Density Wave Research Articles

Interfacial Charge-Transfer Excitonic Insulator in a Two-Dimensional Organic-Inorganic Superlattice.

Excitonic insulators are long-sought-after quantum materials predicted to spontaneously open a gap by the Bose condensation of bound electron-hole pairs, namely, excitons, in their ground state. Since the theoretical conjecture, extensive efforts have been devoted to pursuing excitonic insulator platforms for exploring macroscopic quantum phenomena in real materials. Reliable evidence of excitonic character has been obtained in layered chalcogenides as promising candidates. However, owing to the interference of intrinsic lattice instabilities, it is still debatable whether those features, such as the charge density wave and gap opening, are primarily driven by the excitonic effect or by the lattice transition. Herein, we develop an intercalation chemistry strategy for obtaining a novel charge-transfer excitonic insulator in organic-inorganic superlattice interfaces that serves as an ideal platform to decouple the excitonic effect from the lattice effect. In this system, we observe a narrow excitonic gap, formation of a charge density wave without periodic lattice distortion, and metal-insulator transition, providing visualized evidence of exciton condensation occurring in thermal equilibrium. Our findings identify self-assembly intercalation chemistry as a new strategy for developing novel excitonic insulators.

Real-Time Monitoring of Particle Size in Emulsion Polymerization: Simultaneous Turbidity and Photon Density Wave Spectroscopy.

Particle size evolution in seeded semibatch emulsion polymerization is monitored by two real-time monitoring techniques: online turbidity spectroscopy (TUS) and inline photon density wave spectroscopy (PDWS). An automatic dilution system that withdraws a sample from the reactor and upon dilution transfers to the measurement cell is used for the online TUS analysis. A PDWS probe is immersed in the reactor and collects inline the scattered light directly from the reacting latex. The particle sizes retrieved from TUS and PDWS are compared to offline dynamic light scattering (DLS) values. The particle size obtained by TUS is close to the intensity-average particle size obtained offline by DLS, while the particle size obtained by PDWS lies closer to the number-average particle size from DLS.

In Situ Exsolution-Prepared Solid-Solution-Type Sulfides with Intracrystal Polarization for Efficient and Selective Absorption of Low-Frequency Electromagnetic Wave.

The excellent dielectric properties and tunable structural design of metal sulfides have attracted considerable interest in realizing electromagnetic wave (EMW) absorption. However, compared with traditional monometallic and bimetallic sulfides that are extensively studied, the unique physical characteristics of solid-solution-type sulfides in response to EMW have not been revealed yet. Herein, a unique method for preparing high-purity solid-solution-type sulfides is proposed based on solid-phase in situ exsolution of different metal ions from hybrid precursors. Utilizing CoAl-LDH/MIL-88A composite as a precursor, Fe0.8Co0.2S single-phase nanoparticles are uniformly in situ formed on an amorphous substrate (denoted as CoAl), forming CoAl/Fe0.8Co0.2S heterostructure. Combing with density functional theory (DFT) calculations and wave absorption simulations, it is revealed that Fe0.8Co0.2S solid solution has stronger intracrystal polarization and electronic conductivity than traditional monometallic and bimetallic sulfides, which lead to higher dielectric properties in EM field. Therefore, CoAl/Fe0.8Co0.2S heterostructure exhibits significantly enhanced EMW absorption ability in the low-frequency region (2-6GHz) and can achieve frequency screening by selectively absorbing EMW of specific frequency. This work not only provides a unique method for preparing high-purity solid-solution-type sulfides but also fundamentally reveals the physical essence of their excellent EMW absorption performance.

