Urbanization has been speeding up in China since reform and opening up policies were promoted, which promotes the progression of rural economy, but furthermore provides a certain degree of negative impact on the rural population structure. On the basis of summarizing the concept of urbanization, this study provides a thorough analysis of China's recent rural population structure and urbanization trend, and finally concludes that the quickening pace of urbanization in China makes the rural population structure face some problems and challenges. This study also offers some thoughts and recommendations in this area. At the same time, when analyzing the trend and population structure, by comparing and summarizing the secondary data and relevant literature, this paper concludes that China's urbanization has caused problems such as talent shortage in rural areas, rural aging and gender structure imbalance of the left-behind population. To solve these problems, China should establish a sound and perfect social security system and encourage the integration of rural and urban development. China ought to also establish a sound pension system and optimize the population structure; in rural areas, the promotion of respect for women has been strengthened and relevant laws have been introduced to gradually eliminate gender discrimination. It is beneficial to promote the national economy, cultural development.