Dielectric Anisotropy Research Articles

Dielectric and electrical properties of liquid crystals doped with ferroelectric nanoparticles

ABSTRACT The present work examines the impact of incorporating ferroelectric Ba0.85Sr0.15TiO3 nanoparticles (NPs) on the thermodynamic, dielectric, electrical, ionic, and electro-optical properties of 4-cyano-4’-octylbiphenyl (8CB) as Liquid Crystal (LC). The introduction of ferroelectric NPs results in a notable elevation of the nematic-isotropic phase transition temperature, which is consistent with theoretical models. Impedance spectroscopy was employed to investigate bulk and interfacial phenomena, revealing a low-frequency relaxation mode attributed to space charge polarisation. In comparison to the pure LC, the dielectric anisotropy and the DC conductivity were found to be increased in the doped samples. Furthermore, the reduction in the concentration of ions on the surface, their diffusion constant, and their mobility, coupled with a decrease in the threshold voltage, simultaneously indicate the trapping of ions by the ferroelectric NPs. The screening effect renders dispersed ferroelectric NPs an optimal solution for addressing the issue of ionic contamination and eliminating its deleterious effects.

Local Orientation Transitions to a Lying Helix State in Negative Dielectric Anisotropy Cholesteric Liquid Crystal

Orientation transitions in a cholesteric liquid crystal (CLC) layer with negative dielectric anisotropy, under the influence of a non-uniform spatially periodic electric field created using a planar system of interdigitated electrodes, were studied experimentally and numerically. In the interelectrode space, transitions are observed from a planar Grandjean texture, with the helix axis perpendicular to the layer plane, to states with a lying helix, when the helix axis is parallel to the layer plane and perpendicular to the electrode stripes. It was found that the relaxation time of the induced state in the Grandjean zones, corresponding to two or more half-turns of the helix, significantly exceeded the relaxation time for the first Grandjean zone with one half-turn. An analysis of experimentally observed and numerically simulated textures shows that slow relaxation to the initial state in the second Grandjean zone, as well as in higher-order zones, is associated with the formation of local topologically equivalent states. In these states, the helix has a reduced integer number of helix half-turns throughout the layer thickness or unwound into the planar alignment state.

Widely tunable reflection by a hybrid ion-doped positive-negative chiral nematic liquid crystal under an electric field.

In this study, a new methodology, in which the cation and chiral agent are doped in positive and negative nematic liquid crystal mixture to form cation-doped positive-negative chiral nematic liquid crystals (PN-CNLCs), is proposed. These PN-CNLCs are capable of achieving a wide wavelength tuning range close to 90 nm under the action of a high-frequency electric field. The dielectric interaction between these two liquid crystals with different dielectric anisotropies in the electric field allows for the effective change of the pitch of the CLCs. We discovered the tilting of the pitch in the PN-CNLCs by a series of well-designed validation experiments. The experimental results prove the symmetrical helix is formed along the alignment direction in PN-CNLCs. Furthermore, the experiments demonstrated that an increase in voltage does not directly affect the pitch, but it increases the tilt angle of the helix axis with respect to the normal of the LC cell. This study offers, to our knowledge, a novel perspective on the tuning performance of CLCs under electric field conditions, by integrating the properties of positive and negative liquid crystals. This finding not only contributes to the understanding of the electric field response mechanism of CLCs but also provides new avenues for the application of CLCs in fields such as wavelength tuning.

Controlling the dielectric constant values of nematic liquid crystals using ferroelectric and multiferroic nanoparticles

Notably, the simultaneous manifestation of ferromagnetic and ferroelectric properties at ambient temperature has spurred significant interest in incorporating multiferroic bismuth ferrite nanoparticles (BiFeO3) into liquid crystal matrices. In this study, the parallel and perpendicular dielectric components ( and ) and dielectric anisotropy () of two different nanoparticles, barium titanate (BaTiO3) and BiFeO3, doped into E7, were measured at various temperatures and frequencies. Nematic mixture E7, a widely utilized nematic liquid crystal in research and display technologies, is a eutectic mixture composed of four cyanobiphenyl derivatives i.e. 5CB, 7CB, 8OCB, and 5CT. The findings indicate a substantial reduction in dielectric anisotropy upon introducing nanoparticles into the nematic liquid crystal environment. This research highlights the significant influence of barium titanate nanoparticles, which are smaller (approximately 12 nm), on the dielectric constant. This effect was analyzed based on varying concentrations and compared to a nanoparticle with ferroic properties. Moreover, the dielectric constant can be modulated through an alternative approach. Specifically, applying an electric field during the filling process of liquid crystal cells leads to changes in the dielectric constant. These changes, observed for both nanoparticles, were particularly evident at a precise concentration of 0.1 wt%, resulting in a decreased dielectric constant.

