Continuous Phase Research Articles

Colloidal synthesis of two-dimensional nanocrystals by the polyol route.

The field of 2D nanomaterials is ever-growing with a myriad of synthetic advancements that have been used to obtain such materials. There are top-down, as well as bottom-up, fabrication methods for obtaining 2D nanomaterials; however, synthesis of 2D nanomaterials from solution offers a simple scalable way to control size, shape, and surface. This review outlines the recent advances in colloidal polyol synthesis of 2D nanomaterials and provides perspectives on the similarities and differences in various syntheses. Various materials classes are presented and discussed, including metals, oxides, chalcogenides, and halides, that can be synthesized as 2D nanomaterials via a polyol process. Throughout the literature, polyol media is demonstrated to be versatile not only as a solvent and reducing agent for metal precursors but also as a binding and shape-directing agent for many 2D nanomaterials. Polyols also offer the ability to dissolve various surfactants and additives that can further control the morphology and composition of various nanomaterials. In this review, we outline the various 2D materials that have been realized via the solution polyol route.

Food-grade emulsion gels and oleogels prepared by all-natural dual nanofibril system from citrus fiber and glycyrrhizic acid

The natural dual nanofibril system consisting of the rigid semicrystalline nanofibrils disintegrated from citrus fiber (CF) and soft semiflexible nanofibrils self-assembled from glycyrrhizic acid (GA) has been recently shown to be effective structural building blocks for fabrication of emulsion gels. In this work, the effect of the CF nanofibrils prepared by different mechanical disintegration approaches (i.e., high-pressure microfluidization and hydrodynamic cavitation) on the interfibrillar CF-GA interactions and the subsequent formation and properties of emulsion gels were investigated, with the aim of evaluating the potential of the dual nanofibril-stabilized emulsion gels as templates for synthesizing all-natural edible oleogels. The obtained results demonstrate that compared to the cavitation, the high-pressure microfluidization is more capable of generating CF nanofibrils with a higher degree of nanofibrillation and individualization, thus forming a denser CF-GA gel network with higher viscoelasticity and structural stability due to the stronger multiple intrafibrillar and interfibrillar interactions. The emulsion gels stabilized by the dual nanofibril system are demonstrated to be an efficient template to fabricate solid-like oleogels, and the structural properties of the oleogels can be well tuned by the mechanical disintegration of CF and the GA nanofibril concentration. The prepared oleogels possess high oil loading capacity, dense network microstructure, superior rheological and large deformation compression performances, and satisfactory thermal stability, which is attributed to the compact and ordered CF-GA dual nanofibrillar network via multiple hydrogen-bonding interactions in the continuous phase as well as at the droplet surface. This study highlights the unique use of all-natural dual nanofibrils to develop oil structured soft materials for sustainable applications.

Development of an ecofriendly dispersive liquid phase microextraction method for the preconcentration of β-blockers in waste and environmental samples

Effective sample preparation is crucial in instrumental analysis to enhance selectivity, sensitivity, and instrument protection. The current trend of miniaturization in liquid–liquid extraction aims to conserve solvents and promote environmental sustainability. Liquid phase microextraction, requiring only small volumes of the extractant, facilitates sample preconcentration without the need for evaporation and reconstitution. This study presents the development of an eco-friendly ispersive liquid–liquid microextraction method employing solidification of floating organic droplets for the determination of five β-blocker drugs in waste and environmental samples. The optimization of key variables affecting extraction efficiency, including extractant type and volume, pH of the diluent, dispersion technique, vortexing, and centrifugation time, was carried out. Optimal results were achieved using 50 μL of dodecanol as the extractant, 1 min of vortexing for dispersion, followed by 2 min of centrifugation for phase separation. The sample was then subjected to a 5 min cooling in an ice bath to solidify the dodecanol before UHPLC/UV analysis. The method yielded enrichment factors within the range of 23–55. The applicability of this approach was demonstrated in laboratory waste and environmental water analysis, with acceptable % recoveries ranging from 98.07 % to 101.83 % and %RSD below 1.96. Moreover, we assessed the method’s performance and greenness with ComplexGAPI, BAGI, and carbon footprint. This method not only provides high efficiency and reliability but also aligns with the principles of sustainablility.

