Diallyl Phthalate Research Articles

Microwave-assisted derived polymers from crude glycerol: syntheses, thermogravimetric characteristics, and kinetics

Allyl alcohol was polymerized into poly (diallyl phthalate), poly (allyl formate), and poly (allyl alcohol) using a microwave-assisted reaction. Thermal analysis identified poly (diallyl phthalate) as the most thermally stable polymer. Different reaction mechanisms were discussed in kinetics, with the three-dimensional Jander mechanism identified as the rate-determining step. Furthermore, thermodynamic parameters indicated the endothermicity and spontaneity of the degradation processes.

Electrospun nanofibers-based thin film microextraction for enrichment of phthalate esters in biodegradable plastics.

In this work, a novel electrospun nanofiber (PAN/TpBD; 2,4,6-triformylphloroglucinol [Tp] and benzidine [BD]; polyacrylonitrile [PAN]) was fabricated via a facile electrospinning method and utilized as adsorbent in thin film microextraction (TFME) of phthalate esters (PAEs) (dimethyl phthalate, diethyl phthalate, diallyl phthalate, dibutyl phthalate, and dioctyl phthalate) in biodegradable plastics. The prepared PAN/TpBD combines the strong stability of nanofibers with increased exposure sites for covalent organic frameworks and enhanced interactions with the target, thus improving the enrichment effect on the target. The extraction efficiency of PAN/TpBD reached above 80%. Based on PAN/TpBD, a TFME-high-performance liquid chromatography method was established, and the experimental parameters were optimized. Under the optimal extraction conditions, the PAEs of this method varied linearly in the range of 10-10 000µg/L with low detection limits (0.69-2.72µg/L). The intra-day and inter-day relative standard deviation values of the PAEs were less than 8.04% and 8.73%, respectively. The adsorbent can achieve more than 80% recovery of the five targets after six times reuse. The developed method was successfully applied for the determination of trace PAEs in biodegradable plastics with recoveries ranging from 80.1% to 113.4% and relative standard deviations were less than 9.45%. The as-synthesized PAN/TpBD adsorbent exhibited great potential in PAE analysis.

Easily recycled thiol-ene elastomers with controlled creep

Starting from in-house synthesized allylic monomers containing dynamic disulfide (SS) bonds, a set of vitrimeric thiol-ene elastomers were prepared and characterized with respect to their viscoelastic and tensile properties. A mixture of a disulfide-containing diallyl monomer and disulfide-free diallyl, namely diallyl phthalate, was combined stoichiometrically with a thiol crosslinker, trimethylolpropane tris (3-mercaptopropionate), to obtain soft thiol-ene thermosets with varying degrees of dynamic bond content. The materials were able to relax strain induced stress completely and rapidly at moderately high temperatures when the disulfide content was above a certain threshold, which was accurately predicted by a statistically-based network (de)crosslinking model. Relaxation of materials with disulfide content below this threshold required the activation of an additional transesterification bond exchange process by increasing the temperature. Recycling of the materials could be achieved by hot-press molding at convenient temperatures. Especially in low-disulfide containing materials, changes were observed in the material structure and properties with increasing number of reprocessing cycles. However, a significant reduction in ambient temperature creep was observed upon reducing the disulfide content. The disulfide content can be easily optimized to yield minimal loss of mechanical property and minimal creep. This work opens up new avenues for the cost-effective development of vitrimeric elastomers with minimal ambient temperature creep.

Fabrication of a biochar-doped monolithic adsorbent and its application for the extraction and determination of coumarins from Angelicae Pubescentis Radix

A monolithic adsorbent was designed aiming to the structure of osthole and columbianadin, and fabricated using diallyl phthalate as the monomer and ethylene dimethacrylate as the crosslinker with the addition of bamboo biochar, via polymerization reaction in a stainless-steel tube. The prepared composite adsorbent packed in the tube was used as a solid-phase extraction column for the extraction and determination of two coumarins (osthole and columbianadin) in Angelicae Pubescentis Radix, combing with a C18 analytical column through an HPLC instrument, which show excellent matrix-removal ability and good selectivity to osthole and columbianadin. Furthermore, the present adsorbent shows good applicability, which was used for the extraction of osthole from Duhuo Jisheng Pill. Compared to the commercial C18 and phenyl adsorbent, the present adsorbent own better selectivity and higher resolution. These results attributed to the enhanced specific surface area (141 m2/g) and enriched interaction sites of the resulting composite adsorbent, due to the doping of bamboo biochar, which can produce hydrogen bond, dipole-dipole, π-π and hydrophobic force interactions with the osthole and columbianadin. The methodology validation indicated that the present method showed good precision and good accuracy, and the composite adsorbent showed good preparative repeatability, which can be reused for no less than 100 times with the relative standard deviation ≤4.6 % (n = 100). The present work provided a simple and efficient method for the extraction and determination osthole and columbianadin from Angelicae Pubescentis Radix.

