Ceramics or refractories prepared in the Al2O3-rich corner of the Al2O3-MgO-CaO system show excellent high-temperature mechanical properties and chemical stability because of the presence of spinel (MgAl2O4) and calcium hexaluminate (CaAl12O19). However, the densification of these two crystals usually requires high firing temperatures due to their poor sinterability. To address this issue, La2O3-doped MgAl2O4-CaAl4O7-CaAl12O19 refractory composites were designed, and the influence of the doping level on the densification, microstructure, and mechanical properties of the composite was investigated. It was found that the doped La3+ was predominantly dissolved in the CA6 grains by replacing Ca2+, forming uniform solid solutions regardless of doping concentration. This reaction significantly accelerates ion diffusion and CA2 grain growth. Besides, it reduces the aspect ratio of CA6 crystals, weakening the negative effect of the elongated grains on mass transfer and sintering. As a result, the relative density increases from 79.5 % to 95.1 % after sintering at 1600 °C with doping only 0.5 wt% La2O3 into the composite, producing a uniform and dense microstructure with regular angular grains. The above effects result in a significant improvement in flexural strength and fracture toughness (increasing by 61 % and 57 %, respectively). Moreover, the La2O3-doped refractory composite achieves a decline of the high-temperature creep rate by one order of magnitude at 1600 °C.