Desalination Performance Research Articles

Introducing the SNW-1 Covalent Organic Framework to the Polyamide Layer of the TFC-RO Membrane with Enhanced Permeability and Desalination Performance.

This study investigates the synthesis and characterization of Schiff base network-1 (SNW-1) covalent organic framework (COF) nanomaterials and their application in the fabrication of thin-film nanocomposite (TFN) membranes. The embedding of SNW-1 COF in reverse osmosis (RO) membranes with a polysulfone (PSf) substrate was done using the interfacial polymerization method. The result of the study demonstrated that the porous and hydrophilic structure of the COF increased the hydrophilic properties of the produced RO membranes. When the COF was embedded with a concentration of 0.02 wt %, the hydrophilicity of the RO membrane was higher than that of the other membranes, with a contact angle value of 45.2°. Pure water flux, saline solution flux, and humic acid (HA)/sodium chloride (NaCl) foulant solution flux were measured to determine the membrane performance, and it was found that as the COF ratio increased, the fluxes increased up to a certain concentration rate. The RO membrane with a SNW-1 concentration of 0.005 wt % had the highest values of pure water flux and saline solution flux with high salt rejection (34.2 and 32.2 LMH, 97.1%, respectively) and was the most resistant membrane against fouling. This study presents the potential of the SNW-1 COF with precise design capabilities and controlled unique properties as an additive for desalination applications.

Numerical Investigation of Pyramid Solar Stills with PCM‐Nanoparticles and Absorber Fins: Enhanced Thermal Performance for Sustainable Water Desalination

ABSTRACTIn arid regions facing challenges of limited access to potable water and electricity, solar desalination stands out as a promising solution for producing clean water from brackish sources. This research intends to examine and enhance an innovative and sustainable solar desalination system. A computational study is conducted on a pyramid solar still (PSS) combined with a phase‐change material incorporated with nanoparticles, with a variety of absorber fins. The study investigates three configurations: a traditional pyramid–shaped solar still, one with square absorber fins, and another with circular fins. Paraffin wax mixed with Al2O3 nanoparticles is used beneath the absorber fins. Conservation equations are solved using COMSOL Multiphysics. Simulation outcomes demonstrate that the incorporation of finned absorbers, coupled with elevated water temperatures, significantly enhances the yield of the improved PSS compared with its conventional counterpart. The square‐finned absorber PSS exhibits a substantial increase in total accumulated productivity over the conventional design. Moreover, the PSS with square‐finned absorbers demonstrates an impressive average peak daily thermal efficiency improvement of 49.19% compared with a conventional solar still. This study highlights the effectiveness of the modified PSS as a superior option for household water generation.

Electrospun Membranes of Hydrophobic Polyimide and NH2‐UiO‐66 Nanocomposite for Desalination

Hydrophobic nanofiber composite membranes comprising polyimide and metal–organic frameworks are developed for desalination via direct contact membrane distillation (DCMD). Our study demonstrates the synthesis of hydrophobic polyimides with trifluoromethyl groups, along with superhydrophobic UiO‐66 (hMOF) prepared by phenylsilane modification on the metal‐oxo nodes. These components are then combined to create nanofiber membranes with improved hydrophobicity, ensuring long‐term stability while preserving a high water flux. Integration of hMOF into the polymer matrix further increases membrane hydrophobic properties and provides additional pathways for vapor transport during MD. The resulting nanofiber composite membranes containing 20 wt% of hMOFs (PI‐1‐hMOF‐20) were able to desalinate hypersaline feed solution of up to 17 wt% NaCl solution, conditions that are beyond the capability of reverse osmosis systems. These membranes demonstrated a water flux of 68.1 kg m−2 h−1 with a rejection rate of 99.98% for a simulated seawater solution of 3.5 wt% NaCl at 70 °C, while maintaining consistent desalination performance for 250 h.

Performance analysis of coupling vapor compression cycle to freeze and humidification-dehumidification based high-performance desalination

Although freeze desalination has a lower latent heat of ice formation (334 kJ/kg), its energy performance is still insufficient because of energy loss associated with not using the waste heat of the active cooling system. To address this challenge, this research introduces an innovative hybrid desalination system that synergistically combines freeze, humidification-dehumidification (HDH), and vapor compression cycle (VCC) technologies. The novelty of our approach lies in simultaneously leveraging the VCC's cooling and thermal energy for freeze and dehumidification processes, respectively, which greatly increases the desalination energy performance over only achieving freeze desalination. A thermodynamic model is developed to analyze the proposed system, and a series of parametric analyses are carried out to determine the system configuration that obtains the highest performance. Ultimately, a higher ice recovery rate of 20 % offers the best total desalination performance of only 63 Wh/kg. Furthermore, the HDH desalination unit can make up the for loss of freeze desalination performance at higher feed seawater temperatures, ensuring robust performance even under high-temperature conditions.