Effect of Guest Particles on the Functional Dielectric Properties of Materials for Display Application

AbstractIn this study the dielectric properties are experimentally studied and also analyzed the influence of guest particles on the functional properties of various liquid crystals. The polar and elastic energy of the nanoparticles is found to affect the functional energy of pure suspension. In addition to this, the functional dielectric anisotropy of the dispersed system takes modified form. In this study experiments are performed on various materials to find dielectric anisotropy and also found in good agreement with theoretical explanation.

Boolean Logic Gate Operation in Bacteriorhodopsin of Purple Membrane Based on a Molten Globule-like State.

Bacteriorhodopsin (bR) of purple membrane (PM) has increasing technical interests, particularly in photonic devices and bioelectronics. The present work has concerned with monitoring the temperature dependence of passive electric responses in-plane and out-of-plane of the membranes. Based on thermal properties observed orthogonally here for PM, a high-temperature intermediate of bR has been suggested to populate at around 60 °C, which may be ascribed to a molten globule-like state. This intermediate has been found to be enclosed between two reversible thermal transitions for PM. Large-scale turnover in the energy of activation, for these two thermal transitions, occurs steeply at such state at 60 °C, above which does bR reverse the sign of dielectric anisotropy (i.e. crossover) provided the operating frequency should be above the crossover frequency, at which the reversal occurs. No such crossover was found to occur below the crossover frequency, even above the crossover temperature (i.e. 60 °C). Likewise, no such crossover was found to occur below the crossover temperature, even above the crossover frequency. Relying on this reasoning, a logic gate operation may be declared implicating bR for bioelectronics and sense technological relevance. In addition, the results specify "dual frequency" as well as "dual temperature" characteristics to bacteriorhodopsin.

Magnetically induced tunable exceptional and Dirac points

The photonic properties of cholesteric liquid crystals (CLCs) in an external magnetic field parallel to the helix axis are theoretically investigated for the first time in the short-wavelength band of the spectrum, where exceptional points (EPs) are found. It was shown that at the EP the real parts of two of four wave numbers touch each other or intersect at the absence of the dielectric anisotropy, and their imaginary parts intersect. At the EP the reflection, transmission and absorption show the same magnitudes for two eigenmodes of CLC layer. At anisotropic absorption near the EP there appear points where the magnetically induced transmittance/absorption are observed. The tunability of the EP was shown, i.e. we can change its wavelength by changing the magnitude of the external magnetic field. It was demonstrated the resonant enhancement of the chirality near the EP. Then it was shown that near the EP the two eigenmodes of CLC layer become strongly non-orthogonal.

Synergistic effects of anionic surfactant doping on dielectric and electro-optical properties of nematic liquid crystals by cyano-ionic interactions

Modern research has long focused on controlling and optimizing the dielectric, electro-optical and optical attributes of liquid crystals (LCs) to increase their technological value. Numerous approaches have been investigated for this reason in an effort to overcome various issues such as high response time, high driving voltage requirements, low dielectric anisotropy and limited operating temperature range, etc. The strategy utilizing binary/multicomponent systems is the most investigated and seems to have the most potential out of all the other techniques. In keeping with the same subject, the influence of anionic surfactant on the dielectric, electro-optical, and optical properties of nematic LC (NLC) has been examined. Precisely, dodecane-1-sulfonic acid sodium salt (SDS) which is an anionic surfactant was dispersed in a room temperature NLC E7 at various concentrations. Our findings reveal a significant alteration in the electro-optical behavior resulting from the introduction of an anionic surfactant, extending well beyond the instance of electrode polarization, albeit with a detrimental impact on performance within the low-frequency range as a result of increased ionic contribution. The main findings of this study include a 17.5%% increase in dielectric anisotropy, an appreciable reduction of about 30%% in threshold voltage and rotational viscosity, and approximately 64% reduction in response time in the host NLC due to the addition of anionic salt in it. A significant photoluminescence quenching of about 64%% is observed after dispersion of 3.0% by weight anionic surfactant in E7. These findings offer potential pathways for the development of future technologies in various domains, including photonic devices, biological imaging, light-emitting diodes (LEDs), and luminescent markers.

