Gas Diffusion Research Articles

Intrinsically Conductive and Cu-Functionalized Polymer-Composite Membranes as Gas Diffusion Electrodes for CO2 Electroreduction.

We introduced a new class of gas diffusion electrodes (GDEs) with adjustable pore morphology. We fabricated intrinsically conductive polymer-composite membranes containing carbon filler, enabling a pore structure variation through film casting cum phase separation protocols. We further selectively functionalized specific pore regions of the membranes with Cu by a NaBH4-facilitated coating strategy. The as-obtained GDEs can facilitate the electrochemical CO2 reduction reaction (CO2RR) at Cu active sites that are presented inside a defined and electrically conductive pore system. When employing them as free-standing cathodes in a CO2 flow electrolyzer, we achieved >70% Faradaic efficiencies for CO2RR products at up to 200 mA/cm2. We further demonstrated that deposition of a dense Cu layer on top of the membrane leads to obstruction of the underlying pore openings, inhibiting an excessive wetting of the pore pathways that transport gaseous CO2. However, the presentation of Cu inside the pore system of our novel membrane electrodes increased the C2H4/CO selectivity by a factor of up to 3 compared to Cu presented in the dense layer on top of the membrane. Additionally, we found that gaseous CO2 could still access Cu in macropores after wetting with electrolyte, while CO2RR was completely suppressed in wetted nm-scale pores.

Porous Bi Nanosheets Derived from β-Bi2O3 for Efficient Electrocatalytic CO2 Reduction to Formate.

The electrochemical CO2 reduction reaction (ECO2RR) is a promising strategy for converting CO2 into high-value chemical products. However, the synthesis of effective and stable electrocatalysts capable of transforming CO2 into a specified product remains a huge challenge. Herein, we report a template-regulated strategy for the preparation of a Bi2O3-derived nanosheet catalyst with abundant porosity to achieve the expectantly efficient CO2-to-formate conversion. The resultant porous bismuth nanosheet (p-Bi) not only exhibited marked Faradaic efficiency of formate (FEformate), beyond 91% in a broad potential range from -0.75 to -1.1 V in the H-type cell, but also demonstrated an appreciable FEformate of 94% at a high current density of 262 mA cm-2 in the commercially important gas diffusion cell. State-of-the-art X-ray absorption near edge structure spectroscopy (XANES) and theoretical calculation unraveled the distinct formate production performance of the p-Bi catalyst, which was cocontributed by its smaller size, plentiful porous structure, and stronger Bi-O bond, thus accelerating the absorption of CO2 and promoting the subsequent formation of intermediates. This work provides an avenue to fabricate bismuth-based catalysts with high planar and porous morphologies for a broad portfolio of applications.

Aiming the water transport issues of anion exchange membrane fuel cells by introducing hydrophobic carbon nanotube diffusion layer

The gas diffusion layer (GDL) enhances the transport efficiency of reaction gases and facilitates the removal of accumulated liquid water, thereby improving water management in anion exchange membrane fuel cells (AEMFCs). Carbon nanotubes (CNTs) are recognized as one of the promising materials to optimize mass transport within GDLs. In this study, we successfully synthesized an abundance of CNTs on the surface of commercial gas diffusion media. The as-prepared CNT layer exhibits exceptionally high hydrophobic properties and forms a hierarchically hydrophobic structure combined with the gas diffusion media, effectively enhancing the mass transfer of the membrane electrode assembly (MEA) and reducing ohmic impedance. Under supersaturation conditions, the power density of the MEA containing CNTs reaches 1031.7 mW/cm2, significantly higher than the 760.64 mW/cm2 observed for the commercial GDL. Further testing demonstrates that the MEA containing CNTs exhibits a limiting current density of 2507.4 mA/cm2, which is much superior to the benchmark MEA with the commercial GDL (1591 mA/cm2). Electrochemical impedance spectroscopy analysis reveals that the mass transfer resistance of MEAs with CNTs is lower than that of MEAs with the commercial GDL. More importantly, the phase-field modeling is performed to simulate the transport of the liquid water in the hierarchical GDL.

