An updated catalog consisting of 1092 6.7 GHz methanol maser sources is reported in this work. Additionally, the NH3 (1, 1), NH3 (2, 2), and NH3 (3, 3) transitions were observed toward 214 star-forming regions using the Shanghai Tianma radio telescope in order to examine the differences in physical environments, such as the excitation temperature and column density of molecular clouds associated with methanol masers on the Galactic scale. Statistical results reveal that the number of 6.7 GHz methanol masers in the Perseus arm is significantly lower than that in the other three main spiral arms. In addition, the Perseus arm also has the lowest gas column density among the main spiral arms traced by the NH3 observations. Both findings suggest that the Perseus arm has the lowest rate of high-mass star formation compared to the other three main spiral arms. We also observed a trend in which both the luminosity of the 6.7 GHz methanol masers and the ammonia gas column density decreased with the galactocentric distance. This finding indicates that the density of material in the inner Milky Way is generally higher than that in the outer Milky Way. This further suggests that high-mass stars are more easily formed at the head of the spiral arms. Furthermore, we found that the column density of ammonia gas is higher in the regions on the arms than in the inter-arm regions, supporting that the former is more likely to be the birthplace of high-mass stars.
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