Colloidally synthesized Cu3VS4 nanocrystals as a long cycling anode material for sodium-ion batteries

We report on the colloidal synthesis of Cu3VS4 nanocrystals as an earth abundant anode material for sodium-ion battery applications. The nanocrystals were structurally characterized prior to testing in half-cells, where they displayed excellent cycling stability up to 1000 cycles, demonstrating the potential of colloidally synthesised materials for sustainable battery applications.

Influence of carbon template and ultrasound irradiation on combustion design of nanostructured calcium manganese oxides used in biodiesel production

Biodiesel, derived from renewable biomass, serves as a sustainable alternative to diesel produced from fossil fuels. This study explores the use of nanostructured MgO/Ca2Mn3O8 catalysts for biodiesel production through transesterification. Ca2Mn3O8 was synthesized as a support catalyst via combustion synthesis, employing carbon templates to control pore size. MgO was impregnated as the active phase using ultrasonic irradiation to enhance particle dispersion. Various characterization techniques, including XRD, FESEM, AFM, TEM, EDX, BET-BJH, and TPD-CO2, were utilized to analyse morphology, porosity, basicity, and active phase dispersion. The use of carbon templates increased pore diameters compared to catalysts without templates, while ultrasonic irradiation improved MgO dispersion. The MgO/Ca2Mn3O8 catalyst with a 10 wt% carbon template and ultrasonic irradiation achieved a maximum conversion rate of 95.5%. Its mesoporous structure, resembling a sponge, facilitated triglyceride diffusion. Stability tests indicated a 90% conversion rate after five reuses. The nanostructured MgO/Ca2Mn3O8 catalyst, with its tailored porosity and structure, demonstrated excellent performance in biodiesel production. Systematically adjusting support porosity and active site dispersion provides a viable approach for designing effective heterogeneous catalysts.

Modification of Silica with Sucrose and Ammonium Fluoride Agents: A Facile Route to Prepare Supports of Iridium Catalysts for Hydrogenation Reaction

Mesoporous silica materials were synthesized using inexpensive and environmentally friendly sucrose as a porogeneous agent. It was found that the presence of sucrose and the products of its chemical transformation during synthesis (e.g., furfural polymer) significantly affected the structure of the obtained porous silica. The influence of synthesis conditions (pH, temperature, time) on the textural properties of the final materials was determined. Samples obtained in an acidic medium, at pH = 1, and treated at room temperature, yielded products with a large surface area and a narrow pore size distribution in the range of 2–5 nm, while the synthesis at pH = 8 allowed for the formation of mesoporous systems with pores in the range of 14–20 nm. To generate acidity, the silicas were modified with an ammonium fluoride solution and then used as supports for iridium catalysts in a hydrogenation reaction, with toluene as a model hydrocarbon. The influence of parameters such as specific surface area, support acidity, and iridium dispersion on catalytic activity was determined. It was shown that modification with sucrose improved the porous structure, and NH4F modification generated acidity. These parameters favored better reducibility and dispersion of the active phase, resulting in higher activity of the catalysts in the studied hydrogenation reaction.

Preparation of deep eutectic solvent modified magnetic graphene oxide/metal organic framework nanocomposites for the extraction of three estrogens in cosmetics.

Anovel magnetic dispersive solid phase extraction (MDSPE) procedure based on the deep eutectic solvent (DES) modified magnetic graphene oxide/metal organic frameworks nanocomposites (MGO@ZIF-8@DES) was established and used for the efficient enrichment of estradiol, estrone, and diethylstilbestrol in cosmetics (toner, lotion, and cream) for the first time. Then, thethree estrogens were separated and determined by UHPLC-UV analysis method. In order to study the features and morphology of the synthesized adsorbents, various techniques such as FT-IR, SEM, and VSM measurements were executed. The MGO@ZIF-8@DES nanocomposites combine the advantages of high adsorption capacity, adequate stability in aqueous solution, and convenient separation from the sample solution. To achieve high extraction recoveries, the Box-Behnken design and single factor experiment were applied in the experimental design. Under the optimum conditions, the method detection limits for three estrogens were 20-30ngg-1. This approach showed a good correlation coefficient (r more than 0.9998) and reasonable linearity in the range 70-10000ngg-1. The relative standard deviations for intra-day and inter-day were beneath 7.5% and 8.9%, respectively. The developed MDSPE-UHPLC-UV method was successfully used to determine three estrogens in cosmetics, and acceptable recoveries in the intervals of 83.5-95.9% were obtained. Finally, three estrogens were not detected in some cosmetic samples. In addition, the Complex GAPI tool was used to evaluate the greenness of the developed pretreatment method. The developed MDSPE-UHPLC-UV method is sensitive, accurate, rapid, and eco-friendly, which provides a promising strategy for determining hormones in different complex samples.

