Development Of Innovative Materials Research Articles

Synthesis of All-Peptide-Based Rotaxane from a Proline-Containing Cyclic Peptide.

Rotaxane cross-linkers enhance the toughness of the resulting rotaxane cross-linked polymers through a stress dispersion effect, which is attributed to the mobility of the interlocked structure. To date, the compositional diversity of rotaxane cross-linkers has been limited, and the poor compatibility of these cross-linkers with peptides and proteins has made their use in such materials challenging. The synthesis of a rotaxane composed of peptides may result in a biodegradable cross-linker that is compatible with peptides and proteins, allowing the fortification of polypeptides and proteins and ultimately leading to the development of innovative materials that possess excellent mechanical properties and biodegradability. However, the chemical synthesis of all-peptide-based rotaxanes has remained elusive because of the absence of strong binding motifs in peptides, which prevents an axial peptide from penetrating a cyclic peptide. Here, we synthesized all-peptide-based rotaxanes using an active template method for proline-containing cyclic peptides. The results of molecular dynamics simulations suggested that cyclic peptides with an expansive inner cavity and carbonyl oxygens oriented toward the center are favorable for rotaxane synthesis. This rotaxane synthesis method is expected to accelerate the synthesis of peptides and proteins with mechanically interlocked structures, potentially leading to the development of peptide- and protein-based materials with unprecedented functionalities.

TiO2/AgBr nanocomposite as a novel hydrophilic and photocatalytic modifier in the fabrication of polyethersulfone membrane for wastewater treatment

Enhancing the performance of filtration membranes to improve their antifouling, permeability, and stability is a crucial objective. This can be acquired through the development of innovative materials and methods. With this in mind, the exertion of novel materials is considered a promising approach for modifying polymeric membranes. This study focuses on the potential of incorporating TiO2/AgBr photocatalytic nanocomposites to improve the hydrophilicity, antifouling, and permeability of polyethersulfone (PES) membranes. Following the synthesis of TiO2/AgBr, the study examines its impact on the performance of PES membranes by introducing various concentrations of TiO2/AgBr nanocomposite. Notably, the water contact angle significantly decreases from 68.5° to 44.2°, indicating an improvement in hydrophilicity. This enhanced overall porosity leads to almost a twofold increase in pure water permeability, with the bare membrane registering 78.3 L/m2h.bar and the membrane containing 0.2 wt% TiO2/AgBr achieving 152.4 L/m2h.bar. Due to the photocatalytic activity of TiO2/AgBr, the modified membranes demonstrate promoted antifouling performance, when UV irradiation is used in the washing step of the fouled membranes, as evidenced by the increased flux recovery ratio values, rising from 48 to 60.6 %. The rejection of two different dyes was assessed and the results of 83.9 % and 95.2 % rejection were obtained for Reactive Black 5 (RB5) and Lanasol Red 6G, respectively. Furthermore, the antibacterial activity of TiO2/AgBr was also indicated by confocal microscopy analysis. Thus, embedding TiO2/AgBr not only enhances antifouling properties but also improves the membranes’ ability to reject dyes effectively.

Comprehensive investigation of the electronic properties of zinc and cobalt doped hydroxyapatite

AbstractThis study presents a comprehensive investigation into the electronic properties of Hydroxyapatite (HAp) doped with Zinc (Zn) and Cobalt (Co). Five distinct compositions, denoted as 0.15Zn-HAp, 0.15Co-0.15Zn-HAp, 0.30Co-0.15Zn-HAp, 0.45Co-0.15Zn-HAp, and 0.6Co-0.15Zn-HAp (at%,) have been systematically studied employing Density of States (DOS) and band structure calculations. The computed band gap values for these compositions were determined to be 4.6663, 4.6888, 4.7049, 4.7159, and 4.7082 eV, respectively. These results illuminate the profound influence of Zn and Co doping on the electronic structure of Hydroxyapatite. These findings hold significant implications for the potential applications of these materials in diverse technological and biomedical domains. The systematic approach and precise electronic property characterizations presented in this study provide a robust foundation for further advancements in the realm of advanced materials, with particular relevance to the development of innovative materials for use in cutting-edge technologies and medical applications.

