Dispersion Properties Research Articles

Microstructural Investigation and Mechanical Properties of Resistance Spot Welding Joints of Mild Steel Sheets

Due to its high productivity, low cost, and increased work efficiency, resistance spot welding (RSW) can instantly join two or more steel sheets and it is widely used in the automotive industry and lately in the manufacturing of thin-walled cold-formed steel constructions. However, the RSW of zinc-coated mild steel sheets presents metallurgical challenges, especially when different thickness combinations are used. Therefore, in the present paper a resistance welding machine was used which uses direct current (MFDC) inverter technology combined with SMART AUTOSET technology to weld S250 GD and S350 GD galvanised mild steel sheets with different thicknesses. It is well known that, due to the elevated temperature that occurs during the welding process, followed by rapid cooling, defects such as cracking, porosity, lack of fusion, and an increased amount of brittle phases affect the welding quality. Therefore, the influence of the RSW process parameters established by an automatic sequence on the nugget geometry, microstructure, and mechanical properties was investigated. The phase transformations that took place during the heating-cooling cycle were analysed in detail through metallographic studies. The results showed that the microstructure of the weld nuggets was similar, characterised by columnar grains elongated in the direction of heat evacuation. Nevertheless, there were differences in terms of phase dispersion, defects and mechanical properties that have been linked to the RSW process parameters.

Molecular Simulation and Impact of Solvent‐Based Analysis of 2‐Methoxy‐4‐Allylphenol (Eugenol) Targeting Progesterone Receptor for Breast Cancer Therapy

ABSTRACTBreast cancer is a leading cause of cancer‐related morbidity and mortality among women globally. It arises from the abnormal proliferation of cells within breast tissue and can manifest in several subtypes, classified by the expression of hormone receptors. The main objective of this work is to assess the effect of solvent on 2‐methoxy‐4‐allylphenol's (2M4AP) in quantum chemical calculations and ability of 2M4AP to bind with the proteins associated with breast cancer. The non‐toxic nature of 2M4AP was initially validated through drug‐likeness studies and it complies with Lipinski's criteria. The optimization of 2M4AP structure was carried out in gas and liquid phase in DFT technique with B3LYP/6‐311++G (d, p) level. Then the electronic spectrum was calculated in TD‐DFT technique and the transition was determined to be n → σ*. The steadiness, charge dispersal and electronic properties were assessed and the band energy value was calculated to be 5.58 eV (gas) and 5.64 eV (liquid), exhibiting a stable confirmation of 2M4AP structure. Topological characteristics exhibited the intermolecular connections of 2M4AP along with electronic features. From the simulated results, the effect of solvent (water) in 2M4AP was very minimal and the structure is stable in both gas and liquid phase. Further, the docking studies, 2M4AP exhibited highest binding score of −7.3 kcal/mol with progesterone receptor, confirming the better ability of 2M4AP to react in hormone‐positive breast cancer. The Ramachandran plot confirms the stability of interacted amino acids with the ligand molecule. Thus, 2M4AP can be considered as a potent candidate for treatment of breast cancer after clinical studies.

Application of quantum graph theory to metamaterial design: Negative refraction of acoustic waveguide modes

We leverage quantum graph theory to quickly and accurately characterize acoustic metamaterials comprising networks of interconnected pipes. Anisotropic bond lengths are incorporated in the model that correspond to space-coiled acoustic structures to exhibit dispersion spectra reminiscent of hyperbolic metamaterials. We construct two metasurfaces with embedded graph structure and, motivated by the graph theory, infer and fine-tune their dispersive properties to engineer nonresonant negative refraction of acoustic surface waves at their interface. Agreement between the graph model, full-wave simulations, and experiments bolsters quantum graph theory as a new paradigm for metamaterial design. Published by the American Physical Society 2024

Comparative study on predicting turbulent kinetic energy budget using high-order upwind scheme and non-dissipative central scheme

