Dissipation Factor Research Articles

Low dielectric properties of alkali-free aluminoborosilicate fiber glasses for PCB applications at 10GHz.

Alkali-free aluminoborosilicate glasses without (GDMC-Si) and with La2O3 addition (GDMC-La) were fabricated with an aim to develop low dielectric glass fibers for use in printed circuit boards (PCBs) as a reinforcing material in high-speed 5G/6G telecommunications application. This study presents the structural, thermo-physical, and dielectric properties of the glasses. The decrease in glass transition temperature (Tg) and the increase in coefficient of thermal expansion (CTE) were found by the addition of SiO2 and La2O3 in the present glass system, which are due to the depolymerization of the glass networks confirmed by the FTIR analysis. The dielectric constants (Dk) and the dissipation factors (Df) of the glasses were investigated at a high frequency of 10GHz. The Dk values of the GDMC-Si and GDMC-La glass systems reached a minimum of 4.50 and 4.75, while their Df values reached a minimum of 2.86 × 10-3 and 3.01 × 10-3, respectively. Notably, the Dk and Df values of the present glasses were lower than the commercial E-glass (Dk: 6.9, Df: 7.0 × 10-3 at 10GHz) and L-glass (Dk: 4.8, Df: 3.0 × 10-3 at 10GHz). Glass fibers with a diameter of 10μm were successfully drawn by the continuous melt-spinning process and their mechanical properties were investigated.

SUSTAINABLE CONVERSION OF BANANA WASTE INTO ELECTRICAL INSULATION MATERIALS FOR HIGH VOLTAGE APPLICATIONS

<p style="text-align:justify;"><span style="font-family:"Times New Roman","serif";font-size:12.0pt;line-height:150%;text-justify:inter-ideograph;">The study examined the electrical characteristics of epoxy composites that were reinforced with fibers derived from banana leaves and pseudostems. Specifically, the study focused on analysing the dissipation factor, loss factor, and dielectric constant of these composites. The study found that composites containing banana leaf fibers demonstrated enhanced dielectric properties in comparison to pure epoxy composites. This improvement can be attributed to the effective interlocking between the fibers and the matrix, as well as the polarization effects. Enhancing the amount of fibre in the material resulted in greater dielectric constants, reaching a maximum at a critical volume of 17.2%. However, at higher frequencies, the dielectric constants fell due to decreasing polarization. Chemical treatments, such as alkali and peroxide solutions, improved the bonding between the fibers and the matrix, leading to higher resistance to water and greater electrical insulation. The results also showed that banana leaf fibers had superior dielectric performance compared to pseudostem fibers, mostly because of enhanced nanoparticle bonding. Using banana fibers is particularly noteworthy since it contributes to environmental sustainability by recycling agricultural waste, hence mitigating the ecological consequences of synthetic products.</span></p>

Microwave‐Assisted Fabrication of Highly Crystalline, Robust COF Membrane for Organic Solvent Nanofiltration

AbstractFabrication of crystalline, robust covalent organic framework (COF) membranes based on disorder‐to‐order strategy is promising yet highly challenging. Herein, a microwave‐assisted method for fabricating COF membranes is proposed. Initially, monomers polymerize rapidly on the surface of porous Al2O3 substrate at room temperature to form an amorphous pristine membrane. Subsequently, a microwave field is exerted to trigger fast crystallization, acquiring a crystalline COF membrane within 60 min. The amorphous pristine membrane exhibits a high dissipation factor, indicating excellent microwave absorption capability, which accelerates the dynamic reversible reactions during the microwave treatment and thus ensures a rapid transition from the amorphous to the crystalline state. Owing to the high‐crystallinity and robust structure, the COF membranes exhibit high rejection rates for solute molecules with molecular weights exceeding 700 Da (e.g., Evans blue: 98.7%) and high solvent permeance for organic solvents (e.g., ethanol: 87.8 Lm−2h−1 bar−1, n‐hexane: 222.3 Lm−2h−1 bar−1). Surprisingly, the COF membranes exhibit superior mechanical properties, with Young's modulus of 33.91 ± 3.94 GPa, outperforming previously reported polycrystalline COF membranes and are close to those for inorganic zeolite membranes. The microwave‐assisted COF crystallization method opens a new avenue to fabricating a variety of crystalline membranes for advanced separations.