ANALYSIS OF THE PROPERTIES OF COATINGS USED TO PROTECT THE PUMP AND COMPRESSOR PIPE

In this article considers basic properties of protective coatings applied to the inner wall of tubing in order to extend pump and compressor pipe (PCP) service life PCP and minimize operational risks. The main complicating factors, such as scale deposits, corrosion aggressiveness, mechanical impurities, etc., arising during PCP operation are specified, groups of test media and test parameters for grading different types of coatings according to their resistance to complicating factors are singled out. Influence of various aggressive media on PCP, such as distilled water, petroleum product simulator, etc., coatings is described, and test media and test parameters for protective coatings are reviewed. The basic methods for determining the physical and mechanical characteristics, such as determining adhesion, thickness and dielectric continuity, of coatings are given, and brief informative and descriptive references for each of them are given. Recommendations are given for testing protective coatings on the inner surface of PCP for compliance with technical requirements, which ultimately allows selecting materials most resistant to aggressive field environments. The relevance of studying the influence of aggressive media on the protective coatings of the inner wall of tubing is due to the need to increase the level of reliability and durability of technical systems in operating conditions. The work is of interest to specialists in the field of materials science, technical expertise and tubing design, as well as researchers involved in the development of new materials and methods for surface protection in operating conditions. The results obtained will optimize the choice of protective coatings for specific operating conditions, which helps to increase the service life of tubing and reduce maintenance costs. This is of direct importance for reducing the risks of accidents and the environmental consequences of oil and gas production processes. In addition, the development of innovative materials and methods for protecting the surfaces of the inner wall of the tubing contributes to improving the efficiency of the operation of oil and gas wells, as well as helps to reduce equipment downtime.

Flax/ramie hybrid fibers enhanced with SiC nanoparticles

To create a hybrid material of ramie and flax fibers with silicon carbide (SiC) nanoparticles, it should have better thermal and mechanical properties. Across industries, sustainable materials are growing in demand for high performance, which is the impetus behind this study. A sustainable future is more about contributing to sustainable alternatives like ramie and flax fibers made from traditional synthetic materials. A key area focused on increasing strength, temperature resistance, and stiffness will be the addition of SiC nanoparticles to hybrid fibers. The research process carefully mixes the ramie and flax fibers with SiC nanoparticles to achieve optimal flexibility, thermal stability, and balance of strength. Hybrid material is examined using characterization techniques such as mechanical testing and scanning electron microscopy to determine the functioning of the microstructure. The possibility of composite material recycling, the impact of hybrid fibers, and accounting for natural fibers for sustainability are considered possible in this research. It should be innovative material development that has significant implications from the findings that meet environmental sustainability goals and satisfy performance requirements.

Solvent-free thiol-Ene/-Yne click reactions for the synthesis of alkoxysilyl telechelic poly(propylene oxide)s

Thiol-ene/−yne click reactions can be a versatile toolbox for the design and modification of polymers, enhancing functionality and providing opportunities for the development of innovative materials and applications. Here, we report a simple strategy to synthesize alkoxysilyl telechelic poly(propylene oxide)s (PPO)s: a) through a post-polymerization functionalization via Williamson reactions, commercial PPO is modified at the chain-end secondary alcohols with allyl or propargyl units, achieving >99% conversion; b) subsequent click reactions of (3-mercaptopropyl)trimethoxysilane (MPTMS), triggered by thermal and photochemical radical initiators, result in the incorporation of alkoxysilane groups on the polyether chain. Both thermal and photochemical thiol-ene/−yne click pathways are robust methodologies for preparing alkoxysilyl-modified PPOs in excellent yields (> 99%). Optimal conditions were identified as solvent-free, at 65 °C with 2,2′-azobis(2-methylpropionitrile) (AIBN) as the radical source. Detailed NMR analyses confirm the quantitative transformation of vinyl/propargyl functionalities in the resulting alkoxysilyl telechelic PPOs. Preliminary studies on the stability of alkoxysilyl end-groups are reported using 29Si NMR spectroscopy.