Development of Reconfigurable High-Frequency Devices Using Liquid Crystal in Substrate-Integrated Gap Waveguide Technology

This article presents the theoretical study, numerical simulation and fabrication of a phase shifter and a stub resonator for use in microstrip ridge gap waveguide (MRGW) technology, using a liquid crystal (LC) in the substrate as a reconfigurable material. The phase shifter and the stub resonator are filled with LC, and thanks to the LC’s dielectric anisotropy properties, the phase shift and the resonance response can be easily controlled using an external electric or magnetic bias field. The phase shifter was designed to operate in the range of 10 to 20 GHz, and the resonator was designed to operate in the range of 7.8 to 8.8 GHz. The phase shifter’s responses (including both phase shift and insertion losses), associated with both the parallel and perpendicular permittivity values of the LC, were computed and measured, and then the corresponding figure of merit (FoM) was extracted. The resonator’s frequency responses, associated with both the LC’s parallel and perpendicular permittivity, were computed. The resonator’s frequency responses, which provided different polarization voltages, were measured and compared to the simulation results. All technological issues related to both prototypes are also discussed here. The good agreement between the simulation and measurement results confirm this technology as a viable approach to the practical implementation of these microwave reconfigurable devices.

New Series of Hydrogen-Bonded Liquid Crystal with High Birefringence and Conductivity.

Liquid crystals with high dielectric anisotropy, low operational thresholds, and significant birefringence (Δn) represent a key focus in soft matter research. This work introduces a novel series of hydrogen-bonded liquid crystals (HBLCs) derived from 4-n-alkoxybenzoic, 4-alkoxy-3-fluorobenzoic derivatives (nOBAF), 4-alkoxy-2,3-fluorobenzoic derivatives (nOBAFF), and 2-fluoro-4-nitrobenzoic acid. The HBLCs were characterized using Fourier transform infrared spectroscopy, and their thermal behavior was evaluated via differential scanning calorimetry. Optical observations were conducted using polarized optical microscopy. The results indicate that mixtures containing benzoic acid with a bilateral fluorine substituent exhibit both SmA and SmC phases, while those with a unilateral fluorine substituent exhibit nematic and SmA phases. Moreover, an increase in the length of the alkoxy chain results in an expanded mesophase temperature range. This study demonstrates that the presence of a fluorine substituent and the incorporation of an NO2 group in the molecular structure result in an increase in dielectric permittivity, DC conductivity, dielectric anisotropy, and birefringence.

Dielectric anisotropy in self-assembling MXene-based lyotropic nematic compounds

The formation of a lyotropic liquid crystal phase at the level of MXene-based aqueous dispersions due to the self-assembling capacity of these two-dimensional (2D) materials has been previously successfully reported. However, the influence of electrical external factors has been less studied in spite of the fact that understanding the electrical behaviour of 2D-based liquid crystal compounds is vital for fostering the development of new innovative applications. Consequently, within this paper, we report an in-depth evaluation of the dielectric properties of liquid crystalline phases in Ti3C2 MXene aqueous dispersions. The dependence on the low voltage of planar ε⊥′ to homeotropic ε∥′ orientational transition is emphasized and discussed, while the influence of the electric field frequency at the level of dielectric anisotropy is assessed in respect to various concentrations of MXene flakes within the same 2D-based compounds. Nonetheless, dielectric spectroscopy highlights the biphasic nature (containing both nematic and isotropic phases) of the studied aqueous Ti3C2 MXene inks visible up to 20% MXene. Above this concentration, the existence of a pure nematic phase in the dispersion of highMXene concentration (>20 wt%) was detected based on the evaluation of dielectric permittivity against various voltage values.

On the effects of dispersing polar nanoparticles in liquid crystals

We have investigated the effect of adding polar rodlike nanoparticles (NPs) to a liquid crystal using Monte Carlo simulations. The mesogens (Ms) are represented with Gay–Berne elongated ellipsoids endowed with a central axial electric dipole. A NP is instead modelled by a overall rod-like set of rigidly assembled Lennard–Jones spherical beads (Orlandi et al. Phys. Chem. Chem. Phys. 18, 2428–2441 (2016). doi:10.1039/C5CP05754J) that are either non-polar or endowed with a central axial dipole of different strengths. We consider two cases: one of strong NP-M affinity and weak NP-NP interactions (case 1) and the opposite one of weak NP-M affinity and strong NP-NP interactions (case 2). We find that for case 1 adding polar NPs slightly lowers the nematic-isotropic transition temperature T NI which instead, for case 2, is essentially unaffected. Having strongly polar, instead of non-polar NPs reduces the T NI difference with the pristine one, while significantly increasing the dielectric anisotropy in the nematic phase, which could be useful in applications.

