Diffuse Molecular Clouds Research Articles

H2 Fluorescent Emission from the Diffuse Interstellar Medium

Near-IR spectroscopy, which can now be performed at unprecedented sensitivity with the NIRSpec instrument on JWST, can offer a novel probe of diffuse clouds through the observation of H2 fluorescent emissions. Whereas previous observations of interstellar H2 fluorescent emissions were primarily confined to dense clouds lying close to a source of UV radiation, JWST opens the possibility of detecting such emissions from diffuse molecular clouds exposed to the average radiation field in the Galaxy. A simple analytic model is presented to predict the near-IR H2 fluorescent line intensities emitted by diffuse interstellar clouds with a Plummer density profile. It is applicable to sightlines where the column densities of H and H2 have been measured and the peak gas density can be estimated.

The Densities in Diffuse and Translucent Molecular Clouds: Estimates from Observations of C2 and from Three-dimensional Extinction Maps

Newly computed collisional rate coefficients for the excitation of C2 in collisions with H2, presented recently by Najar & Kalugina, are significantly larger than the values adopted previously in models for the excitation of the C2 molecule, a widely used probe of the interstellar gas density. With these new rate coefficients, we have modeled the C2 rotational distributions inferred from visible and ultraviolet absorption observations of electronic transitions of C2 toward a collection of 46 nearby background sources. The inferred gas densities in the foreground interstellar clouds responsible for the observed C2 absorption are a factor 4–7 smaller than those inferred previously, a direct reflection of the larger collisional rate coefficients computed by Najar & Kalugina. These lower-density estimates are generally in good agreement with the peak densities inferred from 3D extinction maps for the relevant sight lines. In cases where H3+ absorption has also been observed and used to estimate the cosmic-ray ionization rate (CRIR), our estimates of the latter will also decrease accordingly because the H3+ abundance is a function of the ratio of the CRIR to the gas density.

Reevaluation of the Cosmic-Ray Ionization Rate in Diffuse Clouds

All current estimates of the cosmic-ray (CR) ionization rate rely on assessments of the gas density along the probed sight lines. Until now, these have been based on observations of different tracers, with C2 being the most widely used in diffuse molecular clouds for this purpose. However, dust extinction maps have recently reached sufficient accuracy to give an independent measurement of the gas density on parsec scales. In addition, they allow us to identify the gas clumps along each sight line, thus localizing the regions where CR ionization is probed. We reevaluate H3+ observations, which are often considered as the most reliable method to measure the H2 ionization rate ζH2 in diffuse clouds. The peak density values derived from the extinction maps for 12 analyzed sight lines turn out to be, on average, an order of magnitude lower than the previous estimates and agree with the values obtained from revised analysis of C2 data. We use the extinction maps in combination with the 3d-pdr code to self-consistently compute the H3+ and H2 abundances in the identified clumps for different values of ζH2 . For each sight line, we obtain the optimum value by comparing the simulation results with observations. We show that ζH2 is systematically reduced with respect to the earlier estimates by a factor of ≈9 on average, to ≈6 × 10−17 s−1, primarily as a result of the density reduction. We emphasize that these results have profound consequences for all available measurements of the ionization rate.

Turbulent Diffuse Molecular Media with Nonideal Magnetohydrodynamics and Consistent Thermochemistry: Numerical Simulations and Dynamic Characteristics