Fluoride removal using membrane capacitive deionization: The role of pH-dependent dissolved inorganic carbon

Defluorination technology is crucial for ensuring safe and accessible water. The application of capacitive deionization (CDI) technology faces challenges due to competitive adsorption of fluoride ions within complex natural fluoride-rich brackish water matrices, which often contain high levels of dissolved inorganic carbon (DIC) species (mainly HCO3– and CO32–). These DIC species are pH-dependent, playing a significant role in the selective removal of fluoride by the CDI process. Thus, there is a knowledge gap in understanding the effects of membranes in membrane capacitive deionization (MCDI) on fluoride removal. In this study, we examined the key operating parameters in CDI and MCDI, including applied constant voltages and different types of anion-exchange membranes (AEMs), on the desalination performance in F- and dissolved inorganic carbon water matrices. The application of AEMs significantly improved the salt adsorption capacity (SAC) for both F- and DIC species, and reduced energy consumption. However, it simultaneously resulted in a notable decrease in F- selectivity as membranes control mass transfer. Higher applied voltages enhance the SAC performance for F- and DIC species, but also induce more severe Faradaic reactions, leading to increased energy consumption and lower energy efficiency. Additionally, ion species and pH changes during CDI and MCDI processes are interrelated, indicating that stability tests of CDI electrodes in batch mode are not reliable when using the same testing solution repeatedly. The diverse valence states of ions in the solution impact pH variations under different voltages in the CDI/MCDI process. These findings provide valuable insights into the development of water purification and desalination technology, particularly for the application and further advancement of selective fluoride removal by the CDI process.

Highly efficient porous MXene desalination membranes controlled by the thickness of the transition metal carbides

MXene membrane has the vast potential to alleviate the global freshwater crisis. Herein, a new strategy for improving the desalination performance is proposed through tunable the thickness transition metal carbides of the nano-porous MXene membrane. The thickness of porous MXene is investigated by molecular dynamics (MD) simulation, including the Ti2CF2, Ti3C2F2, and Ti4C3F2. The results show that the porous MXene membrane can reach highly efficient desalination. The water density distribution reveals that more water gathers in the thicker transition metal carbides layer, contributing to the poor water flux; the average charge distribution indicates that the transition metal layer plays an essential role in effectively rejecting Na+/trapping Cl- ions. Multilayered porous membranes are explored to improve the trade-off desalination performance. The number of pores enhances the water permeability, and the multilayers improve the ion rejection. The two-layered Ti3C2F2 membrane with three nanopores achieves nearly doubled water flux and keeps 100% ion rejection. Our work reported that the nano-porous MXene membrane offers a prospective strategy to eliminate the current design defects, which provides an innovative method for the desalination semipermeable membrane industry.

Porous N, P co-doping Ti3C2Tx MXene for high-performance capacitive deionization

The emerging energy-saving and environmentally friendly capacitive deionization (CDI) technology has attracted more and more attention. However, it remains a great challenge to develop CDI electrode materials with excellent comprehensive properties. Herein, the porous N, P co-doping Ti3C2Tx MXene (N, P-Ti3C2Tx) was prepared successfully by combining simple flocculation with an annealing process. Benefitting from the synergistic effect of the combination of porous structure and co-doping of N and P heteroatoms, the N, P-Ti3C2Tx exhibits substantial specific surface area, which provides more surface bounding active sites for electrochemical reactions, thus assisting to boost the CDI performance. As a result, the N, P-Ti3C2Tx exhibited an admirable salt (Na+) adsorption capacity of 53.3 mg g−1 and exceptional recycling property. Impressively, the N, P-Ti3C2Tx also exhibited superior desalination performance of Pb2+, characterized by an exceptionally high desalination capacity of up to 168.2 mg g−1 at 1.2 V, and the corresponding desalination rate reached 0.047 mg g−1 s−1. Additionally, the deionization mechanism involved was elucidated through a series of characterizations. This work will furnish an effective avenue for the innovative design of MXene-based electrode materials toward high-performance CDI.

