Density Wave Research Articles

Nanomechanically-induced nonequilibrium quantum phase transition to a self-organized density wave of a Bose-Einstein condensate

Nanomechanically-induced nonequilibrium quantum phase transition to a self-organized density wave of a Bose-Einstein condensate

Enhanced Superconductivity in 2H-TaS2 Devices through in Situ Molecular Intercalation.

The intercalation of guest species into the gap of van der Waals materials often leads to the emergence of intriguing phenomena such as superconductivity. While intercalation-induced superconductivity has been reported in several bulk crystals, reaching a zero-resistance state in flakes remains challenging. Here, we show a simple method for enhancing the superconducting transition in tens-of-nanometers thick 2H-TaS2 crystals contacted by gold electrodes through in situ intercalation. Our approach enables measuring the electrical characteristics of the same flake before and after intercalation, permitting us to precisely identify the effect of the guest species on the TaS2 transport properties. We find that the intercalation of amylamine molecules into TaS2 flakes causes a suppression of the charge density wave and an increase in the superconducting transition with an onset temperature above 3 K. Additionally, we show that a fully developed zero-resistance state can be achieved in flakes by engineering the conditions of the chemical intercalation. Our findings pave the way for the integration of chemically tailored intercalation compounds in scalable quantum technologies.

Intertwined charge and spin density waves in a topological kagome material

Using neutrons and x rays we show the topological kagome antiferromagnet Mn3Sn for T<285K forms a homogeneous spin and charge ordered state comprising a longitudinally polarized spin density wave with wave vector kβ=kβĉ, a helical modulated version of the room temperature antichiral magnetic order with kχ=kχĉ, and charge density waves with wave vectors 2kβ,2kχ, and kβ+kχ. Though kχ and kβ coincide for 200K<T<230K, they exhibit distinct continuous Tdependencies before locking to commensurate values of kβ=112c* and kχ=548c* at lowT. Density functional theory indicates this complex modulated state may be associated with the nesting of Fermi surfaces from correlated flat kagome bands, which host Weyl nodes that are annihilated as it forms. Published by the American Physical Society 2024

Unveiling the Interlayer Interaction in a 1H/1T TaS2 van der Waals Heterostructure.

This study delves into the intriguing properties of the 1H/1T-TaS2 van der Waals heterostructure, focusing on the transparency of the 1H layer to the charge density wave of the underlying 1T layer. Despite the sizable interlayer separation and metallic nature of the 1H layer, positive bias voltages result in a pronounced superposition of the 1T charge density wave structure on the 1H layer. The conventional explanation relying on tunneling effects proves insufficient. Through a comprehensive investigation combining low-temperature scanning tunneling microscopy, scanning tunneling spectroscopy, non-contact atomic force microscopy, and first-principles calculations, we propose an alternative interpretation. The transparency effect arises from a weak yet substantial electronic coupling between the 1H and 1T layers, challenging prior understanding of the system. Our results highlight the critical role played by interlayer electronic interactions in van der Waals heterostructures to determine the final ground states of the systems.

Field theoretic description of nonlinear electro-optical responses in centrosymmetric electronic systems.

Motivated by the recent developments in terahertz spectroscopy using pump-probe setups to study correlated electronic materials, we review the field theoretical formalism to compute finite frequency nonlinear electro-optical responses in centrosymmetric systems starting from basic time dependent perturbation theory. We express the nonlinear current kernel as a sum of several causal response functions. These causal functions cannot be evaluated using perturbative field theory methods, since they are not contour ordered. Consequently, we associate each response function with a corresponding imaginary time ordered current correlation function, since the latter can be factorized using Wick's theorem. The mapping between the response functions and the correlation functions, suitably analytically continued to real frequencies, is proven exactly. We derive constraints satisfied by the nonlinear current kernel and we prove
a generalized f-sum rule for the nonlinear conductivity, all of which are consequences of particle number conservation. The constraints guarantee that the nonlinear static responses are free from spurious divergences. We apply the theory to compute the gauge invariant nonlinear conductivity of a system of noninteracting electrons in the presence of weak disorder. As special cases of this generalized nonlinear response, we discuss its third harmonic and its instantaneous terahertz Kerr signals. The formalism can be used to compute the nonlinear conductivity in symmetry broken phases of electronic systems such as superconductors, density waves and nematic states.