Electroosmotic mechanism of Ellis fluid with Joule heating, viscous dissipation and magnetic field effects in a pumping microtube.

The dynamics of electro-osmotically generated flow of biological viscoelastic fluid in a cylindrical geometry are investigated in this paper. This flux is the result of walls contracting and relaxing sinusoidally in a magnetic environment. The rheology of the fluid is accurately captured with the Ellis fluid (blood) model. Both Joule heating and viscous dissipation are accounted for during thermal analysis. The electric potential induced in the EDL is obtained by applying the Debye-Huckel linearization to the non-linear Poisson-Boltzmann equation. Mathematical modelling is incorporated in cylindrical coordinates in wave frame of reference. Assuming a long wavelength characterized by a low Reynolds number, the Ellis fluid model's governing equations are simplified. Subsequently, the differential equations that result are computed numerically utilizing the NDSolve utility that is integrated into Mathematica. Graphical representations are utilized to visually and comprehensively assess the thermal characteristics, flow features, heat transfer coefficient, and skin friction coefficient. Various factors are taken into consideration, including the impact of Ellis fluid parameters, electric double layer, magnetic field, Brinkman number, and Ohmic dissipation. Ellis fluid's axial velocity boosts with a rise of the electroosmotic parameter and power-law index while decreasing with an increase in the Hartmann number and material fluid parameter. The fluid temperature is directly proportional to EDL parameter and parameters of Ohmic and viscous dissipation. The current model may be used in clinical scenarios involving the gastrointestinal system and capillaries, electro-hydrodynamic therapy, delivery of drugs in pharmacological, and biomedical devices.

Constant-roll warm inflation within Rastall gravity

This research paper used a newly proposed strategy for finding the exact inflationary solutions to the Friedman equations in the context of Rastall theory of gravity (RTG), which is known as constant-roll warm inflation (CRWI). The dissipative effects produced during WI are studied by introducing a dissipation factor Q=Γ3H, where Γ is the coefficient of dissipation. We establish the model to evaluate the inflaton field, effective potential requires to produce inflation, and entropy density. These physical quantities lead to developing the important inflationary observables like scalar/tensor power spectrum, scalar spectral index, tensor-to-scalar ratio, and running of spectral-index for two choices of obtained potential that are V0=0 and V0≠0. In this study, we focus on the effects of the theory parameter λ, CR parameter β, and dissipation factor Q (under a high dissipative regime for which Q=constant) on inflation, and are constrained to observe the compatibility of our model with Planck TT+lowP (2013), Planck TT, TE, EE+lowP (2015), Planck 2018 and BICEP/Keck 2021 bounds. The results are feasible and interesting up to the 2σ confidence level. Finally, we conclude that the CR technique produces significant changes in the early universe.

Coherent Acoustic Phonons in Plasmonic Nanoparticles: Elastic Properties and Dissipation at Low Temperatures.

We studied the frequency and quality factor of mechanical plasmonic nanoresonators as a function of temperature, ranging from ambient to 4 K. Our investigation focused on individual gold nanorods and nanodisks of various sizes. We observed that oscillation frequencies increase linearly as temperature decreases until saturation is reached at cryogenic temperatures. This behavior is explained by the temperature dependence of the elastic modulus, with a Debye temperature compatible with reported bulk values for gold. To describe the behavior of the quality factor, we developed a model considering the nanostructures as anelastic solids, identifying a dissipation peak around 150 K due to a thermally activated process, likely of the Niblett-Wilks mechanism type. Importantly, our findings suggest that external dissipation factors are more critical to improving quality factors than internal friction, which can be increased by modifying the nanoresonator's environment. Our results enable the future design of structures with high vibration frequencies and quality factors by effectively controlling external losses.