Turbulent diffuse molecular clouds can exhibit complicated morphologies caused by the interactions among radiation, chemistry, fluids, and fields. We performed full 3D simulations for turbulent diffuse molecular interstellar media, featuring time-dependent nonequilibrium thermochemistry coevolved with magnetohydrodynamics (MHD). Simulation results exhibit the relative abundances of key chemical species (e.g., C, CO, OH) vary by more than one order of magnitude for the “premature” epoch of chemical evolution (t ≲ 2 × 105 yr). Various simulations are also conducted to study the impacts of physical parameters. Nonideal MHD effects are essential in shaping the behavior of gases, and strong magnetic fields (∼10 μG) tend to inhibit vigorous compressions and thus reduce the fraction of warm gases (T ≳ 102 K). Thermodynamical and chemical conditions of the gas are sensitive to modulation by dynamic conditions, especially the energy injection by turbulence. Chemical features, including ionization (cosmic ray and diffuse interstellar radiation), would not directly affect the turbulence power spectra. Nonetheless, their effects are prominent in the distribution profiles of temperatures and gas densities. Comprehensive observations are necessary and useful to eliminate the degeneracies of physical parameters and constrain the properties of diffuse molecular clouds with confidence.

Diffuse interstellar bands in the near-infrared: expanding the reddening range

ABSTRACT We have investigated the behaviour of three strong near-infrared diffuse interstellar bands (DIBs) at λ13177 Å, λ14680 Å, and λ15272 Å, on a larger sample of sightlines and over a wider range of extinctions than previously studied, utilizing spectra from three observatories. We applied two telluric correction techniques to reduce atmospheric contamination and have used Gaussian fits to characterize the DIB profiles and measure equivalent widths. We confirmed strong and approximately linear correlations with reddening of the λ13177 Å, λ14680 Å, and λ15272 Å DIBs, extending them to higher reddening values and strengthening their link to interstellar matter. Modelling of the λ14680 Å DIB profiles revealed intrinsic variations, including line broadening, linked to their formation processes. This effect is particularly pronounced in the Galactic Centre (GC) environment, where multiple diffuse molecular clouds along the line of sight contribute to line broadening. We have detected one new DIB candidate at λ14795 Å on sightlines with high reddening.

The CO-dark molecular gas in the cold H I arc

The CO-dark molecular gas (DMG), which refers to the molecular gas not traced by CO emission, is crucial for the evolution of the interstellar medium (ISM). While the gas properties of DMG have been widely explored in the Solar neighborhood, whether or not they are similar in the outer disk regions of the Milky Way is still not well understood. In this Letter, we confirm the existence of DMG toward a cold H I arc structure at 13 kpc away from the Galactic center with both OH emission and H I narrow self-absorption (HINSA). This is the first detection of HINSA in the outer disk region, in which the HINSA fraction (NHINSA/NH2 = 0.022 ± 0.011) is an order of magnitude higher than the average value observed in nearby evolved dark clouds, but is consistent with that of the early evolutionary stage of dark clouds. The inferred H2 column density from both extinction and OH emission (NH2 ≈ 1020 cm−2) is an order of magnitude higher than previously estimated. Although the ISM environmental parameters are expected to be different between the outer Galactic disk regions and the Solar neighborhood, we find that the visual extinction (AV = 0.19 ± 0.03 mag), H2-gas density (nH2 = 91 ± 46 cm−3), and molecular fraction (58% ± 28%) of the DMG are rather similar to those of nearby diffuse molecular clouds. The existence of DMG associated with the expanding H I supershell supports a scenario where the expansion of supershells may trigger the formation of molecular clouds within a crossing timescale of the shock wave (∼106 yr).

Dissociative Recombination of Rotationally Cold OH+ and Its Implications for the Cosmic Ray Ionization Rate in Diffuse Clouds

Observations of OH+ are used to infer the interstellar cosmic ray ionization rate in diffuse atomic clouds, thereby constraining the propagation of cosmic rays through and the shielding by interstellar clouds, as well as the low energy cosmic ray spectrum. In regions where the H2-to-H number density ratio is low, dissociative recombination (DR) is the dominant destruction process for OH+ and the DR rate coefficient is important for predicting the OH+ abundance and inferring the cosmic ray ionization rate. We have experimentally studied DR of electronically and vibrationally relaxed OH+ in its lowest rotational levels, using an electron–ion merged-beams setup at the Cryogenic Storage Ring. From these measurements, we have derived a kinetic temperature rate coefficient applicable to diffuse cloud chemical models, i.e., for OH+ in its electronic, vibrational, and rotational ground level. At typical diffuse cloud temperatures, our kinetic temperature rate coefficient is a factor of ∼5 times larger than the previous experimentally derived value and a factor of ∼33 times larger than the value calculated by theory. Our combined experimental and modeling results point to a significant increase for the cosmic ray ionization rate inferred from observations of OH+ and H2O+, corresponding to a geometric mean of (6.6 ± 1.0) × 10−16 s−1, which is more than a factor of 2 larger than the previously inferred values of the cosmic ray ionization rate in diffuse atomic clouds. Combined with observations of diffuse and dense molecular clouds, these findings indicate a greater degree of cosmic ray shielding in interstellar clouds than has been previously inferred.