Assessment of the UV/DCCNa and UV/NaClO oxidation process for the removal of diethyl phthalate (DEP) in the aqueous system

In this work, the removal and transformation process of diethyl phthalate (DEP) in UV/dichloroisocyanurate (UV/DCCNa) and UV/sodium hypochlorite (UV/NaClO) systems were compared to evaluate the application potential of UV/DCCNa technology. Compared with UV/NaClO, UV/DCCNa process has the advantage of DEP removal and caused a higher degradation efficiency (93.8%) within 45 min of oxidation in ultrapure water due to the sustained release of hypochloric acid (HOCl). Fourteen intermediate products were found by high-resolution mass spectrometry, and the transformation patterns including hydroxylation, hydrolysis, chlorination, cross-coupling, and nitrosation were proposed. The oxidation processes were also performed under quasi-realistic environmental conditions, and it was found that DEP could be effectively removed in both systems, with yields of disinfection byproduct meeting the drinking water disinfection standard (<60.0 μg/L). Comparing the single system, the removal of DEP decreased in the mixed system containing five kinds of PAEs, which could be attributed to the regeneration of DEP and the competitive effect of •OH occurred among the Dimethyl phthalate (DMP), DEP, Dipropyl phthalate (DPrP), Diallyl phthalate (DAP) and Diisobutyl phthalate (DiBP). However, a greater removal performance presented in UV/DCCNa system compared with UV/NaClO system (69.4% > 62.1%). Further, assessment of mutagenicity and developmental toxicity by Toxicity Estimation Software Tool (T.E.S.T) software indicated that UV/DCCNa process has fewer adverse effects on the environment and is a more environmentally friendly chlorination method. This study may provide some guidance for selecting the suitable disinfection technology for drinking water treatment.

Development of a universal sol–gel sorbent for fabric phase sorptive extraction and its application in tandem with high performance liquid chromatography-ultraviolet detection for the analysis of phthalates in environmental and drinking water samples

Most sorbent-based sample preparation methods are designed to interact with a class of analytes i.e., a polar sorbent for polar analytes, a non-polar sorbent for non-polar analytes, an ion-exchange sorbent for ionized compounds. A big challenge surfaces when making a choice of an appropriate sorbent when there is a mixture of compounds of varying polarities and ionization states in the complex sample matrices. Hence, the aim of this study was to develop a universal sol–gel sorbent coating for fabric phase sorptive extraction that would effectively and simultaneously extract polar, nonpolar, organic acids and bases via different intermolecular/interionic interactions. The universal sol–gel sorbent coated fabric phase sorptive extraction membrane was created by exploiting sol–gel surface coating technology to implant different functional moieties, ion exchanging ligands and an organic polymer that results in a 3-D organic–inorganic hybrid structure on the fabric substrate with a high level of selectivity/affinity for the target compounds. The preconcentrated extracts containing the isolated phthalates after the fabric phase sorptive extraction procedure were injected into the high-performance liquid chromatography-ultraviolet detection (HPLC-UV) system for the quantification. The FPSE-HPLC-UV method demonstrated a linear range between 50 and 1000 ng/mL for dimethyl phthalate, diethyl phthalate, dipropyl phthalate, diallyl phthalate, benzyl butyl phthalate, 1–10000 ng/mL for di-n-heptyl phthalate, 1–5000 ng/mL for di-n-heptyl phthalate, 10–5000 ng/mL for di-n-ethyl hexyl phthalate and 100–7500 ng/mL di-n-octyl phthalate. The intra-day and inter-day reproducibility (in terms of percentage relative standard deviation, %RSD) did not exceed 13.6. This method proves to be a selective, accurate, reproducible, cheap, and fast analytical approach for the quantitative and qualitative determination of the phthalates which is useful in crafting regulations for phthalates content in beverages and juices as well as in environmental monitoring.