Investigation of the Dielectric Characteristics of Chromium-substituted Zinc and Cobalt Nanoferrite Systems

Abstract The series of Cr-substituted Zn and Co nanoferrite systems having the chemical composition CrxZnFe2–xO4 and CrxCoFe2–xO4 (0.0 ≤ x ≤0.5) were prepared by sol–gel technique. The present investigation aims to compare the impact of Cr3+ concentration on dielectric characteristics of Zn and Co-nanoferrite systems. The investigation of various dielectric characteristics was conducted using an LCR meter at 1kHz frequency and across the frequency range of 100Hz to 1MHz. The measurements were conducted at room temperature. In the case of both ferrite systems, the plots of frequency Vs dielectric constant (ε′) and AC conductivity (σac) show a common dielectric behavior of spinel ferrites. The plots of frequency Vs dissipation factor (D) of Cr- Cr-substituted zinc and Cobalt nanoferrite samples were observed to be unusual and display a relaxation peak at a particular frequency. In the current study, CrxZnFe2-xO4(x=0.2 and 0.3) and CrxCoFe2–xO4 (x=0.3) ferrite samples were found to exhibit very high values of dielectric constant. So these ferrites may be useful for a wide range of applications in electrical storage devices. According to LCR reports, all the Cr3+ substituted ferrite samples in both ferrite systems exhibit higher dielectric constant and AC conductivity values. Possible mechanisms that may be accountable for the outcomes are thoroughly scrutinized in this paper.

The thermal deformation behavior and processing map of TC9 titanium alloy

This investigation delves into the thermal deformation behavior of TC9 titanium alloy. Compression tests at isothermal conditions were performed on a Gleeble thermal simulator under conditions spanning 700–1200 °C and strain rates of 0.001–1 s−1. The true stress-true strain curves indicated that stress increases with rising strain rate and decreasing temperatures. The softening mechanisms in the biphasic and monophasic regions were discussed. By correcting errors caused by friction, the strain-compensated Arrhenius-type constitutive equation, which accurately describes the flow behavior of TC9 titanium alloy, has been established. A processing map at a strain of 0.7 was constructed based on the power dissipation factor, revealing an unstable region at 700–800 °C/0.01–1 s−1 and 800–900 °C/0.1–1 s−1, where microcrack defects were observed, suggesting that processing should be avoided in this region. Efficiency values as high as 60–70 % indicate superplasticity deformation, with corresponding m values within this efficiency range of approximately 0.4–0.5, reaching the strain rate sensitivity index range of superplasticity titanium alloys. Tensile tests conducted at 900 °C and a deformation rate of 0.001 s−1 showed elongation exceeding 100 %. The sample compressed at 900 °C and 0.001 s−1 exhibits small grain size, uniform orientation, the lowest dislocation density, and a uniform two-phase mixture. These microstructural features indicate the material's good machinability.

Mechanism of airborne sound absorption through triboelectric effect for noise mitigation

Mitigating broadband noise with passive airborne sound absorbers has been a long-lasting challenge, particularly for low-frequency anthropogenic sounds below kilohertz with long wavelengths, which require bulky materials for effective absorption. Here, we propose a strategy that utilizes local triboelectric effect and in-situ electrical energy dissipation mechanism for airborne sound absorption. This approach involves a fundamentally different mechanism that converts airborne sound into electricity for energy dissipation, in contrast to conventional mechano-thermal energy conversion mechanisms. We establish an equivalent acoustic impedance model to provide theoretical analysis of the underlying sound absorption mechanisms, with a theoretical maximum mechano-electro-thermal coupling efficiency approaching 100% under optimal conditions. We design fibrous triboelectric composite foam materials accordingly and show their substantially boosted acoustic absorption performance experimentally, where the adoption of diverse triboelectric material pairs validates that a larger difference in material charge affinities intensifies the local triboelectric effect and results in higher acoustic absorbing performance.

