Direct Contact Membrane Distillation Performance Research Articles

Desalination Performance Evaluation of hBN@UiO‐66 MOF Incorporated Hollow Fiber Membrane using Membrane Distillation

AbstractIn the present study, the polyvinylidene fluoride (PVDF) modified hollow fiber (HF) membranes have been synthesized by dry‐jet wet phase inversion technique for desalination via direct contact membrane distillation (DCMD). UiO‐66 metal‐Organic framework (MOF) and surface‐modified UiO‐66 with h‐BN nanomaterial have been incorporated with PVDF‐HF membrane. The various analytical methods like FE‐SEM, FTIR, PXRD, TGA, tensile strength, were used to characterize prepared MOF and HF membranes. It was observed from DCMD results that the h‐BN@UiO‐66/PVDF (M3) HF membrane gives higher flux than UiO‐66/PVDF (M2) and pure PVDF (M1) membrane. In the present investigation, response surface methodology (RSM) by box‐behnken design (BBD) was used to optimize the DCMD system and evaluate the behavior of operating parameters such as feed temperature, feed concentration, and feed flow rate. The optimum operating values of feed temperature, feed flow rate, and feed concentration were found as 65 °C, 1 LPM, and 1.5 wt.%, respectively. Under optimum conditions, the M3 HF membrane gives the highest flux of 26.78 L/m2 ⋅ h compared to M2 and M1 membranes. During DCMD, salt rejection is almost greater than 99.8 % for all prepared membranes. Other salts like potassium chloride (KCl), Magnisium Sulphate (MgSO4), and calcium sulphate (CaSO4) are also used to check salt rejection of all membranes at optimum operating conditions. Moreover, the M3 membrane exhibits stable permeate flux and high salt rejection (>99.9 %) at optimized process parameters over 80 h running. Overall, the present study provides the positive effects of h‐BN nanoparticles and UiO‐66 MOF on HF membrane to improve performance in DCMD.

Investigation of direct contact membrane distillation (DCMD) performance using CFD and machine learning approaches

Direct Contact Membrane Distillation (DCMD) is emerging as an effective method for water desalination, known for its efficiency and adaptability. This study delves into the performance of DCMD by integrating two powerful analytical tools: Computational Fluid Dynamics (CFD) and Artificial Neural Networks (ANN). The research thoroughly examines the impact of various factors, such as inlet temperatures, velocities, channel heights, salt concentration, and membrane characteristics, on the process's efficiency, specifically calculating the water vapor flux. A rigorous validation of the CFD model aligns well with established studies, ensuring reliability. Subsequently, over 1000 data points reflecting variations in input factors are utilized to train and validate the ANN. The training phase demonstrated high accuracy, with near-zero mean squared errors and R2 values close to one, indicating a strong predictive capability. Further analysis post-ANN training shed light on key relationships: higher membrane porosity boosts water vapor flux, whereas thicker membranes reduce it. Additionally, it was detailed how salt concentration, channel dimensions, inlet temperatures, and velocities significantly influence the distillation process. Finally, a mathematical model was proposed for water vapor flux as a function of key input factors. The results highlighted that salt mole fraction and hot water inlet temperature have the most effect on the water vapor flux. This comprehensive investigation contributes to the understanding of DCMD and emphasizes the potential of combining CFD and ANN for optimizing and innovating water desalination technology.

Evaluating the efficiency of modified hydrophobic PVDF membrane for the removal of PFOA substances from water by direct contact membrane distillation

This study addresses the global issue of the contamination of water resources by per- and poly-fluoroalkyl substances (PFAS). PFAS are notoriously difficult to remove due to their resilient alkyl-fluorinated chains. We examined the potential of hydrophobic PVDF membranes in direct contact membrane distillation (DCMD) to eliminate perfluorooctanoic acid (PFOA) from Water. For desalination, both commercial and custom-made PVDF membranes exhibited a permeate flux of approximately 13 LMH, with salt rejections of 98.39 % and 99.95 %, respectively. In the case of PFOA removal, the fabricated PVDF membrane outperformed its commercial counterpart. It boasted an initial permeate flux of 16 LMH and a PFAS rejection of 95.8 %, compared to the commercial membrane's 13 LMH and 67.31 %. Furthermore, the custom membrane exhibited superior resistance to fouling, experiencing less flux decline. Employing response surface methodology (RSM), we identified the optimal combination of feed concentration (30 ppm), (60 °C), and flow rate (1.5 LPM) to yield a flux of 9 LMH and a PFOA rejection of 95.41 %. Feed temperature emerged as the most influential factor in DCMD performance. This study offers a novel approach to concentrating and removing emerging contaminants from wastewater and highlights the efficacy of tailored membrane technology in addressing pressing environmental challenges.

