Dark Gray Mudstone Research Articles

Sedimentary dynamics and depositional model for mud accumulation in deep lake basins: A case study in the Upper Triassic Chang-7 Member, Ordos Basin, northern China

Shales in deep lake basins have become the main focus of continental shale oil and gas exploration. In order to highlight the sedimentary dynamics of mud deposition in deep lake basins, a combination of core observation, thin section examination, X-ray diffraction, and QEMSCAN (quantitative evaluation of minerals by scanning electron microscopy) was used to analyze the depositional characteristics of mudrocks in the Chang-7 Member from the Yanchang Formation (Upper Triassic) in Ordos Basin, and to establish a depositional model for mud accumulation in deep lake basins. This study recognizes four mudrock lithofacies in the Chang-7 Member: (1) the laminated silt-bearing mudstone, which generally develops a binary composition of “silt–clay” or a ternary composition of “silt–clay–organic matter”; (2) the graded mudstone, mainly composed of dark gray and gray-black mudstone sandwiched by silt-bearing mudstone; (3) the massive mudstone, internally showing a uniform distribution of quartz, clay, and carbonate minerals, with also a small amount of organic detritus; and (4) the laminated shale, which is generally composed of clay laminae, and organic laminae of the former two. Sediment supply, topographic slope, and flood intensity combine to control the evolution of gravity flows and the transport and deposition of the mudrock in the Chang-7 Member. The influence of orogeny provides terrain gradient, water depth, abundant sediments at source areas, and triggering mechanism for the formation of gravity flows. Floods triggered by wetting events provide the impetus for sediment transport. Mud deposition in the Chang-7 Member was mainly related to the transport and sedimentation of mud by hyperpycnal flows and rapid sedimentation by buoyant plume flocculation. A comprehensive evolutionary model for shale accumulation in the deep lake basin is established by integrating various triggering mechanisms and mud transport sedimentary processes.

Mineralogical and geochemical characteristics of mudstones from the Lower Cretaceous Prosopis Formation in the Bongor basin, Chad: Implications for provenance, paleoenvironment and organic matter enrichment

The Cretaceous greenhouse represents the largest global warming event since the Phanerozoic, significantly affecting the provenance, weathering, regional climate, and paleoenvironment of lake basins globally. During the period of global warming, the control of regional paleoenvironment over organic matter enrichment is still unclear. The Lower Cretaceous Prosopis Formation in the Bongor Basin features thick lacustrine organic-rich mudstones as major effective hydrocarbon source rocks with excellent hydrocarbon potential in the basin. However, the provenance, paleoclimate, paleoenvironment and mechanism of organic matter accumulation in this location have not yet been systematically studied. In this study, 22 dark gray mudstone samples were collected from three cored wells. Clay mineralogy, along with organic and inorganic elemental geochemical analyses were jointly carried out to determine the characteristics of the provenance, paleoclimate and paleoenvironment as well as the major controlling factors for organic matter enrichment. The results imply that the Prosopis Formation mudstones are mainly composed of clay minerals such as illite, kaolinite, chlorite, and illite/smectite mixed layers (I/S). Organic geochemistry indicated that all the studied mudstones reached the standard of good to excellent source rocks (the total organic carbon content ranged from 1.27% to 7.41%). Inorganic elemental geochemistry is characterized by high enrichment of Fe, Mg, P, Mn, Ti, Na, Ca, V, Co, Cu, Sr, Ba and B relative to UCC and PAAS, whereas rare earth elements (REEs) show enrichment of light rare earth elements (LREEs) and a deficiency of heavy rare earth elements (HREEs) relative to chondrite. The source composition of the mudstones is predominantly intermediate-felsic igneous rocks that have not undergone sediment recycling. The parent rocks experienced weak to moderate weathering, corresponding to semiarid paleoclimatic conditions of transitional nature. The organic-rich mudstones were deposited in fresh to brackish waters with paleoredox conditions ranging from weakly oxic to anoxic semi-deep to deep lake environments having relatively low initial productivity. Comprehensive study indicates that paleoredox and paleoclimate are important parameters affecting the enrichment of organic matter in lake basins during global warming. The aridification of climate is one of the most important reasons for the high input and efficient preservation of organic matter. The relatively semiarid climate both increased the supply of terrigenous nutrients to the lake basins and provided a driving force for the increase in salinity, thereby providing better sources and preservation conditions for organic matter.

