss of about 0.9 g/30 g sample (or 3%) in one year due to dissolution of carbonate by microborers (revealed by direct measurement of weight change and point-count analysis). This figure may be converted to about 350 g CaCO3 dissolved/m2 lagoon floor/year, which is equivalent to between 18 and 30% of the sediment influx rate to this lagoon, averaged over the past 9,000 years. Consideration of the exp rimental design suggests that the experiment underestimated the true rate of microboring in lagoon floor sediments. We conclude that the extent of microboring in carbonate sands may provide information on the rate of sediment deposition, and that dissolution of carbonate sediments by microborers is a significant factor in whole-reef CaCO3 budgets.