Firing rate adaptation affords place cell theta sweeps, phase precession, and procession

Hippocampal place cells in freely moving rodents display both theta phase precession and procession, which is thought to play important roles in cognition, but the neural mechanism for producing theta phase shift remains largely unknown. Here, we show that firing rate adaptation within a continuous attractor neural network causes the neural activity bump to oscillate around the external input, resembling theta sweeps of decoded position during locomotion. These forward and backward sweeps naturally account for theta phase precession and procession of individual neurons, respectively. By tuning the adaptation strength, our model explains the difference between ‘bimodal cells’ showing interleaved phase precession and procession, and ‘unimodal cells’ in which phase precession predominates. Our model also explains the constant cycling of theta sweeps along different arms in a T-maze environment, the speed modulation of place cells’ firing frequency, and the continued phase shift after transient silencing of the hippocampus. We hope that this study will aid an understanding of the neural mechanism supporting theta phase coding in the brain.

Firing rate adaptation affords place cell theta sweeps, phase precession, and procession.

Hippocampal place cells in freely moving rodents display both theta phase precession and procession, which is thought to play important roles in cognition, but the neural mechanism for producing theta phase shift remains largely unknown. Here, we show that firing rate adaptation within a continuous attractor neural network causes the neural activity bump to oscillate around the external input, resembling theta sweeps of decoded position during locomotion. These forward and backward sweeps naturally account for theta phase precession and procession of individual neurons, respectively. By tuning the adaptation strength, our model explains the difference between 'bimodal cells' showing interleaved phase precession and procession, and 'unimodal cells' in which phase precession predominates. Our model also explains the constant cycling of theta sweeps along different arms in a T-maze environment, the speed modulation of place cells' firing frequency, and the continued phase shift after transient silencing of the hippocampus. We hope that this study will aid an understanding of the neural mechanism supporting theta phase coding in the brain.

Thermal, Morphological, Mechanical, and Biodegradation Properties of Poly(L-lactide)-b-poly(ethylene glycol)-b-poly(L-lactide)/High-Density Polyethylene Blends

Polymer blends of poly(L-lactide)-b-poly(ethylene glycol)-b-poly(L-lactide) (PLLA-PEG-PLLA) and high-density polyethylene (HDPE) with different blend ratios were prepared by a melt blending method. The thermal, morphological, mechanical, opacity, and biodegradation properties of the PLLA-PEG-PLLA/HDPE blends were investigated and compared to the PLLA/HDPE blends. The blending of HDPE improved the crystallization ability and thermal stability of the PLLA-PEG-PLLA; however, these properties were not improved for the PLLA. The morphology of the blended films showed that the PLLA-PEG-PLLA/HDPE blends had smaller dispersed phases compared to the PLLA/HDPE blends. The PLLA-PEG-PLLA/HDPE blends exhibited higher flexibility, lower opacity, and faster biodegradation and bioerosion in soil than the PLLA/HDPE blends. Therefore, these PLLA-PEG-PLLA/HDPE blends have a good potential for use as flexible and partially biodegradable materials.

Foam coarsening in a yield stress fluid.

Foams coarsen because of pressure differences between bubbles of different sizes. We study the coarsening of quasi-2D foams made from model yield stress fluids: concentrated oil-in-water emulsions. We show that increasing the yield stress of the foamed emulsion continuous phase leads to both slower coarsening and irreversible structural change. The impact of the continuous phase rheology is stronger when the foamed emulsion is wetter or more confined. The bubble growth and organisation both become highly heterogeneous with an excess of small bubbles. We present a model that rationalises the impact of these three parameters by taking into account a resisting pressure required to displace the yield stress fluid around the bubbles.

Zeolitic imidazolate framework-8 as a high-affinity adsorbent for dispersive solid-phase extraction in the analysis of plant growth regulators in fruits.