Modeling and measurement of dielectric anisotropy in materials manufactured via fused filament fabrication processes

Additive manufacturing (AM) is increasingly recognized as an enabling technology for novel devices with increased functionality and bandwidth for microwave applications. However, due to the layer-by-layer build approach employed by most AM techniques, internal patterns are introduced to printed materials, which cause an effective anisotropy in their material parameters. An electrostatic model inspired by parallel plate capacitors, describing the dielectric anisotropy of materials manufactured with fused filament fabrication (FFF) AM techniques is proposed in this work. The accuracy of the model’s predictions about the permittivity tensor of printed materials is investigated via numerical simulations. Furthermore, permittivity tensor measurements are carried out for samples printed with various materials and print settings. Measurement data is fitted to the model via a least squares approach, and excellent agreement is observed. Novel conclusions about the impact of material and print parameters on the effective permittivity of additively manufactured materials, improving the accuracy in modeling and designing additively manufactured microwave devices are drawn.

P‐193: Ring‐shaped circular Patch liquid crystal display structure based on fringe field effect

The liquid crystal display (LCD) continues to hold a prominent position in the display industry. These years' key research topic is the fringe field effect, which aims to improve the LCD's performance. A new LCD structure utilizing the fringe field effect has been identified as a promising solution. This structure allows for the control of the electromagnetic field of the liquid crystal cell by regulating the voltage of the ring‐shaped and circular‐patch cell (RCC). This innovative structure is comprised of nematic liquid crystals (LCs) with negative dielectric anisotropy, a two‐electrode system consisting of a ring‐shaped ITO structure on the top layer and a circular patch structure on the bottom layer, and a SiO2 porous structure. Finite element simulation tests have verified the electric field strength, transmittance, and contrast of the cell and the 2x2 matrix structure, meeting the design objectives. This breakthrough has significant potential for application in the display field.

Comparative Study of the Optical and Dielectric Anisotropy of a Difluoroterphenyl Dimer and Trimer Forming Two Nematic Phases.

We present a comparative study of the optical and dielectric anisotropy of a laterally fluorinated liquid crystal dimer and its homologous trimer, both exhibiting two nematic phases. In the high-temperature nematic phase, both oligomers exhibit positive optical anisotropy with similar magnitude, which, however, is lower in comparison with the optical anisotropy of the monomer. In the same temperature range, the dielectric permittivity along and perpendicular to the nematic director, measured on magnetically aligned samples, reveals negative dielectric anisotropy for both oligomers, which saturates as the temperature approaches the N-N phase transition temperature. Comparison of the dielectric anisotropies of the oligomers with the corresponding anisotropy of the monomer indicates a systematic variation of its magnitude with the number of the linked mesogenic units. Results are compared with the corresponding anisotropies of the cyanobiphenyl dimers, the archetypal compounds with two nematic phases, and are discussed in terms of the dipolar structure of the mesogens and the dipolar correlations in their nematic phases.

Ferroelectric and antiferroelectric chiral multilactate liquid crystalline materials with negative dielectric anisotropy

In this work, the mesomorphic, electro-optic and dielectric properties have been discussed in the light of molecular structure-property correlations of two chiral multilactate liquid crystalline materials possessing the orthogonal paraelectric Smectic A* phase, tilted ferroelectric Smectic C* phase and the tilted antiferroelectric Smectic CA* phase, over a substantially broad temperature range. Interestingly, a reasonably rare re-entrant Smectic C* phase (SmCre*) has also been identified in one of the investigated materials. These materials differ in their linkage groups (keto or ether) and an additional chiral unit in the terminal chain. The phase transition temperatures and transition enthalpies were determined from Polarizing Optical Microscopy and Differential Scanning Calorimetry (DSC) measurements. The compounds exhibit negative dielectric anisotropy (Δε) throughout the mesomorphic range (maximum −18 and −4 in SmA* for both the compounds) and moderately high values of spontaneous polarization (∼153 nC/cm2 in SmCre* phase). The temperature dependence of the response time (τ), bulk viscosity (η) and the activation energies (Ea) throughout the mesomorphic phase have been determined from the spontaneous polarization measurements. To emphasize the structure-property correlations in more detail, dielectric spectroscopy measurement has also been performed to measure the dielectric strength, dielectric loss, frequency dependent permittivities, relaxation time and relaxation frequencies. The clear evidence of the relatively rare SmCre* phase has also been confirmed from the temperature and frequency dependence of the dielectric permittivity. These results shed important light on the emergence of these materials as a smart alternative for their application in multicomponent mixtures targeted for advanced electro-optic and photonic devices.

