Deep Ocean Sites Research Articles

Evaluating Existing Ocean Glider Sampling Strategies for Submesoscale Dynamics

Abstract Mixing in the upper ocean is important for biological production and the transfer of heat and carbon between the atmosphere and deep ocean, properties commonly targeted by observational campaigns using ocean gliders. We assess the reliability of ocean gliders to obtain a robust statistical representation of submesoscale variability in the ocean mixed layer of the Weddell Sea. A 1/48° regional simulation of the Southern Ocean is sampled with virtual “bow-tie” glider deployments, which are then compared against the reference model output. Sampling biases of lateral buoyancy gradients associated with the arbitrary alignment between glider paths and fronts are formally quantified, and the magnitude of the biases is comparable to observational estimates, with a mean error of 52%. The sampling bias leaves errors in the retrieved distribution of buoyancy gradients largely insensitive to deployment length and the deployment of additional gliders. Notable sensitivity to these choices emerges when the biases are removed by sampling perpendicular to fronts at all times. Detecting seasonal change in the magnitude of buoyancy gradients is sensitive to the glider-orientation sampling bias but the change in variance is not. We evaluate the impact of reducing the number of dives and climbs in an observational campaign and find that small reductions in the number of dive–climb pairs have a limited effect on the results. Lastly, examining the sensitivity of the sampling bias to path orientation indicates that the bias is not dependent on the direction of travel in our deep ocean study site. Significance Statement Recent observational campaigns have focused on using autonomous vehicles to better understand processes responsible for mixing in the surface region of the ocean. There exists uncertainty around how effective these missions are at returning reliable and representative information. This study seeks to quantify the performance of existing strategies in observing mixing processes, and we confirm that strategies are biased to underestimate indicators of mixing. Furthermore, compensating for the bias by increasing the number of resources or changing the manner in which resources are used has limited reward. Our findings are important for decision-making during the planning phase of an observational campaign and display that further innovations are required to account for the sampling bias.

Dynamic near-seafloor sediment transport in Kaikōura Canyon following a large canyon-flushing event

ABSTRACTSubmarine canyons are important deep-sea environments and conduits for transferring and accumulating sediment and organic matter and pollutants. Recent advances in observing, sampling, and analyzing modern canyon sediment transport systems illustrate near-seafloor dynamics and highlight the potential roles of submarine canyons in transporting and storing organic carbon, nutrients, and contaminants in the deep sea, with implications for deep-sea ecosystems and global carbon budgets. Kaikōura Canyon, offshore northeastern Te Waipounamu South Island, Aotearoa New Zealand, is a benthic biomass hotspot that experienced an earthquake-triggered, canyon-flushing event in 2016. On return to the canyon in October 2020, benthic landers, with sediment traps at 2 m above the seafloor, were deployed along the canyon axis in ∼ 900–1500 m water depths for a period of three weeks. These instrumented platforms provide a detailed view of near-seafloor sediment and organic-carbon transport between canyon-flushing events, showing that the canyon environment hosts dynamic physical processes and short-term sediment fluxes and transport. Variations in sediment and organic carbon flux down-canyon and over time include small-scale sediment transport events, some of which are interpreted as turbidity currents, occurring on much shorter timescales than earthquake recurrence. We compare Kaikōura Canyon results with other longshore-fed, shelf-incised global submarine canyons and deep-ocean sites, revealing differences and likely multiple controlling factors for near-seafloor sediment flux. This Kaikōura Canyon high-resolution, benthic lander timeseries dataset highlights the complexity of submarine canyons and their role in organic carbon flux to the deep ocean, even under high present-day sea-level conditions. Evolving insights underscore the need for more observational data and samples to further quantify submarine canyon sediment and organic-carbon transport and contribute to global evaluations of deep-sea canyon distributary systems.

