Magnetic catheter robots have great potential for application in minimally invasive surgical interventions that require submillimeter soft catheters to be inserted into the body. Compared to other medical continuum robots, the kinematic characteristics of the magnetic continuum robot are required to be improved, including operating dexterity. The opposite magnetic continuum robot (OMCR), which has oppositely-magnetized magnets on the robot, is capable of deforming in large and high-order curvatures and shows improved dexterity. However, unstable kinematic behaviors emerge owing to solution multiplicity and affect the actual operation. For example, snapping, which indicates the sudden jump from one state to another, induces danger for medical operations. In addition, the motion sequence of the external mobile magnet affects the final state of OMCR. Therefore, in this study, we first analyze the reason for these emerging behaviors by understanding the solution multiplicity of an OMCR. We then modified the OMCR kinematic model with instability analysis and additional constraints, to predict the critical point for snapping and avoid other unexpected behavior for path planning. Herein, our study aims to analyze the stability of the OMCR with relatively unstable configurations in their actuation space to ensure stable and dexterous motions for medical applications. <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">Note to Practitioners</i> —The motivation of this work is to analyze, predict, and avoid the unexpected behaviors of the medical magnetic catheter robots, and ensure stable and dexterous operation. Submillimeter magnetic catheter robots have received considerable attention in the past ten years owing to their small size and dexterous motion. They have great potential for minimally invasive surgical interventions that require the navigation of “tighter corners” inside the human body. However, there may exist multiple local solutions under an external field, especially when the robot deforms in high-order curvature for dexterous operation. This situation induces unexpected behaviors and danger for medical use, such as a sudden jump from one state to another. Herein, we analyze the solution evolution as the external field varies and predict the unexpected behaviors using a modified kinematic model with instability analysis. Preliminary experiments demonstrated the effectiveness of the modified model, which can predict unexpected behaviors, and evaluate and enhance the stability during path planning. This method can be implemented for the dexterous and stable operation of magnetic catheter robots, which is significant for medical applications.