Clean-In-Place (CIP) wastewater management using nanofiltration (NF)-forward osmosis (FO)-direct contact membrane distillation (DCMD): Effects of draw salt

A substantial amount of water is being used during Clean-in-Place (CIP) operation, and is transformed into wastewater that can cause eutrophication to the nearby ecosystem. The present study proposed the Nanofiltration (NF) – Forward Osmosis (FO) – Direct Contact Membrane Distillation (DCMD) to recover the cleaning agents and reclaim freshwater from the model CIP wastewater. NF steps were suggested as prefiltration steps to remove organic compounds from the CIP wastewater. NF steps reduced the lactose and protein contents by 100 % and 95.6 %, respectively. The permeates from NF steps were further managed by the integrated FO-DCMD system. Several draw salts such as NaCl, KCl, MgCl2, and CaCl2 were compared to investigate the influence on FO and DCMD performance. It was found that monovalent salts (NaCl and KCl) outperformed the divalent salts (MgCl2 and CaCl2) in terms of water flux for both FO and DCMD. This can be attributed to the lower viscosity and higher mass transfer coefficient. In addition, the replenishment costs of each salt were evaluated since salts loss occurred during FO and DCMD operation. The cost evaluation revealed that NaCl is most the cheapest salts per reclaimed water. All of this observation indicates that NaCl is preferred in terms of water flux and replenishment cost. The NF permeate kept concentrated using the integrated FO-DCMD or single FO with 2 M of NaCl. Compared to a single FO that showed a consistent decline in draw solution concentration, FO-DCMD could maintain the concentration of the draw solution. Despite the constant concentration, flux decline of FO was observed due to fouling formation caused by the high-temperature operation. However, the FO-DCMD could accomplish the recovery of pure water. Finally, the cleaning agents recovered by the NF-FO-DCMD showed the cleaning efficacy comparable to the fresh NaOH. These results suggest the potential of the proposed system to manage the CIP wastewater.

Behavior and removal of microplastics during desalination in a lab-scale direct contact membrane distillation system

The behavior of microplastic particles (MPPs) is explored in a lab-scale direct contact membrane distillation (DCMD) system used to produce drinking water from seawater, while also analyzing the impact of their presence on the process performance. Commercial MPPs (LDPE, PET and uPVC) were first studied by temperature stress (TS) tests (using amber bottles) to mimic the exposure to the high temperatures commonly used in DCMD (ca. 80 °C), which led to uPVC being selected to be tested under different loads and aging degrees in the DCMD system. By analyzing uPVC MPPs samples before and after the TS and DCMD experiments by ATR-FTIR, UV–Visible spectroscopy and SEM, it was concluded that minor aging is expected to occur. High loads (>0.1 g L−1) of uPVC MPPs decreased the DCMD performance in terms of permeate flux (from 32.8 ± 0.3 with filtered seawater to 28.7 ± 0.3 kg m−2 h−1 with a load of 0.2 g L−1), although no signs of inferior treated water quality were found based on the conductivity and salinity results. The removal of MPPs (size > 1.2 μm) in DCMD applications with seawater was analyzed by μRaman, with all the results suggesting very high removal efficiencies (≥99 %).

A numerical analysis of the electromagnetic field effect on direct contact membrane distillation performance

Using an advanced CFD model, this study attempts to determine how electromagnetic field (EMF) affects the performance of the direct contact membrane distillation (DCMD) process. The influence of electromagnetic fields (EMF) on the permeate flow, evaporation efficiency (EE), and temperature polarization coefficient (TPC) of the DCMD process are studied using a thorough theoretical model linked with a CFD model. Experiments conducted in-house with and without the EMF influence are used to verify the CFD model. High magnetic potency propagates the turbulence in the feed channel, hence boosting the driving force and transport phenomena for vapor transport to the permeate side. Permeate flux increased by 30%, and EE increased by 15% when the magnetic field strength was raised from 0 to 0.5 T, particularly at a lower intake feed velocity (0.02 m/s) and temperature of 333.05 K. In contrast, with the same magnetic potency (0.5 T) at a higher velocity at an input feed temperature, there is less improvement in EE (5%) and permeate flux (12%) due to the elevated turbulence intensity at high feed velocity. This research contributes to studies aimed at elucidating how electromagnetic fields affect separation processes such as MD, opening the door for more tuning and use of the fascinating phenomenon.