The accurate computation of different turbulent statistics poses different requirements on numerical methods. In this paper, we investigate the capabilities of two representative numerical schemes in predicting mean velocities, Reynolds stress and budget of turbulent kinetic energy (TKE) in low Mach number flows. With concerns on numerical order of accuracy, dissipation and dispersion properties, a high-order upwind scheme with relatively good dispersion and dissipation and a second-order non-dissipative central scheme with perfect dissipation but poor dispersion are adopted for this comparative study. By carrying out a series of numerical simulations including Taylor-Green vortex, turbulent channel flow at Reτ=180\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$Re_{\ au }=180$$\\end{document} and turbulent flow over periodic hill at Reb=10595\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$Re_{b}=10595$$\\end{document}, it can be obtained that although the high-order upwind scheme lacks perfection of dissipation in high wave number range, it still demonstrates superior predictive capability compared with the second-order non-dissipative central scheme, especially with relatively coarse grids. Finally, by taking the high-order upwind scheme as a suitable selection for turbulence simulation, the turbulent flow over a 30P30N multi-element airfoil is investigated as an application study. After briefly comparing the simulated profiles and spectrum with reference experimental results as validation, the budget of TKE is analyzed to locate the dominant flow structures and regions. It is found that the production and dissipation terms behave in a “monopole” pattern in the locations with strong shears and wakes. Whereas the advection and diffusion terms show an “inward” pattern and an “outward” pattern, which indicate the spatial transport of TKE between the center of the shear layer and nearby locations.

Nonlinear plane-wave expansion method for analyzing dispersion properties of piezoelectric metamaterial lattices with encapsulated resonators

Nonlinear plane-wave expansion method for analyzing dispersion properties of piezoelectric metamaterial lattices with encapsulated resonators

Chirped fiber Bragg gratings directly inscribed by a femtosecond laser in an ytterbium-doped fiber for spectrum recovery, loss compensation and effective use in a CPA scheme

Point-by-point femtosecond laser inscribed chirped Bragg gratings are good candidates for use in fiber chirped pulse amplification systems due to the high flexibility of their dispersion properties, low cost, and no length limitation. However, such gratings have two significant drawbacks: high losses and distortions of the short-wavelength part of the spectrum when operating in the normal group velocity dispersion mode. We propose a novel approach based on writing such gratings in a highly doped active fiber, which allows us to correct both shortcomings. We have also demonstrated, for the first time to our knowledge, a successful use of such gratings as stretchers in a fiber chirped pulse amplification system.

Flexibility, Dispersion Property, and Giant Sunlight Absorption of Monolayer MX2 (M = Zr, Hf; X = S, Se) and Related Janus MXY (M = Zr, Hf; X = S, Y = Se)

IVB–VIA transition metal dichalcogenides (TMDs) MX2 (M = Zr, Hf; X = S, Se) and related Janus MXY (M = Zr, Hf; X = S, Y = Se) have garnered significant attention due to their unique optoelectronic properties. To further explore their potential in flexible photonics, their mechanical, band dispersion, and optical dielectric properties using orbital hybrid theory are investigated. The results reveal that the out‐of‐plane linear compression resistance of these materials is considerably lower than their in‐plane resistance, primarily because van der Waals interactions are much weaker compared to ionic bond interactions. This characteristic makes them less susceptible to external pressure and torsional forces, positioning them as promising candidates for flexible optoelectronic devices. Furthermore, the presence of multiple energy bands at the same momentum state suggests a tendency toward metal–insulator transitions. Notably, the materials exhibit a high photon flux, indicating robust photoelectric conversion capabilities, making them suitable for applications in photoelectric transducers. This study not only deepens the understanding of the optoelectronic and mechanical properties of IVB–VIA TMD materials, but also offers theoretical guidance for the development and application of flexible optoelectronic devices based on IVB‐VIA TMDs and related Janus materials.