Solar driven integrated CO2 capture and CH4 dry reforming via FexMny/Ni/CaAl multi-function materials

Integrated CO2 capture and dry reforming of CH4 (ICCU-DRM) holds great promise in mitigating greenhouse gas emissions and producing value-added syngas simultaneously. However, the in-situ conversion is a highly endothermic process, which requires a large amount of energy to drive, making it very difficult for large-scale applications. The combination of solar energy in ICCU-DRM provide a potential solution to tackle the problem, but it needs to construct and evaluate multi-function materials (MFMs) with good features of CO2 adsorption, catalytic conversion and light absorption. Herein, we report a synthesis approach to prepare Fe5Mn5/Ni/CaAl for use in the solar driven ICCU-DRM, which directly utilize the solar energy for syngas production with excellent comprehensive performance. The material prepared demonstrates an average spectral absorbance of 85.81 %, and a CO2 capacity of 8.46 mmol·g−1 with up to 89 % conversion to syngas. We expect the synthesis strategy has good implications on the development of innovative materials for carbon reduction and energy storage applications.

Production and assessment of UV-cured resin coated stearyl alcohol/expanded graphite as novel shape-stable composite phase change material for thermal energy storage

Expanded graphite-phase change materials (PCM) structures are reinforced to polymers with various methods to fabricate advanced thermal energy storage materials. However, these methods still suffer from processing time and product efficiency challenges. In this study, the UV-curing method was used to produce shape-stable EG-PCM-reinforced resin composites with fast curing and low process temperature of the resin. The composite material, comprising UV-curable resin (30 %), stearyl alcohol (65 %), and Expanded graphite (5 %), was synthesized. This synthesis aimed to address the limitations of traditional PCMs, such as low thermal conductivity and leakage. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were used to characterize the materials' phase change behavior and thermal stability. Scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR) analyses were conducted to elucidate the microstructure and crystallinity of composite materials. The composites, exhibiting near-perfect impermeability with leakage as minimal as 0.89 %, not only enable the attainment of cooler environments by 2–3 °C under hot air conditions but also demonstrate exceptional thermal stability up to 207 °C, as evidenced by TGA results. Additionally, they offer a remarkable melting enthalpy value of 153.1 J/g. These composites, with their shape-retention ability during phase transitions and high thermal energy storage capacity, are a versatile and efficient option for sustainable energy management. This research contributes to the development of innovative materials for renewable energy integration and reducing carbon emissions.

Overcoming Challenges in OLED Technology for Lighting Solutions

In academic research, OLEDs have exhibited rapid evolution thanks to the development of innovative materials, new device architectures, and optimized fabrication methods, achieving high performance in recent years. The numerous advantages that increasingly distinguish them from traditional light sources, such as a large and customizable emission area, color tunability, flexibility, and transparency, have positioned them as a promising candidate for various applications in the lighting market, including the residential, automotive, industrial, and agricultural sectors. However, despite these promising attributes, the widespread industrial production of OLEDs encounters significant challenges. Key considerations center around efficiency and lifetime. In the present review, after introducing the theoretical basis of OLEDs and summarizing the main performance developments in the industrial field, three crucial aspects enabling OLEDs to establish a competitive advantage in terms of performance and versatility are critically discussed: the quality and stability of the emitted light, with a specific focus on white light and its tunability; the transparency of both electrodes for the development of fully transparent and integrable devices; and the uniformity of emission over a large area.

Simulation approach to study kinetic heterogeneity of gadolinium catalytic system in the 1,4-cis-polyisoprene production

Abstract This article presents a novel simulation approach for solving the inverse problem of kinetic heterogeneity in polymerization processes, specifically focusing on the production of polyisoprene using a gadolinium chloride solvate-based catalytic system. The proposed method is based on the assumption that the distribution of active centers (ACs) can be described by model distributions. By utilizing primary physicochemical data, such as the polymerization rate and molecular weight distribution, the simulation approach automatically identifies the kinetic parameters, determining the Frenkel statistical parameter and solving the problem of kinetic heterogeneity. The experimental results revealed the presence of at least three distinct types of ACs, each contributing different proportions to the polymerization process. The simulation approach offers valuable insights into the complexities of catalytic systems and their role in polymerization, paving the way for optimizing reaction conditions and advancing industrial polymer synthesis processes. This study marks a significant step forward in understanding and controlling polymerization reactions, with potential implications for the development of innovative materials and industrial applications.

