Decomposition Of Acetyl Peroxide Research Articles

Reversal of low-field CIDNP due to deuterium substitution

A perturbation method is applied to the problem of low-field CIDNP. It is shown that in the intermediate magnetic field region the most important deviation from the high-field formulae is due to a perturbation of the S—T 0 mixing by interaction with the T ± levels of the radical pair. In the case of a symmetrical radical pair this contribution decreases to zero and higher order contributions become dominant. An experimental example is the reversal of low-field CIDNP of ethane formed during the thermal decomposition of acetyl peroxide compared with that of ethane- d 3 during the decomposition of acetylperoxide- d 3. A qualitative rule is given for net CIDNP effects in the intermediate field region.

Secondary deuterium isotope effects in radical forming reactions. III. Decomposition of acetyl peroxide

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSecondary deuterium isotope effects in radical forming reactions. III. Decomposition of acetyl peroxideTamas Koenig and R. CruthoffCite this: J. Am. Chem. Soc. 1969, 91, 10, 2562–2569Publication Date (Print):May 1, 1969Publication History Published online1 May 2002Published inissue 1 May 1969https://doi.org/10.1021/ja01038a029RIGHTS & PERMISSIONSArticle Views49Altmetric-Citations7LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (976 KB) Get e-Alerts Get e-Alerts

Decomposition of acetyl peroxide in the presence of acetate salts

Decomposition of acetyl peroxide in the presence of acetate salts

Reaktionen substituierter alkylradikale in lösung—II : Zerfall von acetylperoxid in lösungsmittelgemischen H-übertragungs- und kombinationsreaktionen substituierter alkylradikale in lösung

The combination products of benzyl with acetonyl, cyanomethyl, dichloromethyl and trichloromethyl radicals formed by hydrogen abstraction during the decomposition of acetyl peroxide in liquid mixtures of toluene with acetone, acetonitrile, dichloromethane and chloroform have been studied. Cross combination is much less favoured than estimated from copolymerization kinetics. Φ values are between 1 and 2.5 and decrease with increasing temperature. Rate constants for the hydrogen abstraction reactions of acetonyl, cyanomethyl and trichloromethyl radicals with toluene have been determined for a temperature range of 55–100°. The energies of activation for these reactions are 9.3, 10.0 and 11.6 kcal/mole respectively.

The Decomposition of Acetyl Peroxide in Solution. III. Kinetics and Use of Radical Traps

<b>The Decomposition of Acetyl Peroxide in Solution. III. Kinetics and Use of Radical Traps</b>

PEROXIDE DECOMPOSITION AND CAGE EFFECT

Abstract : The decomposition of acetyl peroxide is discussed in terms of cage theory and a rate constant for the decarboxylation of the resultant acetoxy free radical is derived.

Competitive Abstraction of H and D Atoms by Radicals Formed in the Decomposition of Acetyl Peroxide, t-Butyl Peroxide and in the Photolysis of Azomethane1

Competitive Abstraction of H and D Atoms by Radicals Formed in the Decomposition of Acetyl Peroxide, t-Butyl Peroxide and in the Photolysis of Azomethane¹

The Oxidation of Hydrocarbons. III. The Decomposition of Acetyl Peroxide in Cyclohexene Solutions

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Oxidation of Hydrocarbons. III. The Decomposition of Acetyl Peroxide in Cyclohexene SolutionsH. J. Shine and J. R. SlagleCite this: J. Am. Chem. Soc. 1959, 81, 23, 6309–6313Publication Date (Print):December 1, 1959Publication History Published online1 May 2002Published inissue 1 December 1959https://doi.org/10.1021/ja01532a049RIGHTS & PERMISSIONSArticle Views54Altmetric-Citations8LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (696 KB) Get e-Alerts Get e-Alerts

Mechanism of the decomposition of acetyl peroxide in acetic-2-C14 acid

Mechanism of the decomposition of acetyl peroxide in acetic-2-C14 acid

Reactions of Atoms and Free Radicals in Solution. IV. Decomposition of Acetyl Peroxide in Aliphatic Acids—A New Synthesis of Succinic Acid and its Substitution Derivatives

Reactions of Atoms and Free Radicals in Solution. IV. Decomposition of Acetyl Peroxide in Aliphatic Acids—A New Synthesis of Succinic Acid and its Substitution Derivatives

CCLXV.—The decomposition of acetyl peroxide and the mechanism of Kolbe's electrosynthesis

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