Implementation of Fuzzy Logic Scheme for Assessment of Power Transformer Oil Deterioration Using Imprecise Information

This research aims to analyze the implementation of a fuzzy logic-based approach in improving the diagnosis of power transformer oil deterioration, which is critical for maintaining the efficient performance and operational life of transformers. Traditional diagnoses are based on strict measurements that do not account for the factors of variability and uncertainty of the actual data. In this article, we perform six different types of tests in this regard, and data have been collected during the period of 2021 to 2022 of 188 power transformer failures in the New KotLakhpat Lahore unit, whose voltage range is 132/66 kv and rating capacity is 40/50 MVA. In this case, a fuzzy logic-based scheme is developed based upon the membership function, a rule-based and defuzzification method that works with imprecision and the implementation of uncertainty in assessing the condition of transformer oils. Moisture, acidity, and a dissolved gas analysis indicator, along with other indication approaches such as interfacial tension, viscosity, and tangent delta measurement, are used to analyze the deterioration process in transformer oils. In the visual representation, oil samples with the following properties were first fuzzified: 19.9 mm2/s of viscosity, 0.453 mgKOH/g of acidity, 695 ppm of DGA, 20.8 mg/kg of moisture, 19.98 of IFT, and 4.35 × 100.14 of tangent delta. The output that was generated by software using the values entered into the parameters (HI and Age) after defuzzification is 45. Fuzzy logic serves as a concrete framework for transforming the diagnostics system and deterring the threats to the entire transformer’s health and reliability in the future. By using this technique, various faults were hypothetically and practically analyzed in a transformer to implement early detection technologies with the possibility to reduce maintenance costs and extend operational life up to 45 years. Various case studies indicate the effectiveness of fuzzy logic in comparison to traditional diagnostics.

Understanding Heat Dissipation Factors for Fixed‐Tilt and Single‐Axis Tracked Open‐Rack Photovoltaic Modules: Experimental Insights

ABSTRACTThis paper presents the results of long‐term experiments conducted on fixed‐tilt (FT) and single‐axis tracked (SAT) open‐rack photovoltaic (PV) modules in South Africa. Utilising Faiman's heat dissipation model and data filtering method, the study demonstrates favourable comparisons of FT experimental results with literature while yielding novel heat dissipation factors for SAT modules. Enhanced heat dissipation is observed in no/low wind conditions for SAT modules compared to FT modules. Analyses reveal the influence of plane‐of‐array (POA) irradiance, wind speed and direction on module temperature, with SAT modules exhibiting greater heat dissipation stability. An investigation into data filtering methods suggests minor sensitivity for both configurations, with a slightly more pronounced impact on SAT modules. Assessments comparing module temperature predictions using diverse heat dissipation factors for FT modules reveal negligible sensitivity. This suggests that exact heat dissipation factor values may not be crucial for accurate predictions of module temperature in FT open‐rack systems. Annual power output simulations using PVsyst software demonstrate a 2.9% and 3.3% enhancement for FT and SAT configurations, respectively, when employing experimentally determined heat dissipation factors. These findings highlight the importance of realistic, configuration‐specific heat dissipation factors in optimising PV system performance, particularly in the competitive context of modern PV power plant construction and techno‐economic calculations.

Accurate Technique for the Calibration of High-Voltage Capacitance and Dissipation Factor Bridges up to 1 kHz

This paper presents a comprehensive methodology for the precise calibration of high-voltage capacitance and dissipation factor (DF) bridges. The technique involves meticulous adjustments using a digital high-precision phase and ratio-measuring system to determine correction factors for DF and capacitance measurements. Unlike other methods that are limited to a narrow range, this approach allows calibration across the entire operational working spectrum of any bridge. While the method has been developed up to 1 kHz, its adaptability for future requirements is facilitated by the developed software. This method has been carried out by calibrating a highly accurate bridge for a capacitor ratio of up to 100, with DFs ranging from −0.01 to 0.01 and currents ranging from 0.1 mA to 1 A. Linear correction factors are established, with their accuracies being rigorously quantified. This methodology achieves expanded uncertainties as low as 3.5 µF/F (3.5 ppm) for capacitance and 2.2 × 10−⁶ for DFs, significantly enhancing measurement reliability across diverse high-voltage capacitor applications.