Green synthesis of carbon nanotubes functionalized with iron nanoparticles and coffee husk biomass for efficient removal of losartan and diclofenac: Adsorption kinetics and ANN modeling studies

The presence of emerging contaminants in wastewater poses a global environmental challenge, requiring the development of innovative materials or methods for their treatment. This study focused on the production of green functionalized carbon nanotubes (CNTs) and using them in the adsorption of the pharmaceuticals Losartan (LOS) and Diclofenac (DIC). The efficiency of the methodology was verified by characterization techniques. Elemental composition analysis indicated a significant increase in the iron content after the green functionalization, proving the effectiveness of the method. Thermogravimetric analysis showed similar thermal degradation profiles for pristine CNTs and functionalized CNTs, indicating better post-functionalization thermal stability. BET analysis revealed mesoporous characteristics of CNTs, with increased surface area and pore volumes after functionalization. X-Ray diffraction confirmed the preservation of the lattice structure of the CNTs post-functionalization and post-adsorption, with changes in peak broadening suggesting surface modifications. LOS and DIC adsorption were evaluated via kinetic studies at four different concentrations (0.1–0.4 mmol/L) that were best represented by the pseudo-second order model, suggesting chemisorption mechanisms, with faster and higher uptakes for DIC (0.084–0.261 mmol/g; teq = 5 min) when compared to LOS (0.058–0.235 mmol/g; teq = 20 min). The curves were also studied via artificial neural networks (ANN) and revealed that the best ANN architecture for representing the experimental data is a network with [3 5 5 2] neurons trained using the Bayesian-Regularization algorithm and the Log-sigmoid (hidden layers) and Linear (output layer) transfer functions. The desorption study showed that CaCl2 had better performance in CNT regeneration, reaching its removal capacity above 50% up to 3 cycles, for both pharmaceuticals. These findings reveal the potential of the developed material as a promising adsorbent for targeted removal of pollutants, contributing to advances in the remediation of emerging contaminants and the application of artificial intelligence in adsorption research.

Antifungal Susceptibility Assessment of Innovative and Non-Conventional Lime Mortars Incorporating Almond-Shell Powder Bio-Waste Subjected to Particle-Dispersion Technique.

A favorable environment for fungi colonization in building materials' surfaces can emerge when certain hygrothermal conditions occur. Thus, reducing fungal growth susceptibility is of major interest. Furthermore, if the integration of bio-wastes is performed in parallel with the development of innovative materials for this purpose, a more sustainable and environmentally friendly material can be obtained. In this study, the fungal susceptibility of lime mortars incorporating almond-shell powder (ASP) microparticles (2 and 4%, wt.-wt. in relation to the binder content) was evaluated. The particle-dispersion technique was employed to prepare the bio-waste introduced in the mixtures. The fungal susceptibility of ASP samples was compared with nanotitania (n-TiO2) with recognized antifungal properties. Mechanical strength, water absorption, and wettability tests were also performed for a better characterization of the composites. Although the addition of 2% ASP led to mechanical properties reduction, an increase in the compressive and flexural strength resulted for 4% of the ASP content. Difficulties in fungal growth were observed for the samples incorporating ASP. No fungal development was detected in the mortar with 2% of ASP, which may be correlated with an increase in the surface hydrophobic behavior. Furthermore, mortars with ASP revealed a reduction in water absorption by capillarity ability, especially with 4% content, suggesting changes in the microstructure and pore characteristics. The results also demonstrated that an improvement in the physical and mechanical properties of the lime mortars can be achieved when ASP microparticles are previously subjected to dispersion techniques.

Green Light‐Responsive D‐π‐A‐π‐D Quinoxaline Emitters for Luminescent Solar Concentrators: Potential Integration in Agrivoltaic Systems

the integration of photovoltaic technologies within agricultural settings, also known as agrivoltaic, is attracting increasing attention as a sustainable approach to ensure both clean energy and food supply. The success of this strategy relies on the development of innovative materials that can selectively convert specific wavelengths into energy while being transparent to photosynthetically relevant light. To this aim, here we report our endeavors in the synthesis of a new class of D‐π‐A‐π‐D quinoxaline fluorophores and their use in the preparation of wavelength‐selective luminescent solar concentrators (LSC). The dyes were expeditiously prepared following a direct arylation protocol and extensively characterized by spectroscopic analyses and computational studies. They present high light harvesting ability in the green region of the visible spectrum and good emission properties, which were fully retained in the solid state when embedded into a PMMA matrix. These materials were employed to construct LSC devices of promising efficiency, fostering further developments for the use of wavelength‐selective LSC in agrivoltaic systems.

