A proposal was made for a photosensitive electrode with a bilaminar film consisting of PXV-PSS2 and [(C17H35)2Dipy]Ru(Dipy)22+ deposited on a conducting base. Its use in a photoelectrochemical cell permits electron transport from EDTA in one half-cell through the bilaminar film and external circuit to Fe(CN)63− in the other half-cell.