Pollutant Dispersion of Aircraft Exhaust Gas during the Landing and Takeoff Cycle with Improved Gaussian Diffusion Model

Evaluating aviation emissions and examining the dispersion properties of contaminants are crucial for understanding atmospheric pollution. To assess the pollutant emissions and dispersion of aircraft during the landing and takeoff (LTO) cycle, and address air pollution surrounding the airport resulting from flight operations, this study evaluated emissions throughout the LTO phase based on Quick Access Recorder (QAR) data in conjunction with the first-order approximation method. An improved Gaussian diffusion model for mobile point sources was employed to examine the diffusion characteristics of contaminants. Additionally, CFD calculation outcomes for various exhaust velocities and wind speeds were utilized to validate the trustworthiness of the improved Gaussian model. The discussion also encompasses the influence of diffusion time, wind direction, wind speed, temperature gradient, and particle deposition on the concentration distribution of contaminants. The findings indicated that the Gaussian diffusion model aligned with the results of the CFD calculations. The diffusion distribution of contaminants around airports varies over time and is significantly influenced by atmospheric environmental factors, including wind direction, wind speed, and atmospheric stability. Specifically, a change in wind direction from 0° to 45° caused a shift of approximately 1000 m in the contaminant’s center. An increase in wind speed from 3 m/s to 5 m/s led to a decrease in concentration by about 15%. Furthermore, a transition in atmospheric stability from category ‘a’ (very unstable) to ‘f’ (very stable) resulted in a two-order-of-magnitude increase in contaminant concentrations.

Optimization of Rotational Hydrodynamic Cavitation Reactor Geometry

A Rotary-Pulsation Apparatus (RPA), also known in the literature as a Rotational Hydrodynamic Cavitation Reactor (RHCR), is a device which typically consists of a rotating mechanism that generates pulsations or vibrations within a fluid. This can be achieved through various means such as mechanical agitation, pneumatic pulses, or hydraulic forces. It is widely used in food, chemical, pharmaceutical, and microbiological industries to improve the mixing of different fluids, dispersion, pasteurization, and sterilization. In the present paper, a CFD study was conducted to develop and optimize the geometry of the RPA’s rotor and stator to induce cavitation in the fluid flow. The effect of cavitation has the potential to improve dispersion and emulsion properties and to significantly reduce operation pressure, in comparison to conventional mixing systems.

Functional and rheological investigations on hydrophilic nanoclay blended bitumen

Functional and rheological characteristics are two essential criteria for the success of any modifiers for the modification of bitumen. Recently, nanoclay has grabbed extensive attention as a key solution for enhancing the performance of bitumen. This study focuses on evaluating the dispersion, storage stability, high-temperature performance, and aging resistance potential properties of bitumen VG-30 modified with montmorillonite bentonite hydrophilic nanoclay (NC). Various proportions (0, 2, 4, 6, and 8% by weight of bitumen) of NC were blended with VG-30 using a high shear mixer (HSM). Various performance assessments, including kinematic viscosity by Brookfield Rotational Viscometer (BRV), multiple stress creep recovery (MSCR), high-temperature performance grade (PG), frequency sweep along with scanning electron microscopy (SEM) were conducted. SEM images and viscosity data analysis show that dispersion problem arises beyond 6% of NC addition while phase separation is in the acceptable range. Further, considerable increment in Superpave rutting parameter (G*/Sinδ) and recovery percentage (%R), and decrease in non-recoverable compliance (Jnr) was seen, resulted up to 30% improvement in rutting performance of the bitumen. Furthermore, the potential for aging resistivity resulted a significant drop in aging index (AI) values, suggesting that introducing NC to bitumen could significantly improve aging resistivity. Moreover, rheological approaches can be helpful to understand temperatures and frequency dependent aging behaviours of bitumen.