Natural coil springs: Biomechanics and morphology of the coiled tendrils of the climbing passion flower Passiflora discophora

Tendrils of climbing plants possess a striking spring-like structure characterized by a minimum of two helices of opposite handedness connected by a perversion. By performing tensile experiments and morphological measurements on tendrils of the climbing passion flower Passiflora discophora, we show that these tendril springs act as coil springs within the plant's attachment system and resemble technical coil springs. However, tendril springs have a low spring index and a high pitch angle compared with typical metal coil springs resulting in a more complex loading situation in the plant tendrils. Moreover, the tendrils undergo a drastic shift from the fresh turgescent stage to a dried-off and dead senescent stage. This entails changes in material properties (elastic modulus in tension), morphology (tendril and helix diameter, number of windings), anatomy (tissue composition), and failure behavior (susceptibility to delamination) and reduces the degree of elasticity and strain at failure of the tendrils. Nevertheless, senescent tendrils remain functional as springs and maintain high energy dissipation capacity and high break force. This renders the system highly energy efficient, as the plant no longer needs to metabolically sustain the died-back tendrils. Because of its energy-storing spring system, its high energy dissipation and high safety factor, the attachment system can be considered a ‘fail-safe’ system. Statement of significanceThe use of coil springs as mechanical devices is not restricted to man-made machinery; striking spring structures can also be found within the attachment systems of climbing plants. Passiflora discophora climbs by using long thin tendrils with adhesive pads at their tips. Once the pads have attached to a support, the tendrils coil and form a spring-like structure. Here, we analyze the form and mechanics of these ‘tendril springs’, compare them with conventional technical coil springs, and discuss changes in the tendril springs during plant development. We reveal the main features of the attachment system, which might inspire new artificial attachment devices within the emerging field of plant-inspired soft-robotics.

Incremental Cost Benefit Ratio (ICBR) of Poly House and Open Field Conditions in Cabbage (Brassica oleracea var. capitata) after Chemical Intervention

This study evaluates the Incremental Cost Benefit Ratio (ICBR) between Poly house and Open field conditions in cabbage cultivation chemical intervention. The research aimed to compare the economic feasibility of adopting poly house technology over traditional open field methods, considering costs and benefits associated with chemical inputs. A comparative cost analysis was conducted to assess production expenses like costs for insecticidal treatments and labor charges. Yield data from both environments were collected to determine output differences and subsequent economic returns. Results indicate that Incremental cost benefit ratio of cabbage heads yields to the cost of treatments in poly house and open field presented as there was a significant superior difference in ICBR ratio of poly house with 1: 0.946 as compared to open field with 1: 0.639 of cabbage heads. The economic analysis revealed that the higher yields and quality achieved in poly house conditions due to less dissipation and undisturbed environmental factors on insecticide applied. Resulting in a favorable incremental Cost benefit ratio compared to open field cultivation.

A thermal performance study on magnetic dipole based viscoplastic nanomaterial deploying distinct rheological aspects

Magnetic nanoliquids stand inimitable when compared with conventional liquids as their distinctive magnetic attributes can be regulated utilizing magnetic fields. For this reason, heat transference can be stimulated or regulated subjected to externally imposed magnetic fields. Magnetic nanoliquids are useful in comparison to orthodox or non-magnetic nanoliquids. These encompasses, energy conversion, electronics, hydraulics, thermal engineering and bioengineering. This study elaborates the magnetic dipole impact on convectively heated rheological nanomaterial confined by stretchy surface. Mathematical modeling is based on thermally radiative viscoplastic (Casson) model. Porous medium features are scrutinized through Darcian Forchheimer (DF) relation. Two-component Buongiorno nanomaterial model which captures Brownian diffusive together with thermophoretic diffusion is under consideration. Energy and solutal transportation expressions capture thermal source and chemical reaction effects. The dimensionalized nanomaterial flow model for stretching flow is obtained by deploying similarity variables. Numerical solutions are computed through Bvp4c scheme. The physical outcomes are elucidated graphically and arithmetically on dimensionless quantities (i.e., Nusselt number, temperature, skin-friction, velocity, Sherwood number and concentration streams). A benchmark is reported to authenticate the acquired numeric solutions. It is further visualized that nanomaterial temperature escalates subject to higher estimations of thermal Biot number, Curie temperature factor, radiation factor, thermophoresis parameter, heat source, ferrohydrodynamic interaction factor and Brownian diffusive parameter while it diminishes with Prandtl number and dissipation factor.