A ratiometric fluorescent probe for hypoxanthine detection in aquatic products based on the enzyme mimics and fluorescence of cobalt-doped carbon nitride

A ratiometric fluorescent probe for hypoxanthine (Hx) detection was established based on the mimic enzyme and fluorescence characteristics of cobalt-doped graphite-phase carbon nitride (Co doped g-C3N4). In addition to emitting strong fluorescence, the peroxidase activity of Co doped g-C3N4 can catalyze the reaction of O-phenylenediamine and H2O2 to produce diallyl phthalate which can emit yellow fluorescence at 570 nm. Through the decomposition of Hx by xanthine oxidase, Hx can be indirectly detected by the generating hydrogen peroxide based on the measurement of fluorescent ratio I (F570/F370). The linear range was 1.70–272.2 mg/kg (R2 = 0.997), and the detection limit was 1.52 mg/kg (3σ/K, n = 9). The established method was applied to Hx detection in bass, grass carp, and shrimp, and the data were verified by HPLC. The result shows that the established probe is sensitive, accurate, and reliable, and can be used for Hx detection in aquatic products.

Assessment of endocrine disruptor pollutants and their metabolites in environmental water samples using a sustainable natural deep eutectic solvent-based analytical methodology

In this work, an evaluation of the occurrence of fifteen phthalates, four metabolites and one adipate in different groundwater, seawater and wastewater samples has been carried out due to their relevance on human health as they act as endocrine disruptors. For this purpose, a sustainable, fast and easy-handling vortex-assisted liquid-liquid microextraction method using a natural hydrophobic deep eutectic solvent based on menthol and carvacrol as extraction agent, combined with ultra-high performance liquid chromatography-mass spectrometry technique, has been developed and applied for the first time. An optimization was performed to evaluate four important factors affecting the extraction performance, and an analytical validation was carried out in terms of matrix effect, linearity, extraction efficiency, and sensitivity. Recovery values were obtained in the range 72–119% for all analytes (except for monoethyl phthalate: 61.1–72.3%) with relative standard deviation values lower than 17%. Limits of quantification were found between 0.91 and 8.09 μg L−1. As a result of the assessment of 31 different environmental water samples, monoethyl phthalate, diethyl phthalate, dibutyl phthalate and bis (2-ethylhexyl) phthalate were detected and quantified at different concentrations in the range 2.59–21.17 μg L−1 in 6 samples, and diallyl phthalate, butyl benzyl phthalate, dipentyl phthalate, dicyclohexyl phthalate, dihexyl phthalate and bis (2-ethylhexyl) adipate were detected in 20 more, showing the exposition of the population to these hazardous substances.

Preparation and UV‐curing properties of rosin‐based allyl phthalate oligomer

AbstractThe acid–base stability of UV cured materials is an important issue in the field of material applications. Bio‐based rosin modified diallyl phthalate oligomers (RS‐DAP) with higher hydrophobicity were synthesized by the radical reaction of rosin with diallyl phthalate. The structures of RS‐DAP were confirmed by FT‐IR, 1H NMR and electrospray ionization high resolution mass spectrometry (ESI‐HRMS). The UV‐curing properties of acrylate components containing RS‐DAP were investigated by FT‐ATR. And the effects of RS‐DAP dosage on the double bond conversion of neopentyl glycol diacrylate (NPGDA) and the properties of cured film were evaluated. The results show that the introduction of aromatic rings of DAP and the rigid structure of rosin moiety can improve the UV curing rate, gelation ratio, hardness, and chemical resistance of cured film. The composition of RS‐DAP resin with acrylate monomer and RJ313 resin can be 3D printed into specimen with smooth surface, good precision, good thermal stability, hardness of 6 H, and 93% of gel content.

The transformation and interaction of diallyl phthalate (DAP) in the three kinds of plastic under ultraviolet/sodium dichloroisocyanurate (UV/DCCNa) disinfection process

In this work, the degradation kinetics and transformation pathways of diallyl phthalate (DAP) in polyethylene (PE), polypropylene (PP), and polyvinyl chloride (PVC) plastics under UV/sodium dichloroisocyanurate (UV/DCCNa) disinfection process were studied comparatively. The results showed that the degradation efficiency of DAP in PE plastics was highest compared with PP and PVC plastics, and it was not affected by hypochlorous acid (HOCl) concentration. These phenomena were attributed to the different reaction activation energy (Ea) between plastics and active free radicals (OH, Cl, and ClO) and the difference in the contribution of Cl under the action of UV illumination. Moreover, some ions such as NH4+, Cl−, NO3−, SO42−, and HCO3− could significantly affect the degradation of DAP. Then, we detected a total of fifty-four kinds of interactive products between DAP and plastics and proposed the transformation pathways including hydroxylation, chlorination, hydrolysis, nitrosation, bond breaking, coupling, and interactive reaction after intermediate products were identified. The UV/chlorination process was also performed under low-temperature conditions, and it was found that the degradation of DAP was not inhibited even at 0 °C, with yields of disinfection byproduct in PP plastics being the highest. Further, the results of the toxicity assessment for products indicated that sixty-six of the intermediates were developmental toxicants and nine of them were mutagenicity positive with a higher possibility than DAP, which means there are still some environmental health risks after the UV/DCCNa disinfection process for plastics. This study provided insights into the interaction and health risk management between DAP and plastics during the cold chain disinfection process.