On the Vertical Structure of Deep-Ocean Subinertial Variability

Abstract The vertical structure of subinertial variability is examined using full-depth horizontal velocity and vertical isopycnal displacement observations derived from the Ocean Observatory Initiative (OOI). Vertical profiles on time scales between 100 h and 1 yr or longer are characterized through empirical orthogonal function decomposition and qualitatively compared with theoretical modal predictions for the cases of flat, sloping, and rough bathymetry. OOI observations were obtained from mooring clusters at four deep-ocean sites: Argentine Basin, Southern Ocean, Station Papa, and Irminger Sea. Because no single OOI mooring in these arrays provides temperature, salinity, and horizontal velocity information over the full water column, sensor observations from two or more moorings are combined. Depths greater than ∼150–300 m were sampled by McLane moored profilers; in three of the four cases, two profilers were utilized on the moorings. Because of instrument failures on the deployments examined here, only ∼2 yr of full-ocean-depth observations are available from three of the four sites and some 3+ yr from the other. Results from the OOI “global” sites are contrasted with a parallel analysis of 3.5 yr of observations about the axis of the Gulf Stream where much of the subinertial variability is associated with stream meandering past the moorings. Looking across the observations, no universal vertical structure is found that characterizes the subinertial variability at the five sites examined; regional bathymetry, stratification, baroclinicity, nonlinearity, and the forcing (both local and remote) likely all play a role in shaping the vertical structure of the subinertial variability in individual ocean regions.

Orbital phasing of the Paleocene-Eocene Thermal Maximum

Paleocene-Eocene sedimentary archives record a series of global warming events called hyperthermals. These events occurred across a long-term increasing temperature trend and were associated with light carbon injections that produced carbon isotope excursions (CIEs). Early Eocene hyperthermals occurred close to both long (∼405 kyr) and short (∼100 kyr) eccentricity maxima. It has been proposed that under long-term global warming, orbital forcing of climate crossed a thermodynamic threshold that destabilized carbon reservoirs and produced Early Eocene hyperthermals. However, orbital control on triggering of the largest hyperthermal, the Paleocene-Eocene Thermal Maximum (PETM), remains unclear. Identification of the precise orbital phasing of the PETM has been hindered by extensive calcium carbonate (CaCO3) dissolution, which introduces uncertainty into PETM age models. Here, we report orbital signatures in marine sediments from Contessa Road (Italy), a western Tethyan section with reduced PETM CaCO3 dissolution compared to other deep ocean sites. Orbitally controlled lysocline depth adjustments and orbital phasing of the PETM CIE onset close to both long and short eccentricity maxima are documented here. Precession-based age models from the well-resolved PETM section of Ocean Drilling Program (ODP) Site 1262 (South Atlantic) confirm these results and reveal that the PETM CIE onset was partially triggered by an orbitally controlled mechanism. Climate processes associated with orbital forcing of both long and short eccentricity maxima played an important role in triggering the carbon cycle perturbations of all Paleocene-Eocene CIE events.

Deep-ocean anoxia across the Pliensbachian-Toarcian boundary and the Toarcian Oceanic Anoxic Event in the Panthalassic Ocean

The early Toarcian Oceanic Anoxic Event (T-OAE, or Jenkyns Event, ~183 million years ago) was a major hyperthermal and global carbon-cycle perturbation, likely associated with the release of a substantial volume of 12 C-enriched carbon to the Earth's surface. Seawater deoxygenation and the associated deposition of organic-rich facies during this event have been noted in many locations around the world, but evidence for pervasive and extreme oceanic anoxia has thus far been described mainly from European sections deposited in hydrographically restricted basins. Here we present new geochemical data on redox changes during the T-OAE, as well as the preceding Pliensbachian-Toarcian boundary (Pl/To) event, from a deep Panthalassic Ocean site at Inuyama, Japan. Redox-sensitive trace element data reveal an extended interval of seawater deoxygenation that began prior to the Pl/To and continued to the end of the T-OAE. A marked expansion of anoxic and possibly euxinic conditions to the seafloor occurred during both the Pl/To and T-OAE, accompanied by increased organic carbon burial. During these intervals of severe deep-ocean deoxygenation, our data suggest a global drawdown of trace elements such as Mo, U and As. Our findings highlight that: (1) the Panthalassic Ocean was likely an important locus of deoxygenation and organic carbon burial during the early Toarcian, and (2) the spread of anoxia during the T-OAE was a globally distributed phenomenon. • Anoxia in deep water Panthalassa from late Pliensbachian to early Toarcian. • A putative Oceanic Anoxic Event at the Pliensbachian-Toarcian boundary. • Global drawdown of redox-sensitive trace elements during Toarcian OAE. • Deep sea organic carbon burial at Pliensbachian-Toarcian and Toarcian OAE.