Revealing the Intrinsic Correlation between Cu Scales and Free Radical Chain Reactions in the Regulation of Catalytic Behaviour.

Defining the copper-based catalysts that are responsible for the catalytic behaviour of oil-paper insulation systems and implementing effective regulation are of great significance. Accelerated ageing experiments were conducted to reveal variations in copper scales and deterioration in insulation properties. As ageing progressed, TEM images demonstrated that copper species were adsorbed and aggregated on the fibre surface in the form of nanoparticles (NPs). The scale of NPs exhibited a continuous increase, from 27.06 nm to 94.19 nm. Cu(I) and Cu(II) species were identified as the active sites for inducing intense free radical reactions, which significantly reduced the activation energy, making the insulating oil more susceptible to oxidation. The role of the antioxidant di-tert-butyl-p-cresol (DBPC) in extending the insulation life was regulated by determining the optimal addition time based on variations in the interfacial tension. After the second addition of DBPC, the ageing rates of the dissipation factor, acidity, micro-water and breakdown voltage in the Cu+DBPC group decreased by 28.8%, 43.2%, 52.9% and 46.7%, respectively, compared to the Cu group. This finding not only demonstrates the crucial role of DBPC in preventing the copper-based catalyst-induced oxidation of insulating oil, but also furnishes a vital foundation for enhancing the long-term stability of transformer insulation systems.

Exploring dielectric and electrical characteristics in Sr0.5Ba0.5SnxFe12-xO19/CoFe2O4 nanocomposites

This study examined the morphological, structural, electrical, and dielectric characteristics of hard-soft (H-S) Sr0.5Ba0.5SnxFe12-xO19/CoFe2O4 (x ≤ 0.10) ferrite nanocomposites (NCs), created using one-pot sol-gel combustion route. This study systematically investigated the electrical/dielectric features of H-S Sr0.5Ba0.5SnxFe12-xO19/CoFe2O4 NCs where x is within the range of 0.00 ≤ x ≤ 0.10. The examination realizes frequencies that reach 3.0 MHz, conducted within 20 °C–120 °C. A detailed analysis was performed to investigate various conduction mechanisms linked with dielectric constant, dissipation factor, AC/DC conductivity, loss of dielectric capacity, and real/imaginary modulus, which were explored across the entire range of Sn ion substitution ratios. Observations reveal that the conductivity variations adhere to power law dynamics concerning frequency, predominantly influenced by the Sn ion substitution ratios within the NCs. Furthermore, the frequency dependency of the dielectric coefficient across all NCs substantiates the common propagation of dielectric behavior, prominently contingent upon the substitution ratio of "x". Notably, the majority of dielectric parameters observed in H-S Sr0.5Ba0.5SnxFe12-xO19/CoFe2O4 (x ≤ 0.10) NCs are attributable to grain-to-grain boundaries, elucidated by conduction mechanisms similar to those observed in most compositional ferrites, explicable through Koop's model.