Thiol‐ene emulsion polymerization using a semi‐continuous approach

AbstractThe thermally initiated thiol‐ene emulsion polymerization of diallyl phthalate (DAP) diene and ethylenedioxy diethanthiol (EDDT) dithiol monomers in batch and semibatch emulsion polymerization is investigated. The batch process leads to larger and broader particle sizes than when the polymerization is carried out in semibatch. The evolution of the particle size and the final particle size distribution indicate that the stability of the latexes is limited and, hence, aggregation phenomena occurred in both processes. In particular, the evolution of the particle size distribution (PSD) in the semibatch process indicates nucleation, growth, and aggregation occurring simultaneously that produced a bimodal particle size. When the diene monomer was changed to diallyl terephthalate (DATP), the semibatch polymerization yielded smaller particles and narrow distribution without any indication of aggregation. The partial substitution of the dithiol by a trithiol monomer that is substantially more water insoluble affected nucleation of the particles, yielding for both systems smaller particles. The polythioether polymers synthesized present low glass transition temperatures (~ −30/−40°C) and those containing the therephthalate yield crystalline films. The potential application of the polymers as pressure sensitive adhesives (PSAs) was preliminarily assessed.

Seasonal fluctuations in phthalates’ contamination in pond water: A case study

Phthalates are endocrine disruptors, reported to cause deformities and reproductive damages in animals. Numerous studies reported the presence of phthalates in water samples of rivers, wetlands, and estuaries, while the scenario in case of ponds is different, however they are reported as an integral part of biosphere. In this study, the level of phthalates’ contamination in the water samples collected from the different ponds of Amritsar district for four consecutive seasons in two years was analysed. The maximal level of phthalate contamination was found in samples collected during the monsoon season (July 2015) of first year of sampling followed by post-monsoon (October 2015) and winter season (January 2016). S8 sampling site was found to be the most phthalate contaminated site followed by S1=S11&gt;S2=S9=S4=S5=S7&gt;S6=S3&gt;S10. Benzyl butyl phthalate was most abundant (found in 32% water samples) followed by di-n-butyl and dimethyl phthalate, while diallyl phthalate and diethyl phthalate were not detected. The two main drivers for these seasonal variations were observed to be temperature and precipitation. Hence, this data will be useful to explain the temporal and spatial distributions of phthalates in aquatic ecosystem, as well as to devise cost-effective ways to reduce their ecological footprints.

Dissipation, uptake, translocation and accumulation of five phthalic acid esters in sediment-Zizania latifolia system

The dissipation, uptake, translocation and accumulation of phthalic acid esters (PAEs) including diallyl phthalate (DAP), diisobutyl phthalate (DIBP), dibutyl phthalate (DBP), benzyl butyl phthalate (BBP) and di-(2-ethylhexyl) phthalate (DEHP) in sediment-Zizania latifolia system were investigated by gas chromatography-flame ionization detector after a QuEChERS pretreatment method. The dissipation rates of PAEs in sediment were positively correlated with exposure time, and more than 68.12% of PAEs in sediment were decreased after 28 d even when the spiked contents were extremely high. All the five PAEs could be taken up by roots from contaminated sediment and subsequently be transported into stems and leaves. There were significant linear correlations between the sediment content and the content in each tissue. DEHP was most readily transported from sediment to roots and stems, followed by BBP, DBP, DIBP and DAP, whereas the order of transportation from roots to leaves was reversed. During 28 d of exposure, the average concentration of each PAE in stems was the highest, followed by roots, leaves and edible parts. DEHP and BBP were the major contaminants in edible parts but could not pose a risk to human health. The accumulation of PAEs in edible parts was influenced by the species and concentration of PAEs as well as the survival time and harvest time of edible parts. The differences in uptake and translocation behaviors among PAEs in plant tissues were significantly correlated to their physicochemical properties, such as alkyl chain length and octanol/water partition coefficient (logKow). The results reveal that Zizania latifolia is not only a kind of safe food, but also a potential plant to remediate contaminated sediment by accumulating and degrading PAEs from the habitats.