Evidence of a distinct collective mode in Kagome superconductors

The collective modes of the superconducting order parameter fluctuation can provide key insights into the nature of the superconductor. Recently, a family of superconductors has emerged in non-magnetic kagome materials AV3Sb5 (A = K, Rb, Cs), exhibiting fertile emergent phenomenology. However, the collective behaviors of Cooper pairs have not been studied. Here, we report a distinct collective mode in CsV3-xTaxSb5 using scanning tunneling microscope/spectroscopy. The spectral line-shape is well-described by one isotropic and one anisotropic superconducting gap, and a bosonic mode due to electron-mode coupling. With increasing x, the two gaps move closer in energy, merge into two isotropic gaps of equal amplitude, and then increase synchronously. The mode energy decreases monotonically to well below 2Δ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${{2}}{{\\Delta }}$$\\end{document} and survives even after the charge density wave order is suppressed. We propose the interpretation of this collective mode as Leggett mode between different superconducting components or the Bardasis-Schrieffer mode due to a subleading superconducting component.

Interfacial Charge-Transfer Excitonic Insulator in a Two-Dimensional Organic-Inorganic Superlattice.

Excitonic insulators are long-sought-after quantum materials predicted to spontaneously open a gap by the Bose condensation of bound electron-hole pairs, namely, excitons, in their ground state. Since the theoretical conjecture, extensive efforts have been devoted to pursuing excitonic insulator platforms for exploring macroscopic quantum phenomena in real materials. Reliable evidence of excitonic character has been obtained in layered chalcogenides as promising candidates. However, owing to the interference of intrinsic lattice instabilities, it is still debatable whether those features, such as the charge density wave and gap opening, are primarily driven by the excitonic effect or by the lattice transition. Herein, we develop an intercalation chemistry strategy for obtaining a novel charge-transfer excitonic insulator in organic-inorganic superlattice interfaces that serves as an ideal platform to decouple the excitonic effect from the lattice effect. In this system, we observe a narrow excitonic gap, formation of a charge density wave without periodic lattice distortion, and metal-insulator transition, providing visualized evidence of exciton condensation occurring in thermal equilibrium. Our findings identify self-assembly intercalation chemistry as a new strategy for developing novel excitonic insulators.

Real-Time Monitoring of Particle Size in Emulsion Polymerization: Simultaneous Turbidity and Photon Density Wave Spectroscopy.

Particle size evolution in seeded semibatch emulsion polymerization is monitored by two real-time monitoring techniques: online turbidity spectroscopy (TUS) and inline photon density wave spectroscopy (PDWS). An automatic dilution system that withdraws a sample from the reactor and upon dilution transfers to the measurement cell is used for the online TUS analysis. A PDWS probe is immersed in the reactor and collects inline the scattered light directly from the reacting latex. The particle sizes retrieved from TUS and PDWS are compared to offline dynamic light scattering (DLS) values. The particle size obtained by TUS is close to the intensity-average particle size obtained offline by DLS, while the particle size obtained by PDWS lies closer to the number-average particle size from DLS.

In Situ Exsolution-Prepared Solid-Solution-Type Sulfides with Intracrystal Polarization for Efficient and Selective Absorption of Low-Frequency Electromagnetic Wave.

The excellent dielectric properties and tunable structural design of metal sulfides have attracted considerable interest in realizing electromagnetic wave (EMW) absorption. However, compared with traditional monometallic and bimetallic sulfides that are extensively studied, the unique physical characteristics of solid-solution-type sulfides in response to EMW have not been revealed yet. Herein, a unique method for preparing high-purity solid-solution-type sulfides is proposed based on solid-phase in situ exsolution of different metal ions from hybrid precursors. Utilizing CoAl-LDH/MIL-88A composite as a precursor, Fe0.8Co0.2S single-phase nanoparticles are uniformly in situ formed on an amorphous substrate (denoted as CoAl), forming CoAl/Fe0.8Co0.2S heterostructure. Combing with density functional theory (DFT) calculations and wave absorption simulations, it is revealed that Fe0.8Co0.2S solid solution has stronger intracrystal polarization and electronic conductivity than traditional monometallic and bimetallic sulfides, which lead to higher dielectric properties in EM field. Therefore, CoAl/Fe0.8Co0.2S heterostructure exhibits significantly enhanced EMW absorption ability in the low-frequency region (2-6GHz) and can achieve frequency screening by selectively absorbing EMW of specific frequency. This work not only provides a unique method for preparing high-purity solid-solution-type sulfides but also fundamentally reveals the physical essence of their excellent EMW absorption performance.