STRUCTURAL POSITION AND DISTRIBUTION OF THE LOWER CRETACEOUS BLACK SHALE DEPOSITS WITHIN THE SILESIAN NAPPE OF THE UKRAINIAN CARPATHIANS

The article presents the results of studying the structural position and distribution of potentially oil-generating, organic-enriched Lower Cretaceous black shale deposits of the Shypot Formation, developed within the Silesian Nappe, using the methods of geological mapping and structural analysis. We concluded, that these deposits, which are exposed in the Vicha River basin near the town of Volovets among a continuous field of Oligocene flysch, are the part of the stratigraphic succession of the Silesian Nappe, and they are not a large olistolith or an allochthonous tectonic remnant of another, more internal nappe. Shypot Formation fills a large (1 × 3 km) subvertical tectonic lens. The rocks of the Shypot Formation are represented here by medium-rhythmic flysch: sandstone beds alternating with dark gray and black foliated mudstone (black shale) layers. They are lithified products of both medium-density turbidite flows and hemipelagic deposition of clayey material with a significant amount of organic matter. In the contact zone of the tectonic lens with the surrounding rocks, the deposits are intensively deformed, almost isoclinal folds with subvetrical hinges are observed, which suggest the strike-slip movements. A tectonic mélange is recorded here, which is represented by small blocks (clastolites) of brittle sandstones, sometimes similar to Shypot sandstones, placed in a silt-pelitic ductile matrix. Foliation of the mélange matrix is also subvertical and close to the meridional and/or subcarpathian direction. The structural studies carried out show that in the zone of this contact there were compressive stresses perpendicular to the Carpathian orogen, and stress fields that caused strike-slip movements, most likely right-lateral along the Carpathian thrusts. The tectonic lens is located within the broad Latorytsa-Stryi shear zone, and probably extruded out from deep horizons by transpressive movements (compression and strike-slip) and forms a “positive flower structure”. The vertical foliation in the mélange suggests that small blocks of Shypot sandstones were extruded up together with the ductile mélange matrix during diapirism. Similar processes probably led to the rise of a large lens of Shypot sandstones as the positive flower structure. The studies suggests that the black shale deposits of the Shypot Formation, enriched with organic matter, are widespread at some depth within the Silesian Nappe, and in some places are pushed up to the level of the Oligocene flysch. As a result, the Shypot Formation and Oligocene flysch are now in direct contact along faults/mélange zones. The presence of Lower Cretaceous potentially oil- and gas-generating black shale deposits within the Silesian Nappe significantly increases the prospects for oil and gas exploration in this area.

Upper Jurassic – Lower Cretaceous of eastern Wollaston Forland, North-East Greenland: a distal marine record of an evolving rift

Two drill cores covering the Upper Jurassic – Lower Cretaceous succession in Wollaston Forland, NE Greenland, offer an exceptional insight into mud-accumulation in an evolving distal fault block. Previous studies have revealed the presence of long-lasting black mudstone accumulation extending through the oxygen-restricted early rift and rift climax phases (Bernbjerg and Lindemans Bugt Formations). Here, we revisit the depositional evolution recorded in these cores to present a detailed description of the sedimentary succession extending into the late syn-rift settings (Palnatokes Bjerg and Stratumbjerg Formations). The results indicate that the Kimmeridgian – lower Volgian early rift-phase was characterized by suspension settling, laminae-scale event deposition in a tectonically-affected, prodeltaic offshore setting. The event-related depositional processes are expressed by starved wave-ripples, scour-and-fill structures, putative mud floccule ripples, and mud-dominated gravity-flow deposits. During the middle Volgian – Ryazanian rift climax phase, the depositional environment evolved into a narrow half-graben that was detached from the proximal depocentre flanking the coarse sediment fueled deltaic coastline. The correlative sedimentary facies in the detached half-graben are bioclastic and pyrite-rich black mudstones documenting suspension settling and gravity flow/mass wasting deposition in sub-storm wave-base slope and basin-floor environments. Black shale sedimentation ended abruptly in the late Ryazanian when the accumulation of condensed, bioturbated deep sea marls was initiated linked to broader oceanographic reorganization concomitant with waning rift activity in the west. Deposition of red bioclastic mudstones with a common gravity-flow component characterized the Hauterivian, potentially representing final draping of the submerged fault block crest. The top of the cored succession is demarcated by the appearance of dark grey bioturbated mudstones of Barremian age, reflecting the onset of regionally continuous deep-sea mud accumulation in thermally subsidizing basins. Although superficially monotonous, the mudstone-dominated succession reveals a highly dynamic depositional system that reflects shifting marine processes during almost a full rift cycle.