Action of Hydraulic Pressure on Portland Cement Mortars - Current Understanding and Related Progress of the First-Ever In-Situ Deep Sea Tests at a 3515 m Depth

In order to realize the utilization of cement-based materials in the special extreme environment, the deep sea, the authors have launched a project targeted at creating a technology platform with in-situ methods and systems for monitoring and evaluating cement-based materials located at deep ocean bottom sites. The first in-situ test in the world with a view to investigating the time-dependence of the volumetric stability and microstructure of Portland cement mortar following its long-term exposure to deep-sea conditions is currently underway at a 3515-m depth in the Nankai Trough. This paper reviews previous studies about the influences of deep-sea hydraulic pressure on cement-based materials, verifies the action of short-term hydraulic pressure using Portland cement mortars on a laboratory scale, and introduces the ongoing progress of in-situ deep-sea tests. Results from laboratory tests indicate that dimensional changes were provoked by liquid water infiltration and confinement while under short-term hydraulic pressure, however, time-dependent behavior under stresses such as creep has not appeared. Weight gain, changes in pore-size distribution, compressive strength and bending strength of the cement mortar were monitored after pressurization and depressurization processes.

Organic matter from the Chicxulub crater exacerbated the K–Pg impact winter

An asteroid impact in the Yucatán Peninsula set off a sequence of events that led to the Cretaceous-Paleogene (K-Pg) mass extinction of 76% species, including the nonavian dinosaurs. The impact hit a carbonate platform and released sulfate aerosols and dust into Earth's upper atmosphere, which cooled and darkened the planet-a scenario known as an impact winter. Organic burn markers are observed in K-Pg boundary records globally, but their source is debated. If some were derived from sedimentary carbon, and not solely wildfires, it implies soot from the target rock also contributed to the impact winter. Characteristics of polycyclic aromatic hydrocarbons (PAHs) in the Chicxulub crater sediments and at two deep ocean sites indicate a fossil carbon source that experienced rapid heating, consistent with organic matter ejected during the formation of the crater. Furthermore, PAH size distributions proximal and distal to the crater indicate the ejected carbon was dispersed globally by atmospheric processes. Molecular and charcoal evidence indicates wildfires were also present but more delayed and protracted and likely played a less acute role in biotic extinctions than previously suggested. Based on stratigraphy near the crater, between 7.5 × 1014 and 2.5 × 1015 g of black carbon was released from the target and ejected into the atmosphere, where it circulated the globe within a few hours. This carbon, together with sulfate aerosols and dust, initiated an impact winter and global darkening that curtailed photosynthesis and is widely considered to have caused the K-Pg mass extinction.

Environmental controls on calcareous nannoplankton response to the Cretaceous/Paleogene mass extinction in the Tethys realm

The Cretaceous/Paleogene (K/Pg) mass extinction exhibits a remarkable geographical contrast between the Northern and Southern Hemispheres in extinction severity and recovery response, yet environmental facets of this extinction selectivity are still poorly known. Here, we statistically analyze the calcareous nannofossil counts from six K/Pg boundary sections from the Tethys Ocean, representing a northern subtropical depth transect from continental shelf to abyssal plain. Our analyses reveal that calcareous nannoplankton from all environments underwent an ecological crisis and responded similarly to the K/Pg environmental catastrophe, providing a solid basis for paleoecological reconstruction with nannofossils across the world oceans. Most interesting is the environment-dependent response pattern, as demonstrated by the increasing separation between shelf and deep ocean sites that signals a deepened environmental stress gradient. This environment-dependent response can be attributed to the marked difference in primary production and community composition between shelf and pelagic ecosystems, as well as the smaller accommodation and buffering capacity of shelves, while the progressive removal of susceptible species with increasing water depth seems to be of little influence.