Tracing of magnetic fields with gradients: subsonic turbulence

ABSTRACT The recent development of the velocity gradient technique shows the capability of the technique for tracing magnetic field morphology in diffuse interstellar gas and molecular clouds. In this paper, we perform a systematic numerical study of the performance of the velocity and synchrotron gradient for a wide range of magnetization in the subsonic environment. Addressing the studies of magnetic fields in atomic hydrogen, we also study the formation of velocity caustics in spectroscopic channel maps in the presence of thermal broadening. We show that the velocity caustics can be recovered when applied to the cold neutral medium and the gradient technique (GT) can reliably trace magnetic fields there. Finally, we discuss the changes in the anisotropy of observed structure functions when we apply to the analysis the procedures developed within the framework of GT studies.

Magnetic Field Strength from Turbulence Theory. I. Using Differential Measure Approach

The mean plane-of-sky magnetic field strength is traditionally obtained from the combination of polarization and spectroscopic data using the Davis–Chandrasekhar–Fermi (DCF) technique. However, we identify the major problem of the DCF technique to be its disregard of the anisotropic character of MHD turbulence. On the basis of the modern MHD turbulence theory we introduce a new way of obtaining magnetic field strength from observations. Unlike the DCF technique, the new technique uses not the dispersion of the polarization angle and line-of-sight velocities, but increments of these quantities given by the structure functions. To address the variety of astrophysical conditions for which our technique can be applied, we consider turbulence in both media with magnetic pressure higher than the gas pressure, corresponding, e.g., to molecular clouds, and media with gas pressure higher than the magnetic pressure, corresponding to the warm neutral medium. We provide general expressions for arbitrary admixtures of Alfvén, slow, and fast modes in these media and consider in detail particular cases relevant to diffuse media and molecular clouds. We successfully test our results using synthetic observations obtained from MHD turbulence simulations. We demonstrate that our differential measure approach, unlike the DCF technique, can be used to measure the distribution of magnetic field strengths, can provide magnetic field measurements with limited data, and is much more stable in the presence of induced large-scale variations of nonturbulent nature. Furthermore, our study uncovers the deficiencies of earlier DCF research.

PDRs4All: A JWST Early Release Science Program on Radiative Feedback from Massive Stars

Massive stars disrupt their natal molecular cloud material through radiative and mechanical feedback processes. These processes have profound effects on the evolution of interstellar matter in our Galaxy and throughout the universe, from the era of vigorous star formation at redshifts of 1–3 to the present day. The dominant feedback processes can be probed by observations of the Photo-Dissociation Regions (PDRs) where the far-ultraviolet photons of massive stars create warm regions of gas and dust in the neutral atomic and molecular gas. PDR emission provides a unique tool to study in detail the physical and chemical processes that are relevant for most of the mass in inter- and circumstellar media including diffuse clouds, proto-planetary disks, and molecular cloud surfaces, globules, planetary nebulae, and star-forming regions. PDR emission dominates the infrared (IR) spectra of star-forming galaxies. Most of the Galactic and extragalactic observations obtained with the James Webb Space Telescope (JWST) will therefore arise in PDR emission. In this paper we present an Early Release Science program using the MIRI, NIRSpec, and NIRCam instruments dedicated to the observations of an emblematic and nearby PDR: the Orion Bar. These early JWST observations will provide template data sets designed to identify key PDR characteristics in JWST observations. These data will serve to benchmark PDR models and extend them into the JWST era. We also present the Science-Enabling products that we will provide to the community. These template data sets and Science-Enabling products will guide the preparation of future proposals on star-forming regions in our Galaxy and beyond and will facilitate data analysis and interpretation of forthcoming JWST observations.