Controls on preservation of organic matter during the Cenomanian Ocean Anoxic Event II (OAE2) and Turonian global sea-level rise: Agadir Basin, Morocco

The Ocean Anoxic Event II (OAE2) was a significant global event associated with a positive carbon isotope excursion, occurring from the Late Cenomanian to the Early Turonian (C/T). It has been commonly associated with enhanced organic carbon preservation. Carbon isotopic analysis carried out over the C/T interval in the Agadir Basin, Morocco, integrated with previous biostratigraphic data, allows a refined correlation of the OAE2 interval. Detailed sedimentary facies analysis identifies ten lithofacies that record the transition from shallow marine environments in the Late Cenomanian to relatively deeper conditions in the Early Turonian. The variation in lithofacies can be correlated to relative sea level changes that show a correlation to the global eustatic curve.The OAE2 interval comprises dark grey mudstones beds that display low total organic carbon (TOC) values. Trace element and facies analysis suggest dilution from high detrital influx, along with oxic water conditions and low productivity. OM-rich black mudstones are identified in post-OAE2 Early Turonian strata. Trace element analysis suggests this increase in organic matter accumulation was related to increased sea surface productivity and oxygen-depleted bottom water conditions, which facilitated organic matter preservation. Deposition of OM-rich black mudstones is widely reported during the global Early Turonian marine transgression, suggesting the very high sea level was a major control on organic matter generation and preservation.

Alternations of open and closed lakes in the Lower Aptian Codó Formation (Parnaíba Basin, Brazil)

Lakes can be classified as open, semi-closed, and closed based on the balance between accommodation space and sediment–water fill. Different lake types can coexist in adjacent basins and rapidly change throughout time from one type to another. Understanding the processes that result from shifts in a lake's hydrological properties can be challenging, as well as characterizing its sedimentary products. The Aptian Codó Formation, in the Parnaíba Basin, north–northeast Brazil, contains in its record a complex facies succession deposited in a continental lacustrine system. In order to better understand the depositional aspects of different lake types, we characterized the lower portion of the Codó Formation using a multi-proxy approach. We combined litho- and microfacies analysis, ichnology, bulk chemical data, mineralogy, isotopic geochemistry, and organic matter analysis in the recently drilled, fully recovered borehole, 2-CO-1-MA. We defined eight lithofacies: bioturbated siltstones, dark gray mudstones, laminites, stratiform and domal stromatolites, heterolites rich in ostracods and organic muddy, and anhydrite and gypsum rocks. The isotopic data and the palynofacies analysis pointed out the existence of restricted conditions (TOC up to 19.6 wt%) with intermittent connections with seawater. Integrating all techniques, we interpreted five depositional stages: expanded lake, brackish ephemeral lake, perennial shallow lake, evaporitic sabkha, and stratified lake. These stages were influenced by the relation between inflow and evaporation rate, which were the main controls on sedimentation in the lacustrine-sabkha system studied. Our findings provide a detailed description and interpretation of the paleoenvironmental conditions related to the alternation from open to closed lakes, combining sedimentological, geochemical, and palynological characteristics of an inland lake system.

An integrated study of core and borehole image data: palaeokarst development in late Permian siliceous dolomites and the structural evolution of the Loppa High from the Gohta discovery well, SW Barents Shelf