Wave-transparent and eco-friendly flame-retardant phosphorus-based phthalonitrile/quartz composites by a synchronized self-curing strategy with cyano and alkynyl groups

The robust human–machine interaction systems of the aerospace industry necessitate the development of thermal resistant wave-transparent composites, with a pivotal focus on organic resin matrix. However, enhancing the heat resistance of such materials while preserving other critical attributes has been a formidable challenge. In this study, a novel designed strategy of a dual-curing functional phosphorus-based phthalonitrile monomer (P-ALK-PN) has been proposed. The optimized curing temperatures for intra- or intermolecular Diels-Alder reactions of alkynyl groups and polyaddition reaction of cyano groups resulted in a homogeneous and highly crosslinked N-enriched phthalonitrile system. After curing at 450 °C, the resin, namely P-ALK-PN-450 °C, demonstrated exceptional thermal stability (T5% = 644 °C), thermo-oxidative stability (T5% = 554 °C), and char yield at 800 °C (90.7 % in N2 and 67.5 % in air). Their quartz fiber reinforced composites (P-ALK-PN/QFs) were subsequently fabricated by the hot-pressing process. Upon post-curing at 420 °C, P-ALK-PN-420 °C/QF displayed elevated glass transition temperature (550 °C), flexural strength (319 MPa), and relatively low dielectric properties with a dielectric constant (Dk) of approximately 4.2 and a dissipation factor (Df) less than 0.02 across a wide temperature ranging from 25 °C to 600 °C. Especially, it exhibited excellent flame retardancy (only a 6.7 % weight loss at ambient temperatures exceeding 1300 °C for 200 s) as well, stemming from release of eco-friendly inert gases (NH3) and formation of a graphitized protective layer during pyrolysis. These promising results highlight the potential applications of P-ALK-PN resins in aerospace and high-performance engineering fields.

Study of circumferential SH-wave interaction with a piezoelectric cylinder having pre-stressed viscoelastic imperfect coating

In this study, the circumferential interaction behavior of the SH-wave with a piezoelectric cylinder coated with a viscoelastic material is investigated. The coating interface is imperfect and the viscoelastic material is subjected to pre-stress. By applying mathematical methods to the dynamical governing equations, expressions for displacement components and electric potential is obtained. Utilizing the set of boundary conditions, dispersion and damping equations are established for this model. The impacts of perfect & imperfect interfaces, piezoelectric & dielectric constants, initial stress, dissipation factor, attenuation coefficient and radial thickness ratio of materials on the phase and damped velocities of SH-wave are observed by numerical examples and graphical visuals.

A "Bottom-Up" Strategy for High-Performance Benzocyclobutene (BCB)-Subnanometer Inorganic Nanocomposites.

Developing benzocyclobutene (BCB) nanocomposites with ultra-small inorganic sizes represents a formidable challenge, although it offers great potential to produce materials with customizable structural and rich functional properties. In this study, we present a "bottom-up" design strategy for creating cross-linked benzocyclobutene (BCB) nanocomposites with highly dispersed nanodomains, such as organoalkoxysilane. This approach leverages ring-opening metathesis polymerization (ROMP) and thermally induced cycloaddition reactions to embed oligomeric silsesquioxanes, achieving a unique molecular structure with promising low-dielectric applications. The synthesis involves organoalkoxysilane and BCB as pendant groups of polynorbornenes that are covalently integrated. Additionally, the methoxyl groups of linear polymers could be further hydrolyzed under acidic conditions, and BCB groups could undergo thermal-induced ring-opening at high temperatures and Diels-Alder addition between themselves and vinyl groups, respectively. Fourier transform infrared (FTIR) spectroscopy analyses suggested the presence of ladder or network structures and high-resolution transmission electron microscopy (HRTEM) images presented the well-dispersed inorganic clusters, facilitating excellent dielectric properties with a dielectric constant (Dk) of 2.25 and a dissipation factor (Df) of 2.27 × 10-4. Compared with previously reported low-Dk materials, the cured nanocomposites also exhibited a significantly balanced enhancement of their comprehensive properties. This molecular bottom-up strategy provided a simple and universal method for constructing BCB-inorganic nanocomposites featuring a subnanometer inorganic structure, paving the way for future investigation into new classes of polymer-inorganic nanocomposites with a low Dk.