Hydrophobic modification of a PVDF hollow fiber membrane by plasma activation and silane grafting for membrane distillation.

Polyvinylidene fluoride (PVDF) hollow fibers were hydrophobically modified using a simple and scalable method of plasma activation and silane grafting. The effects of plasma gas, applied voltage, activation time, silane type, and concentration were investigated according to the membrane hydrophobicity and direct contact membrane distillation (DCMD) performance. Two kinds of silane were used, including methyl trichloroalkyl silane (MTCS) and 1H,1H,2H,2H-perfluorooctane trichlorosilane silanes (PTCS). The membranes were characterized by techniques such as Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and contact angle. The contact angle of the pristine membrane was 88°, which increased to 112°-116° after modification. Meanwhile, the pore size and porosity decreased. In DCMD, the maximum rejection reached 99.95% by the MTCS-grafted membrane, while the flux decreased by 35% and 65% for the MTCS- and PTCS-grafted membranes, respectively. Treating humic acid-contained solution, the modified membrane showed steadier water flux and higher salt rejection than the pristine membrane, and 100% flux recovery was achieved by simple water flushing. This two-step method of plasma activation and silane grafting is very simple and effective to improve the hydrophobicity and DCMD performance of PVDF hollow fibers. However, further study on improving the water flux should be carried out.

Assessment of the DCMD performances of poly(vinylidene difluoride) vapor-induced phase separation membranes with adjusted wettability via formation process parameter manipulation

Poly(vinylidene difluoride) (PVDF) membranes for direct contact membrane distillation (DCMD) are commonly modified to decrease their wettability by water. Yet, the vapor-induced phase separation (VIPS) process may be a suitable alternative to avoid complex and expensive modifications. Superhydrophobic membranes with a water contact angle >152° were prepared in one single step by adjusting the polymer concentration, dissolution temperature, relative humidity, and exposure time to vapors to 10 wt%, 40 °C, 80 % and 10 min, respectively with N-Methyl-2-pyrrolidone (NMP) as the solvent. Compared to commercial polytetrafluorethylene (PTFE) membrane, the VIPS PVDF membrane showed higher water vapor flux (38 LMH vs 36 LMH), lower flux decline ratio (22 % vs 39 %) and superior salt rejection (99.99 % vs. 99.90 %) in a 3 h-DCMD process. In wetting tests, the VIPS membrane failed for a sodium dodecyl sulfate concentration of 0.2 mM while 0.1 mM was enough to trigger wetting of the commercial membrane. The energy barrier to heterogeneous crystallization was slightly larger for the VIPS membrane, and a higher rejection was measured during scaling tests (99.8 % vs. 94.2 % for PTFE membrane). Finally, the VIPS membrane outperformed the commercial membrane in a long-term test (100 h). These results evidence the suitability of VIPS PVDF membranes for DCMD.

Optimization of a continuous flow electrocoagulation as pretreatment for membrane distillation of the waste stream in vinyl ester resin production

Vinyl ester resin production wastewater (VERW) contains high concentrations of organics particularly, methacrylic acid and bisphenol A, which are hazardous chemicals and harmful to the aquatic environment. Therefore, there is an urgent need to properly treat the effluent before discharge into the aquatic system. In this work, direct contact membrane distillation (DCMD) was explored as an advanced treatment of the VERW pre-treated by a continuous flow electrocoagulation (EC) and peroxi-electrocoagulation (PEC) processes. Optimization of EC and PEC processes were investigated and the DCMD performance was evaluated. Results showed that the optimal value of current density and polyacrylamide (PAM) dosage was 15 mA/cm2 and 1 mg/L, respectively in the EC process. For the PEC process, the optimal addition of hydrogen peroxide (H2O2) dosage was four times of the chemical oxygen demand (COD) concentration of EC effluent. The COD of VERW was effectively removed via EC followed by PEC (EC-PEC), resulting in the significant alleviation of membrane fouling during DCMD filtration of VERW. The initial flux of DCMD filtration of VERW pre-treated via EC-PEC improved by 35%, compared that only pre-treated by EC. Moreover, the concentration factor (CF) of the DCMD system reached up to 8.1 and the conductivity of distillate was less than 33.2 μS/cm. Hence, the EC and membrane distillation hybrid process paves a new way for the effective treatment of waste steam from resin production.