Aeolian transport and deposition of plant wax n-alkanes across the tropical North Atlantic Ocean

Long chain n-alkanes are terrestrial higher plant biomarkers analysed in marine sedimentary archives to reconstruct continental palaeoclimatic and palaeohydrological conditions. Latitudinal variation in their concentration and distribution in marine sediments relatively close to the continent has been widely studied, but little is known on the extent to which this continental signal extends to the ocean. Furthermore, no studies have examined the seasonal variation in the deposition of these biomarkers in marine sediments. Here we studied longitudinal variation in the composition of long chain n-alkanes and two other terrestrial higher plant biomarkers (long chain n-alkanols and long chain fatty acids) in atmospheric particles, as well as longitudinal and seasonal variation in long chain n-alkanes in sinking particles in the ocean at different water depths and in surface sediments, all collected along a 12°N transect across the tropical North Atlantic Ocean. The highest abundance of all three biomarker classes was closest to the African coast, as expected, because they are transported with Saharan dust and the largest part of the dust is deposited close to the source. At this proximal location, the seasonal variability in long chain n-alkane flux and the chain length distribution of the n-alkanes in sinking particles was most pronounced, due to seasonal change in the dust source or to change in vegetation composition in the source area, related to the position of the Intertropical Convergence Zone (ITCZ). In contrast, in the open ocean the seasonal variability in both the long chain n-alkane flux and chain length distribution of the n-alkanes was low. The abundance of the alkanes was also lower, as expected because of the larger source-to-sink distance. At the western part of the transect, close to South America, we found an additional source of the alkanes in the sinking particles during spring and autumn in the year 2013. The δ13C values of the alkanes in the surface sediment closest to the South American continent indicated that the isotope signal was likely derived from C3 vegetation from the Amazon, implying an input from the Amazon River, as there is no significant aeolian input from South America there since the prevailing wind direction is from the east. Finally, the concentration of the alkanes was similar in the material collected from the atmosphere, the particles collected while settling through the marine water column, and in the surface sediments, providing evidence that degradation of long chain n-alkanes from the atmosphere to settling at the sediment–water interface at deep open ocean sites is minimal.

Estimation of Wind-Driven Coastal Waves Near a Mangrove Forest Using Adaptive Neuro-Fuzzy Inference System

At the coastline of the Carey Island, mangroves provide natural protection against the wind-driven coastal waves. The area is located at the west Malaysia within the waters of the Straits of Malacca. Recently, its coastline has been exposed to increasing rates of coastal erosion due to mangrove deforestation. In order to provide mitigating measures, it is necessary to study wave characteristics in this region. For this purpose, we collected 5 years (2009 to 2013) of hourly measurements for wind direction, wave height, wind speed and wave period. Moreover, we used the adaptive neuro-fuzzy inference system (ANFIS) to estimate the wave period and height. The model was trained using the measured data. The validation of the model gave satisfactory R2 values of 0.8484 and 0.9496 for wave height and wave period, respectively. The findings from this study suggest that fuzzy logic based technique satisfactorily predicts the differences between multiple inputs and single output in terms of non-linear relationship. The developed model can be used to further study the effect of non-linear wind-driven waves on the depleting coastal mangrove forests in similar tropical and sub-tropical areas. We suggest further research to test the model in different geographical locations, such as in deep-ocean, narrow straits and other coastal sites, which were not covered in this study.

On the Leading Negative Phase of Major 2010–2014 Tsunamis

Time series observations from instruments sited in the deep ocean and along coastal margins of the Pacific during major tsunami events in the years since 2010 were systematically processed. Examination of these records during four events, 2010 Chile (Maule), 2011 East Japan (Tohoku), 2012 Haida Gwaii and 2014 Chile (Iquique), show the prevalence of a small negative phase leading the first major positive tsunami wave, a phase that is not typically reproduced by current modelling approaches. We present leading negative phase signatures in examples from the more than 40 deep-ocean bottom pressure and approximately 200 tide gauge records investigated for this study. High sampling rate time series (15-s) were given greater weight in our investigation than the more readily available 1-min series. Careful investigation of tsunami arrival at each deep-ocean site highlights the role filtering techniques may play in misleading researchers or masking specific tsunami features such as the leading negative phase that is the basis of this study. The main focus of this investigation is to characterise the scale and repeatability of the phenomenon in support of recent similar findings rather than to provide a definitive explanation as to the cause. In general, our findings are in good agreement with and support the theoretical results of Watada et al. (J Geophys Res Solid Earth 119:4287–4310, 2014).