Ti3C2Tz Supported Pulse‐Electrodeposited Pt Nanostructures for Enhanced Acidic Electrochemical Hydrogen Evolution

Platinum (Pt)‐based electrocatalysts are considered benchmark materials for the hydrogen evolution reaction (HER) in acidic solution. However, widespread use is limited by the high price of Pt. Tuning the Pt morphology to increase the catalytic surface area for the same mass loading is therefore essential to increase its utilization. Herein, single Ti3C2Tz flakes were deposited by electrophoresis onto a carbon‐fiber gas diffusion layer, after which Pt nanostructures were selectively deposited onto the Ti3C2Tz flakes by pulse electrodeposition. It was observed that the pulse on‐time (ton) and duration had a significant effect on the morphology and activity of the composite electrode towards HER. Flower‐like and spherical morphologies were produced at long and short values of ton, respectively. As‐synthesized electrocatalysts were studied for HER in 0.5 M sulfuric acid (H2SO4). The catalyst with the lowest Pt loading (10 mg/cm2), exhibited outstanding HER performance. It attained a current density of 10 mA/cm2 at an overpotential of 38 mV, close to that of commercial carbon supported platinum (Pt/C, Vulcan XC). This catalyst exhibited a high turnover frequency (23.9 H2 s‐1 @ 100 mV), small Tafel slope (41 mV/dec), and high mass‐specific activity (2.45 A/mgPt @ 100 mV).

Revisiting the Effect of the Resistance to Gas Accumulation in Constant Volume Systems on the Membrane Time Lag

The time-lag method is commonly used to determine membrane permeability, diffusivity and solubility in a single gas permeation experiment in a constant volume system. An unwritten assumption on which this method relies is that there is no resistance to gas accumulation in the downstream receiver of the system. However, this is not the case, even with the specially designed receiver used in this study when, in addition to tubing, the receiver utilizes an additional accumulation tank. The resistance to gas accumulation originates from a finite diffusivity (Knudsen diffusion) of gases in tubing, which are magnified by “resistance-free” accumulation tank(s). As a result of the resistance to gas accumulation, the time lag of the membrane is underestimated, which leads to an overestimation of gas diffusivity in the membrane. The experimentally predicted resistances in different configurations of the receiver, expressed by the difference in the time lag at two different receiver locations, were several times greater than the theoretically predicted values. A high molecular PPO membrane was used to demonstrate this effect. The time lags measured at different locations differed by as much as 30%. The diffusivity of nitrogen in a PPO of 4.04 × 10−12 m2/s determined at the optimum configuration of the receiver is at least 50% lower than the literature-reported values.

Exploring Porous Flow Behavior of the Decomposed Gas from CH4 Hydrate in Clayey Sediments by Molecular Dynamics Simulation.

A fundamental understanding of the fluid flow mechanism during CH4 hydrate dissociation in nanoscale clayey sediments from the molecular perspective can provide invaluable information for macroscale natural gas hydrate (NGH) exploration. In this work, the fluid flow behaviors of the decomposed gas from CH4 hydrate within clayey nanopores under different temperature conditions are revealed by molecular dynamics (MD) simulation. The simulation results indicate that the key influencing factors of gas-water flow in nanoscale clayey sediments include the diffusion and the random migration of gas molecules. The influencing mechanisms of fluid flow in nanopores are closely related with the temperature conditions. Under a low temperature condition, the gas diffusion process is impeded by the secondary hydrate formation, leading to the decline in gas transport velocity within nanopores. However, it is still noteworthy that the gas-water fluid flow channels are not completely blocked by the occurrence of secondary hydrate. Under a high temperature condition, the significant phenomenon of water migration during gas flow is observed, which can be ascribed to the gas-liquid entrainment effect in nanopores of the clayey sediment. These results may provide valuable implications and fundamental evidence for improving gas production efficiency in future field tests of NGH exploitation in marine sediments.