The Dense Gas Mass Fraction and the Relationship to Star Formation in M51

Observations of 12CO J = 1 – 0 and HCN J = 1 – 0 emission from NGC 5194 (M51) made with the 50 m Large Millimeter Telescope and the SEQUOIA focal plane array are presented. Using the HCN-to-CO ratio, we examine the dense gas mass fraction over a range of environmental conditions within the galaxy. Within the disk, the dense gas mass fraction varies along the spiral arms but the average value over all spiral arms is comparable to the mean value of interarm regions. We suggest that the near-constant dense gas mass fraction throughout the disk arises from a population of density-stratified, self-gravitating molecular clouds and the required density threshold to detect each spectral line. The measured dense gas fraction significantly increases in the central bulge in response to the effective pressure, P e , from the weight of the stellar and gas components. This pressure modifies the dynamical state of the molecular cloud population and, possibly, the HCN-emitting regions in the central bulge from self-gravitating to diffuse configurations in which P e is greater than the gravitational energy density of individual clouds. Diffuse molecular clouds comprise a significant fraction of the molecular gas mass in the central bulge, which may account for the measured sublinear relationships between the surface densities of the star formation rate and molecular and dense gas.

The impact of cosmic-ray attenuation on the carbon cycle emission in molecular clouds

Context. Observations of the emission of the carbon cycle species (C, C+, CO) are commonly used to diagnose gas properties in the interstellar medium, but they are significantly sensitive to the cosmic-ray ionization rate. The carbon-cycle chemistry is known to be quite sensitive to the cosmic-ray ionization rate, ζ, controlled by the flux of low-energy cosmic rays which get attenuated through molecular clouds. However, astrochemical models commonly assume a constant cosmic-ray ionization rate in the clouds. Aims. We investigate the effect of cosmic-ray attenuation on the emission of carbon cycle species from molecular clouds, in particular the [CII] 158 μm, [CI] 609 μm, and CO (J = 1–0) 115.27 GHz lines. Methods. We used a post-processed chemical model of diffuse and dense simulated molecular clouds and quantified the variation in both column densities and velocity-integrated line emission of the carbon cycle with different cosmic-ray ionization rate models. Results. We find that the abundances and column densities of carbon cycle species are significantly impacted by the chosen cosmic-ray ionization rate model: no single constant ionization rate can reproduce the abundances modeled with an attenuated cosmic-ray model. Further, we show that constant ionization rate models fail to simultaneously reproduce the integrated emission of the lines we consider, and their deviations from a physically derived cosmic-ray attenuation model is too complex to be simply corrected. We demonstrate that the two clouds we modeled exhibit a similar average AV,eff – nH relationship, resulting in an average relation between the cosmic-ray ionization rate and density ζ(nH). Conclusions. We conclude by providing a number of implementation recommendations for cosmic rays in astrochemical models, but emphasize the necessity for column-dependent cosmic-ray ionization rate prescriptions.

