Decay Time Research Articles

MBE-grown ZnTe epitaxial layer based broadband photodetector with high response and excellent switching characteristics

Abstract Zinc telluride (ZnTe) epitaxial layers were grown on gallium arsenide (GaAs) (211) substrate at different growth temperatures by molecular beam epitaxy (MBE). The fabricated interdigitated metal semiconductor metal (MSM) configuration-based photodetector on ZnTe epitaxial layers exhibited stable and excellent photo response in a broad spectral range (250 to 550 nm) up to 125 ℃. The room temperature and higher temperature (125 ℃) values of maximum current, spectral responsivity, and detectivity at an applied bias of 5 V and 550 nm wavelength were 3.5×10-8 A, 0.1 A/W and 1×1011 Jones and 1.7×10-6 A, 2.5 A/W and 1.5×1011 Jones, respectively. The maximum photo-to-dark-current ratio (PDCR) value at zero bias and 100 ℃ was obtained for the ZnTe layer grown at an optimum growth temperature of 380 ℃. The high PDCR value exhibits the self-powered capability of the detector. Further, the detector exhibits good On-Off switching to the illuminating light with rise and decay times less than 0.29 s and 0.4 s, respectively, at room temperature. The dependence of photo response on material quality was analysed by varying the substrate growth temperature. The broadband responsivity of the ZnTe-based photodetector shows its capability as a multicolour detector in UV and visible region with the use of suitable blocking filters.

Collective dynamics of liquid sulphur across the polymerisation transition temperature probed by inelastic x-ray scattering

Inelastic x-ray scattering (IXS) experiments on liquid sulphur were carried out below (140 ∘C) and above (180 ∘C) the polymerisation temperature T λ of about 159 ∘C to investigate changes in the collective dynamics of this unique liquid, that exhibits a liquid–liquid transition. As reported earlier, broad longitudinal acoustic excitation signals were observed at both temperatures, and only the width of the quasielastic peaks slightly decreased when the temperature crossed the transition temperature. A model analysis was performed using a generalised Langevin formalism with a memory function having one thermal and two viscoelastic decay channels with the help of simple sparse modelling, and large positive deviations from the hydrodynamic sound velocity by 51%–54% were observed. The fast viscoelastic relaxation time τ µ is close to the correlation times of intermolecular stretching and bending motions of local sulphur connections in both ring and chain structures, and is similar to those of other molecular liquids. The small contrasts in the IXS spectra across the λ transition result in large changes in only the slow viscoelastic decay time τ α of the memory function. The τ α value at 140 ∘C matches the mixed internal/external torsional modes of S8 molecules well, whereas that at 180 ∘C has no corresponding molecular motion mode. The kinematic viscosity values at the Q→0 limit are much smaller than the minimum values of macroscopic shear viscosity, indicating that large changes in relaxation dynamics are expected with Q in the GHz and MHz excitation regimes.

Modulation of large rhythmic depolarizations in human large basket cells by norepinephrine and acetylcholine

Rhythmic brain activity is critical to many brain functions and is sensitive to neuromodulation, but so far very few studies have investigated this activity on the cellular level in vitro in human brain tissue samples. This study reveals and characterizes a novel rhythmic network activity in the human neocortex. Using intracellular patch-clamp recordings of human cortical neurons, we identify large rhythmic depolarizations (LRDs) driven by glutamate release but not by GABA. These LRDs are intricate events made up of multiple depolarizing phases, occurring at ~0.3 Hz, have large amplitudes and long decay times. Unlike human tissue, rat neocortex layers 2/3 exhibit no such activity under identical conditions. LRDs are mainly observed in a subset of L2/3 interneurons that receive substantial excitatory inputs and are likely large basket cells based on their morphology. LRDs are highly sensitive to norepinephrine (NE) and acetylcholine (ACh), two neuromodulators that affect network dynamics. NE increases LRD frequency through β-adrenergic receptor activity while ACh decreases it via M4 muscarinic receptor activation. Multi-electrode array recordings show that NE enhances and synchronizes oscillatory network activity, whereas ACh causes desynchronization. Thus, NE and ACh distinctly modulate LRDs, exerting specific control over human neocortical activity.