In Situ-Grown Ultrathin Catalyst Layers for Improving both Proton Exchange Membrane Fuel Cell and Anion Exchange Membrane Fuel Cell Performances.

The mass transport and ion conductivity in the catalyst layer are important for fuel cell performances. Here, we report an in situ-grown ultrathin catalyst layer (UTCL) to reduce the oxygen mass transport and a surface ionomer-coated gas diffusion layer method to reduce the ion conducting resistance. A significantly reduced catalyst layer thickness (ca. 1 μm) is achieved, and coupled with the ionomer introduction method, the ultrathin catalyst layer is in good contact with the membrane, resulting in high ion conductivity and high Pt utilization. This ultrathin catalyst layer is suitable for both proton exchange membrane fuel cells and anion exchange membrane fuel cells, giving peak power densities of 2.24 and 1.11 W cm-2, respectively, which represent an increase of more than 30% compared with the membrane electrode assembly (MEA) fabricated by using traditional Pt/C power catalysts. Electrochemical impedance spectra and limiting current tests demonstrate the reduced charge transfer, mass transfer, and ohmic resistances in the ultrathin catalyst layer membrane electrode assembly, resulting in the promoted fuel cell performances.

Novel Water-Splitting Electrolyzer Design Incorporating a Gas Diffusion Electrode and a Gel Membrane for Highly Efficient Hydrogen Production.

Advancements in cost-effective, high-performance alkaline water-splitting systems are crucial for the hydrogen industry. While the significance of electrode material design has been widely acknowledged, the practical implementation of these advancements remains challenging. In this study, we focused on the holistic design of the electrolysis system and successfully developed a novel alkaline water-splitting electrolyzer. The unique configuration of our electrolyzer allows the designed NiFe-LDH/carbon cloth gas diffusion anode to interact solely with the PVA-based gel membrane and air, enabling the direct discharge of oxygen into the gas phase. This innovative feature accelerates anode bubble overflow, reduces gas interference, and decreases the system impedance by minimizing electrode spacing. As a result, by utilizing the NiFeSn-alloy/nickel mesh cathode, our electrolyzer achieves a high current density of 308 mA cm-2 at a cell voltage of 2.0 V and demonstrates exceptional stability over 1000 h.

Femtosecond laser ablated trench array for improving performance of commercial solid oxide cell

The performance of electrode-supported solid oxide cells (SOCs) is limited adversely by gas diffusion impedance in thick and porous support. This work focuses on the improvement of gas transport properties of commercial Ni-YSZ anode-supported SOFC by femtosecond laser-based micromachining where micro-holes of identical depth but different hole separations pitches with minimal heated affected zones were imposed. The polarization resistance calculations and DRT analysis revealed that the presence of the micro-holes improves fuel transport in the anode active zone of commercial SOFC. The presence of the micro-holes resulted in up to 20.8 % and up to 17.2 % reduction in polarization resistance for dry H2 and wet H2 gas-fueled SOFC samples, respectively. Moreover, the decrease in intensity of peaks responsible for fuel diffusion with increasing micro-holed density was observed. Therefore, dense and sparse cells exhibited a performance augmentation of 25 % and 11 % in dry H2 and enhancement of 16 % and 15.6 % in wet H2, respectively. Fs-laser ablation appeared as a unique capability for the post-processing of SOFC elements via imposing different gas channel geometries.

Enhancing CO2 Transport Across the PEG/PPG-Based Crosslinked Rubbery Polymer Membranes with a Sterically Bulky Carbazole-Based ROMP Comonomer.