A two-pronged strategy to boost the capacitive deionization performance of nitrogen-doped porous carbon nanofiber membranes

Carbon-based capacitive deionization (CDI) systems are universally subject to the limited desalination capacity, due to the electrosorption characteristics and undesirable pore structures. Herein, a two-pronged strategy is proposed to boost the desalination performance of the electrospun carbon nanofibers (CNFs), where silicalite-1 nanoparticles as the internal porogen create mesopores and macropores, and zeolitic imidazolate framework (ZIF-L) leaves as the external carbon source provide micropores and mesopores. This combination results in the large surface area, well-developed graded pore structure, and increased nitrogen content of the core-shell polyacrylonitrile/silicalite-1@ZIF-L-derived CNFs (defined as PCNFs-SZ) electrode, which delivers a superior specific capacitance of 145.4 F g−1 in a neutral electrolyte. The symmetric CDI cell assembled by the self-supporting PCNFs-SZ membrane electrodes holds a prominent desalination capacity of 37.09 mg g−1 and a rapid salt removal rate of 10.36 mg g−1 min−1 at 1.2 V (initial NaCl concentration: 500 mg L−1), and demonstrates significant potential for real-world applications in the desalination and purification of reclaimed water. Furthermore, theory calculations confirm the enhanced Na+-capture capability of PCNFs-SZ. The present work highlights an effective and viable approach to enhance the desalination performance of carbon-based CDI cells.

Amino acid-based nanoparticles-incorporated thin-film nanocomposite forward osmosis membranes for efficient desalination and heavy metal ions rejection

The current study explores potential applications of state-of-the-art thin-film nanocomposite forward osmosis (TFN-FO) membranes, modified with histidine-functionalized graphene quantum dots (His-GQDs) and MIP-202(Zr) nanoparticles (NPs), for sustainable desalination and heavy metal ions rejection. The porous and layered structure of the applied NPs, along with various hydrophilic functional groups on their surface, contribute to improving the fabricated membranes' ion/water separation performance. The successful preparation and incorporation of desired NPs into the polyamide layer was investigated using typical analytical methods. Under the common FO test conditions, the best-performing TFN-MQ2 membrane displayed a water flux of 21.8 LMH, which was over 1.5 times greater than the water flux of blank TFC. Simultaneously, the selectivity was found to be approximately 1.7 times greater than that of the unmodified TFC membrane. Moreover, the optimal TFN-MQ2 membrane exhibited superior rejection rates for Cu2+ ions (98.5 %) and Pb2+ ions (98.1 %), surpassing all other samples in heavy metal ion rejection. The findings of this study suggest that carefully choosing cost-efficient and eco-friendly nanofillers (such as amino acid-based NPs) can enhance the desalination performance of TFN-FO membranes and bolster their resistance to fouling and rejection of heavy metal ions. Not to mention, the overall costs of membrane production will be reduced.

Maximizing desalination performance in pyramid distiller: Integration of vertical wick still and enhanced phase change material by nanoparticle and emerging fins

The growing global water crisis, driven by population growth and dwindling freshwater resources, demands innovative solutions for sustainable desalination. While traditional solar still designs have been explored, their efficiency remains limited. This study introduces an advanced approach to solar distillation by integrating a modified pyramid solar still (MPSS) with two key innovations: a vertically positioned wick still (VWSS) and phase change material (PCM) enhanced with silver nanomaterials (PCM-Ag Nano). In addition, the design features two absorber plate configurations—flat and finned—coupled with emerging fins (EF) within the PCM unit to improve heat conductivity, addressing a common limitation in solar distillation systems. By incorporating PCM-Ag Nano and finned absorbers, the MPSS achieved significant improvements in desalination performance. The combined system of MPSS-FA-PCM-Ag-EF and VWSS produced a total distillate volume of 12,870 ml, representing a 154 % increase over a conventional pyramid solar still (PSS). Specifically, daily outputs of 9,270 ml, 5,050 ml, and 3,600 ml were recorded for MPSS, PSS, and VWSS, respectively. Furthermore, the enhanced MPSS configuration attained the highest thermal efficiency at 60.5 %, and the desalination cost was reduced to $0.0142/L, compared to $0.019/L for the PSS. These results underscore the potential of this novel MPSS design, which combines PCM-Ag Nano and VWSS, to deliver substantial improvements in freshwater production, thermal efficiency, and cost-effectiveness. This innovative system offers a promising alternative to traditional desalination techniques, contributing to the global effort to mitigate water scarcity.