Mitoxantrone release from Fmoc-protected amino acids coated magnetic carbon nanotubes: Computational and experimental study for cancer treatment

Nanoparticles have a high potential for use as drug carrier systems in cancer treatment to reduce severe side effects, as in the treatment of many other diseases. Due to their unique properties, carbon-based nanoparticles such as carbon nanotubes (CNTs) are among the most frequently used nanoparticles in drug carrier systems. In this study, magnetic single-walled CNTs (mCNTs) were synthesized, characterized, coated and their ability to carry the anticancer drug mitoxantrone (MTO) was investigated using computational and experimental methods. First, the mCNT coating capabilities of Fmoc-protected amino acids, Fmoc-Cys(trt)-OH and Fmoc-Trp-OH were demonstrated by Raman spectroscopy, thermogravimetric analysis, and X-ray photoelectron spectroscopy. Then, full-atom molecular dynamics simulations of MTO-CNT complexes in explicit water were used to understand Fmoc-amino acid and MTO loading experiments at the molecular level. Binding free energies calculated by the Molecular Mechanics/Poisson-Boltzmann Surface Area method suggested MTO-CNT complex stability even at elevated temperatures up to 350 K that can be achieved due to external magnetic stimuli. Drug loading at pH 9 and releases at physiological (pH 7.4) and lysosomal pH (pH 5.5) were carried out for uncoated and coated mCNTs. The drug release and characterization results showed that coated mCNTs have pH-responsive drug release, enhanced dispersibility, and superparamagnetic properties so they promise to be beneficial for MTO delivery in cancer treatment. Cell viability results demonstrated that the mCNT-Fmoc-Cys samples had higher cell viability compared to the mCNT and mCNT-Fmoc-Trp groups.

Study on increasing polymer gel strength with Janus nanoparticles and its feasibility in profile control and water plugging

In formations subjected to prolonged flooding, dominant channels are formed in high permeability layers, thereby reducing the displacement efficiency in medium- and low-permeability layers. In this study, the Janus synthesis method was employed to produce Janus Nano-TiO2 with a particle size range of 60–120 nm and superior dispersion properties. These nanoparticles were subsequently combined with polyacrylamide to formulate a high-strength polymer nano-gel for water plugging applications. The successful synthesis of the material was confirmed through FTIR and TGA. Gelation experiments indicated that the gelation strength and time augmented significantly with the increased addition of Janus-T6. Conversely, an increase in temperature or salinity resulted in a reduction of both gelation strength and time. Rheological experiments demonstrated a decrease in polymer viscosity with rising shear rates or temperatures, revealing significant shear thinning behavior in the water-plugging agent solution. System viscosity increased with more Janus-T6. Flow experiments revealed decreasing resistance coefficients at higher permeabilities, while all cores exhibited plugging rates above 85%. Additionally, the breakthrough pressure continuously rose with the increased addition of Janus-T6. Ultimately, displacement experiments indicated a 22.83% increase in the recovery rate after employing PNG plugging followed by secondary water flooding, compared to primary water flooding alone.

A 3D wideband electromagnetic horn antenna applicator for biomedical applications

Abstract This paper proposes a new, compact, wideband 3D horn antenna for biomedical wireless applications such as cancer and tumor detection. In order to achieve the best penetration level, the antenna has been built and tuned to work in the low frequency range of 0.48–1.24 GHz, which can exhibit a high-resolution detection result. The proposed applicator is a double ridge horn antenna (DRHA). The layout and operation of the key needed components to assemble a wideband hyperthermia system are provided in this study. We assume a cylindrical human tissue phantom with wideband dispersive tissue properties, and simulation results are given. The resulting field maps are displayed in several planes to illustrate the energy localization process. The findings indicate that, in contrast to traditional narrowband systems, wideband operation may improve energy localization in deep tumor locations while eliminating hot spots. The suggested antenna was built and measured to verify the result.