A series of poly(ethylene glycol)-block-poly(propylene glycol) (PEG/PPG)- and 5,6-di(9H-carbazol-9-yl)isoindoline-1,3-dione (2CZPImide)-based crosslinked rubbery polymer membranes, denoted as PEG/PPG-2CZPImide (x:y), are prepared from the norbornene-functionalized PEG/PPG oligomer (NB-PEG/PPG-NB) and 2-(bicyclo[2.2.1]hept-5-en-2-ylmethyl)-5,6-di(9H-carbazol-9-yl)isoindoline-1,3-dione (2CZPImide-NB) via ring-opening metathesis polymerization (ROMP). The molar ratio (x:y) of the NB-PEG/PPG-NB (x) to 2CZPImide-NB (y) monomers is varied from 10:1 to 6:1. X-ray diffraction (XRD), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS), and pure gas permeability studies reveal that the comonomer 2CZPImide-NB successfully increases the d-spacing among the crystalline PEG/PPG segments, hence enhancing the diffusivity of gases through the membranes. The synthesized membranes exhibit good CO2 separation performance, with CO2 permeabilities ranging from 311.1 to 418.1 Barrer and CO2/N2 and CO2/CH4 selectivities of 39.4-52.0 and 13.4-16.0, respectively, approaching the 2008 Robeson upper bound. Moreover, PEG/PPG-2CZPImide (6:1), displaying optimal CO2 permeability and CO2/N2 and CO2/CH4 selectivities, shows long-term stability against physical aging and plasticization resistance up to 20 days and 10 atm, respectively.

Zn-Cu bimetallic gas diffusion electrodes for electrochemical reduction of CO2 to ethylene

The application of renewable energy to drive the electroreduction of carbon dioxide (CO2) into valuable compounds serves as a means of energy storage and simultaneously aids in the mitigation of climate change. In this study, a bimetallic catalyst consisting of Zinc and Copper is synthesized using the Zinc-doped HKUST-1 metal-organic framework. The catalyst is then fabricated on gas diffusional electrode and investigated in both H-Cell and Flow cell configurations for electrochemical CO2 reduction reaction (ECO2RR). In the H-Cell, the catalysts that have been developed exhibit an ethylene faradaic efficiency (FE) up to 40 % when operated at a potential of −0.8 V relative to the reversible hydrogen electrode (RHE). The Zn-Cu bimetallic gas diffusion electrodes (GDE) exhibit an impressive ethylene FE up to 45 % when operating at a current density of −200 mA cm−2 at −1.0 V versus RHE in the flow cell. This research offers valuable insights into the strategic development of copper-based bimetallic catalysts with the aim of enhancing the efficiency of electrochemical reduction of CO2 to yield multicarbon compounds.

Three-dimensional simulation of a proton exchange membrane fuel cell with non-integrated metal foam as flow distributor

In proton exchange membrane fuel cells (PEMFCs), the presence of metal foam in the flow channels improves the polarity diagram and increases the cell generated power, but this leads to an increase in pressure drop and, as a result, an increase in parasitic power. In this study, two types of non-integrated arrangements of metal foam are introduced, which, in addition to having high generated power, have lower pressure drop, and subsequently, lower parasitic power, and will also result in a more uniform distribution of temperature and current density. In the first arrangement, which is called IPTG, an abbreviation of Increased Porosity Toward the gas diffusion layer (GDL), the channels are divided into four equal parts with variable porosities from 0.65 to 0.95, in such a way that the metal foam layer with the highest porosity (0.95) is located in the closest area to the GDL. In the second arrangement which is called Reduced Porosity Toward the GDL, the metal foam layer with the least porosity (0.65) is located in the closest area to the GDL. To make a better comparison between the present model and the conventional one, the net power parameter with subtracting parasitic power from generated electrical power of the fuel cell is calculated for all models. The numerical study of this paper is conducted by developing a three-dimensional computational fluid dynamics model by employing user-defined functions. The results show that the net power of the PEMFC with IPTG arrangement is 3.8 % higher than that of the one with integrated metal foam arrangement with a porosity of 0.95. Also, the higher the pores per inch (PPI) of metal foam used in the non-integrated metal foam model, the greater the net power of the fuel cell, so that, the net power of PEMFC with IPTG arrangement with PPI=80 is 3.2 % more than that of PPI=20.