Optimized performance of membrane-based desalination by high-throughput molecular dynamic simulations and machine learning analysis

The influence of pore size and hydrophilicity on the permeance of reverse osmosis (RO) membranes has been mostly focused. However, their influence is hardly to be clearly identified as these two kinds of factor interfere with each other. In this work, high-throughput molecular dynamics (HTMD) simulations with CNTs are used to extensively produce the data of water permeance and NaCl rejection. These data are then analyzed by machine learning (ML) method to obtain the optimized desalination performance. The HTMD results indicate that the pressure drop has little effect on the water permeance. Moreover, rising pore size and degrading hydrophilicity will generally boost water permeance but will somehow sacrifice the NaCl rejection. The interference effect between pore size and hydrophilicity is also found in this work, the mechanism of which is then revealed from molecular level. Additionally, ML is applied to analyze the abundant data of water permeance and NaCl rejection. The optimal conditions are identified to achieve the highest water permeance with 100% NaCl rejection, which are also validated via additional MD simulations. This work suggests that the integration of HTMD and ML promises the future of designing new kind of RO membranes for better performance.

Enhanced desalination performance of flow capacitive deionization with the addition of conductive polymer in redox couples and activated carbon

Freshwater scarcity is a critical global issue and desalination of brackish water and seawater technologies are regarded as effective solution to mitigate the increasing severity of water shortage. Flow-electrode capacitive deionization (FCDI) is an emerging electrochemical desalination technology capable of continuous deionization behavior. However, reducing energy consumption and enhancing desalination rate are now markedly needed for its advancement. Herein, we propose a FCDI system with energy consumption as low as 88.08 kJ mol−1 and a desalting rate of 1.75 μg cm−2 s−1. This is achieved by using flow electrodes containing 0.03125 wt% conductive polymer, 5 wt% activated carbon/carbon black and 80 mM/80 mM ferricyanide/ferrocyanide at a current density 3 mA cm−2 (3.36 mA current for a 1.12 cm2 active area). We further investigate the effects of polymer content, redox pair content, salt content and current densities on desalination performance. Seawater with a conductivity of 52.78 mS cm−1 was successfully desalinated to 0.50 mS cm−1 in continuous process. This research provides a promising approach to enhance FCDI system by achieving a low energy consumption and high salt removal rate, representing a significant advancement in continuous electrochemical desalination technology.

Efficient desalination and synergistic toxic organics removal in RO concentrates with electrochemical advanced oxidation processes

A novel Ce-doped Ti4O7 (Ti/Ti4O7-Ce) electrode was fabricated and investigated in treatment of reverse osmosis (RO) concentrates with Electrochemical advanced oxidation processes (EAOPs). Characterization results showed that Ce was successfully incorporated into the Ti4O7, leading to an increase on the hydroxyl radical (•OH) generation and electrochemical stability compared with Ti/Ti4O7. Ti/Ti4O7-Ce electrodes achieved efficient desalination and oxidation of toxic organics, which was mainly attributed to the indirect oxidation induced by electro-generated •OH and change of electrochemical properties. The action of electric field had great effect on desalination process, and the anions in reverse osmosis concentrates (ROC) deposited on the cathode through this action by characterization and analysis. In the treatment, about 10.8–11.2 % of desalination efficiencies can be obtained, and the removal efficiency of toxic organics enhanced with the increase of Ce addition and current density. In the experiments, TOC removal efficiencies were 57 %, 66 % and 69 % under 10, 20 and 30 mA/cm2 in the 180 min treatment. Toxic chemicals, such as alkanes, haloalkanes, etc., were the main components in treatment, and the organic pollutants with medium molecular weight (MMW) (1400 g/mol) and low molecular weight (LMW) (40–230 g/mol) in ROC were removed. Although slight decreased durability was observed due to Ce leaching, Ti/Ti4O7-Ce electrode maintained stable desalination performance and total organic carbon (TOC) removal efficiency within 60 cycles. This study indicated that Ti/Ti4O7-Ce was a promising electrode for synergistic toxic organics removal and desalination in EAOPs.