Photophysical properties of benzo[i]dipyrido[3,2-a:2′,3′-c] phenazine (dppn) – A prospective ligand for light-activated anticancer complexes

Benzo[i]dipyrido[3,2-a:2′,3′c]phenazine (dppn) is a prospective ligand for constructing light-activated anticancer complexes of platinum metals. In spite of practical importance, only scarce information on the dppn photophysics and photochemistry was found in the literature. In this work photophysical properties of dppn in acetonitrile solutions were studied by means of stationary and laser flash photolysis, time-resolved luminescence, time-resolved singlet oxygen detection and ultrafast TA spectroscopy. Quantitative characteristics of luminescence (quantum yield 0.26, lifetime 52 ns in deaerated solutions) were measured. Triplet state of the initial compound 3dppn* is formed with the quantum yield estimated as 0.4 from the singlet oxygen production; the main channels of 3dppn* are quenching by dissolved oxygen and self-quenching by the ground state of dppn. Combining the data of ultrafast TA absorption and time-resolved luminescence, we detected the formation of “dark” (not emissive) excited state of dppn with the decay time ca. 150 ps. Two hypotheses on the nature of the dark state were put forward.

Optical characterizations of densely doped Tm3+:KYW crystals at low temperatures

We investigate the optical lifetime, decay characteristics, spectral linewidth and energy level properties of thulium ions doped in a KY(WO 4 ) 2 crystal at 4 K temperature. High doping concentration of thulium ions with inhomogeneous broadening allow us to study nonradiative behaviors, instantaneous spectral diffusion, and spectral power broadening in this solid-state material. The theoretical consideration of ion–ion interactions is shown to accurately characterize the absorption, decay and other spectral behaviors of Tm 3+ ions. We observe more than ten-fold reduction in the decay time of 3H4 state and about three-fold reduction in the spectral-hole lifetime as we approach the center of the inhomogeneous broadening, corresponding to higher optical densities.

On‐Chip Room‐Temperature Operated Short‐Wavelength‐Infrared Si:S Photodetector with a Vertical Junction

AbstractSilicon (Si)‐based photodetectors are cost‐effective, eco‐friendly, and compatible with on‐chip complementary metal‐oxide‐semiconductor (CMOS) technology. However, expanding their photoresponse into the short‐wavelength‐infrared region beyond 1.1 µm remains challenging because of the intrinsic bandgap of Si. In this study, an ion implantation sulfur‐doped Si‐based infrared photodetector featuring a blocked impurity band (BIB) structure is investigated. The detector achieves an extended sub‐bandgap infrared response up to 2 µm through impurity band transitions, facilitated by the artificial creation of a deep‐level impurity band within the Si bandgap. The device exhibited a competitive photodetection effect with a high responsivity of 107.3 mA W−1 and an external quantum efficiency of 10.2%. Notably, the detector yielded an enhanced response speed with a raising time of 46 µs and a decay time of 135 µs at 1310 nm under room temperature. Finally, the versatile applications of this detector is presented in a multitude of scenarios encompassing material composition identification, multi‐band imaging, and optical communication. The proposed investigation not only proposed a method for Si‐based infrared detectors but also constituted a contribution to the advancement of silicon photonics.

Decadal-scale decay of landslide-derived fluvial suspended sediment after Typhoon Morakot