Mechanisms for gas-phase molecular formation of neutral formaldehyde (H2CO) in cold astrophysical regions

Context. Formaldehyde is a potential biogenic precursor involved in prebiotic chemical evolution. The cold conditions of the interstellar medium (ISM) allow H2CO to be reactive, playing a significant role as a chemical intermediate in formation pathways leading to interstellar complex organic molecules. However, gas-phase molecular formation mechanisms in cold regions of the ISM are poorly understood. Aims. We computationally determine the most favored gas-phase molecular formation mechanisms at local thermodynamic equilibrium conditions that can produce the detected amounts of H2CO in diffuse molecular clouds (DMCs), in dark, cold, and dense molecular clouds (DCDMCs), and in three regions of circumstellar envelopes of low-mass protostars (CELMPs). Methods. The potential energy surfaces, thermodynamic functions, and single-point energies for transition states were calculated at the CCSD(T)-F12/cc-pVTZ-F12 and MP2/aug-cc-pVDZ levels of theory and basis sets. Molecular thermodynamics and related partition functions were obtained by applying the Maxwell-Boltzmann quantum statistics theory from energies computed at CCSD(T)-F12/cc-pVTZ-F12 with corrections for zero-point energy. A literature review on detected abundances of reactants helped us to propose the most favorable formation routes. Results. The most probable reactions that produce H2CO in cold astrophysical regions are: 1CH2 + ⋅3O2 →1H2CO + O⋅(3P) in DMCs, ⋅3CH2 + ⋅3O2 →1H2CO + ⋅O(3P) in DCDMCs, and ⋅CH3 + ⋅O(3P) →1H2CO + ⋅H in region III, ⋅CH3 +⋅O(1D) →1H2CO + ⋅H in region II, and 1CH2 + ⋅3O2 →1H2CO + ⋅O(3P) in region I belonging to CELMPs. Conclusions. Quantum chemical calculations suggest that the principal carbonaceous precursors of H2CO in cold regions for the gas-phase are CH2(a1A1), and ⋅CH2(X3B1) combined with ⋅O2(3Σg) and ⋅CH3(2A”) + ⋅O(3P) / O(1D). Reactions based on more complex reagents yield less effective thermodynamics in the gas-phase H2CO molecular formation.

Extending the view of ArH+chemistry in diffuse clouds

Context.One of the surprises of theHerschelmission was the detection of ArH+towards the Crab Nebula in emission and in absorption towards strong Galactic background sources. Although these detections were limited to the first quadrant of the Galaxy, the existing data suggest that ArH+ubiquitously and exclusively probes the diffuse atomic regions of the interstellar medium.Aims.In this study, we extend the coverage of ArH+to other parts of the Galaxy with new observations of itsJ= 1−0 transition along seven Galactic sight lines towards bright sub-millimetre continuum sources. We aim to benchmark its efficiency as a tracer of purely atomic gas by evaluating its correlation (or lack of correlation as suggested by chemical models) with other well-known atomic gas tracers such as OH+and H2O+and the molecular gas tracer CH.Methods.The observations of theJ= 1−0 line of ArH+near 617.5 GHz were made feasible with the new, sensitive SEPIA660 receiver on the APEX 12 m telescope. Furthermore, the two sidebands of this receiver allowed us to observe theNKaKc= 11,0−10,1transitions of para-H2O+at 607.227 GHz simultaneously with the ArH+line.Results.We modelled the optically thin absorption spectra of the different species and subsequently derived their column densities. By analysing the steady state chemistry of OH+and o-H2O+, we derive on average a cosmic-ray ionisation rate,ζp(H), of (2.3 ± 0.3) × 10−16s−1towards the sight lines studied in this work. Using the derived values ofζp(H) and the observed ArH+abundances we constrain the molecular fraction of the gas traced by ArH+to lie below 2 × 10−2with a median value of 8.8 × 10−4. Combined, our observations of ArH+, OH+, H2O+, and CH probe different regimes of the interstellar medium, from diffuse atomic to diffuse and translucent molecular clouds. Over Galactic scales, we see that the distribution ofN(ArH+) is associated with that ofN(H), particularly in the inner Galaxy (within 7 kpc of the Galactic centre) with potentially even contributions from the warm neutral medium phase of atomic gas at larger galactocentric distances. We derive an average ortho-to-para ratio for H2O+of 2.1 ± 1.0, which corresponds to a nuclear spin temperature of 41 K, consistent with the typical gas temperatures of diffuse clouds.