Study on the Desalination and Regeneration Performance of PBA/AC Electrode Enhanced by MCDI

Study on the Desalination and Regeneration Performance of PBA/AC Electrode Enhanced by MCDI

Novel post-heat treatment green biodegradable PLA@SiO2 nanocomposite membrane for water desalination

Membrane distillation (MD) has received significant attention because of its energy efficiency and ability to treat industrial wastewater and salty water. However, the synthetic nature of commonly used membranes raises environmental disposal concerns, requiring the development of alternative eco-membranes. To address this issue, a novel, eco-friendly membrane using polylactic acid (PLA) coated with green silica nanoparticles (SiO2 NPs), modified by post-heat treatment, was developed for effective direct contact membrane distillation (DCMD). Herein, two nanofibrous membranes were fabricated via electrospinning/electrospraying: one, PLA, with a 12.5 wt% PLA solution, and another, PLA@SiO2, with 2 % (w/v) SiO2 NPs coating. The PLA@SiO2 membrane demonstrated enhanced hydrophobicity. Various post-heat treatments were applied to optimize membrane properties, such as structure, pore size, hydrophobicity, liquid entry pressure (LEP), thickness, and thermal stability. In addition, the desalination performance of all membranes was evaluated using a DCMD unit for 6 h. Results showed that the heat-pressed then annealed PLA@SiO2 membrane (denoted M44) exhibited notable improvements, including an LEP of 128.7 kPa, a tunable pore size of 0.21 μm, and a contact angle of 135.9°. Furthermore, the M44 membrane demonstrated a porosity of 80.5 %, a stable permeate flux of 14.3 kg.m−2.h−1, and an exceptional salt rejection of 99.99 % over a 24 h DCMD test. This novel eco-membrane shows promising potential for efficient desalination and represents a significant advancement in sustainable MD applications.

Rational design of MoS2 nanoflowers-decorated carbon nanofibers with enhanced electronic transmission for boosting capacitive deionization

Capacitive deionization (CDI) has sparked considerable interest for its promising application in handling brackish water. Unfortunately, most traditional carbonaceous materials are still plagued by the limited desalination capacity and sluggish adsorption kinetics with the single adsorption mechanism and irrational pore structure. Herein, we developed a facile and affordable strategy to integrate electrospinning with hydrothermal method to fabricate MoS2 nanoflowers-decorated carbon nanofibers (MoS2/CNF) composite for boosting desalination performance. CNF not only serves as a supportive framework to inhibit the agglomeration of MoS2 nanosheets favoring the full contact with salt solutions, but also typically diminishes the charge transfer resistance of the composite. By taking advantage of the double layer adsorption of CNF and the hierarchically micro-mesoporous structure of MoS2 nanoflowers with large interlayer spacer for salt ions intercalation, the optimized sample MoS2/CNF-1 employed as a cathode for the asymmetric hybrid CDI cell showed an eminent capacity for desalination of 30.9 mg·g−1, an ultrafast rate for desalination of 3.7 mg·g−1·min−1, and an attractive circulation stability for desalination with the capacity reservation remaining at 94.8 % after 30 cycles in the solution of 500 mg·L−1 NaCl at 1.2 V. This research sheds fresh light on the evolution of advanced CDI electrode materials for practical utilization.

Tailoring iron MOF/carbon nanotube composites as flow electrodes for high-performance capacitive deionization

Capacitive deionization techniques are of interest in water treatment technology due to their low cost, excellent efficiency, and environmental friendliness. Currently, metal–organic frameworks are highly impactful candidates for use as electrode materials in electrochemistry. It provides a large pore volume, good chemical stability, and a high specific surface area. Tuning metal–organic frameworks with carbon materials will have a good impact on electrode materials with increasing performance. This study shows a facile and effective strategy for arranging flow capacitive desalination technology for salt removal. The conducting network of Fe-MOF/CNTs provides rapid electron transport and offers a high diffusion length of ions. This material exhibited excellent desalination performance, with a high salt adsorption of 80.575 mg/g at 1.6 V at an initial NaCl concentration of 1000 mg/L. Overall, the facile method and fabrication strategy greatly advances water treatment applications.

