This paper describes the role of the canopy in the collection of airborne acid substances and in the neutralization of the acids by cation exchange processes. Bulk throughfall was collected in three different types of forest in the suburban area of Yokohama. Bulk precipitation was also collected in the open field outside of the forest studied. Samples were analyzed for Ca 2+, Mg 2+, K +, Na +, NH 4 +, H +, Cl −, NO 3 −, SO 4 2, and Al. For almost all components, bulk throughfall exceeded bulk precipitation in elemental flux, owing to interception deposition and canopy leaching. Only the H + flux decreased during passage of precipitation through the canopy. Canopy leaching of Ca 2+, Mg 2+, and K + was determined by assuming that Ca 2+ /Al, Mg 2+ /Al, or K + /Al ratios in interception deposition are equal to the corresponding ratios in bulk precipitation. Total acid deposition to the forest, assumed to be equal to the throughfall fluxes of SO 4 2− and NO 3 −, exceeded the flux of acid substances (H + + NH 4 +) in bulk precipitation by factors of 1.7, 2.0, and 2.5 for Japanese deciduous oak forest, Japanese evergreen oak forest, and Japanese cedar forest, respectively, indicating the importance of interception deposition of acid substances to the canopy. From 49 to 74% of total acid deposition was neutralized at the canopy. A major part of the neutralization was attributable to the cation exchange processes at the canopy surface. Evidently the processes depend on the nature and form of the leaf surface.