Facile and sensitive determination of plant growth regulators (PGRs) in food samples is crucial but still poses a significant challenge. In this study, to enhance the sensitivity of the HPLC-DAD method for PGR detection, a dispersive solid phase extraction (d-SPE) method using zeolitic imidazolate framework-8 (ZIF-8) as the highly effective adsorbent is developed. ZIF-8 nanoparticles are formed through the coordination of Zn2+ with 2-methylimidazole. Due to its high porosity, large surface area, abundant π electronics and nitrogen electronics, ZIF-8 exhibits a strong affinity to PGRs due to the synergistic effects of π-π interaction, van der Waals force, H-bond, and surface effect. Under the optimal d-SPE conditions, the sensitivity of the method is significantly enhanced with outstanding performances, including a wide range of linearity (2.0-200 ng g-1) with high correlation coefficients (R ≥ 0.9989), low limits of detection (LODs, 0.9-8.0 ng g-1 for all PGRs), satisfactory precision (intra-day RSDs ≤ 3.3%, inter-day RSDs ≤ 4.2%), and high accuracy (recovery: 86.6-101.5%). The developed method was successfully applied to quantitatively detect 9 PGRs in fruit samples, yielding satisfactory results. This d-SPE-HPLC-DAD method, characterized by high sensitivity, simplicity, efficiency, ease of practice and cost-effectiveness for PGR detection, shows potential for detecting PGRs in other complex samples and provides a strategy for designing target-affinity adsorbents.

Reconfigurable terahertz stretchable spoof surface plasmon polariton waveguide for filter applications

In this paper, a reconfigurable terahertz spoof surface plasmon polariton (SPP) waveguide is proposed on a stretchable polydimethylsiloxane (PDMS) substrate. The SPP unit incorporates a folded stub and a conventional V-shaped SPP groove, enhancing the equivalent capacitance and consequently reducing the cutoff frequency. The cutoff frequency of the proposed SPP unit can be tuned from 285 to 390 GHz with stretchable factors of 1 ∼ 1.2, thereby achieving a reconfigurable operating frequency. The horizontal dimension of the proposed SPP waveguide can be tuned from 6.36 mm to 7.12 mm. Moreover, the SPP waveguide can generate transmission continuous phase shifts of −30°, −60°, −90°, and −120° with stretchable factors of 1.05, 1.1, 1.15, and 1.2, respectively, in the 150–190 GHz band. Applying the characteristic mode theory, a split ring resonator (SRR) functions as the equivalent magnetic dipole, which remains unaffected by stretchable deformation. When loaded with four SRR cells, the proposed SPP waveguide generates a tunable passband with a fixed notched frequency at 193 GHz. Another stretchable SPP resonator serves as the equivalent electric dipole, operating from 284 GHz to 256 GHz in 1∼1.2 stretchable states. By loading three SPP resonators, the SPP waveguide can achieve a passband for the initial state, and a tunable stopband is introduced under 1.1 and 1.2 stretchable states. The proposed stretchable method provides a promising solution for planar terahertz components and systems with reconfigurable functions.

Droplet Microfluidic Method for Estimating the Dynamic Interfacial Tension of Ion-Crosslinked Sodium Alginate Microspheres.

The research focuses on optimizing the production of hydrogel microspheres using droplet microfluidics for pharmaceutical and bioengineering applications. A semiempirical method has been developed to predict the dynamic interfacial tension at the interface of ion-cross-linked sodium alginate microsphere-sunflower oil modified with glacial acetic acid and Tween 80 surfactant. These microspheres are produced in a small-scale coaxial device that is manufactured using affordable DLP/LCD 3D printing technology with a transparent photopolymer. The method was tested to design the minireactor in the device, which allows for the production of fully cross-linked microspheres that are ready for use at the output of the reactor without additional cross-linking steps in the microsphere collector. The mathematical expression for estimating the interfacial tension at the moment of formation of a hydrogel microsphere includes the Reynolds number for a two-phase liquid, the Ohnesorge number, and the surface tension at the liquid-air interface for continuous medium flow (modified oil). The reliability of the prediction is confirmed for continuous medium and dispersed phase flow rates of 0.8-3.2 and 0.01-0.08 mL/min, respectively. The evolution of the interfacial tension from the moment the microspheres formed and the estimated ultimate interfacial tension in a cross-linked hydrogel-modified oil system contributed to the reliable determination of the linear size of a minireactor. The ultimate interfacial tension of 76.5 ± 0.3 mN/m was determined using the Young-Laplace equation, which is based on measuring the surface free energy of the hydrogel as soft matter using the Owens-Wendt method. Additionally, the equilibrium static contact angle of the fully cross-linked hydrogel surface wetted with oil is measured using the sessile drop method. From a practical perspective, a method for optimizing and streamlining the high-tech manufacturing of cross-linked polymer microspheres and mini- and microchannel devices for use in bioengineering and pharmaceutical applications is suggested.