Terahertz spectroscopy of collective charge density wave dynamics at the atomic scale

AbstractCharge density waves are wave-like modulations of a material’s electron density that display collective amplitude and phase dynamics. The interaction with atomic impurities induces strong spatial heterogeneity of the charge-ordered phase. Direct real-space observation of phase excitation dynamics of such defect-induced charge modulation is absent. Here, by utilizing terahertz pump–probe spectroscopy in a scanning tunnelling microscope, we measure the ultrafast collective dynamics of the charge density wave in the transition metal dichalcogenide 2H-NbSe2 with atomic spatial resolution. The tip-enhanced electric field of the terahertz pulses excites oscillations of the charge density wave that vary in magnitude and frequency on the scale of individual atomic impurities. Overlapping phase excitations originating from the randomly distributed atomic defects in the surface create this spatially structured response of the charge density wave. This ability to observe collective charge order dynamics with local probes makes it possible to study the dynamics of correlated materials at the intrinsic length scale of their underlying interactions.

Universal sublinear resistivity in vanadium kagome materials hosting charge density waves

Universal sublinear resistivity in vanadium kagome materials hosting charge density waves

Unconventional Spectral Gaps Induced by Charge Density Waves in the Weyl Semimetal (TaSe4)2I.

Coupling Weyl quasiparticles and charge density waves (CDWs) can lead to fascinating band renormalization and many-body effects beyond band folding and Peierls gaps. For the quasi-one-dimensional chiral compound (TaSe4)2I with an incommensurate CDW transition at TC = 263 K, photoemission mappings thus far are intriguing due to suppressed emission near the Fermi level. Models for this unconventional behavior include axion insulator phases, correlation pseudogaps, polaron subbands, bipolaron bound states, etc. Our photoemission measurements show sharp quasiparticle bands crossing the Fermi level at T > TC, but for T < TC, these bands retain their dispersions with no Peierls or axion gaps at the Weyl points. Instead, occupied band edges recede from the Fermi level, opening a spectral gap. Our results confirm localization of quasiparticles (holes created by photoemission) is the key physics, which suppresses spectral weights over an energy window governed by incommensurate modulation and inherent phase defects of CDW.

General skin and nasal decolonization with octenisan® set before and after elective orthopedic surgery in selected patients at elevated risk for revision surgery and surgical site infections—a single-center, unblinded, superiority, randomized controlled trial (BALGDEC trial)

BackgroundThe preoperative body surface and nasal decolonization may reduce the risk of surgical site infections (SSI) but yields conflicting results in the current orthopedic literature.MethodsWe perform a single-center, randomized-controlled, superiority trial in favor of the preoperative decolonization using a commercial product (octenidine® set). We will randomize a total number of 1000 adult elective orthopedic patients with a high risk for SSI and/or wound complications (age ≥ 80 years, chronic immune-suppression, American Society of Anesthesiologists score 3–4 points) between a decolonization (octenisan® wash lotion 1 × per day and octenisan® md nasal gel 2–3 × per day; during 5 days) and no decolonization. Decolonized patients will additionally fill a questionnaire regarding the practical difficulties, the completeness, and the adverse events of decolonization. The primary outcomes are SSI and revision surgeries for postoperative wound problems until 6 weeks postoperatively (or 1 year for surgeries with implants or bone). Secondary outcomes are unplanned revision surgeries for non-infectious problems and all adverse events. With 95% event-free surgeries in the decolonization arm versus 90% in the control arm, we formally need 2 × 474 elective orthopedic surgeries included during 2 years.DiscussionIn selected adult orthopedic patients with a high risk for SSI, the presurgical decolonization may reduce postoperative wound problems, including SSI.Trial registrationClinicalTrial.gov NCT05647252. Registered on 9 December 2022.Protocol version: 2 (5 December 2022).