Terahertz spectroscopy of collective charge density wave dynamics at the atomic scale

AbstractCharge density waves are wave-like modulations of a material’s electron density that display collective amplitude and phase dynamics. The interaction with atomic impurities induces strong spatial heterogeneity of the charge-ordered phase. Direct real-space observation of phase excitation dynamics of such defect-induced charge modulation is absent. Here, by utilizing terahertz pump–probe spectroscopy in a scanning tunnelling microscope, we measure the ultrafast collective dynamics of the charge density wave in the transition metal dichalcogenide 2H-NbSe2 with atomic spatial resolution. The tip-enhanced electric field of the terahertz pulses excites oscillations of the charge density wave that vary in magnitude and frequency on the scale of individual atomic impurities. Overlapping phase excitations originating from the randomly distributed atomic defects in the surface create this spatially structured response of the charge density wave. This ability to observe collective charge order dynamics with local probes makes it possible to study the dynamics of correlated materials at the intrinsic length scale of their underlying interactions.

Universal sublinear resistivity in vanadium kagome materials hosting charge density waves

Universal sublinear resistivity in vanadium kagome materials hosting charge density waves

Unconventional Spectral Gaps Induced by Charge Density Waves in the Weyl Semimetal (TaSe4)2I.

Coupling Weyl quasiparticles and charge density waves (CDWs) can lead to fascinating band renormalization and many-body effects beyond band folding and Peierls gaps. For the quasi-one-dimensional chiral compound (TaSe4)2I with an incommensurate CDW transition at TC = 263 K, photoemission mappings thus far are intriguing due to suppressed emission near the Fermi level. Models for this unconventional behavior include axion insulator phases, correlation pseudogaps, polaron subbands, bipolaron bound states, etc. Our photoemission measurements show sharp quasiparticle bands crossing the Fermi level at T > TC, but for T < TC, these bands retain their dispersions with no Peierls or axion gaps at the Weyl points. Instead, occupied band edges recede from the Fermi level, opening a spectral gap. Our results confirm localization of quasiparticles (holes created by photoemission) is the key physics, which suppresses spectral weights over an energy window governed by incommensurate modulation and inherent phase defects of CDW.

General skin and nasal decolonization with octenisan® set before and after elective orthopedic surgery in selected patients at elevated risk for revision surgery and surgical site infections—a single-center, unblinded, superiority, randomized controlled trial (BALGDEC trial)

BackgroundThe preoperative body surface and nasal decolonization may reduce the risk of surgical site infections (SSI) but yields conflicting results in the current orthopedic literature.MethodsWe perform a single-center, randomized-controlled, superiority trial in favor of the preoperative decolonization using a commercial product (octenidine® set). We will randomize a total number of 1000 adult elective orthopedic patients with a high risk for SSI and/or wound complications (age ≥ 80 years, chronic immune-suppression, American Society of Anesthesiologists score 3–4 points) between a decolonization (octenisan® wash lotion 1 × per day and octenisan® md nasal gel 2–3 × per day; during 5 days) and no decolonization. Decolonized patients will additionally fill a questionnaire regarding the practical difficulties, the completeness, and the adverse events of decolonization. The primary outcomes are SSI and revision surgeries for postoperative wound problems until 6 weeks postoperatively (or 1 year for surgeries with implants or bone). Secondary outcomes are unplanned revision surgeries for non-infectious problems and all adverse events. With 95% event-free surgeries in the decolonization arm versus 90% in the control arm, we formally need 2 × 474 elective orthopedic surgeries included during 2 years.DiscussionIn selected adult orthopedic patients with a high risk for SSI, the presurgical decolonization may reduce postoperative wound problems, including SSI.Trial registrationClinicalTrial.gov NCT05647252. Registered on 9 December 2022.Protocol version: 2 (5 December 2022).