Water-in-oil microemulsions with greener oil solvents as sustainable nanoreactors of biopolymer nanoparticles

Microemulsions have been widely used in multidisciplinary fields, yet reverse water-in-oil microemulsions are traditionally dispersed in petroleum-based oil solvents. For greener approaches, it should be also feasible to use less toxic, bio-based hydrocarbon solvents as continuous oil phase. Herein, reverse microemulsions in different alkanes, middle-chain alkanols, middle-chain esters or combinations of nonpolar solvent with alkanol are compared, using Aerosol-OT as common surfactant. As model of bio-based solvents, ethyl caprylate, isoamyl acetate and isoamyl alcohol are proposed as a more sustainable approach of oil solvents. Various characterization techniques were used to compare the properties and stability of reverse microemulsions for the different oil phase compositions, ranging from ternary phase diagrams to conductometry and turbidity titrations, micro-Differential Scanning Calorimetry and cryo-Scanning Electron Microscopy. As sustainable application, these microemulsions in bio-based solvents were proved suitable as template phase for the synthesis of cross-linked chitosan nanoparticles. The sizes of the resulting biopolymer nanoparticles were characterized by Dynamic Light Scattering and Atomic Force Microscopy, so that the effect of different crosslinkers and different the oil phase compositions was also compared. Thus, the use bio-based alkyl esters can provide similar microemulsion properties as the conventional alkanes, especially when using a combination of nonpolar solvents with alkanols.

Catalytic Biomass Transformation to Hydrocarbons under Supercritical Conditions over Nickel Supported on Schungite

Liquid fuel production from biomass-derived molecules has received great attention due to the diminished fossil fuel reserves, growing energy demand, and the necessity of CO2 emission reduction. The deoxygenation of oils and fatty acids is a promising process to obtain “green” diesel. Herein, we report the results of the study of the deoxygenation of stearic acid to alkanes as a model reaction. Series of Ni-supported on schungite were obtained by precipitation in subcritical water (hydrothermal deposition) and for comparison via wetness impregnation followed, in both cases, by calcination at 500 °C and a reduction in H2 at 300 °C. The catalyst obtained via hydrothermal synthesis showed a three-fold higher specific surface area with a four-fold higher active phase dispersion compared to the catalysts synthesized via conventional impregnation. The catalysts were tested in stearic acid deoxygenation in supercritical n-hexane as the solvent. Under optimized process conditions (temperature of 280 °C, hydrogen partial pressure of 1.5 MPa, and 13.2 mol of stearic acid per mol of Ni), a close to 100% yield of C10–C18 alkanes, containing over 70 wt.% of targeted n-heptadecane, was obtained after 60 min of reaction.

Propagation of Freezing in Supercooled Water-In-Antifreeze-Oil Emulsions.

Water-in-oil (W/O) emulsions, in which water droplets are separated by a continuous oil phase, are frequently used in food and cosmetic products. However, the freezing kinetics of W/O emulsions are not yet well understood. In this study, we find that freezing propagates to individual water droplets that are in direct contact with other frozen droplets. When droplets are not in contact, freezing does not propagate even when the emulsions are cooled to -18 °C. Two measures of the perimeter and the area of the frozen droplets in emulsions are defined to evaluate the propagation velocity of freezing using a simple mathematical model. The velocity is highest (4 × 102 μm s-1) at -18 °C, which is lower than the freezing velocity of individual droplets at the same temperature (1.2 × 103 μm s-1). Water-oil interfaces, or a thin layer of oil between droplets, act as a barrier to propagation of freezing. The dependence of the freezing velocity on the degree of supercooling is consistent with results from a previous study; however, the absolute value of the freezing velocity is smaller by a factor of 102. The propagation velocity also depends on the degree of supercooling but its dependence is different from that of the freezing velocity. Features of freezing of water droplets immersed in antifreeze oil are discussed.