Abstract. Landslides influence fluvial suspended sediment transport by changing sediment supply and grain size, which alter suspended sediment concentrations and fluxes for a period of time after landsliding. To investigate the duration and scale of altered suspended sediment transport due to landsliding, we analyzed suspended sediment concentration and water discharge measurements at 87 gauging stations across Taiwan over an 11-year period after Typhoon Morakot, which generated nearly 20 000 landslides in 2009. At each gauging station, we computed annual rating curves to quantify changes over time in the sensitivity of suspended sediment concentrations to water discharge. Among the 40 stations in basins that were impacted by landsliding, the discharge-normalized rating curve coefficient ã was higher than that before Morakot by a factor of 5.1±1.1 (mean ± standard error) in 2010, the first year after Morakot. The rating curve exponent b did not decrease at most stations until a year later (2011), when the average b value was lower than that before Morakot by 0.25±0.05. Across the compilation of gauging stations, post-Morakot changes in discharge-normalized sediment concentration (ã) were positively correlated with landslide intensity for 7 years after Morakot, while post-Morakot changes in the exponent of the discharge–concentration relationship (b) were negatively correlated with landslide intensity from 2011 to 2014. This reflects a tendency for larger changes in ã and b to occur in basins with more intense landsliding. At 26 of these 40 stations, elevated values of ã declined after the initial post-Morakot peak, consistent with a gradual return to pre-Morakot suspended sediment transport conditions. Exponential regressions to these ã values reveal a median characteristic decay time of 8.8 years (interquartile range: 5.7–14.8 years). Values of ã increased more and declined faster in basins with more intense landsliding, with a mean characteristic decay time of 6 years in the basins hit hardest by landsliding. Furthermore, changes in ã and b tended to be larger in basins with more intense landsliding. At stations that were not impacted or only minimally impacted by landsliding, neither ã nor b exhibited systematic responses to Morakot. To quantify the effect of landsliding on sediment discharge, we compared the measured sediment discharges after Morakot to the hypothetical sediment discharges that would have occurred if Morakot had induced no landslides, calculated by applying each station's pre-Morakot rating curve to its post-Morakot water discharge history. This analysis suggests that Morakot-induced landsliding increased sediment discharge by as much as > 10-fold in some basins in the 1–2 years after Morakot. Together, these results indicate that the influence of Morakot-induced landsliding on rating curves was large shortly after Morakot but diminished in less than a decade in most of the study rivers and will be imperceptible in another few decades in all of the study rivers. To the extent that these results are applicable to other landscapes, this suggests that periods of elevated sediment transport efficiency after landsliding should persist for years to decades, even if the landslide deposits persist for centuries to millennia.

Charge (in)stability and superradiance of Topological Stars

We study linear massive scalar charged perturbations of Topological Stars in the fuzzball and in the black hole (Black String) regimes. The objects that naturally couple to the electric 3-form field strength of these solutions are charged strings, wound around the compact direction. We explore the possibility of instabilities of these solutions, in analogy with the charge instability already highlighted for other non-BPS geometries like JMaRT. This issue is addressed by calculating quasi-normal mode frequencies with a variety of techniques: WKB approximation, direct integration, Leaver method and by exploiting the recently discovered correspondence between black hole/fuzzball perturbation theory and quantum Seiberg-Witten curves. All mode frequencies we find have negative imaginary parts, implying an exponential decay in time. This suggests a linear stability of Topological Stars also in this new scenario. In addition, we study the charge superradiance for the Black String. We compute the amplification factor with the numerical integration method and a quantum Seiberg-Witten motivated definition including instantonic corrections.

Density-Driven CO2 Dissolution in Depleted Gas Reservoirs with Bottom Aquifers

Depleted gas reservoirs with bottom water show significant potential for long-term CO2 storage. The residual gas influences mass-transfer dynamics, further affecting CO2 dissolution and convection in porous media. In this study, we conducted a series of numerical simulations to explore how residual-gas mixtures impact CO2 dissolution trapping. Moreover, we analyzed the CO2 dissolution rate at various stages and delineated the initiation and decline of convection in relation to gas composition, thereby quantifying the influence of residual-gas mixtures. The findings elucidate that the temporal evolution of the Sherwood number observed in the synthetic model incorporating CTZ closely parallels that of the single-phase model, but the order of magnitude is markedly higher. The introduction of CTZ serves to augment gravity-induced convection and expedites the dissolution of CO2, whereas the presence of residual-gas mixtures exerts a deleterious impact on mass transfer. The escalation of residual gas content concomitantly diminishes the partial pressure and solubility of CO2. Consequently, there is an alleviation of the concentration and density differentials between saturated water and fresh water, resulting in the attenuation of the driving force governing CO2 diffusion and convection. This leads to a substantial reduction in the rate of CO2 dissolution, primarily governed by gravity-induced fingering, thereby manifesting as a delay in the onset and decay time of convection, accompanied by a pronounced decrement in the maximum Sherwood number. In the field-scale simulation, the injected CO2 improves the reservoir pressure, further pushing more gas to the producers. However, due to the presence of CH4 in the post-injection process, the capacity for CO2 dissolution is reduced.