Paired windward and leeward biogeochemical time series reveal consistent surface ocean CO2 trends across the Hawaiian Ridge

Sustained time series have provided compelling evidence for progressive acidification of the surface oceans through exchange with the growing atmospheric reservoir of carbon dioxide. However, few long-term programs exist, and extrapolation of results from one site to larger oceanic expanses is hampered by the lack of spatial coverage inherent to Eulerian sampling. Since 1988, the Hawaii Ocean Time-series program has sampled CO2 system variables nearly monthly at Station ALOHA, a deep ocean site windward and 115 km north of the island of Oahu. Surface measurements have also been made at Station Kahe, a leeward site 12 km from the island and on the opposite side of the Hawaiian Ridge. Despite having different physical settings, the sites exhibit identical rates of surface pCO2 increase and hydrogen ion accumulation, suggesting that atmospheric forcing dominates over local dynamics in determining the CO2 trend in the surface waters of the North Pacific subtropical gyre.

Passive sampling of nonpolar contaminants at three deep-ocean sites

Concentrations of polychlorinated biphenyls, polyaromatic hydrocarbons, hexachlorobenzene, and DDE were determined by passive sampling (semipermeable membrane devices) with exposure times of 1–1.5 years at 0.1–5 km depth in the Irminger Sea, the Canary Basin (both North Atlantic Ocean), and the Mozambique Channel (Indian Ocean). The dissipation of performance reference compounds revealed a pronounced effect of hydrostatic pressure on the sampler-water partition coefficients. Concentrations in the Irminger Sea were uniform over the entire water column (0.1–3 km). At the Canary Basin site, concentrations were 2–25 times lower near the bottom (5 km) than at 1.4 km. Concentrations in the Mozambique Channel (0.6–2.5 km) were lower than at the other two locations, and showed a near-bottom maximum. The data suggest that advection of surface waters down to a depth of about 1 km is an important mechanism of contaminant transport into the deep ocean.

Evaluating highly branched isoprenoid (HBI) biomarkers as a novel Antarctic sea-ice proxy in deep ocean glacial age sediments

Antarctic sea-ice plays a primary role in the climate system, potentially modulating interhemispheric millennial-scale climate change and deglacial warming. Recently, microfossil proxy data have provided important insights into this potential forcing. However, additional proxies for glacial sea-ice reconstructions are required, to support the microfossil data and to control for potential preservation issues. We considered highly branched isoprenoids (HBIs) as a sea-ice proxy, building on earlier studies in the Arctic and Antarctic. This study focused on measuring HBIs in glacial deposits in Southern Ocean deep ocean sediment cores. These deep ocean sites provided a study location away from the local sea-ice complexities associated with coastal and shallow water sites and allowed the comparison of HBIs during several phases of glacial sea-ice variability inferred from microfossils. Down-core profiles of di- and tri-unsaturated HBI isomers diene II and triene III were compared with diatom-based reconstructions of Antarctic sea-ice derived in three high resolution sediment cores recovered from a transect across the Scotia Sea, Southwest Atlantic. High quality chronological control was achieved through a combination of abundance stratigraphy, relative geomagnetic palaeointensity data, and down-core magnetic susceptibility/ice core dust correlation. Significant positive correlations, observed between HBI diene II and sea-ice presence, and between HBI triene III and open waters in the Marginal Ice Zone indicated that the two HBIs are both closely related to sea-ice and sea-ice edge dynamics, respectively. Highly significant down-core correlations between the HBIs indicate coeval sedimentation related to the summer breakdown of sea-ice melt-induced stratification. Combined, the two HBIs and diatoms demonstrated their potential as proxies for permanent sea-ice cover and sea-ice seasonality, two parameters poorly resolved in current climate models. The sea-ice reconstructions presented have developed our knowledge regarding HBIs and their relationship with the surface ocean environment and further highlight their potential as an important proxy for glacial Antarctic sea-ice and sea-ice dynamics back to at least ∼60 ka.