The impact of diabetes mellitus on foot perfusion measured by ICG NIR fluorescence imaging

IntroductionDiabetes Mellitus (DM) is a common chronic disease, affecting 435 million people globally. Impaired vasculature in DM patients leads to complications like lower extremity arterial disease (LEAD) and foot ulcers, often resulting in amputations. DM causes additional peripheral neuropathy leading to multifactorial wound problems. Current diagnostics often deem unreliable, but Near-Infrared Fluorescence with Indocyanine Green (ICG NIR) can be used to assess the foot perfusion. Therefore, this study explores DM’s impact on foot perfusion using ICG NIR. MethodsBaseline ICG NIR fluorescence imaging was performed in LEAD patients with and without DM. Ten perfusion parameters were extracted and analyzed to assess differences in perfusion patterns. ResultsAmong 109 patients (122 limbs) of the included patients, 32.8% had DM. Six of ten perfusion parameters, mainly inflow-related, differed significantly between DM and non-DM patients (p-values 0.007–0.039). Fontaine stage 4 DM patients had the highest in- and outflow values, with seven parameters significantly higher (p-values 0.004–0.035). ConclusionDM is associated with increased in- and outflow parameters. Patients with- and without DM should not be compared directly due to different vascular pathophysiology and multifactorial wound problems in DM patients. Quantified ICG NIR fluorescence imaging offers additional insight into the effect of DM on foot perfusion.

A geological telescope through the galaxy?

We reside within a relatively interior position within the Milky Way galaxy which hinders our ability to understand its structure. Nonetheless, astrophysical observations of other galaxies in unison with spectroscopic measurements have produced a model for the Milky Way as a grand design, barred, spiral arm galaxy, with either two or four arms. Viewing through the plane of the Milky Way is not possible with any current astrophysical technique. However, perhaps terrestrial geology can help where current observations of our stellar environment cannot. During the orbit of our solar system around the galactic centre, Earth will have seen different cosmic surroundings, as a function of the solar system's orbit (240 km/s) that is faster than the spiral arm's density waves (210 km/s). Specifically, if the terrestrial impact record, or proxies for it, in some cryptic way reflect perturbations on the gravity field of the local solar system, then Earth may act as a geological orrery, with some interesting implications. Here we explore various models for the design of the Milky Way and compare these to geological proxies proposed by some as indicators for impact flux, through the deep time record within our planet. Isotope signatures in zircon are statistically coherent with a four-armed spiral model. However, even better correspondence is shown between the terrestrial isotopic record and more complex atomic hydrogen models of the galaxy.

Electronic instability in pressured black phosphorus under strong magnetic field

In this paper, we have systematically studied the electronic instability of pressured black phosphorous (BP) under strong magnetic field. We first present an effective model Hamiltonian for pressured BP near the Lifshitz point. Then we show that when the magnetic field exceeds a critical value, the nodal-line semimetal (NLSM) state of BP with a small band overlap re-enters the semiconductive phase by re-opening a small gap. This results in a narrow-bandgap semiconductor with a partially flat valence band edge. Moreover, we demonstrate that above this critical magnetic field, two possible instabilities, i.e. charge density wave phase and excitonic insulator (EI) phase, are predicted as the ground state for high and low doping concentrations, respectively. By comparing our results with the experiment (Sun et al 2018 Sci. Bull. 63 1539), we suggest that the field-induced instability observed experimentally corresponds to an EI. Furthermore, we propose that the semimetallic BP under pressure with small band overlaps may provide a good platform to study the magneto-exciton insulators. Our findings bring the first insight into the electronic instability of topological NLSM in the quantum limit.

Electron–electron interactions in partially mixed helical states

We theoretically study the effect of electron–electron interactions in one-dimensional partially mixed helical states. These helical states can be realized at the edges of two-dimensional topological insulators with partially broken time-reversal symmetry, resulting in helical gapped states. Using the bosonization method and renormalization group analysis, we identify weak gap, crossover, and strong gap regimes in the phase diagram. We find that strong electron–electron interaction mixes the helicity of the states, leading to the relevant strong gap regime. We investigate the charge and spin density wave correlation functions in different relevancy regimes of the gap mediated by interactions, where in the case of strong repulsive interaction, the spin density wave dominates the charge density wave. Additionally, employing the Memory function technique, we calculate the effect of mixed helicity on the charge transport in a sufficiently long edge. We find a non-uniform temperature dependence for the charge conductivity in both the strong and weak gap regimes with distinct features.

Computational demonstrations of density wave of Cooper pairs and paired-electron liquid in the quarter-filled band-A brief review.