A Scalable and Robust Water Management Strategy for PEMFCs: Operando Electrothermal Mapping and Neutron Imaging Study.

Effective water management is crucial for the optimal operation of low-temperature polymer electrolyte membrane fuel cells (PEMFCs). Excessive liquid water production can cause flooding in the gas diffusion electrodes and flow channels, limiting mass transfer and reducing PEMFC performance. To tackle this issue, a nature-inspired chemical engineering (NICE) approach has been adopted that takes cues from the integument structure of desert-dwelling lizards for passive water transport. By incorporating engraved, capillary microchannels into conventional flow fields, PEMFC performance improves significantly, including a 15% increase in maximum power density for a 25 cm2 cell and 13% for a 100 cm2 cell. Electro-thermal maps of the lizard-inspired flow field demonstrate a more uniform spatial distribution of current density and temperature than the conventional design. Neutron radiography provides evidence that capillary microchannels in the lizard-inspired flow field facilitate the efficient transport and removal of generated liquid water, thereby preventing blockages in the reactant channels. These findings present a universally applicable and highly efficient water management strategy for PEMFCs, with the potential for widespread practical implementation for other electrochemical devices.

Sufficiency of near-surface water ice as a driver of dust activity on comets. Rethinking the old enigma

Nearly all contemporary theoretical research on cometary dust activity relies on models depicting heat transfer and sublimation products within the near-surface porous layer. Gas flow exerts a pressure drag to the crust agglomerates, counteracting weak gravity and the tensile strength of that layer. Our interpretation of data from the Rosetta mission, and our broader comprehension of cometary activity, hinges significantly on the study of this process. We investigate the role played by the structure of the near-surface porous layer and its associated resistance to gas flow, tensile strength, pressure distribution, and other characteristics in the scenario of the potential release of dust agglomerates and the resulting dust activity. We employ a thermophysical model that factors in the microstructure of this layer and radiative heat conductivity. We consider gas flow in both the Knudsen and transition regimes. To accomplish this, we use methods such as test-particles Monte Carlo, direct-simulation Monte Carlo, and transmission probability. Our study encompasses a broad spectrum of dust-particle sizes. We evaluated the permeability of a dust layer composed of porous aggregates in the submillimetre and millimetre ranges. We carried out comparisons among various models that describe gas diffusion in a porous dust layer. For both the transition and Knudsen regimes, we obtained pressure profiles within a non-isothermal layer. We discuss how the gaps in our understanding of the structure and composition could impact tensile strength estimates. We demonstrate that for particles in the millimetre range, the lifting force of the sublimation products of water ice is adequate to remove the layer. This scenario remains feasible even for particles on the scale of hundreds of microns. This finding is crucial as the sublimation of water ice continues to be the most probable mechanism for dust removal. This study partially overturns the previously held, pessimistic view regarding the possibility of dust removal via water sublimation. We demonstrate that a more precise consideration of various physical processes allows elevation of the matter of dust activity to a practical plane, necessitating a fresh quantitative analysis.

Geometrical parameters optimization to improve the effective thermal conductivity of the gas diffusion layer for PEM fuel cell

The main concern of this article is a numerical investigation of the geometrical parameters of composite gas diffusion layers (CGDLs) and their impact on effective thermal conductivity (ETC). The geometric parameters under investigation include porosity, thicknesses of the gas diffusion layer (GDL) and micro porous layer (MPL), as well as fibers diameter and orientation. Additionally, non-geometric parameters such as saturation level and operating temperature are examined. This study utilizes realistic full microstructure simulations (GDL + MPL + PolyTetraFluoroEthylene/PTFE + binder) of a paper GDL type (SGL 25BC) to examine and enhance ETC in both in-plane (IP) and through-plane (TP) directions by optimizing the parameters under investigation. To achieve this, a MATLAB code was used to generate microstructures under various conditions, which were simultaneously imported into COMSOL multi-physics via live link technique (LLT). Subsequently, the non-dominated sorting genetic algorithm II (NSGAII) was employed as an optimization method to refine the geometric/non-geometric parameters. Finally, the ETC results for both TP and IP directions were compared with experimental data from the literature. The optimized microstructure exhibits higher ETC values compared to both the initial simulated microstructure and the experimental data. This finding indicates that fabricating CGDLs within the recommended range of optimal geometric values can lead to a substantial increase in their ETC.