Ionogels, Promising Exploration for Flexible Optically Transparent Tunable All‐Dielectric Electromagnetic Metamaterials

AbstractIonogels, as a novel class of environmentally friendly electronic materials, have received extensive attention. This study successfully prepared P(AM‐co‐AA) ionogel with optical transparency and flexibility via chemical polymerization. Experimental outcomes reveal that the dispersion of anions and cations within the ionogel is effectively controlled by the polymer network, resulting in distinct dispersive dielectric property, which is suitable for applications in electromagnetic metamaterials. Leveraging these properties, two distinct electromagnetic metamaterial devices are developed: An Ionogel‐based Broadband Absorber achieves over 90% absorption across 10.9–25.36 GHz, and An Ionogel‐based Frequency Selective Rasorber (FSR) transmits within 4.62–5.86 GHz, exhibiting minimal insertion loss −1.45 dB and achieves greater than 90% absorption from 13 to 17.8 GHz. High agreement between experimental results and simulations validates the feasibility of utilizing ionogel in electromagnetic metamaterial applications and introduces a novel paradigm and methodology for designing and fabricating flexible electromagnetic metamaterial devices.

Lubrication and antibacterial performance and mechanism of functionalized ionic liquids in glycerol media with different water contents

Glycerol lubricants face limitations in industrial applications due to their inadequate antimicrobial properties. In this study, a functionalized long-chain quaternary ammonium salt ionic liquid, BTA-16-BTA, was synthesized. The antimicrobial and tribological properties of BTA-16-BTA as a lubricant additive in glycerol media with different water contents were investigated. The results show that the antimicrobial performance of the glycerol medium is positively correlated with the amount of BTA-16-BTA added. At the optimal concentration of 1.5 % BTA-16-BTA dispersion, excellent friction-reducing, anti-wear, and extreme pressure properties were observed. The friction-reducing and anti-wear effects were further enhanced when 1 % water was added to the system. The liquid medium containing BTA-16-BTA can inhibit the growth of Escherichia coli, indicating that BTA-16-BTA possesses antimicrobial properties.

ORGANOPHILIC BENTONITES OF UKRAINE. 1. SCIENTIFIC PRINCIPLES OF PRODUCTION. THE MECHANISM OF ORGANOPHILIZATION OF THE SURFACE

In connection with the inevitable integration of Ukraine into the EU and the discovery of new deposits of high-quality bentonite clays in Ukraine, the issues of studying, developing and industrially producing organophilic bentonites — analogues of foreign trademarks Bentone, Geltone, Petrotone — are becoming especially relevant. Without structuring additives of such bentones, the normal functioning is impossible of the most important industries: automotive, paint and varnish, petrochemical, oil producing, rubber, foundry, mechanical engineering, cosmetics, etc. This work is intended for the first time in Ukraine to lay the scientific foundations for obtaining such materials based on local mineral raw materials. For this purpose, the adsorption of a number of cationic surfactants (quaternary alkylammonium salts) on 4 montmorillonites of bentonite deposits in Ukraine and its effect on the stability, electrosurface and rheological properties of mineral aqueous dispersions were studied. Based on the obtained X-ray data and the dependences of adsorption, z-potential and yield point of dispersions on the concentration of surfactants, the mechanism of surface organophilization was clarified and optimal conditions for modifying montmorillonites for obtaining structure-forming agents for organic media were determined. It was shown that montmorillonite from the Neporotovskoye deposit is the most promising for this purpose. Bibl. 48, Fig. 12, Tab. 6.