Physical Conditions in Shocked Interstellar Gas Interacting with the Supernova Remnant IC 443*

Abstract We present the results of a detailed investigation into the physical conditions in interstellar material interacting with the supernova remnant (SNR) IC 443. Our analysis is based on a comprehensive examination of high-resolution far-ultraviolet spectra obtained with the Space Telescope Imaging Spectrograph onboard the Hubble Space Telescope of two stars behind IC 443. One of our targets (HD 43582) probes gas along the entire line of sight through the SNR, while the other (HD 254755) samples material located ahead of the primary supernova shock front. We identify low-velocity quiescent gas in both directions and find that the densities and temperatures in these components are typical of diffuse atomic and molecular clouds. Numerous high-velocity components are observed in the absorption profiles of neutral and singly ionized atomic species toward HD 43582. These components exhibit a combination of greatly enhanced thermal pressures and significantly reduced dust-grain depletions. We interpret this material as cooling gas in a recombination zone far downstream from shocks driven into neutral gas clumps. The pressures derived for a group of ionized gas components at high positive velocity toward HD 43582 are lower than those of the other shocked components, pointing to pressure inhomogeneities across the remnant. A strong, very high velocity component near −620 km s−1 is seen in the absorption profiles of highly ionized species toward HD 43582. The velocity of this material is consistent with the range of shock velocities implied by observations of soft thermal X-ray emission from IC 443. Moderately high velocity gas toward HD 254755 may represent shocked material from a separate foreground SNR.

The Structure of Dark Molecular Gas in the Galaxy. II. Physical State of “CO-dark” Gas in the Perseus Arm

We report the results from a new, highly sensitive ($\Delta T_{mb} \sim 3 $mK) survey for thermal OH emission at 1665 and 1667 MHz over a dense, 9 x 9-pixel grid covering a $1\deg$ x $1\deg$ patch of sky in the direction of $l = 105\deg, b = +2.50\deg$ towards the Perseus spiral arm of our Galaxy. We compare our Green Bank Telescope (GBT) 1667 MHz OH results with archival CO J=1-0 observations from the Five College Radio Astronomy Observatory (FCRAO) Outer Galaxy Survey within the velocity range of the Perseus Arm at these galactic coordinates. Out of the 81 statistically-independent pointings in our survey area, 86% show detectable OH emission at 1667 MHz, and 19% of them show detectable CO emission. We explore the possible physical conditions of the observed features using a set of diffuse molecular cloud models. In the context of these models, both OH and CO disappear at current sensitivity limits below an A$_{\rm v}$ of 0.2, but the CO emission does not appear until the volume density exceeds 100-200 cm$^{-3}$. These results demonstrate that a combination of low column density A$_{\rm v}$ and low volume density $n_{H}$ can explain the lack of CO emission along sight lines exhibiting OH emission. The 18-cm OH main lines, with their low critical density of $n^{*}$ $ \sim 1 $ cm$^{-3}$, are collisionally excited over a large fraction of the quiescent galactic environment and, for observations of sufficient sensitivity, provide an optically-thin radio tracer for diffuse H$_2$.

Molecular envelope around the HII region RCW 120

ABSTRACT The H ii region RCW 120 is a well-known object, which is often considered as a target to verify theoretical models of gas and dust dynamics in the interstellar medium. However, the exact geometry of RCW 120 is still a matter of debate. In this work, we analyse observational data on molecular emission in RCW 120 and show that 13CO(2–1) and C18O(2–1) lines are fitted by a 2D model representing a ring-like face-on structure. The changing of the C18O(3–2) line profile from double-peaked to single-peaked from the dense molecular Condensation 1 might be a signature of stalled expansion in this direction. In order to explain a self-absorption dip of the 13CO(2–1) and 13CO(3–2) lines, we suggest that RCW 120 is surrounded by a diffuse molecular cloud, and find confirmation of this cloud on a map of interstellar extinction. Optically thick 13CO(2–1) emission and the infrared 8 $\mu$m PAH band form a neutral envelope of the H ii region resembling a ring, while the envelope breaks into separate clumps on images made with optically thin C18O(2–1) line and far-infrared dust emission.