There has been strong interest recently in the so-called Cooper pair density wave, subsequent to the proposition that such a state occurs in the hole-doped cuprate superconductors. As of now, there is no convincing demonstration of such a state in the cuprate theoretical literature. We present here a brief but complete review of our theoretical and computational work on the paired-electron crystal (PEC), which has also been experimentally seen in the insulating phase proximate to superconductivity (SC) in organic charge-transfer solid (CTS) superconductors. Within our theory, SC in the CTS does indeed evolve from the PEC. A crucial requirement for the finding of the PEC is that the proper carrier density of one charge carrier per two sites is taken into consideration at the outset. Following the discussion of CTS superconductors, we briefly discuss how the theory can be extended to understand the phase diagram of the cuprate superconductors that has remained mysterious after nearly four decades of the discovery of SC in this family.

FlexLogNet: A flexible deep learning-based well-log completion method of adaptively using what you have to predict what you are missing

Well logs are essential tools for understanding the characteristics of subsurface formations and exploring petroleum resources. However, well logs are often missing randomly due to cost constraints, instrument failures, or other factors. Many methods have been developed for completing missing well logs, but these methods are all based on fixed types of known well-log inputs to predict specific types of missing logs. This fixed input–output mode severely limits the application of these methods in actual data, where the known and missing well-log types are often varying. To address this problem, we propose a hybrid deep learning method with two heads of heterogeneous graph neural network (HGNN) and fully connected network (FCN) to achieve mutual prediction among multiple types of well logs. It can adaptively use all known well logs to predict any missing well logs, achieving a very flexible and practical well log completion function of using what you have to complete what you are missing. Specifically, the HGNN head infers the inter-relationships among multiple well logs to predict normalized logs that contain detailed information, which achieved by using multiple independent kernels to extracting and aggregating the features of the multiple logs. The FCN head estimates the global statistics of the predicted logs, including means and standard deviations, for de-normalizing the well logs estimated by the HGNN head. Both the HGNN and FCN heads are trained simultaneously by a hybrid loss function to ensure the consistency of their predictions. Furthermore, we present an adaptive training strategy that leverages all well logs, including those with missing segments. We demonstrate the capability of our model using four well logs: gamma ray (GR), bulk density (RHOB), neutron porosity (NPHI), and compressional waves sonic (DTC). Theoretically, the model trained on other logs can also predict each other. Our approach yields high Pearson correlation coefficients and small root mean square error on a dataset obtained from an offshore North Sea field near Norway, demonstrating the efficacy of our proposed technique.

FlexLogNet: A flexible deep learning-based well-log completion method of adaptively using what you have to predict what you are missing

Well logs are essential tools for understanding the characteristics of subsurface formations and exploring petroleum resources. However, well logs are often missing randomly due to cost constraints, instrument failures, or other factors. Many methods have been developed for completing missing well logs, but these methods are all based on fixed types of known well-log inputs to predict specific types of missing logs. This fixed input–output mode severely limits the application of these methods in actual data, where the known and missing well-log types are often varying. To address this problem, we propose a hybrid deep learning method with two heads of heterogeneous graph neural network (HGNN) and fully connected network (FCN) to achieve mutual prediction among multiple types of well logs. It can adaptively use all known well logs to predict any missing well logs, achieving a very flexible and practical well log completion function of using what you have to complete what you are missing. Specifically, the HGNN head infers the inter-relationships among multiple well logs to predict normalized logs that contain detailed information, which achieved by using multiple independent kernels to extracting and aggregating the features of the multiple logs. The FCN head estimates the global statistics of the predicted logs, including means and standard deviations, for de-normalizing the well logs estimated by the HGNN head. Both the HGNN and FCN heads are trained simultaneously by a hybrid loss function to ensure the consistency of their predictions. Furthermore, we present an adaptive training strategy that leverages all well logs, including those with missing segments. We demonstrate the capability of our model using four well logs: gamma ray (GR), bulk density (RHOB), neutron porosity (NPHI), and compressional waves sonic (DTC). Theoretically, the model trained on other logs can also predict each other. Our approach yields high Pearson correlation coefficients and small root mean square error on a dataset obtained from an offshore North Sea field near Norway, demonstrating the efficacy of our proposed technique.