Utilizing thermokinetic and calorimetric methods to assess the impact of an initiator on the thermal hazard of diallyl phthalate

Utilizing thermokinetic and calorimetric methods to assess the impact of an initiator on the thermal hazard of diallyl phthalate

Evaluating different web applications to assess the toxicity of plasticizers

Plasticizers increase the flexibility of plastics. As environmental leachates they lead to increased water and soil pollution, as well as to serious harm to human health. This study was set out to explore various web applications to predict the toxicological properties of plasticizers. Web-based tools (e.g., BOILED-Egg, LAZAR, PROTOX-II, CarcinoPred-EL) and VEGA were accessed via an 5th–10th generation computer in order to obtain toxicological predictions. Based on the LAZAR mutagenicity assessment was only bisphenol F predicted as mutagenic. The BBP and DBP in RF; DEHP in RF and XGBoost; DNOP in RF and XGBoost models were predicted as carcinogenic in the CarcinoPred-EL web application. From the bee predictive model (KNN/IRFMN) BPF, di-n-propyl phthalate, diallyl phthalate, dibutyl phthalate, and diisohexyl phthalate were predicted as strong bee toxicants. Acute toxicity for fish using the model Sarpy/IRFMN predicted 19 plasticizers as strong toxicants with LC50 values of less than 1 mg/L. This study also considered plasticizer effects on gastrointestinal absorption and other toxicological endpoints.

Determination of phthalate esters in bottled beverages by direct immersion solid-phase microextraction with a porous boron nitride coated fiber followed by gas chromatography-mass spectrometry.

A porous boron nitride with a large surface area was synthesized by a one-step grinding method with melamine, urea, and boric acid as the precursors. The prepared porous boron nitride was used as the fiber coating material for the solid-phase microextraction of seven phthalate esters (diethyl phthalate, diallyl phthalate, diisobutyl phthalate, dibutyl phthalate, butylbenzyl phthalate, dicyclohexyl phthalate, and di-2-ethylhexyl phthalate) prior to their gas chromatography-mass spectrometric detection. The important experimental parameters including the extraction time, extraction temperature, salt concentration, and stirring rate were optimized by both single factor and central composite design methods. Under the optimized experimental conditions, the linear response range for the analytes was from 0.030 to 30.0 μg/L, and the limits of detection were from 0.010 to 0.040 μg/L, respectively. The relative recoveries of the analytes for spiked samples at two concentration levels were 83.0-109% with the relative standard deviations less than 12%. The established method was successfully applied for the determination of the phthalate esters in bottled juice beverage samples.

Wafer-Level 3D Integration Based on Poly (Diallyl Phthalate) Adhesive Bonding

Three-dimensional integration technology provides a promising total solution that can be used to achieve system-level integration with high function density and low cost. In this study, a wafer-level 3D integration technology using PDAP as an intermediate bonding polymer was applied effectively for integration with an SOI wafer and dummy a CMOS wafer. The influences of the procedure parameters on the adhesive bonding effects were determined by Si–Glass adhesive bonding tests. It was found that the bonding pressure, pre-curing conditions, spin coating conditions, and cleanliness have a significant influence on the bonding results. The optimal procedure parameters for PDAP adhesive bonding were obtained through analysis and comparison. The 3D integration tests were conducted according to these optimal parameters. In the tests, process optimization was focused on Si handle-layer etching, PDAP layer etching, and Au pillar electroplating. After that, the optimal process conditions for the 3D integration process were achieved. The 3D integration applications of the micro-bolometer array and the micro-bridge resistor array were presented. It was confirmed that 3D integration based on PDAP adhesive bonding is suitable for the fabrication of system-on-chip when using MEMS and IC integration and that it is especially useful for the fabrication of low-cost suspended-microstructure on-CMOS-chip systems.