The impact of diabetes mellitus on foot perfusion measured by ICG NIR fluorescence imaging

IntroductionDiabetes Mellitus (DM) is a common chronic disease, affecting 435 million people globally. Impaired vasculature in DM patients leads to complications like lower extremity arterial disease (LEAD) and foot ulcers, often resulting in amputations. DM causes additional peripheral neuropathy leading to multifactorial wound problems. Current diagnostics often deem unreliable, but Near-Infrared Fluorescence with Indocyanine Green (ICG NIR) can be used to assess the foot perfusion. Therefore, this study explores DM’s impact on foot perfusion using ICG NIR. MethodsBaseline ICG NIR fluorescence imaging was performed in LEAD patients with and without DM. Ten perfusion parameters were extracted and analyzed to assess differences in perfusion patterns. ResultsAmong 109 patients (122 limbs) of the included patients, 32.8% had DM. Six of ten perfusion parameters, mainly inflow-related, differed significantly between DM and non-DM patients (p-values 0.007–0.039). Fontaine stage 4 DM patients had the highest in- and outflow values, with seven parameters significantly higher (p-values 0.004–0.035). ConclusionDM is associated with increased in- and outflow parameters. Patients with- and without DM should not be compared directly due to different vascular pathophysiology and multifactorial wound problems in DM patients. Quantified ICG NIR fluorescence imaging offers additional insight into the effect of DM on foot perfusion.

A geological telescope through the galaxy?

We reside within a relatively interior position within the Milky Way galaxy which hinders our ability to understand its structure. Nonetheless, astrophysical observations of other galaxies in unison with spectroscopic measurements have produced a model for the Milky Way as a grand design, barred, spiral arm galaxy, with either two or four arms. Viewing through the plane of the Milky Way is not possible with any current astrophysical technique. However, perhaps terrestrial geology can help where current observations of our stellar environment cannot. During the orbit of our solar system around the galactic centre, Earth will have seen different cosmic surroundings, as a function of the solar system's orbit (240 km/s) that is faster than the spiral arm's density waves (210 km/s). Specifically, if the terrestrial impact record, or proxies for it, in some cryptic way reflect perturbations on the gravity field of the local solar system, then Earth may act as a geological orrery, with some interesting implications. Here we explore various models for the design of the Milky Way and compare these to geological proxies proposed by some as indicators for impact flux, through the deep time record within our planet. Isotope signatures in zircon are statistically coherent with a four-armed spiral model. However, even better correspondence is shown between the terrestrial isotopic record and more complex atomic hydrogen models of the galaxy.

Electronic instability in pressured black phosphorus under strong magnetic field

In this paper, we have systematically studied the electronic instability of pressured black phosphorous (BP) under strong magnetic field. We first present an effective model Hamiltonian for pressured BP near the Lifshitz point. Then we show that when the magnetic field exceeds a critical value, the nodal-line semimetal (NLSM) state of BP with a small band overlap re-enters the semiconductive phase by re-opening a small gap. This results in a narrow-bandgap semiconductor with a partially flat valence band edge. Moreover, we demonstrate that above this critical magnetic field, two possible instabilities, i.e. charge density wave phase and excitonic insulator (EI) phase, are predicted as the ground state for high and low doping concentrations, respectively. By comparing our results with the experiment (Sun et al 2018 Sci. Bull. 63 1539), we suggest that the field-induced instability observed experimentally corresponds to an EI. Furthermore, we propose that the semimetallic BP under pressure with small band overlaps may provide a good platform to study the magneto-exciton insulators. Our findings bring the first insight into the electronic instability of topological NLSM in the quantum limit.

Electron–electron interactions in partially mixed helical states

We theoretically study the effect of electron–electron interactions in one-dimensional partially mixed helical states. These helical states can be realized at the edges of two-dimensional topological insulators with partially broken time-reversal symmetry, resulting in helical gapped states. Using the bosonization method and renormalization group analysis, we identify weak gap, crossover, and strong gap regimes in the phase diagram. We find that strong electron–electron interaction mixes the helicity of the states, leading to the relevant strong gap regime. We investigate the charge and spin density wave correlation functions in different relevancy regimes of the gap mediated by interactions, where in the case of strong repulsive interaction, the spin density wave dominates the charge density wave. Additionally, employing the Memory function technique, we calculate the effect of mixed helicity on the charge transport in a sufficiently long edge. We find a non-uniform temperature dependence for the charge conductivity in both the strong and weak gap regimes with distinct features.