Marine black shale deposition and Hadley Cell dynamics: A conceptual framework for the Cretaceous Atlantic Ocean

Understanding the controls that determine the spatial distribution and internal heterogeneities of black shales in the Mesozoic ocean has been a focal point of research over many decades. The consensus is that atmosphere–land–ocean interactions influenced variations in marine biogeochemistry and sediment supply, thus exerting fundamental controls on the richness and quality of sedimentary organic matter (OM) and ultimately on petroleum source rock distribution and its generation potential. Internal, small-scale heterogeneities in black shales that have been reported from all ocean settings were often linked to orbitally-driven fluctuations in continental runoff and marine upwelling. The two processes are generically related under the ascending (tropical) and descending (subtropical) limbs of the palaeo-Hadley Cells, with fluctuations at variable time (seasonal, orbital, geological) and spatial (shelf, margin, deep basin) scales. These dynamic variations translate into characteristic patterns of OM quantity and quality, best preserved near the continents where the forcing effects are strongest. The expression of these orbital-scale interactions are not well constrained at the basin scale, however, they may hold a key to better understand the distribution of heterogeneities in black shales. This study presents a conceptual framework that links OM quality and quantity in Cretaceous Atlantic sediments with the dominant processes that operated under the Hadley Cells. Using a comprehensive compilation of bulk organic geochemical data – total organic carbon concentration (TOC), hydrogen index (HI), oxygen index (OI), and kerogen type – we explore how basic geochemical patterns can be used to identify the underlying generic processes. We utilise published and new data from deep ocean sites of the DSDP/ODP program, as well as one palaeo-shelf setting (Tarfaya), spanning a latitudinal transect from the outer subtropics to the palaeo-equator during the Albian, the Cenomanian–Turonian, and the Coniacian–Santonian. This study emphasises the potential of integrating orbital scale datasets and wide spatial coverage as a predictive tool for black shale formation across ocean basins.

An Ocean CAL-VAL Site at Kavaratti in Lakshadweep for Vicarious Calibration of OCM-2 and Validation of Geophysical Products—Development and Operationalization

A pair of buoys (system), MET and OPTICAL, consisting of fully automated hyperspectral radiometers, fluorometer, and meteorological sensors, has been realized and deployed in deep ocean case-I site at Kavaratti in Lakshadweep, Arabian Sea, for preprogrammed in situ data collection and transmission via INSAT-3C satellite. The buoy of described configuration is capable of measuring in-water optical and biological parameters in an unattended manner for long-term time series with less vertical tilt. A robotic sun/sky photometer installed on Kavaratti Island simultaneously provides information on aerosols over the site. A combination of these parameters available hourly in real time throughout the day from unattended systems in the ocean as well as on island provides an ideal reference site. The paper reports recent collection of bio-optical marine observations over the site and use of the data for OCM-2 vicarious calibration and validation of geophysical products.

A geochemical clock in earliest Paleogene pelagic carbonates based on the impact‐induced Os isotope excursion at the Cretaceous‐Paleogene boundary

An impact‐induced osmium (Os) isotope excursion provides a unique means of assessing the completeness of marine Cretaceous‐Paleogene (K‐Pg) boundary sections, and surmounting challenges associated with constraining the time scale of the Earth system recovery from this extreme perturbation. A model of the recovery of seawater187Os/188Os following the impact event allows independent estimates of the time elapsed since the impact, which can be directly compared to time estimates derived from biostratigraphy, magnetostratigraphy and cyclostratigraphy. This approach is tested using data from three deep ocean sites cored by the Ocean Drilling Program (ODP). Data from ODP 1262B (South Atlantic) and ODP 690C (Southern Ocean) display the expected 187Os/188Os minimum very close to the biostratigraphically defined K‐Pg boundary and yield Os‐based accumulation rate estimates similar to those obtained from magnetostratigraphy and orbital tuning. In contrast, the187Os/188Os minimum in ODP 1209C (Western Pacific) occurs ≈9 cm below the K‐Pg boundary. Low Os concentrations throughout the boundary interval and an implausibly rapid recovery to higher, pre‐impact187Os/188Os ratios provide strong evidence for a previously unrecognized gap in the K‐Pg interval of Site 1209. Results presented here provide strong empirical evidence that Os isotope data are uniquely valuable in assessing the completeness and accumulation rates of earliest Paleogene sediments from the deep sea. They are of broad interest because they have implications for astronomical tuning of the geologic time scale and illustrate that whole ocean geochemical perturbations can provide an alternative to biostratigraphy for correlation and timekeeping during abrupt biotic events.

