The paper examines the evolutionary behaviour of acceleration waves in a perfectly conducting inviscid radiating gas permeated by a transverse magnetic field. Solution of the problem in the characteristic plane has been determined. It is shown that a linear solution in the characteristic plane exhibits nonlinear behaviour in the physical plane. Transport equation governing the behaviour of acceleration waves has been derived. The effect of radiative heat transfer under the influence of magnetic field on the formation of shock wave with generalized geometry is analyzed. The critical amplitude of the initial disturbance has been obtained such that the initial amplitude of any compressive wave greater than the critical one always terminates into shock wave. Critical time, when the compressive wave will grow into a shock wave, has been determined. Also, it is assessed as to how the radiative heat transfer in the presence of magnetic field affects the shock formation.