Abstract The Gohta discovery well 7120/1-3, drilled on the Loppa High in the SW Barents Shelf in northern Norway encountered a meteoric karst system hosted by the late Permian lower Røye Formation that formed during a period of sub-Triassic exposure. The karst system is preserved as a series of interbedded collapse breccias representing formerly open palaeocaves, matrix-rich breccias that represent palaeocave fills with in situ and reworked stalactites and stalagmites. Layers of ‘Swiss cheese’ texture are interpreted as zones of dissolution in marine-meteoric mixing zones that may have controlled the levels of palaeocave development within the Gohta structure. These other cavities and the matrix of karst breccias were infilled by layered fine doloarenite matrix interpreted as an internal fill generated by collapse. This was followed by a later matrix of dark grey argillaceous mudstone that is interpreted as an external fill that pre-dates the overlying Klappmyss Formation. The karst system has undergone complex early diagenesis that includes extensive dissolution, early leaching of silica, the precipitation of pyrite on internal surfaces and sediment and the precipitation of carbonate and silica as speleothems and vadose cement. A borehole imaging log (BIL) was run across the lower Røye and Triassic Klappmyss formations, including the cored interval that provides a record of inclination and azimuth of the karst fills and in situ Røye Formation. The core provides information about the origin and timing of the different karst fills, and the BIL provides information about their azimuth and inclination. This integrated use of core and BIL data allows the incremental tilting history of the Loppa High structure during exposure to be reconstructed. At present, the Gohta structure has a finite tilt of 5–10° to the SE. The plunge of in situ stalagmites and stalactites suggests that the karst system was initiated while the Røye Formation was slightly tilted to SE. The dip of karst components and the host stratigraphy indicate several phases of incremental tilting during deposition of the doloarenite and argillaceous mudstone karst matrix. There appears to have been a reversal of tilt of the Gohta structure prior to its onlap by the Klappmyss Formation.

Assessment of Reservoir Quality of the Cretaceous Yolde Sandstone: A Case Study of Doma Stream, Gongola Basin, Northern Benue Trough, Northeast Nigeria.

Sedimentology, petrography and petrophysical studies were applied to the Cretaceous Yolde Formation sediments along the Doma stream, to evaluate its reservoir quality. The Yolde Formation along the Doma Stream is composed of lithologies that are laterally extensive and have reached a thickness of about 80m. They are lithologically made of sandstones with dark grey mudstones, laminated shales and grey to pale yellow limestones. The Sandstones are structurally characterized by planar, tabular and trough cross-beds, convolute beds, and hummocky cross-stratifications with reactivation surfaces. Some of the sediments are bioturbated. The petrophysical evaluation indicated porosity values ranging from 6% to 26%, and permeability values between 12.7mD and 108mD. These values are comparable to the reservoir rocks of proven petroleum basins of the North Sea and Niger Delta. Therefore, the Yolde Sandstones of the study area can have great potential to serve as good reservoir rock in the Gongola Basin.

The role of Triassic source rocks in the formation of oil accumulation in the Fukang Depression (China)

This article presents the results of geological and geochemical studies of the organic matter of source rocks and oil from reservoirs in the Karamay Formation (Anizian–Ladinian stages) in the eastern part of the Fukang Depression in Junggar petroleum basin. The quantity, quality, and degree of maturity of the organic matter in clayey mudstones in upper part of the Karamay Formation (T2k) were considered and the composition of the original organic matter, the conditions of its accumulation and the degree of maturity were reconstructed using pyrolytic parameters and biomarkers. The dark gray and gray mudstone in upper part of the Karamay Formation accumulated in fresh or low salinity lakes with relatively reducing conditions. At present, the organic matter of the Formation within the depression is in the zone of mesocatagenesis MK1–MK3, and therefore has not fully realized its oil-geological potential. It has been previously established that mudstones in upper part of the Karamay Formation provided the hydrocarbon fl uids for the Karamay reservoirs located in the submerged part of the Fukang Depression.

Differences and origins of hydrocarbon generation characteristics between mudstone and shale in the Seventh Member of the Yanchang Formation, Ordos Basin, China

Organic-rich black shale and dark-grey mudstone are widespread in the Seventh Member of the Yanchang Formation, Ordos Basin. There are obviously differences in geochemical characteristics and hydrocarbon generation potential between black shale and dark-grey mudstone. Based on the detailed organic geochemical examination, this paper reveals the differences in hydrocarbon generation processes and characteristics (activation energy and conversion rate of hydrocarbon generation) between dark-grey mudstone and black shale and the causes for the differences. Black shale is characterized by moderate to very high total organic carbon (TOC) contents (5.08%–39.39%) and its kerogen type belongs to type II1 and type I. Dark-grey mudstone has a characteristic of low to moderate TOC contents (0.64%–7.35%) and its kerogen types are mainly composed of type II2 and type II1. The hydrocarbon generation activation energy of black shale mainly oscillates around 250–310 KJ/mol, and the corresponding hydrocarbon generation threshold is high (the simulated temperature is 400 °C). The process of hydrocarbon generation is characterized by fast conversion rate and short cycle. By contrast, the hydrocarbon generation activation energy of dark-grey mudstone has a wide range (170–360 KJ/mol), and the corresponding hydrocarbon generation threshold is low (the simulated temperature is 230 °C). The process of hydrocarbon generation is characterized by slow conversion rate and long cycle. The difference of hydrocarbon generation process and characteristics between black shale and dark-grey mudstone is mainly affected by macerals composition and organic matter source. The organic matter of black shale mainly originated from algae, and its macerals was mainly composed of alginite. The organic matter of dark-grey mudstone mainly originated from the mixture of algae and terrestrial higher plants (conifers), and its macerals was mainly composed of vitrinite, liptodetrinite and inertinite. The complex macerals composition and organic matter source make the activation energy distribution of dark-grey mudstone more dispersed than that of black shale. In addition, affected by the macerals (e.g sporinite and resinite) with low activation energy from terrestrial higher plants, the activation energy of dark-grey mudstone containing sporinite and resinite in the macerals is lower than black shale. Therefore, the dark-grey mudstone containing algae and terrestrial higher plants corresponds to low hydrocarbon generation threshold, slow conversion rate and long hydrocarbon generation cycle. The black shale containing a large number of algae corresponds to high hydrocarbon generation threshold, fast conversion rate and short hydrocarbon generation cycle. Moreover, the conversion rate of black shale containing radioactive elements and more clay minerals is higher than that of dark-grey mudstone.