Novel elastomeric spiropyran-doped poly(dimethylsiloxane) optical waveguide for UV sensing

Novel poly(dimethylsiloxane) (PDMS) doped with two different spiropyran derivatives (SP) were investigated as potential candidates for the preparation of elastomeric waveguides with UV-dependent optical properties. First, free-standing films were prepared and evaluated with respect to their photochromic response to UV irradiation. Kinetics, reversibility as well as photofatigue and refractive index of the SP-doped PDMS samples were assessed. Second, SP-doped PDMS waveguides were fabricated and tested as UV sensors by monitoring changes in the transmitted optical power of a visible laser (633 nm). UV sensing was successfully demonstrated by doping PDMS using one spiropyran derivative whose propagation loss was measured as 1.04 dB/cm at 633 nm, and sensitivity estimated at 115% change in transmitted optical power per unit change in UV dose. The decay and recovery time constants were measured at 42 and 107 s, respectively, with an average UV saturation dose of 0.4 J/cm2. The prepared waveguides exhibited a reversible and consistent response even under bending. The sensor parameters can be tailored by varying the waveguide length up to 21 cm, and are affected by white light and temperatures up to 70 ℃. This work is relevant to elastomeric optics, smart optical materials, and polymer optical waveguide sensors.Graphical

Ultrahigh Performance UV Photodetector by Inserting an Al2O3 Nanolayer in NiO/n‐Si

AbstractUltraviolet (UV) photodetectors have gained much attention due to their numerous important applications ranging from environmental monitoring to space communication. To date, most p‐NiO/n‐Si heterojunction photodetectors (HPDs) exhibit poor UV responsivity and slow response. This is mainly due to a small valence band offset (ΔEV) at the NiO/Si interface and a high density of dangling bonds at the silicon surface. Herein, an UV HPD consisting of NiO/Al2O3/n‐Si is fabricated using magnetron sputtering technique. The HPD has a large rectification ratio of 2.4 × 105. It also exhibits excellent UV responsivity (R) of 15.8 A/W at −5 V and and detectivity (D*) of 1.14 × 1013 Jones at −4 V, respectively. The excellent performance of the HPD can be attributed to the defect passivation at the interfaces of the heterojunction and the efficient separation of photogenerated carriers by the Al2O3 nanolayer. The external quantum efficiency (EQE) of the HPD as high as 5.4 × 103%, hence implying a large optical gain due to carrier proliferation resulting from impact ionization. Furthermore, the ultrafast response speed with a rise time of 80 µs and a decay time of 184 µs are obtained.

Offline tagging of radon-induced backgrounds in XENON1T and applicability to other liquid xenon time projection chambers

This paper details the first application of a software tagging algorithm to reduce radon-induced backgrounds in liquid noble element time projection chambers, such as XENON1T and XENONnT. The convection velocity field in XENON1T was mapped out using Rn222 and Po218 events, and the rms convection speed was measured to be 0.30±0.01 cm/s. Given this velocity field, Pb214 background events can be tagged when they are followed by Bi214 and Po214 decays, or preceded by Po218 decays. This was achieved by evolving a point cloud in the direction of a measured convection velocity field, and searching for Bi214 and Po214 decays or Po218 decays within a volume defined by the point cloud. In XENON1T, this tagging system achieved a Pb214 background reduction of 6.2−0.9+0.4% with an exposure loss of 1.8±0.2%, despite the timescales of convection being smaller than the relevant decay times. We show that the performance can be improved in XENONnT, and that the performance of such a software-tagging approach can be expected to be further improved in a diffusion-limited scenario. Finally, a similar method might be useful to tag the cosmogenic Xe137 background, which is relevant to the search for neutrinoless double-beta decay. Published by the American Physical Society 2024

Sloshing reduction with passive spring–mass baffles in partially filled containers