Convective Overstability in Radially Global Protoplanetary Disks. I. Pure Gas Dynamics

Protoplanetary disks are prone to several hydrodynamic instabilities. One candidate, convective overstability (COS), can drive radial semiconvection that may influence dust dynamics and planetesimal formation. However, the COS has primarily been studied in local models. This paper investigates the COS near the midplane of radially global disk models. We first conduct a global linear stability analysis, which shows that linear COS modes exist only radially inward of their Lindblad resonance (LR). The fastest-growing modes have LRs near the inner radial domain boundary with effective radial wavelengths that can be a substantial fraction of the disk radius. We then perform axisymmetric global simulations and find that the COS’s nonlinear saturation is similar to previous incompressible shearing box simulations. In particular, we observe the onset of persistent zonal and elevator flows for sufficiently steep radial entropy gradients. In full 3D, nonaxisymmetric global simulations, we find the COS produces large-scale, long-lived vortices, which induce the outward radial transport of angular momentum via the excitation of spiral density waves. The corresponding α-viscosity values of order 10−3 agree well with those found in previous 3D compressible shearing box simulations. However, in global disks, significant modifications to their radial structure are found, including the formation of pressure bumps. Interestingly, the COS typically generates an outward radial mass transport, i.e., decretion. We briefly discuss the possible implications of our results for planetesimal formation and for interpreting dust rings and asymmetries observed in protoplanetary disks.

Photo-induced collective charge-density-wave dynamics in bulk 1T-VSe2

We investigated temperature (T) and excitation density dependent ultrafast near-infrared (NIR) transient reflectivity dynamics in the charge density wave (CDW) phases of bulk layered 1T-VSe2 using NIR and visible excitations. The data reveal fingerprints of conventional non-adiabatic CDW collective dynamics with rather fast electronic order parameter dynamics showing sub-picosecond suppression and recovery. The slower T-dependent 100-ps dynamics indicates rather isotropic heat transport dominated by the lattice degrees of freedom.

The Role of the Omniflow II Biosynthetic Graft in Postoperative Wound Problems After Lower Limb Revascularization: A Single Center Prospective Registry

To investigate the role of the Omniflow II prosthesis in the prevention of VGI in patients with peripheral arterial disease and to report on short-and mid-term graft-related morbidity. Patients were included in prospective registry between October 2019 and March 2023. The primary endpoint was to report infection related problems, operation related wound problems and short- and mid-term graft-related morbidity. Secondary endpoint was to report the bypass patency rates and limb salvage rates. A total of 146 Omniflow II grafts were implanted in 125 patients. Sixty-seven patients (45.9%) received a femoral interposition graft and 77 patients (52.7%) underwent ipsilateral bypass surgery (femoropopliteal/femorocrural). Forty-one patients (28.1%) underwent crural bypass surgery. Seventy-six patients (52.1%) had previous vascular operation in the groin. Mean Follow-up time was 352 days (range 0-1108 days). 3.4% of the patients suffered a wound infection limited to the dermis and in 8.2% the subcutaneous tissue was involved. Five early VGI (3.4%) and one late VGI (0.7%) occurred. One year primary patency rate of above the knee bypass was significantly better compared to the bypass below the knee (74.5% ± 0.131 versus 54% ± 0.126 (p=0.049)). This difference was not significantly different when below the knee bypass surgery was compared to crural bypass surgery (54% ± 0.126 versus 23.8% ± 0.080 (p=0.098)). The performance of the Omniflow II prosthesis in the preventive setting is highly influenced by the anatomic location of the distal anastomosis. No influence on the incidence of postoperative wound problems could be observed. The rate of Omniflow II VGI in a high risk population is similar to reported outcomes in other prosthetic grafts.