Evaluation of Climatic and Tectonic Imprints In Fluvial Successions of An Early Permian Depositional System (Asselian VrchlabÍ Formation, Krkonoše Piedmont Basin, Czech Republic)

ABSTRACT The Krkonoše Piedmont Basin, an early post-Variscan basin (c. 310–280 Ma) located in the NE Bohemian Massif (Czech Republic, central Europe), contains up to 300-m-thick non-marine Lower Permian (Asselian) deposits of the Vrchlabí Formation that crop out in its western part. The Early Permian Krkonoše Piedmont Basin exhibits striking similarities—in terms of tectonostratigraphic evolution, depositional patterns, and volcanism—to other early post-Variscan, near-equatorial intermontane basins. This work focuses on sedimentological analysis of the Vrchlabí Formation using outcrop data, combined with borehole and newly acquired field gamma spectrometry data. The formation consists predominantly of fluvial deposits in the southern part of the basin that pass laterally into deltaic and lacustrine deposits of the Rudník Member, located in the central part of the basin. Fluvial deposits are formed by sandstone and conglomeratic bodies, decimeters to several meters thick, interpreted as single-story and multi-story channel fills as well as various macroforms (e.g., bars) deposited by a low-sinuosity fluvial system. Channel fills intercalate with floodplain deposits centimeters to few meters thick. Vertically, the studied fluvial succession is divided into five intervals based on i) variable preservation ratio between channel fill and floodplain deposits and ii) external and internal geometries of sandstone and conglomerate channel bodies. In order to explain the observed vertical changes in fluvial style and to determine the main controlling factors, the interaction of the fluvial system with the contemporaneous lake was investigated by interpreting base-level changes of the fluvial system and their correlation with lake level changes. In the central part of the basin the transition from fluvio-deltaic to lacustrine deposits is represented by alternating beige to gray sandstones centimeters to few meters thick and by dark gray mudstones up to several meters thick that pass northwards into shales. At the outcrop scale, the new sedimentological data in combination with newly acquired gamma-ray logs enabled tracing the lateral extent of individual fluvial bodies. The integration of the new data with older borehole data leads to a substantially better understanding of lateral and vertical relationship between the fluvio-deltaic and the lacustrine facies at the basin scale. Tectonic subsidence played a substantial role during the initial deposition of the Vrchlabí Formation. However, the external geometries, the internal architecture of fluvial channel bodies, and the variable degree of floodplain preservation throughout the entire Vrchlabí Formation cannot be explained by tectonics only, but requires the consideration of climatic controls. The Early Permian fluvial system is interpreted to reflect seasonal discharge variability with dry and wet periods under long-term subhumid climatic conditions that shifted towards more arid conditions during the latest depositional stage of the Vrchlabí Formation.