Computational demonstrations of density wave of Cooper pairs and paired-electron liquid in the quarter-filled band-A brief review.

There has been strong interest recently in the so-called Cooper pair density wave, subsequent to the proposition that such a state occurs in the hole-doped cuprate superconductors. As of now, there is no convincing demonstration of such a state in the cuprate theoretical literature. We present here a brief but complete review of our theoretical and computational work on the paired-electron crystal (PEC), which has also been experimentally seen in the insulating phase proximate to superconductivity (SC) in organic charge-transfer solid (CTS) superconductors. Within our theory, SC in the CTS does indeed evolve from the PEC. A crucial requirement for the finding of the PEC is that the proper carrier density of one charge carrier per two sites is taken into consideration at the outset. Following the discussion of CTS superconductors, we briefly discuss how the theory can be extended to understand the phase diagram of the cuprate superconductors that has remained mysterious after nearly four decades of the discovery of SC in this family.

FlexLogNet: A flexible deep learning-based well-log completion method of adaptively using what you have to predict what you are missing

Well logs are essential tools for understanding the characteristics of subsurface formations and exploring petroleum resources. However, well logs are often missing randomly due to cost constraints, instrument failures, or other factors. Many methods have been developed for completing missing well logs, but these methods are all based on fixed types of known well-log inputs to predict specific types of missing logs. This fixed input–output mode severely limits the application of these methods in actual data, where the known and missing well-log types are often varying. To address this problem, we propose a hybrid deep learning method with two heads of heterogeneous graph neural network (HGNN) and fully connected network (FCN) to achieve mutual prediction among multiple types of well logs. It can adaptively use all known well logs to predict any missing well logs, achieving a very flexible and practical well log completion function of using what you have to complete what you are missing. Specifically, the HGNN head infers the inter-relationships among multiple well logs to predict normalized logs that contain detailed information, which achieved by using multiple independent kernels to extracting and aggregating the features of the multiple logs. The FCN head estimates the global statistics of the predicted logs, including means and standard deviations, for de-normalizing the well logs estimated by the HGNN head. Both the HGNN and FCN heads are trained simultaneously by a hybrid loss function to ensure the consistency of their predictions. Furthermore, we present an adaptive training strategy that leverages all well logs, including those with missing segments. We demonstrate the capability of our model using four well logs: gamma ray (GR), bulk density (RHOB), neutron porosity (NPHI), and compressional waves sonic (DTC). Theoretically, the model trained on other logs can also predict each other. Our approach yields high Pearson correlation coefficients and small root mean square error on a dataset obtained from an offshore North Sea field near Norway, demonstrating the efficacy of our proposed technique.

FlexLogNet: A flexible deep learning-based well-log completion method of adaptively using what you have to predict what you are missing

Well logs are essential tools for understanding the characteristics of subsurface formations and exploring petroleum resources. However, well logs are often missing randomly due to cost constraints, instrument failures, or other factors. Many methods have been developed for completing missing well logs, but these methods are all based on fixed types of known well-log inputs to predict specific types of missing logs. This fixed input–output mode severely limits the application of these methods in actual data, where the known and missing well-log types are often varying. To address this problem, we propose a hybrid deep learning method with two heads of heterogeneous graph neural network (HGNN) and fully connected network (FCN) to achieve mutual prediction among multiple types of well logs. It can adaptively use all known well logs to predict any missing well logs, achieving a very flexible and practical well log completion function of using what you have to complete what you are missing. Specifically, the HGNN head infers the inter-relationships among multiple well logs to predict normalized logs that contain detailed information, which achieved by using multiple independent kernels to extracting and aggregating the features of the multiple logs. The FCN head estimates the global statistics of the predicted logs, including means and standard deviations, for de-normalizing the well logs estimated by the HGNN head. Both the HGNN and FCN heads are trained simultaneously by a hybrid loss function to ensure the consistency of their predictions. Furthermore, we present an adaptive training strategy that leverages all well logs, including those with missing segments. We demonstrate the capability of our model using four well logs: gamma ray (GR), bulk density (RHOB), neutron porosity (NPHI), and compressional waves sonic (DTC). Theoretically, the model trained on other logs can also predict each other. Our approach yields high Pearson correlation coefficients and small root mean square error on a dataset obtained from an offshore North Sea field near Norway, demonstrating the efficacy of our proposed technique.