High- and very high-resolution (HR, VHR) remote sensing (RS) images can provide comprehensive and intricate spatial information for land cover classification, which is particularly crucial when analyzing complex built-up environments. However, the application of HR and VHR images to large-scale and detailed land cover mapping is always constrained by the intricacy of land cover classification models, the exorbitant cost of collecting training samples, and geographical changes or acquisition conditions. To overcome this limitation, we propose an unsupervised domain adaptation (UDA) with contrastive learning-based discriminative feature augmentation (CLDFA) for RS image classification. In detail, our method first utilizes contrastive learning (CL) through a memory bank in order to memorize sample features and improve model performance, where the approach employs an end-to-end Siamese network and incorporates dynamic pseudo-label assignment and class-balancing strategies for adaptive domain joint learning. By transferring classification models trained on a source domain (SD) to an unlabeled target domain (TD), our proposed UDA method enables large-scale land cover mapping. We conducted experiments using a massive five billion-pixels dataset as the SD and tested the HR and VHR RS images of five typical Chinese cities as the TD and applied the method on the completely unlabeled world view 3 (WV3) image of Urumqi city. The experimental results demonstrate that our method excels in large-scale HR and VHR RS image classification tasks, highlighting the advantages of semantic segmentation based on end-to-end deep convolutional neural networks (DCNNs).