Membrane distillation for separation and recovery of valuable compounds from anaerobic digestates

Digestate - the wet by-product of the anaerobic digestion (AD) of organic waste - is composed of a mixture of residual organic matter, microbial biomass and inorganic compounds. Although digestate is rich in nutrients, the occurrence of high levels of salinity and soluble ammoniacal nitrogen (N-NH4+) limits its direct exploitation as organic fertilizer and imposes a complex disposal.This study assesses at laboratory-scale the potential of Direct Contact Membrane Distillation (DCMD) for the separation of nutrients and the recovery of water from the liquid phase of the digestate produced by a digester that treats cattle manure and agricultural residues. Experimental tests, carried out at different feed temperature (50–70 °C) and initial pH (6–8.2) of the liquid digestate, aimed at investigating the effect of the operating conditions on the transmembrane flux of water vapor, the concentration of N-NH4+, P-PO3-, and Chemical Oxygen Demand (COD) in both permeate (also referred to as distillate) and retentate streams.For raw digestate, the initial transmembrane flux enhanced from 1.83 L·m−2·h−1 to 5.55 L·m−2·h−1, in response to increasing temperature gradient. Overall, the highest achieved water recovery factor was 40% at a feed temperature of 70 °C. The pH had a limited impact on the transmembrane flux, whereas notably affected the DCMD performance in terms of separation efficiency. In particular, a pH reduction from 8.2 (raw digestate) to 6 was able to completely avoid the transfer of N-NH4+ into the distillate. Compared to the concentration in the raw digestate, the reduction of COD and P-PO3- in the distillate was 99.0% and 99.9%, respectively. Regardless feed temperature, the performance of the process was subjected to a significant decline of evaporation rate due to occurrence of membrane fouling; however, cycles of cleaning with citric acid allowed to partially regenerate the membrane by removing the reversible cake of foulants accumulated on the surface. The results demonstrate an adequate performance of MD process for recovering water and nutrients, leading to a dehydrated fraction of the digestate phase that can be easily stored and used in agronomic practices.

Predicting and evaluating the performance of DCMD: The effect of non-ideal morphology and thermal conductivity of porous nanocomposite membranes

The aim of this work is to explore the effects of the factors affecting the thermal conductivity of the porous nanocomposite membranes and their performance in direct contact membrane distillation (DCMD). The thermal conductivity models were evaluated comprehensively for membrane material involving three-phases (filler particle, polymer and interface). Hashemifard-Matsuura-Fauzi (HMF) and Maxwell models were the most reliable models among three-phase and two-phase (nanocomposite material and pores) models, respectively. Thus, the thermal conductivity of the porous nanocomposite membrane was obtained by the combination of three-phase HMF and two-phase Maxwell model. Finally, the performances of PTFE/Silica aerogel (SiAG) and PTFE/CaCO3 porous nanocomposite membranes were disclosed by the heat and mass transfer model in a DCMD system in order to study the effects of particle loading, interlayer thickness and membrane porosity. It was concluded that both membrane thermal conductivity and the DCMD flux approach almost the same values at the high end of interface thickness, regardless of the thermal conductivity of the filler particle. In other words, the heat loss of the system can be controlled by tuning the interface thickness in order to achieve a high DCMD flux even by incorporating fillers with higher thermal conductivity rather than that of the pure polymer. In summary, our findings revealed that next to the membrane material and porosity, the type of the nanoparticle and interface thickness can be highlighted as the most important parameters for controlling membrane thermal conductivity and improving DCMD performance.

Design of a multistage hybrid desalination process for brine management and maximum water recovery.