Analyzing major controlling factors of shale oil 'sweet spots' in the Chang-7 member of the Triassic Yanchang Formation, Ordos Basin

The Chang-7 Member of the Upper-Triassic Yanchang Formation has favorable geological conditions (e.g., extensive distribution of source rock, broad distribution of fine-grained sand bodies, stable structure, etc.) for developing a large shale oil pool. Initial assessments have estimated that the Chang-7 has shale oil resources of 3.0 × 109 t approximately. The discovered Xin'anbian giant shale oil field has an estimated reserve of one billion tons. The shale oil in the Chang-7 Member has been developed by volumetric fracturing in long horizontal wells since 2011. By the end of 2021, more than 500 horizontal wells had been drilled, with average initial production of 9.6 t/d per well. Some large-scale effective development pilot zones (e.g., X233, Z183, A83, etc.) have been constructed. The source rock and reservoir in the Chang-7 Member are heterogeneous. Under an extensive distribution background of shale oil layers, there are some local 'sweet spots'. In order to reveal controlling factors for the productivity of shale oil, research involving the comparison of development effects, formation of geologic conditions, and technologies of the three typical pilot zones, has been conducted. The results showed that organic abundance in the source rock is the primary controlling factor for “sweet spot” distribution of the shale oil. The average TOC value in the black shale source rock in the Chang-7 Member is about 10% higher than that in the dark gray mudstone. The average hydrocarbon generation intensity is about 2.0 × 103 t/km2, the average hydrocarbon expulsion rate is 34.6%, and the production rate of gaseous hydrocarbons is 14.65–39.46 m3/t. In the vicinity of black shale with a high TOC value, the oil filling intensity in the shale oil reservoirs is high, with oil saturation of up to about 70%, and a gas-to-oil ratio >90 m3/t. Secondly, the 'sweet spots' with such petrophysical properties control the enrichment of reservoirs. Owing to conditions of low-porosityand low-permeability, the shale oil reservoirs in the Chang-7 Member of the Ordos Basin still developed 'sweet spots',with porosity larger than 9% and permeability larger than 0.08 × 10−3 μm2 . These reservoir sweet spots have a pyrolysis yield of hydrocarbons >9 mg/g and the development wells have high initial and total production, a slow decline rate, and low water cut. Moreover, the dissolved gas in shale oil in the Chang-7 Member of the Ordos Basin is an oil-type gas that was generated during the primary pyrolysis stage of sapropel kerogen after entering a mature period. The gas-to-oil ratio in crude oil is controlled by several factors, such as organic abundance and maturity in source rock, thickness, petrophysical properties, and fractures in reservoirs. The overlap of black shale with high TOC, source rock thickness >10 m, thermal maturity Ro > 0.8%, and type I and II high-quality reservoir beds are the pre-requisites for the development of sweet spots with high and stable production of shale oil. The produced gas-to-oil ratio in the development wells is stable (generally 19.68 m3/t). Some wells have produced oil continuously and stably at over 14 t/d for 5 years. This paper delineates the distribution patterns of shale oil sweet spots in the Chang-7 Member of the Ordos Basin and confirms that profitable and efficient development of shale oil can be achieved in this basin.

Characteristics and evolution of the Paleogene overpressured top seal in Niuzhuang Sub-sag, Dongying Sag, Bohai Bay Basin

The buried depth of overpressured top seal layer in Niuzhuang sub-sag is mainly 2700–3600m, which is characterized by deep center and shallow edge in plane. Its lithology is a combination of dark grey, grey mudstone and sandy mudstone. There are a large number of carbonate cements and clay minerals in the argillaceous rocks that form the top sealing layer. The diagenesis of mudstone occurs in the rapid transformation period of illite/smectite mixed layer minerals, and corresponds to a large number of carbonate cements. The displacement pressure, thickness and diagenetic intensity of overpressured top seal are important factors affecting its physical sealing ability. There are five evolution stages of overpressured top seal, namely, at the initial stage of settlement, the strata are normally compacted, and the development of overpressured top seal is not obvious; During the first stage of accumulation, the low-amplitude hydrocarbon generation in the deep sag was supercharged, and the overpressured top seal was initially formed. Intermittent period of reservoir formation, overpressure top seal uplift erosion; During the rapid subsidence period, the strata are undercompacted to form overpressure, and the overpressure top seal is re-formed. During the second stage of storage, the thickness of overpressure top seal increased to the maximum.

