Determination Of Fluorine In Rocks Research Articles

Experience of the Determination of Fluorine in Rocks by X-Ray Fluorescence Spectrometry

Experience of the Determination of Fluorine in Rocks by X-Ray Fluorescence Spectrometry

Experience of the Determination of Fluorine in Rocks by X-Ray Fluorescence Spectrometry

The main fluorine-concentrating minerals in rocks are mainly apatites, amphiboles, micas, fluorites, sphenes, villiomites, in which fluorine is found in compounds with Ca, Mg, Na. The yield of the X‑ray fluorescence of fluorine depends on the element with which it is chemically bound. Taking into account this factor, three versions of calibration dependences for fluorine in the composition of CaF2, MgF2, and NaF were obtained using pressed tablets. Mixtures of these fluorides with granite, basalt, and limestone were used for calibration. To select an adequate calibration for the determination of fluorine in a batch of unknown samples, it was proposed to use the results of a selective analysis of fused samples of the batch

Factors Affecting the Determination of Fluorine in Rocks by X-Ray Fluorescence Spectrometry Using Pressed Pellets

Factors Affecting the Determination of Fluorine in Rocks by X-Ray Fluorescence Spectrometry Using Pressed Pellets

The automated photometric determination of total fluorine in mineral exploration

An analytical method previously applied to the determination of fluorine in rocks and minerals would seem to be ideal for exploration samples such as soils, stream sediments and vegetation. The determination which utilises the Zr-xylenol orange complex is performed on acidified leachates following sodium carbonate fusion. This digestion technique is rapid, simple and amenable to batch sample processing. The method, which is applicable to samples containing from about 10 ppm to over 3% fluorine, is essentially interference free.

Activation analysis with cyclotron-produced fast neutrons. Application to instrumental multi-element analysis and to the radiochemical determination of fluorine

Fast neutrons produced by irradiation of a thick beryllium target with 20–50 MeV deuterons are used for activation analysis. The spatial neutron flux distribution around the target is measured. A rotating sample holder is used for the simultaneous irradiation of samples and standards. Instrumental analysis can be applied for a number of elements. As an example, results for calcium and strontium in some reference materials are given. The19F(n, 2n)18F reaction is used for the radiochemical determination of fluorine in rocks with a fluorine concentration ranging from 9 to 5400 μg·g−1

The determination of fluorine in rocks and minerals by a pyrohydrolytic method

A rapid pyrohydrolytic method, with simple apparatus, is described for the determination of fluorine in rocks and minerals. The sample is heated with a three-component flux in a stream of moist air, and the liberated hydrogen fluoride is absorbed into an alkaline solution. The recovered fluorine is determined either colorimetrically or by means of a fluoride-specific electrode. The method is suitable for determining fluorine at concentrations down to about 50 p.p.m.

Spectrophotometric Determination of Fluorine in Rocks

Spectrophotometric Determination of Fluorine in Rocks