Hypersaline brine production from desalination plants causes huge environmental stress due to the untenable conventional discharge strategies. Particularly, brine production is expected to drastically increase in the coming few decades due to the increasing desalination capacity in attempts of forestalling water scarcity. Thereby, zero liquid discharge (ZLD) is a worth-considering solution for strategic brine management. ZLD or minimal liquid discharge (MLD) systems provide maximum water recovery with least or zero liquid waste generation and valuable salt production. In this work, a theoretical design of ZLD/MLD system is proposed for reverse osmosis (RO) brine management. Different scenarios are investigated utilizing multistage freeze desalination (FD) and its hybridization with multistage direct contact membrane distillation (DCMD), and eutectic freeze crystallization (EFC) technologies. The design is based on the experimental assessment of the indirect FD process at different feed salinities, i.e., 2g/L to 155g/L. FD experiments showed that ice quality is reduced at greater crystallinity levels and initial concentration. Moreover, a computational fluid dynamics (CFD) model is utilized to assess the performance of DCMD. A single DCMD module could produce 53kg/(m2.h) of pure water operating with 69% thermal efficiency. Eventually, water recovery, water quality, as well as specific energy consumption (SEC) are evaluated for the whole system. Based on different configurations of the hybrid ZLD system, the proposed design can achieve water recovery between 40 and 93% with SEC range of 28-114 kWh/m3. Results also showed that the produced water quality exceeds drinkable water standards ( 500mg/L). This work has provided great evidence in the practicality of ZLD/MLD systems for sustainable brine management.

Minerals recovery from a rare earth extraction wastewater by a combined chemical precipitation and membrane distillation process

Rare earth extraction wastewater (REEW) derived from rare earth (RE) extraction contains high value-added resources, such as magnesium. Therefore, it is highly desirable to recover the minerals from REEW to reuse in the RE extraction process. This study investigated the combined chemical precipitation and direct contact membrane distillation (DCMD) process to treat REEW for minerals recovery. Results showed that 99.7% Mg2+ in REEW was precipitated as Mg(OH)2 by adjusting pH of the solution. The MgO was obtained through the calcination of Mg(OH)2. The specific surface area (SSA) and reactivity of the calcined MgO decreased with the increase of calcination duration. MgO calcined at 500 °C for 2 h exhibited higher reactivity and SSA of 188.2 m2/g. DCMD performance decline was mainly caused by gypsum during treatment of the Mg-separated stream and membrane fouling was effectively mitigated by almost complete removal of Ca2+, resulting in the concentrated Na2SO4 solution. Subsequently, Na2SO4 was successfully recovered via freeze crystallization by controlling its solubility. The recovered Na2SO4 exhibited narrow crystal size distribution with mean size of 43.3 μm. With this combined process, it was possible to successfully recover 20.1 g/L MgO, 49.7 g/L Na2SO4 along with 72.6% of the water from REEW. The recovered MgO and Na2SO4 with purity of 98.5% and 99.2%, respectively, achieving industrial grade. The results suggest that the combined technologies, chemical precipitation and DCMD process, can be used as a viable engineering solution for minerals recovery from REEW.

Comprehensive experimental and theoretical investigations on the effect of microbubble two-phase flow on the performance of direct-contact membrane distillation

This study provides a comprehensive and systematic overview of the application of gas-liquid two-phase flow with microbubbles in the feed stream to improve heat and mass transfer in direct-contact membrane distillation (DCMD) processes for seawater desalination. A swirl-flow-type microbubble generator (MBG) was installed at the feed-side inlet of the DCMD module to investigate its effect on transmembrane flux. The maximum improvement in the MBG-assisted DCMD permeation flux was found to be approximately 18% at a lower feed temperature (40 °C) and optimal air flow rate (50 cc/min), and an optimal MBG geometry comprising a swirler, a nozzle tip of diameter 2 mm, and a diffuser at an angle of 30°. The results were observed to be related to the number density of microbubbles less than 100 µm in size, which plays an important role in improving heat and mass transfer in two-phase flow. In addition, the simulation results based on conventional heat transfer correlations of bubbly flow underestimated the experimental results. Therefore, this study also aims to propose and verify a new two-phase flow heat transfer correlation. The proposed correlation considers the effects of bubble size distribution to accurately predict the performance of MBG-assisted DCMD processes.