In situ monitoring of phthalate esters (PAEs) pollution and environmental risk assessment in Poyang Lake Basin by DGT Technology using cyclodextrin polymer as binding phase

Poyang Lake is the first freshwater lake in China, which is an important drinking water source. In recent years, industrial pollution has led to the increased phthalate acid esters (PAEs) in Poyang Lake. PAEs are a class of typical endocrine disruptors that can accumulate in organisms and interfere with their secretion systems. Thus, the accurate determination of PAEs in Poyang Lake is important for health risk prediction and the development of corresponding control means. Monitoring organic pollutants in water using the diffusive gradient in thin films technique (DGT) has attracted much attention due to more accuracy and convenience than the traditional methods. This study used an inexpensive amphiphilic cyclodextrin polymer (PBCD) as the sorbent for the binding gel. This new binding gel has an ultra-high specific surface area and excellent adsorption performance. Diffusion coefficients of the five PAEs were determined, and the performance of DGT such as adsorption capacity and deployment time (1–4 days) was tested using five PAEs as models. The assembled PBCD-DGT was used to examine the performance in a complex simulated water environment. The sampling capability of PBCD-DGT was verified in Yangshan Lake, and a large-scale field application was conducted in Poyang Lake basin. The results of 11 sampling points showed that the concentration ranges of dimethyl phthalate, diethyl phthalate, diallyl phthalate, dipropyl phthalate, and dibutyl phthalate were 434–2594 ng/L, 40–314 ng/L, 80–527 ng/L, 45–308 ng/L, and ND-182 ng/L, respectively. The health risk index (HI) and ecological risk quotient (RQ) values of PAEs in the Poyang Lake watershed were far below 1, indictating a lower health and ecological risk. Considering that PAEs are bioaccumulative and persistent, it is very necessary to continue to pay attention to its pollution status and health and ecological risk changes in Poyang Lake Basin in the future.

The Influence of Monomer Structure on the Properties of Ionogels Obtained by Thiol–Ene Photopolymerization

The influence of ene and thiol monomer structure on the mechanical and electrochemical properties of thiol–ene polymeric ionogels were investigated. Ionogels were obtained in situ by thiol–ene photopolymerization of 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione (TATT), 2,4,6-triallyloxy-1,3,5-triazine (TAT), diallyl phthalate (DAP), and glyoxal bis(diallyl acetal) (GBDA) used as enes and trimethylolpropane tris(3-mercaptopropionate) (TMPTP), pentaerythritol tetrakis(3-mercaptopropionate) (PETMP), and pentaerythritol tetrakis(3-mercaptobutyrate) (PETMB) used as thiols in 70 wt.% of ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMImNTf2). The mechanical strength of ionogels was studied by puncture resistance and ionic conductivity by electrochemical impedance spectroscopy. The course of photopolymerization by photo-DSC method (differential scanning calorimetry) as well as characterization of compositions and its components (by IR and UV spectroscopy-Kamlet–Taft parameters) were also studied. The resulting ionogels were opaque, with phase separation, which resulted from the dispersion mechanism of polymerization. The mechanical and conductive properties of the obtained materials were found to be largely dependent on the monomer structure. Ionogels based on triazine monomers TAT and TATT were characterized by higher mechanical strength, while those based on aliphatic GBDA had the highest conductivity. These parameters are strongly related to the structure of the polymer matrix, which is in the form of connected spheres. The conductivity of ionogels was high, in the range of 3.5–5.1 mS∙cm−1.

Triazine covalent organic polymer coated stir bar sorptive extraction coupled with high performance liquid chromatography for the analysis of trace phthalate esters in mineral water and liquor samples

Cyanuric chloride and 4,4′-diamino-p-terphenyl were adopted as monomers to synthesize poly (4,4′-diamino-p-terphenyl-triazine) (PDT) covalent organic polymer. PDT coated stir bar was prepared and evaluated for the extraction of five phthalate esters (PAEs) with relatively lower logP values (2.7–4.9), including diethyl phthalate, diallyl phthalate, dipropyl phthalate, benzylbutyl phthalate and dibutyl phthalate. It exhibited higher extraction recovery (> 65%) and faster extraction kinetics (50 min vs 240 min) for target PAEs over commercial polydimethylsiloxane coated stir bar. Based on the superior performance, PDT coated stir bar sorptive extraction was combined with high-performance liquid chromatography-diode array detection for trace analysis of five PAEs plasticizers. The limits of detection for target PAEs were 0.04–0.27 μg/L, with the enrichment factors of 54–80-fold. The potential of the method was demonstrated by detecting five target PAEs in Chinese liquor and mineral water samples. No target analytes were detected in Chinese liquor sample, and recoveries of 85.4–109% were obtained for target analytes in spiked liquor samples; trace diethyl phthalate (1.19–2.98 μg/L) and dibutyl phthalate (0.77–0.91 μg/L) were detected in two mineral water samples, with recoveries of 85.4–117% and 87.4–117% respectively in spiked mineral water samples.