Computational Fluid Dynamic Investigation of Local Flow-Field Conditions in Lab Polymer Electrolyte Membrane Fuel Cells to Identify Degradation Stressors and Performance Enhancers

The use of polymer electrolyte membrane (PEM) fuel cells as an alternative to internal combustion engines can significantly contribute to the decarbonization of the transport sector, especially for heavy-duty applications. However, degradation is still an issue for this type of component, affecting their durability and performance. In this scenario, a detailed analysis of the anodic and cathodic distributors’ flow-field geometry may help to identify some local stressors that trigger the degradation mechanism, such as local hot spots and reactants not having a uniform distribution. A computational fluid dynamic (CFD) methodology is able to provide a volumetric description of a PEM fuel cell so it can be a useful tool to better understand the physical phenomena that govern the component operations. In this work, the open-source simulation library openFuelCell2 is adopted for a detailed analysis of two different PEM fuel cells characterized by standard distributor geometries, namely a parallel channel geometry and a serpentine configuration. The library, based on the OpenFOAM code, has been extended with a novel implementation accounting for the catalytic activity reduction due to the platinum oxide (PtOx) formation occurring under certain particular conditions. The adopted methodology is firstly validated resorting to experimental data acquired for the two different fuel cell configurations. The analysis highlights that the PtOx formation leads to a reduction in the fuel cell performance reaching up to 60–80% when operating at high voltages. Then, the effect of the distributor geometries on the component performance is investigated by resorting to in-plane and through-plane physical quantity distribution, such as reactant concentration, pressure or velocity fields. While the parallel flow channel configuration shows some diffusion losses under the rib, the serpentine channel geometry configuration can achieve some local performance peaks thanks to the convective flow in the gas diffusion layer (GDL) driven by local pressure gradients. Furthermore, the local enhancement in terms of higher current density under the rib is associated with an effective heat removal due to the high thermal capacity of the bipolar plate, avoiding the generation of local hot spots.

MUSE Analysis of Gas around Galaxies (MAGG) - VI. The cool and enriched gas environment of z≳3 Lyα emitters

We present a novel dataset that extends our view of the cosmic gas around $z 3-4$ Lyalpha emitters (LAEs) in the Muse Analysis of Gas around Galaxies (MAGG) survey by tracing a cool and enriched gas phase through 47 absorbers identified in newly obtained VLT/X-shooter near-infrared quasar spectra. Jointly with the more ionized gas traced by systems and the neutral from previous work, we find that LAEs are distributed inside cosmic structures that contain multiphase gas in composition and temperature. All gas phases are a strong function of the large-scale galaxy environment: the and the strength and kinematics positively correlate with the number of associated galaxies, and it is $ times more likely to detect metal absorbers around groups of LAEs than isolated ones. Exploring the redshift evolution, the covering factor of around groups of LAEs and isolated ones remains approximately constant from $z to $z but the one of around group galaxies drops by $z Adding the cool enriched gas traced by the absorbers to the results that we obtained for the and gas, we put forward a picture in which LAEs lie along gas filaments that contain high column-density systems and are enriched by strong and absorbers. While the gas appears to be more centrally concentrated near LAEs, weaker systems instead trace a more diffuse gas phase extended up to larger distances around the galaxies.