Self-doped flat band and spin-triplet superconductivity in monolayer 1T-TaSe2−x Te x

Two-dimensional van der Waals materials have become an established platform to engineer flat bands which can lead to strongly-correlated emergent phenomena. In particular, the family of Ta dichalcogenides in the 1T phase presents a star-of-David charge density wave that creates a flat band at the Fermi level. For TaS2 and TaSe2 this flat band is at half filling leading to a magnetic insulating phase. In this work, we theoretically demonstrate that ligand substitution in the TaSe 2−x Te x system produces a transition from the magnetic insulator to a non-magnetic metal in which the flat band gets doped away from half-filling. For x∈[0.846,1.231] the spin-polarized flat band is self-doped and the system becomes a magnetic metal. In this regime, we show that attractive interactions promote three different spin-triplet superconducting phases as a function of x, corresponding to a nodal f-wave and two topologically-different chiral p-wave superconducting phases. Our results establish monolayer TaSe 2−x Te x as a promising platform for correlated flat band physics leading to unconventional superconducting states.

Exceptionally Slow, Long-Range, and Non-Gaussian Critical Fluctuations Dominate the Charge Density Wave Transition.

(TaSe_{4})_{2}I is a well-studied quasi-one-dimensional compound long-known to have a charge-density wave (CDW) transition around 263K. We argue that the critical fluctuations of the pinned CDW order parameter near the transition can be inferred from the resistance noise on account of their coupling to the dissipative normal carriers. Remarkably, the critical fluctuations of the CDW order parameter are slow enough to survive the thermodynamic limit and dominate the low-frequency resistance noise. The noise variance and relaxation time show rapid growth (critical opalescence and critical slowing down) within a temperature window of ϵ≈±0.1, where ϵ is the reduced temperature. This is very wide but consistent with the Ginzburg criterion. We further show that this resistance noise can be quantitatively used to extract the associated critical exponents. Below |ϵ|≲0.02, we observe a crossover from mean-field to a fluctuation-dominated regime with the critical exponents taking anomalously low values. The distribution of fluctuations in the critical transition region is skewed and strongly non-Gaussian. This non-Gaussianity is interpreted as the breakdown of the validity of the central limit theorem as the diverging coherence volume becomes comparable to the macroscopic sample size. The large magnitude critical fluctuations observed over an extended temperature range, as well as the crossover from the mean-field to the fluctuation-dominated regime highlight the role of the quasi-one-dimensional character in controlling the phase transition.

Robust superconductivity and the suppression of charge-density wave in the quasi-skutterudites Ca3(Ir1−xRhx)4Sn13 single crystals at ambient pressure

Single crystals of the quasi-skutterudite compounds Ca3(Ir1-xRhx)4Sn13 (3–4–13) were synthesized by flux growth and characterized by x-ray diffraction, energy dispersive x-ray spectroscopy, magnetization, resistivity, and radio frequency magnetic susceptibility techniques. The coexistence and competition between the charge density wave (CDW) and superconductivity was studied by varying the Rh/Ir ratio. The superconducting transition temperature, Tc , varies from 7 K in pure Ir (x = 0) to 8.3 K in pure Rh (x = 1). Temperature-dependent electrical resistivity reveals monotonic suppression of the CDW transition temperature, T CDW(x). The CDW starts in pure Ir, x = 0, at T CDW ≈ 40 K and extrapolates roughly linearly to zero at xc≈ 0.53–0.58 under the superconducting dome. Magnetization and transport measurements show a significant influence of CDW on superconducting and normal states. Meissner expulsion is substantially reduced in the CDW region, indicating competition between the CDW and superconductivity. The low-temperature resistivity is higher in the CDW part of the phase diagram, consistent with the reduced density of states due to CDW gapping. Its temperature dependence just above Tc shows signs of non-Fermi liquid behavior in a cone-like composition pattern. We conclude that the Ca3(Ir1-xRhx)4Sn13 alloy is a good candidate for a composition-driven quantum critical point at ambient pressure.