The Prospective Applications of Arising Nanostructured Dielectric Materials in Storage of Energy: A Comprehensive Review

Background: The manufacture and study of innovative materials that enable the availability of relevant technologies are vital in light of the energy demands of various human activities and the need for a substantial shift in the energy matrix. Objective: A strategy based on the creation of enhanced applications for batteries has been devised to reduce the conversion, storage, and feeding of renewable energy like fuel cells and electrochemical capacitors. Methods: Conductive polymers (CP) can be utilised instead of traditional inorganic chemicals. Electrochemical energy storage devices with similar capabilities can be built using approaches based on the production of composite materials and nanostructures. Results: CP's nanostructuring is notable for its concentration on synergistic coupling with other materials, which sets it apart from other nanostructures that have been developed in the preceding two decades. This is due to the fact that, when paired with other materials, their distinctive morphology and adaptability significantly enhance performance in areas like the suppression of ionic diffusion trajectories, electronic transport and the improvement of ion penetrability and intercalation spaces. Conclusion: The present study forecasts the wide-ranging modern applications of diverse nanostructured dielectric materials along with its future prospectives. The potential contributions of nanostructured carbon nanotubes to the development of innovative materials for energy storage devices are also critically discussed in this context, which delivers a summary of the present state of information on this emerging topic.

Molecular dynamics investigation of ionanofluids (INFs): Towards a deeper understanding of their thermophysical, structural and dynamical properties

Ionanofluids (INFs) are a novel type of heat transfer fluids consisting of fine nanoparticles suspended in ionic liquids (ILs). They exhibit improved thermal properties, including enhanced thermal conductivity, non-volatility, and non-flammability, making them ideal candidates for various applications, especially solar concentrators. In this work, for the first time, molecular dynamics (MD) simulations are used to investigate the thermophysical, structural, and dynamical properties of a specific INF composed of the [HMIM][BF4] IL and SiC nanoparticles in the temperature range of 298.15–338.15 K and at different nanoparticle volume fractions, i.e. 1.10 %, 2.27 %, and 3.47 %. Radial distribution functions (RDFs) revealed a strong structural correlation between the fluorine atoms of anion and the HR atom of the cation ring and also with the carbon and silicon atoms of the nanoparticle. The results showed that with increasing the volume fraction of nanoparticles, ions tend to have more interactions with nanoparticles, and the interactions between the anions and cations decrease. As a result, the thermal conductivity, viscosity, and density of ions in the INF increases. Finally, we made some comparisons between the simulated thermal conductivities and viscosities of the studied INF with classical models. The results showed that, in some cases, the simulation results were even better than some models compared to the experimental values. The insights obtained from this study not only enhance our understanding of the structure and dynamic behavior of the INF, but also can contribute to the development of innovative materials and more efficient solar thermal systems.

Magnetic spirals and biquadratic exchange in 1D MoX[formula omitted] spin chains

We researched the one-dimensional configurations of MoX3 (X = Cl, Br, and I), a spin chain with antiferromagnetically frustrated moments S=32 located at the Mo sites. Our research revealed a spontaneous magnetic order in this group of one-dimensional setups. The magnetic system within the one-dimensional chain reacts collectively due to various magnetic couplings, creating topological spirals with great potential for technology. The key element is the discovery of compelling evidence for biquadratic exchange, which has recently been studied in two-dimensional magnetism. Moreover, we identified antiferromagnetic couplings that go beyond the nearest neighbor, causing frustration. Our research also revealed the connection between these 1D structures through van der Waals interactions, turning them into appealing quasi-two-dimensional magnets with highly tailored electric and magnetic characteristics. Our extensive calculations provide a strong foundation for comprehending the complex behavior of these one-dimensional chains and provide insight into the development of innovative materials with improved electronic and magnetic characteristics. These advances pave the way for various technological applications, especially in new-generation spintronics and magnonic devices.

Ultrashort Peptide Grafting on Mesoporous Films and Its Impact on Ionic Mesopore Accessibility.

An approach for direct in-pore solid-phase ultrashort peptide synthesis on mesoporous films using the amino acids arginine, leucine, and glycine is presented. Although the number of grafted amino acids remains low, the ionic mesopore accessibility can be gradually adjusted. The addition of arginine in up to five reaction cycles leads to a progressive increase in positive mesopore charge density, which gradually increases the anionic mesopore accessibility at acidic pH. At basic pH, the remaining silanol groups at the pore wall still dominate counter-charged cation mesopore accessibility. Thus, specific peptide sequence design is demonstrated to be a sensitive tool for molecular transport control in nanoscale pores. Overall, the direct in-pore solid-phase ultrashort peptide synthesis on mesoporous films using the sequences of different amino acids opens up exciting opportunities for the development of innovative materials with precisely tailored properties and functions based on specific peptide sequence design.