Modulational instability, modulated wave, and optical solitons for a generalized highly dispersive cubic-quintic-septic-nonic medium with self-frequency shift and self-steepening nonlinear terms

Abstract In this research, we delve into a generalized highly dispersive (HD) nonlinear Schrödinger equation, enriched with cubic-quintic-septic-nonic (CQSN) nonlinearities. The core of our investigation revolves around the perturbation of plane waves, aiming to understand their stability characteristics in such a complex medium. We investigate the influence of various factors such as the amplitude of the plane wave, perturbed wave number, nonic nonlinear term, and fourth-order dispersion term. Our findings indicate that increasing the amplitude of the plane wave widens the modulation instability (MI) bands and amplifies the MI growth rate. In contrast, increasing the nonic nonlinear term has opposing effects, narrowing the MI bands and diminishing the amplitude of the MI growth rate. Increasing the fourth-order dispersion term does not affect the amplitude of the MI growth rate but narrows the MI bands. The observed pattern of increasing and then decreasing MI intensity with rising K can be attributed to the complex interplay among phase matching conditions, dispersion effects, and nonlinear saturation. Initially, higher K enhances phase matching and boosts MI growth. However, as K increases further, the combined influence of dispersion and nonlinear effects can diminish the effectiveness of phase matching, resulting in a reduction in MI intensity. A significant portion of our work is dedicated to identifying and analyzing modulated rational, polynomial Jacobi elliptic function solutions, and the emergence of optical solitons within this framework. These findings provide new insights into the nonlinear dynamics underpinning the generalized HDNLSE, enriched with CQSN nonlinearities, offering valuable contributions to the theoretical understanding of such phenomena.

Enhancing foamability and flame‐retardancy of polylactic acid bead foams through inter‐beads bulk polymerization and continuous phase dispersion of LDHs

AbstractPoly (lactic acid) (PLA) bead foam has a promising application because of its renewable and naturally degradable nature. However, its processing is greatly limited by inherent shortcomings such as the complex polycrystals‐inducing strategy. Herein, we developed a strategy of bulk polymerization reaction of polyvinyl acetate (PVAc) to sinter PLA beads to prepare EPLA foams accompanied by supercritical CO2 foaming technology. In order to enhance the sintering behavior and flame‐retardancy of EPLA foams, two‐dimensional nanolayered double hydroxides (LDHs) were introduced and dispersed in the continuous phase of the sintering layers. The formation of unique dispersion of LDHs and sintering structure of PVAc generated substantial increase in the crystallinity, melt elasticity, and sintering strength of EPLA foams, which facilitated the growth and stabilization of cells. Thus, the cell‐density and expansion ratio could be increased to 8.62 × 106 cell/cm3 to 9.31‐fold, respectively. Moreover, the mechanical properties of the EPLA foams were improved. The tensile strength and the compression strength increased to 2.96 and 62.5 MPa. Additionally, with adding 7 wt.% LDH, the EPLA foam reached UL‐94 V‐0 rating with high limiting oxygen index value of 29.1% and char residue of 20.4%. This study provides a novel strategy for the preparation of flame‐retardant EPLA foams with low density, three dimensional complex shapes, as well as excellent mechanical properties.

Influence of Aluminum Content and Agglomerates Initial Velocity on Erosion in Solid Rocket Motor

Abstract Despite the aluminized propellants offering a high specific impulse, the challenge of nozzle erosion adversely impacts the rocket's performance and its potential for reusability. This study presents a numerical model aiming to predict the mechanical erosion of the propulsion chamber nozzle. The model employs an Eulerian/Lagrangian approach to simulate the complexity of the flow field within the rocket combustion chamber and the interactions between the continuous phase and particles. The model also includes a simplified representation of the aluminum particle combustion process, besides the consideration of secondary breakup phenomena in liquid droplets. Experimental and numerical data from the literature were used to validate the numerical model. Subsequently, the model was utilized to explore the impacts of increasing propellant aluminum content and varying particles' injection velocities on the nozzle mechanical erosion. The outcomes indicated that higher aluminum content leads to a 4-10% increase in nozzle erosion compared to the 15% content case. Furthermore, the aluminum particles tend not to fully burn within the combustion chamber and contribute to nozzle erosion. Lastly, particles with higher initial velocity at the inlet of the combustion chamber increase the nozzle mechanical erosion despite the observed decrease in incident mass flux.