The potential for sloshing reduction of passive, moving baffles with translational motion constrained by springs is investigated numerically in partially filled containers. Simulations are based on the level-set formulation, considering water as the liquid under study and a baffle made of aluminum; this selection allows for direct validation of the model against experimental and analytical data. Depending on the filling ratio V∈(0,1), which simply measures the volume of liquid relative to the total container size, one can find an optimal spring stiffness K(V) that minimizes the kinetic energy and decay time of the sloshing response when subjected to a pulse-like acceleration. Results show that moving baffles significantly reduce sloshing compared to their fixed counterparts, with decreases up to 84.6% in decay time, τd. Frequency analyses for different V reveal one or two resonances in the range of 0.1–1.5Hz whose amplitudes are directly influenced (lowered) by K, analogous to the behavior of Tuned Mass Dampers. For potential applications, the selection of K should look for an adequate sloshing response over the entire range of V, and account for both quasi-static and harmonic excitation, conveniently weighted in accord with the expected operational loads.

Fair value estimates for illiquid cryptocurrency

To address the need for reporting and disclosure of cryptocurrency holdings in compliance with the FASB guidance for the use of fair value measurements for cryptocurrency (FASB, 2023), this paper develops a modeling process for reporting entities to measure the market value of cryptocurrencies with limited or no observable transactions. In this valuation model, we consider the last observable market information with time decay, its comparable assets market index, and dynamic real-time market participants’ sentiment and attention. Notably, the application of exogenous variables allows us to maximize the observable inputs in measuring fair value, such as asset classification based on economic traits and market participants’ attention and sentiment measurement with online media textual analytics. We propose a valuation framework and construct a prediction model that can achieve a prediction accuracy of 87 % on target asset resurging prices.

Tip‐Enhanced Imaging and Control of Infrared Strong Light‐Matter Interaction

AbstractOptical antenna resonators enable control of light‐matter interactions on the nano‐scale via electron–photon hybrid states in strong coupling. Specifically, mid‐infrared (MIR) nano‐antennas coupled to saturable intersubband transitions in multi‐quantum‐well (MQW) semiconductor heterostructures allow for the coupling strength to be tuned through antenna resonance and field intensity. Here, tip‐enhanced nano‐scale variation of antenna‐MQW coupling across the antenna is demonstrated, with a spatially‐dependent coupling strength varying from 73 (strong coupling) to 24 (weak coupling). This behavior is modeled based on the spatially dependent local constructive and destructive interference between tip and antenna fields. Using a quantum‐mechanical density‐matrix model of the MQW system with its designed values of transition dipole moment, doping density, and population decay time, the picosecond IR pulse coupling to intersubband transitions and the associated tip induced strong‐field saturation effects are described. These results present a new regime of nonlinear IR light‐matter control based on the dynamic manipulation of quantum hybrid states on the nanoscale and in the infrared, with a perspective regarding extension to molecular vibrations.

Ag Intercalation in Layered Cs3Bi2Br9 Perovskite for Enhanced Light Emission with Bound Interlayer Excitons.

Cesium bismuth bromide (CBB) has garnered considerable attention as a vacancy-ordered layered perovskite with notable optoelectronic applications. However, its use as a light source has been limited due to its weak photoluminescence (PL). Here, we demonstrate metal intercalation as a novel approach to engineer the room-temperature PL of CBB using experimental and computational methods. Ag, when introduced into CBB, occupies vacant sites in the spacer region, forming octahedral coordination with surrounding Br anions. First-principles density functional theory calculations reveal that intercalated Ag represents the most energetically stable Ag species compared to other potential forms, such as Ag substituting Bi. The intercalated Ag forms a strong polaronic trap state close to the conduction band minimum and quickly captures photoexcited electrons with holes remaining in CBB layers, leading to the formation of a bound interlayer exciton, or BIE. The radiative recombination of this BIE exhibits bright room-temperature PL at 600 nm and a decay time of 38.6 ns, 35 times greater than that of free excitons, originating from the spatial separation of photocarriers by half a unit cell separation distance. The BIE as a new form of interlayer exciton is expected to inspire new research directions for vacancy-ordered perovskites.

Ag Intercalation in Layered Cs3Bi2Br9 Perovskite for Enhanced Light Emission with Bound Interlayer Excitons.