Hybrid nanofluid filtered concentrating photovoltaic/thermal-direct contact membrane distillation system for co-production of electricity and freshwater

The membrane distillation (MD) systems integrated with photovoltaic/thermal (PV/T) collectors can hardly obtain large permeate flux and favorable electrical performance simultaneously. Therefore, an innovative hybrid nanofluid filtered concentrating PV/T (CPV/T)-direct contact membrane distillation (DCMD) system is proposed. The novelty is that Ag/saline water nanofluid acts as a multifunctional fluid capable of absorbing solar spectrum, which cannot be efficiently utilized by solar cells, and converting it into heat to directly produce water in DCMD. Mathematical models of both nanofluid filtered CPV/T and DCMD are established to evaluate the system performance. Results indicated that nearly 70% of solar radiation is converted into useful energy by the nanofluid filtered CPV/T device. Besides, detailed parametric studies are performed to explore how the system performance is affected by the operation and design parameters. It is found that Ag/saline water nanofluid can be heated to 353 K for desalination, at which, the DCMD module can produce 26.4 kg m−2 h−1 of fresh water. Meanwhile, the electrical efficiency of the system is 12.2% and the equivalent system thermal efficiency can reach a maximum of 71.3%. Furthermore, we demonstrate that the use of Ag/saline water nanofluid as feed stream can mitigate the temperature polarization and improve DCMD performance.

Computational fluid dynamics simulations of solar-assisted, spacer-filled direct contact membrane distillation: Seeking performance improvement

Significant downstream performance reduction and concentration polarisation reduce direct contact membrane distillation (DCMD) efficiency. These challenges are not well researched since they are difficult to implement experimentally and numerically. Hence, this study examined the impact of solar absorbers and different spacer filaments upon DCMD performance. A 2D computational fluid dynamics model that considered simultaneous mass and heat transfer across the membrane and throughout the channels was developed to simulate water flux in DCMD modules under the use of solar absorbers and spacer filaments of various designs. The simulation outcomes were in excellent agreement with experimental results provided by two different studies, with the assisted solar absorber module and the spacer-filled module deviating <5 % and 3 % from the experimental results, respectively. A module equipped with the solar absorber membrane enhanced the DCMD performance better than a module with a solar absorber plate. The results also illustrated that a module with cylindrical detached spacer filaments improved DCMD performance more than a module with rectangular and semicircular attached spacers. Finally, it was shown that a module equipped with an integrated developed spacer and solar absorber membrane significantly enhanced water flux and both concentration and temperature polarisations, specifically when the inlet velocity was increased. Water flux and the temperature polarisation coefficient increased by 220 % in the integrated module, and the concentration polarisation coefficient decreased by 10 %. Moreover, the developed module resulted in a substantial increase in downstream performance.

Computational fluid dynamics simulation study of hypersaline water desalination via membrane distillation: Effect of membrane characteristics and operational parameters

In this study, a comprehensive model was developed using Computational Fluid Dynamics (CFD), and the behaviour of a direct contact membrane distillation (DCMD) system was investigated at hypersaline feedwater conditions. The effects of various operating parameters including feed and permeate velocities, temperatures and salinities, as well as different membrane characteristics like thickness, porosity, and thermal conductivity were studied. The developed simulation model was also validated using experimental data. The results showed that the membrane conductivity and thickness had a significant impact on the DCMD performance, and the optimum operational condition was necessary to be determined. The results showed that increasing the feedwater salinity from 50 to 200 g/l decreased the membrane flux by up to 33%, while a four times decrease in thermal conductivity of the membrane could lead to an increase in the membrane flux from 11.2 to 32.4 l/m2·h (LMH). In addition, the optimal membrane thickness was found to increase with salinity, reaching >120 μm for treatment of 22 wt% NaCl feedwater solution. However, the flux declined from >32 LMH to <13 LMH upon the increase in feedwater salinity (up to 22 wt% NaCl solution). It is also shown that a thinner membrane performed better for desalination of low salinity feedwater, while the thicker one produces higher separation performance and thermal efficiency for hypersaline brine desalination.

