Abstract 1. The laws which are obeyed by ideally dilute and by perfect solutions have been obtained by Guggenheim, and he has extended his analysis to obtain the properties of a class of solutions to which the name regular has been given. It is assumed that the solution consists of molecules of two types, α and β, of approximately the same size, and that each molecule, whether of type α or of type β, is surrounded by the same number z of other molecules, and the potential energy is regarded as the sum of contributions from each pair of molecules in direct contact. That is, the molecules are regarded as occupying sites on a regular lattice, and the potential energy arises from the interactions between molecules which occupy closest neighbor sites. Rushbrooke has examined the properties of such a solution, using the Bethe method to set up the partition function for the assembly. The properties of solutions in which the molecules of one type are of such a size and shape that they have to be regarded as occupying two lattice sites have been investigated by Fowler and Rushbrooke, who determined the limiting form of the vapor-pressure equations for extremely dilute and for extremely concentrated solutions. Chang has determined, for a two-dimensional lattice, the value of the combinatory factor, which can be written as g2,1(Nα,Nβ) for the case in which each molecule of type a occupies two closest neighbor sites and each molecule of type β occupies one site. Chang's determination of g2,1(Nα,Nβ) for a two-dimensional lattice is based on an analysis of the corresponding adsorption problem, in which he superimposes some arbitrary assumptions on the Bethe method. It has, however, been shown that the value which Chang obtained for g2,1(Nα,Nβ) is applicable to two- and to three-dimensional lattices in which no two closest neighbors of a given site are also closest neighbors of one another. Fowler and Guggenheim have shown how, once the combinatory factor has been evaluated, it can be used to determine the configurational entropy of mixing and thence the vapor-pressure equations when the energy of mixing is zero. Using Chang's value for g2,1(Nα,Nβ), they obtained for the vapor-pressure equations, when each solute molecule occupies two closest neighbor sites on the lattice and each solvent molecule occupies only one lattice site, the following equations:
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