A highly sensitive Photothermal Immunochromatographic test strip for detection of aflatoxin B1 based on CoS@TA Nanospheres

A novel photothermal immunochromatographic test strip (PITS) with tannic acid (TA) modified cobalt sulfide (CoS) nanospheres (CoS@TA) as immuno-probe element was developed for the detection of aflatoxin B1 (AFB1). CoS nanospheres (CoS NPs) with excellent photothermal conversion efficiency (η = 47.5 %) was synthesized and skillfully chelated with TA to improve its dispersion, biocompatibility, and chromatographic properties. After modification, the CoS@TA coupled with monoclonal antibody (mAb) against AFB1 (CoS@TA-mAb) by simple physical adsorption. The CoS@TA based PITS achieved highly sensitive detection of AFB1 with the limit of detection in photothermal signal (photothermal-LOD) of 0.00503 μg/L, which was 19.88-fold higher than the LOD in visual signal (visual-LOD, 0.1 μg/L). The application of TA in the modification of CoS provided ideas to improve the properties of functional nanomaterials such as dispersion and biocompatibility, and the application of CoS@TA in PITS construction laid a methodological foundation for further improving the detection sensitivity of trace targets.

Enhancing the conductivity and dispersion properties of polyaniline using ethyl orange

In our research, we developed a novel one-step synthesis method for polyaniline (PANI) using the organic dye Ethyl Orange (EO). This method facilitated the formation of PANI nanorods and significantly enhanced their electrical conductivity, achieving up to 13.5 S cm−1. The structural interaction between EO and PANI was confirmed through Fourier-transform infrared (FTIR) and UV–visible (UV-Vis) spectroscopy. Notably, the inclusion of EO improved PANI's dispersion properties, resulting in a zeta potential of 34 mV in water and excellent dispersibility in various organic solvents. These attributes significantly enhance the application potential of PANI nanorods, especially in protective coatings. Electrochemical impedance spectroscopy (EIS) analysis revealed that EO-PANI/WPU coatings (0.5 wt% EO-PANI) exhibited exceptional electrochemical stability and corrosion resistance in a 3.5 wt% NaCl solution. Specifically, the initial impedance magnitude (Zf=0.01 Hz, 1010 ohms) of EO-PANI/WPU coatings was approximately two orders of magnitude higher than that of traditional WPU coatings (108 ohms). Over time, the EO-PANI coatings demonstrated higher phase angles and impedance, indicating superior electrochemical stability and protective performance.

Incorporation of Graphene Oxide Quantum Dots in Gradient Layers of Polyethersulphone Nanofiltration Membranes for Nitrate Rejection from Aqueous Solution.

Graphene oxide quantum dots (GOQDs) have been widely used to prepare nanofiltration membranes due to the merits of excellent dispersity, ultrasmall size, and unique properties related to graphene. In this study, we first prepared the polyethersulphone-based nanofiltration (PES-NF) membrane via an interfacial polymerization process using a piperazine and m-phenylenediamine mixed solution as the aqueous phase. Then GOQDs were incorporated into the top-down gradient structured layers (i.e., ultrathin layer, interlayer, and substrate membrane layer) of the nanofiltration membrane, and subsequently the effect of GOQD addition on the nitrate rejection was evaluated. Compared with the pristine PES-NF membrane without the incorporation of GOQDs, the fabricated NF membrane (GOQD/PES-NF-2) incorporating GOQDs at both the ultrathin layer and interlayer exhibits more remarkable performances (an acceptable permeation flux of 52.2 L m-1 h-1 and excellent nitrate rejection of 96.3% at 0.6 MPa), the permeation flux of this membrane increases by nearly 2.4 times, and its nitrate rejection also shows a slight enhancement (∼7.6%) compared with those of PES-NF. Remarkably, at the operating pressure much lower than that required by reverse osmosis membranes, the GOQD/PES-NF-2 membrane possesses an equivalent monovalent ion rejection to reverse osmosis membranes but a higher permeation flux. Furthermore, the result of a 7 day continuous stability test validates the excellent durability of the GOQD/PES-NF-2 membrane, and its antifouling and chlorine resistance performances also outperform those of the PES-NF membrane.

Measurement of dispersion properties in a short optical fiber for an efficient quantum frequency converter

Measurement of dispersion properties in a short optical fiber for an efficient quantum frequency converter