Cesium bismuth bromide (CBB) has garnered considerable attention as a vacancy-ordered layered perovskite with notable optoelectronic applications. However, its use as a light source has been limited due to its weak photoluminescence (PL). Here, we demonstrate metal intercalation as a novel approach to engineer the room-temperature PL of CBB using experimental and computational methods. Ag, when introduced into CBB, occupies vacant sites in the spacer region, forming octahedral coordination with surrounding Br anions. First-principles density functional theory calculations reveal that intercalated Ag represents the most energetically stable Ag species compared to other potential forms, such as Ag substituting Bi. The intercalated Ag forms a strong polaronic trap state close to the conduction band minimum and quickly captures photoexcited electrons with holes remaining in CBB layers, leading to the formation of a bound interlayer exciton, or BIE. The radiative recombination of this BIE exhibits bright room-temperature PL at 600 nm and a decay time of 38.6 ns, 35 times greater than that of free excitons, originating from the spatial separation of photocarriers by half a unit cell separation distance. The BIE as a new form of interlayer exciton is expected to inspire new research directions for vacancy-ordered perovskites.

Solution processed high aspect ratio ultra-long vertically well-aligned ZnO nano scintillators for potential X-ray imaging applications

We report the photon (PL), electron (CL) and X-ray (XEL) induced luminescence characteristics of high aspect ratio ultra-long (~ 50 µm) ZnO nanorods (NRs) and discuss the potential for fast X-ray detection based on the consistent and efficient visible emission (~ 580 nm) from ZnO NRs. Nanostructured ZnO scintillators were rearranged to form a vertically well-aligned NR design in order to help light absorption and coupling resulting in luminescent and fast scintillation properties. The design of the nanorod array combines the key advantages of a low-cost growth technique together with environmentally friendly and widely available materials. A low temperature hydrothermal method was adopted to grow ZnO NRs in one cycle growth and their structural, optical and X-ray scintillation properties were investigated. The relatively short (~ 10 µm) ZnO NRs emitting in the near-band-edge region were found to be almost insensitive to X-rays. On the other hand, the higher XEL response of long ZnO NRs, which is a key parameter for evaluation of materials to be used as scintillators for high quality X-ray detection and imaging, along with a decay time response in the order of ns confirmed promising scintillation properties for fast and high-resolution X-ray detector applications.

Concentration Dependence Orange Light Generation Through Sm3+‐Doped Soda Lime Alumino Borate Glasses for Orange Laser Medium Material

The melt‐quenching technique is used to fabricate calcium sodium aluminum borate glasses (Sm: ANCB) doped with varying concentrations of Sm3+ ions. Characteristics of ANCBSm glasses, including density, molar volume, refractive index, absorption, emission (via visible light, X‐ray, and proton excitation), decay time, and CIE color coordinates, are analyzed. The density, molar volume, and refractive index of ANCBSm glass increased with Sm2O3 concentration. Sm3+ ions enabled photon absorption in both visible and NIR regions, with a strong reddish‐orange emission at 600 nm due to the 6H5/2 → 6P3/2 transition under various excitations. X‐ray excitation is also compared with BGO scintillation crystals. The J–O theory predicted the radiative properties of Sm3+ ion emission levels. Decay curves of the 6H5/2 levels showed a single exponential nature with a millisecond‐order lifetime. CIE chromaticity of ANCBSm glasses is in the reddish‐orange region. ANCBSm glasses have potential applications in orange laser medium material.

Effects of edge disorder on the stability of quantum oscillations in two-dimensional coupled systems

This paper utilizes the theory of quantum diffusion to analyze the electron probability and spreading width of a wavepacket on each layer in a two-dimensional (2D) coupled system with edge disorder, aiming to clarify the effects of edge disorder on the stability of the electron periodic oscillations in 2D coupled systems. Using coupled 2D square lattices with edge disorder as an example, we show that, the electron probability and wavepacket spreading width exhibit periodic oscillations and damped oscillations, respectively, before and after the wavepacket reaches the boundary. Furthermore, these electron oscillations exhibit strong resistance against disorder perturbation with a longer decay time in the regime of large disorder, due to the combined influences of ordered and disordered site energies in the central and edge regions. Finally, we numerically verified the universality of the results through bilayer graphene, demonstrating that this anomalous quantum oscillatory behavior is independent of lattice geometry. Our findings are helpful in designing relevant quantum devices and understanding the influence of edge disorder on the stability of electron periodic oscillations in 2D coupled systems.