The enhanced performance of NaFe2PO4(SO4)2/C electrode materials in the desalination of brackish water by capacitive deionization

In this study partial substitution of phosphates in Na3Fe2(PO4)3/C (NFP/C) by sulphates to prepare Na2Fe2(PO4)2SO4 (NFP2S/C) and NaFe2PO4(SO4)2/C (NFPS/C) was carried out by dissolution-evaporation method. The idea is to adjust the properties of NFP/C owing to the differences in the inductive effect and sizes of sulphates and phosphates which results the obtained NFPS/C to record excellent electrochemical and desalination performance. Several characterization techniques used to analyse the synthesized materials confirm the successful doping and structure integrity. Electrochemical study reveals NFPS/C to exhibit the highest capacitance of 127.4 F/g when scanned at 10 mV/s. The results show that when the potential of 1.2 V is applied to desalinate 500 mg/L salt solution the salt removal of about 17.3 mg/g is achieved by NFPS/C while NFP/C attaining 9.8 mg/g. The NFPS/C was then tested in the desalination of real Ocean water and promising results obtained. The salt removal performance presented makes the developed materials promising for application in brackish water desalination by capacitive deionization.

The effect of functional group of Graphene-based woven filter on the desalination performance

Abstract Graphene-based braided filter membranes (GWFM) are becoming increasingly crucial in seawater desalination because of their excellent performance, moving from research to practical use and helping to tackle water scarcity. However, the mechanisms associated with GWFMs functionalized by functional groups are unclear. This paper demonstrates that graphene strips are intricately integrated into a filtration membrane characterized by X-functional groups (GWFM-X). Molecular dynamics (MD) simulations are effective for calculating water flux, assessing salt discharge effects, and understanding the physical mechanisms in seawater desalination, making them crucial for optimizing and advancing desalination technology and salt rejection rate of four types of GWFM-X, namely GWFM-1.2nm-COOH, GWFM-1.2nm-NH2, GWFM-1nm-COOH, and GWFM-1nm-NH2, which were designed with different functional groups and nanopore diameters. These results demonstrate the superior performance of GWFM-X in water filtration applications. Salt rejection efficiency of four distinct variants of GWFM-X, namely GWFM-1.2nm-COOH, GWFM-1.2nm-NH2, GWFM-1nm-COOH, and GWFM-1nm-NH2, is designed with different functional groups and nanopore diameters. The test membrane shows exceptional water flux, significantly outperforming current commercial reverse osmosis membranes, with measurements of 30.00±0.49 L cm−2 day−1 MPa−1, 35.41±0.71 L cm−2 day−1 MPa−1, 9.31±0.31 L cm−2 day−1 MPa−1, and 20.66±0.21 L cm−2 day−1 MPa−1, respectively. The free energy profiles of GWFM-X reveal a pronounced disparity in free energy barriers between water molecules and Na+/Cl− ions, with a difference of up to 14.26 kBT. The simulation results show that the seawater desalination system maintains over 75% efficiency at pressures between 10 and 500 MPa, highlighting its effectiveness and versatility. Moreover, advancements in nanofabrication technology are paving the way for new membrane materials that could improve desalination methods and help address water scarcity.

Green self-templated synthesis of P-doped mesoporous carbon from dual sodium salts with improved average pore size for capacitive deionization

Mesoporous carbon materials hold significant potential in capacitive deionization (CDI) technology owing to expansive accessible surface area, more adaptable pore structure, excellent conductivity properties and effective surface modification and functionalization. While templating is a common method for synthesizing mesoporous carbons, the commonly used hard and soft templating approaches among them suffer from the challenges of expensive precursors and templating agents, complex procedures, secondary contaminants and difficulties in template removal. In contrast, the self-templating method not only circumvents the traditional template removal or combustion steps but also eliminates the use of organic solvents and hazardous chemicals, thus minimizing environmental impact. In this paper, we have successfully synthesized phosphorus-doped mesoporous carbon with a large average pore size (paver) using a green and convenient self-templating method employing dual sodium salts of sodium alginate (SA) and sodium phytate (SP). Compared to single SA (6.76 nm) or SP (3.74 nm) self-templated carbonization, the average pore size of carbon materials obtained from dual self-templated carbonization with a proportional mixture (12.97 nm) is significantly improved. The larger average pore size provides a greater surface area for electrode-electrolyte interactions, allowing for easier access and faster diffusion of ions into the pores, thereby enhancing the electrochemical and capacitive deionization properties of the material. The resulting material demonstrates promising electrochemical and desalination performance as evidenced by possessing a specific capacitance of 175.8 A/g and an adsorption capacity of 19.65 mg/g, underlining its potential for application in capacitive deionization utilizing mesoporous carbon materials with large average pore size.