Revisiting the Temperature of the Diffuse ISM with CHESS Sounding Rocket Observations

Measuring the temperature and abundance patterns of clouds in the interstellar medium (ISM) provides an observational basis for models of the physical conditions within the clouds, which play an important role in studies of star and planet formation. The Colorado High-resolution Echelle Stellar Spectrograph (CHESS) is a far ultraviolet rocket-borne instrument designed to study the atomic-to-molecular transitions within diffuse molecular and translucent cloud regions. The final two flights of the instrument observed $\beta^{1}$ Scorpii ($\beta$ Sco) and $\gamma$ Arae. We present flight results of interstellar molecular hydrogen (H$_{\rm 2}$) excitation on the sightlines, including measurements of the column densities and temperatures. These results are compared to previous values that were measured using the damping wings of low J$^{\prime \prime}$ H$_{\rm 2}$ absorption features (Savage et al. 1977). For $\beta$ Sco, we find that the derived column density of the J$^{\prime \prime}$ = 1 rotational level differs by a factor of 2-3 when compared to the previous observations. We discuss the discrepancies between the two measurements and show that the source of the difference is due to the opacity of higher rotational levels contributing to the J$^{\prime \prime}$ = 1 absorption wing, increasing the inferred column density in the previous work. We extend this analysis to 9 $Copernicus$ and 13 $FUSE$ spectra to explore the interdependence of the column densities of different rotational levels and how the H$_{\rm 2}$ kinetic temperature is influenced by these relationships. We find a revised average gas kinetic temperature of the diffuse molecular ISM of T$_{01}$ = 68 $\pm$ 13 K, 12% lower than the value found previously.

Dark molecular gas in Pegasus–Pisces

Abstract We examine the molecular content of a large region (∼2200 square degrees) in Pegasus–Pisces with an estimated dark molecular gas fraction of 59 per cent. Using the extensive CO(1-0) Southern Galactic hemisphere, high-latitude survey by Magnani et al. (2000), we re-examined the CO-detectable mass estimates for the region. By averaging all the CO spectra in subsections ranging in size from 3° × 3° to 15° × 15°, we decreased the rms of the averaged CO spectra by factors of 3–10, effectively trading spatial resolution for sensitivity. With the new spectra, we are able to make estimates of the CO-detectable mass as a function of sensitivity. Using the optimal estimate, the CO-detectable mass increases from 2200 to 4000 M⊙, thereby decreasing the dark molecular gas fraction in the region to 0.24. CO(1–0) observations with rms values in the 20–30 mK range can nearly double the molecular mass in regions with diffuse and translucent molecular clouds.

Questions about the evolution of ices, from diffuse molecular clouds to comets

AbstractThe surfaces of interstellar and circumstellar dust grains are the sites of molecule formation, most of which, except H2, stick and form ice mantles. The study of ice evolution thus seems directly relevant for understanding our own origins, although the relation between interstellar and solar system ices remains a key question. The comparison of interstellar and solar system ices relies evidently on an accurate understanding of the composition and processes in both environments. With the accurate in situ measurements available for the comet 67P/Churyumov-Gerasimenko with the Rosetta mission, improving our understanding of interstellar ices is the more important. Here, I will address three specific questions. First, while laboratory experiments have made much progress in understanding complex organic molecule (COM) formation in the ices, the question remains, how does COM formation depend on environment and time? Second, what is the carrier of sulfur in the ices? And third, can ice absorption bands trace the processing history of the ices? Laboratory experiments, ranging from infrared spectroscopy to identify interstellar ice species, to surface experiments to determine reaction parameters in ice formation scenarios, to heating and irradiation experiments to simulate space environments, are essential to address these questions and analyze the flood of new observational data that will become available with new facilities in the next 2-10 years.