The evolution of pCO2, ice volume and climate during the middle Miocene

The middle Miocene Climatic Optimum (17–15Ma; MCO) is a period of global warmth and relatively high CO2 and is thought to be associated with a significant retreat of the Antarctic Ice Sheet (AIS). We present here a new planktic foraminiferal δ11B record from 16.6 to 11.8Ma from two deep ocean sites currently in equilibrium with the atmosphere with respect to CO2. These new data demonstrate that the evolution of global climate during the middle Miocene (as reflected by changes in the cyrosphere) was well correlated to variations in the concentration of atmospheric CO2. What is more, within our sampling resolution (∼1 sample per 300kyr) there is no evidence of hysteresis in the response of ice volume to CO2 forcing during the middle Miocene, contrary to what is understood about the Antarctic Ice Sheet from ice sheet modelling studies. In agreement with previous data, we show that absolute levels of CO2 during the MCO were relatively modest (350–400ppm) and levels either side of the MCO are similar or lower than the pre-industrial (200–260ppm). These new data imply the presence of either a very dynamic AIS at relatively low CO2 during the middle Miocene or the advance and retreat of significant northern hemisphere ice. Recent drilling on the Antarctic margin and shore based studies indicate significant retreat and advance beyond the modern limits of the AIS did occur during the middle Miocene, but the complete loss of the AIS was unlikely. Consequently, it seems that ice volume and climate variations during the middle Miocene probably involved a more dynamic AIS than the modern but also some component of land-based ice in the northern hemisphere.

Black shale deposition, atmospheric CO2 drawdown, and cooling during the Cenomanian‐Turonian Oceanic Anoxic Event

Oceanic Anoxic Event 2 (OAE2), spanning the Cenomanian‐Turonian boundary (CTB), represents one of the largest perturbations in the global carbon cycle in the last 100 Myr. The δ13Ccarb, δ13Corg, and δ18O chemostratigraphy of a black shale–bearing CTB succession in the Vocontian Basin of France is described and correlated at high resolution to the European CTB reference section at Eastbourne, England, and to successions in Germany, the equatorial and midlatitude proto‐North Atlantic, and the U.S. Western Interior Seaway (WIS). Δ13C (offset between δ13Ccarb and δ13Corg) is shown to be a good pCO2 proxy that is consistent with pCO2 records obtained using biomarker δ13C data from Atlantic black shales and leaf stomata data from WIS sections. Boreal chalk δ18O records show sea surface temperature (SST) changes that closely follow the Δ13C pCO2 proxy and confirm TEX86 results from deep ocean sites. Rising pCO2 and SST during the Late Cenomanian is attributed to volcanic degassing; pCO2 and SST maxima occurred at the onset of black shale deposition, followed by falling pCO2 and cooling due to carbon sequestration by marine organic productivity and preservation, and increased silicate weathering. A marked pCO2 minimum (∼25% fall) occurred with a SST minimum (Plenus Cold Event) showing >4°C of cooling in ∼40 kyr. Renewed increases in pCO2, SST, and δ13C during latest Cenomanian black shale deposition suggest that a continuing volcanogenic CO2 flux overrode further drawdown effects. Maximum pCO2 and SST followed the end of OAE2, associated with a falling nutrient supply during the Early Turonian eustatic highstand.

Low frequency deep ocean ambient noise trend in the Northeast Pacific Ocean

Concern about effects of anthropogenic noise on marine life has stimulated new studies to establish present-day ocean noise levels and compare them to noise levels from previous times. This paper reports on the trend in low-frequency (10-400 Hz) ambient noise levels and presents measurements made using a calibrated multi-element volume array at deep ocean sites in the Northeast Pacific from 1978 to 1986. The experiments provided spectral noise levels as well as horizontal and vertical noise directionality. The data presented here provide evidence that the trend derived from 1960s data extended to around 1980, but has since continued at a lower rate.