Establishment and Solution of a Finite Element Gas Exchange Model in Greenhouse-Grown Tomatoes for Two-Dimensional Porous Media with Light Quantity and Light Direction

An accurate gas utilization model is essential for precisely detecting plant photosynthetic capacity. Existing equipment for measuring the plant photosynthetic rate typically considers the key parameters of mesophyll cell conductance and a photosynthetic model based on the carbon reaction process under direct light conditions. However, the light environment signals received by the plant canopy not only vary significantly in incidence angles, but the effective light intensity also differs greatly from the measured values under vertical incidence conditions. To reduce the deviation between existing photosynthetic models and the actual photosynthetic efficiency of leaves, this study employs the gas diffusion method from engineering, using the finite element approach. Based on elastic mechanics and seepage mechanics, the internal stress field control equation of tomato leaves and the two-phase flow equation under a CO2 porous medium were derived. A mathematical model of porous gas–liquid two-phase fluid-solid coupling was established, solved, and analyzed. Preliminary verification was conducted through tests. The results show that in the initial stage of CO2 entering the leaf, the gas flow velocity is higher because of the larger pressure gradient between the pore and the leaf. In this stage, the gas diffusion rate is higher. As the intake time increases, the pressure gradient gradually decreases, and the inlet velocity slows down. Consequently, the diffusion rate gradually reduces. Because of the coupling of light quantity and light direction, the gas diffusion rate significantly increases compared with the uncoupled model. Additionally, a diffusion model that does not consider fluid–solid coupling will overestimate the gas flow rate as the depth of gas entry increases. Therefore, the internal gas diffusion model must account for the effect of coupling on the diffusion rate.

The experimental study on multiple mechanisms of enhanced CBM recovery by autogenous nitrogen fracturing fluid

Hydraulic fracturing is a widely adopted technique for enhancing the permeability of coalbed methane (CBM) reservoirs, thus improving the recovery of CBM. Although previous studies have extensively explored the role of fracturing fluids in creating fractures and improving permeability, there remains a notable deficiency in the literature regarding the impact of these fluids on enhancing gas desorption and diffusion. This research employs an experimental investigation into a novel autogenous nitrogen (N2) fracturing fluid, demonstrating its significant potential for increasing CBM reservoir permeability and enhancing the desorption and diffusion of CBM. Through optimization experiments, the study initially determines the optimal proportions of sodium nitrite (NaNO2), ammonium chloride (NH4Cl), and an activator to maximize the generation of N2. Kinetic experiments and subsequent analyses reveal that the autogenous N2 fracturing fluid releases a substantial amount of N2 and heat, with the reaction rate highly influenced by initial pressure and temperature conditions. Fracturing experiments on coal samples demonstrate that the release of N2 increases the fluid pressure within the pore spaces, initiating micro-fracture and enhancing permeability. Additionally, the increased pore pressure mitigates the water block effect and improves the gas diffusion. The heat and gas released during the reaction significantly accelerate the desorption of CBM within coals. This fracturing fluid offers a comprehensive approach for enhancing CBM recovery.

Advancing Energy Sustainability Through Solar-to-Fuel Technologies: From Materials to Devices and Systems.

To achieve carbon neutrality and sustainable development, innovative solar-to-fuel systems have been designed through the integration of solar energy harvesting and electrochemical devices. Over the last decade, there have been notable advancements in enhancing the efficiency and durability of these solar-to-fuel systems. Despite the advancements, there remains significant potential for further improvements in the performance of systems. Enhancements can be achieved by optimizing electrochemical catalysts, advancing the manufacturing technologies of photovoltaics and electrochemical cells, and refining the overall design of these systems. In the realm of catalyst optimization, the effectiveness of materials can be significantly improved through active site engineering and strategic use of functional groups. Similarly, the performance of electrochemical devices can be enhanced by incorporating specific additives into electrolytes and optimizing gas diffusion electrodes. Improvements in solar harvesting devices are achievable through efficient passivant and self-assembled monolayers, which enhance the overall quality and efficiency of these systems. Additionally, optimizing the energy conversion efficiency involves the strategic use of DC converters, photoelectrodes, and redox media. This review aims to provide a comprehensive overview of the advancements in solar-powered electrochemical energy conversion systems, laying a solid foundation for future research and development in the field of energy sustainability.