Facile electrochemical determination of sertraline at nanomolar concentration using bimetallic MXene NbTiCTx and MWCNTs hybridized electrodes as sensing platform

A novel and facile electrochemical determination of Sertraline at nanomolar concentration using bimetallic MXene NbTiCTx and MWCNTs hybridized electrodes as sensing platforms is demonstrated. NbTiCTx/MWCNTs composites were produced by etching NbTiAlC to obtain NbTiCTx, and ultrasonically mixing this with MWCNTs. An electrochemical sensor based on NbTiCTx/MWCNTs nanocomposite modified (NbTiCTx/MWCNTs/GCE) was constructed, for use in the sensitive detection of Sertraline (SER). The successful preparation of NbTiCTx/MWCNTs and the electrochemical performance of the electrodes were verified by Scanning electron microscopy, X-ray diffraction, cyclic voltammetry and electrochemical impedance characterization methods. The experimental results show that NbTiCTx/MWCNTs/GCE can increase the SER oxidation peak current, with two good linear relationships (R2 = 0.9910 and 0.9967) between the current and the concentration of SER (5.0–10.0 μM and 10.0–100.0 μM), with a detection limit of 0.16 μM (S/N = 3). The sensor has good selectivity, repeatability, reproducibility and stability, and enables the sensitive determination of SER in human serum and urine samples of clinical biological fluids. It is believed that this work is significant and is of broad interest for work in innovative material development and biomedical applications.

The Role of High‐Entropy Materials in Lithium‐Based Rechargeable Batteries

AbstractThe low energy density, safety concerns, and high cost associated with conventional lithium‐ion batteries pose challenges in meeting the growing demands of emerging applications. While lithiumsulfur batteries (LSBs) offer high specific capacity, their commercial viability is hindered by the prevalent issue of shuttle effects. Furthermore, the potential of solid‐state lithium batteries is constrained by the suboptimal ionic conductivity and significant interphase problems. High‐entropy materials (HEMs) have emerged as a strategic approach for the development of innovative materials possessing exceptional properties. In recent times, some studies have been undertaken to explore the potential of HEMs in lithium‐based rechargeable batteries, showcasing their favorable characteristics. This work provides a comprehensive overview of the impact of various factors associated with HEM materials, encompassing elements, structure, and morphology, on the reversibility of reactions and cycling stability. This work also presents an analysis of the effects of elements and morphology on the properties of HEMs in LSBs, which can trap soluble lithium polysulfides and enhance reaction kinetics. Additionally, the work provides an overview of high‐entropy electrolytes, including both solid‐state and non‐aqueous liquid electrolytes. Furthermore, the research outlines future research directions aimed at investigating more efficient HEMs and enhancing the overall performance of lithium‐based rechargeable batteries.

A functional Pickering emulsion coating based on octadecenylsuccinic anhydride modified γ-cyclodextrin metal-organic frameworks for food preservation

In the rapidly advancing field of colloid and interface chemistry, food-grade nanoparticles are garnering increased attention for their potential applications in food preservation and innovative material development. Pickering emulsions, stabilized by solid particles, are especially noteworthy for their versatile applicability, spanning from food preservation to innovative material engineering. However, crafting a reliable, application-specific Pickering emulsion that amalgamates both stability and functionality poses a substantial challenge. In this research, we present an in-depth analysis of octadecenylsuccinic anhydride (ODSA) modified γ-cyclodextrin metal-organic frameworks (OCMs) stabilized ODSA Pickering emulsions, probing their stability across varying pH values and ionic strengths, and evaluating their groundbreaking applications, notably in paper coating and enhancing food shelf life. Our results unequivocally indicate a pronounced improvement in paper water resistance and fruit preservation after treatment with the OCMs-ODSA emulsion, heralding a novel methodology in these areas. Additionally, our studies illuminate the intrinsic antimicrobial attributes of OCMs, accentuating their cardinal role in augmenting the emulsion's preservation capabilities and heralding potential widespread applications in microbial mitigation, decay deterrence, and beyond.