Effect of membrane surface wetting on the performance of direct contact membrane distillation for seawater desalination

Membrane distillation (MD) is a standalone process to generate fresh water and is especially attractive when low-grade waste heat or renewable thermal energy is available. Surface wetting hinders the commercialization of Membrane distillation (MD) technology by deteriorating the permeate quality, thermal efficiency, and transmembrane flux. There is still a lack of understanding on how and to what extent the partially wetted membranes affect the performance of direct contact MD (DCMD) systems. It is of great importance to optimize the operating conditions under such conditions. The DCMD performance was addressed in the literature by considering non-wetted or fully wetted membranes. This study for the first time proposes a computational model to investigate the effect of membrane surface wetting ratio (R = L wet /L total ) on the transmembrane (J) and thermal efficiency (η) of a DCMD module. Parametric and sensitivity analyses were performed to display the effect of system parameters (feed temperature, feed velocity, permeate temperature, permeate velocity, membrane thickness, and membrane surface wetting ratio) on the Key Performance Indicators (KPIs) of the DCMD module. The obtained results indicate that the permeate side temperature has more effect (more than twice) on KPIs in wetted membranes (∼30% and ∼15% rise in J and η) compared to the non-wetted ones (∼15% and ∼5% enhancement in J and η), and the negative effect of membrane surface wetting could be minimized by adjusting the permeate side operational conditions. The effect of membrane wetting ratio on the performance of the DCMD module in thin membranes (≤0.2 mm) and thick membranes (≥0.25 mm) strongly depends on the permeate and feed temperatures. The parametric and sensitivity analysis performed in this study will be beneficial to optimizing the operational conditions of MD systems for maximizing their performance and could serve as valuable guidelines in the development of efficient water desalination systems. • A numerical model was developed to investigate the performance of the partially wetted DCMD module. • The effect of surface wetting ratio (R = L wet /L total ) was investigated using a parametric study. • A sensitivity analysis was performed to quantify the relative impact of operating conditions. • The effect of permeate properties is more dominant for surface wetted membranes. • Permeate and feed temperatures dramatically alter the R ratio effect in thin and thick membranes, respectively.

Nitrogen recovery from a palladium leachate via membrane distillation: System performance and ammonium chloride crystallization

Ammonia leaching process was often used to separate precious and rare-earth metals during their recovery via hydrometallurgy, resulting in the generation of nitrogen-rich leachate. Therefore, it is significantly important to recover the nitrogen from the leachate for reuse. In this work, we explored the treatment of palladium leachate (PL) via direct contact membrane distillation (DCMD) for nitrogen recovery. Effects of temperature and pH on system performance and nitrogen recovery mainly in the form of ammonium chloride (NH4Cl) were evaluated. Results showed that DCMD performance decline caused by membrane scaling was primarily impacted by feed temperature rather than pH. The higher temperature, the more severe membrane scaling occurrence. However, there was little to no effect of initial pH on distillate flux decline. Nitrogen in the form of NH4Cl was successfully recovered from PL, which was significantly influenced by initial pH. The weight of NH4Cl obtained ranged from 17.4 to 21.5 g/L under various operating conditions, and the purity of the NH4Cl was up to 97.4%, near the industrial grade, at feed temperature of 40°C and initial pH of 8.5. Additionally, results of gas chromatography-mass spectrometry (GC–MS) revealed that the primary dissolved organic matter (DOM) in the virgin PL were tetradecanoic acid and isosorbide. Our results suggest that DCMD can be used as a promising and feasible solution for nitrogen recovery from the PL.

Sonicated direct contact membrane distillation: Influence of sonication parameters

The effect of sonication on the performance of the direct contact membrane distillation (DCMD) is studied in this work. A sonicated DCMD module equipped with a commercial PTFE membrane is built and tested in an immersed temperature-controlled water bath. High fidelity transient and thermally conjugated CFD model is also developed for the DCMD unit accounting for the sonication. Flow metrics, including temperature polarization coefficient (TPC), heat- and mass- flux under different sonication frequencies and amplitudes were evaluated. Parametric study showed a clear improvement in the DCMD system metrics and more pronounced at higher temperature. It was observed that the application of sonication impedes the development of both kinetic and thermal boundary layers due to ultrasonic-induced mixing. The results showed that the application of sonication to DCMD at the intensity of 4525 W/m2 resulted in increase of mass flux from 4.25 L/m2.h to 8.1 L/m2.h corresponding to 90% increase. It is economically unviable due to electrical power demand, i.e., ~ 35 kW.h/m3 (~$5/m3), but can be feasible below 474 W/m2 demanding 3 kW.h/m3 (nearly $0.42/m3). It was also observed that an interesting equivalence exists between the effect of acoustic amplitude and acoustic frequency on the performance of DCMD. For example, sonication at 1 kHz with 0.5 μm amplitude produced similar results, in terms of mass flux and TPC, as sonication at 5 kHz with 0.1 μm amplitude.