Dielectric anisotropy in liquid crystal mixtures with nematic and smectic phases

Abstract The modulation of dielectric anisotropy (△ε) is pivotal for elucidating molecular interactions and directing the alignment of liquid crystals. In this study, we combine liquid crystals with opposing dielectric anisotropies to explore the impact of varying concentrations on their properties. We report the sign-reversal of △ε in both the nematic and smectic A phases of these mixed liquid crystals, alongside a dual-frequency behaviour across a broad temperature spectrum. Our research further quantifies the influence of mixture ratios under various temperatures and electric field frequencies. This exploration may pave the way for the discovery of new physical phenomena.

Memorizable Electro‐Birefringence Effect Exhibited by Transparent Liquid Crystal/Polymer Composite Materials

AbstractPolymer‐dispersed liquid crystals (PDLCs) with nano‐phase‐separated structures, in which nanometer‐sized liquid crystal (LC) domains are dispersed within a polymer matrix (nano‐PDLCs), are transparent solid materials whose optical properties can be modulated by applying an electric field (E‐field). Because the proportion of LC that can respond to an electric field is small, the specific surface area of the phase‐separated interface of nano‐PDLCs is larger than that of conventional PDLCs, resulting in higher drive voltages than those of conventional PDLCs. To lower the driving voltage of nano‐PDLCs, highly polar LCs (C3DIO) are used with a large dielectric anisotropy (>10000), and prepared nano‐PDLCs using DIO mixtures obtained by mixing them with related compounds as the host LC. Nano‐PDLCs employing DIO mixtures exhibit higher E‐field responsivity than those using conventional LC. In addition, the electro‐optical Kerr coefficient at visible wavelength is significantly high, reaching 10−8 m V−2. Furthermore, nano‐PDLCs using the DIO mixture exhibit a memory effect in which the induced birefringence remains even after the removal of the in‐plane E‐field. Memorized birefringence can be erased by heating or applying an E‐field perpendicular to the substrate surface. Nano‐PDLCs using a DIO mixture can be rewritable electro‐birefringence‐responsive materials that can memorize arbitrary birefringence values.

Electro-optic characteristics of chiral nematic layers deformed by in-plane electric field

ABSTRACT Deformations of twisted and super-twisted layers composed of chiral and nonchiral nematic liquid crystals induced by in-plane electric field were studied numerically. The right-hand twisted structures with twist angles equal to 90°, 120°, 150°, 180°, 210°, 240° and 270° placed between crossed polarisers were considered. The optical transmission due to electro-optic effect which occurred in such systems was studied as a function of applied electric field strength. Steep and linear electro-optic characteristics were found in the case of nonchiral nematic confined in cells twisted by 90°. Such characteristics were favoured by large twist elastic constant, large dielectric anisotropy and weak azimuthal anchoring. In the case of super-twisted layers, useful characteristics were found for twist angles 210°, 240° and 270°, small twist elastic constant, strong azimuthal anchoring and large dielectric anisotropy.

Impact of TiO2, ZnO, and Methylene Blue Doping on the Dielectric anisotropy of planar 8CB nematic liquid crystal

In this study, the impact on the dielectric properties of 8CB with the dispersion of TiO2, ZnO, and methylene blue (0% to 5%) is examined. Employing capacitance–voltage (C–V) measurements across frequencies ranging from 10 kHz to 2 MHz, we explore the combined effects of dispersed photoactive nanoparticles and mono/polymeric materials like MB. Our investigation provides novel insights into the nuanced variations induced by transition-metal oxide loaded 8CB, highlighting the role of their oxidation states, and elucidates the influence of larger photoactive monomers on 8CB’s dielectric polarizability. The study found that the dielectric anisotropy was strongly influenced by frequency and doping, changing sign at a critical frequency. Our work represents the first comparative analysis incorporating these oxides alongside photoactive materials like MB.