A new Hauterivian palynoflora from the Vale Cortiço site (central Portugal), and its palaeoecological implications for western Iberia

Abstract Palynofloral assemblages are an invaluable source of information about the interactions between fossil plants and their environments. Here we describe a new Early Cretaceous palynoflora from the Lusitanian Basin in the Estremadura region of central western Portugal. A palynological assemblage of 28 genera and 40 species was extracted from 14 samples collected in the Vale Cortiço clay pit complex near the small village of Ameal (Torres Vedras Municipality). The source is a dark grey mudstone layer belonging to the lower part of the Santa Susana Formation, which is considered to be of early Hauterivian age. The palynoflora is dominated by fern spores and gymnosperm pollen. Bryophyte and lycophyte palynomorphs are also present but subordinate. Angiosperm pollen and algal or dinoflagellate cysts were not recognised in the studied samples. The palynological assemblage represents mixed conifer forest with the ground cover and understorey vegetation dominated by ferns, with patchy occurrences of bryophytes and lycophytes. A riverine environment with surrounding vegetation of open woodland and ground cover primarily of ferns is strongly indicated for the region.

Geology of the area between Bardibas and Sindhuli Madi, Sub-Himalaya, Central Nepal

The Siwalik Group (Sub-Himalaya) is the east-west extending youngest mountain belt formed by the sediments derived from the rising Himalaya on the north. The Siwalik Group is separated from the Lesser Himalaya to the north by the Main Boundary Thrust (MBT), and the Indo-Gangetic Plain to the south by the Main Frontal Thrust (MFT). The study was carried out mainly along the Ratu Nadi, Kamala Nadi river sections and was lithostratigraphically divided into the Lower Siwalik, Middle Siwalik, and Upper Siwalik, from the bottom to the top section, respectively. The Lower Siwalik is composed of fine-grained greenish grey calcareous sandstone (subarkose and lithic arenite), variegated mudstone, and calcareous siltstone. The Lower Siwalik is exposed due to the Marine Khola Thrust in the Gadyauli Khola, and sandstone there is more indurated and non-calcareous. The Middle Siwalik is mainly comprised of the medium- to coarse-grained salt-and-pepper sandstone (arkose and subarkose) with large cross lamination, calcareous sand lenses, convolute bedding, dark grey siltstone and mudstone. Plant fossils are also present in the finely laminated clay bed of the Middle Siwalik along the Ratu Nadi section. The Upper Siwalik comprises of mud- to sand-supported pebble to cobble conglomerates.

Key factors controlling hydrocarbon enrichment in a deep petroleum system in a terrestrial rift basin—A case study of the uppermost member of the upper Paleogene Shahejie Formation, Nanpu Sag, Bohai Bay Basin, NE China

Abstract Mineralogical, petrographical, geochemical analyses, and fluid inclusions petrography and microthermometry were combined to investigate the basic properties of the source rock (organic matter content, kerogen type, and thermal maturity) and sandstone reservoirs (composition, pore systems, porosity, and permeability), the hydrocarbon origin, and the formation mechanisms of the deep (>3.5 km) petroleum system in the Upper Paleogene Es1 (the uppermost member of the Shahejie Formation) in the No. 3 Structural Belt in the Nanpu Sag, Bohai Bay Basin. The results indicate that the Es1 source rock is primarily composed of dark gray mudstone and presents a set of high-quality source rocks (>500 m, average total organic carbon (TOC) 1.38%, in a mature stage (maximum pyrolysis yield of 430 °C–460 °C)). The Es1 sandstone is composed of lithic arkose formed in a braided river delta and has low porosity (average 13.4%) but moderate-high permeability (average 184.9 mD). The hydrocarbons originated from the Es1 source rocks in the Caofeidian subsag during two charging periods: 10 Ma and 3 Ma. The key factors controlling the formation of the deep petroleum system are as follows: (a) High-quality hydrocarbon supply, (b) Medium-high permeability reservoirs, (c) A favorable configuration of the source rock and reservoirs (self-generated and self-accumulated), and (d) Late hydrocarbon charging; the second factor is the most important. The medium-high permeability reservoirs are attributed to a high-energy depositional environment (distributary channels of braid delta front), a high content of rigid detrital grains (mainly quartz and metamorphic rock fragments) provided by the Archean granite provenance, and the secondary pores formed by feldspar dissolution. This study provides a new example for revealing the formation mechanisms of deep (>3.5 km) petroleum systems in the terrestrial rift basin across the Bohai Bay Basin.

Sequence stratigraphy control on fossil occurrence and concentration in the epeiric mixed carbonate-siliciclastic ramp of the Early Permian Irati Formation of southern Brazil

The Early Permian Irati Formation records sedimentation of a mixed carbonate-siliciclastic, storm-influenced ramp in a shallow and restricted epeiric sea. It is formally divided in the dark grey mudstones of the lower Taquaral Member, and alternating dark grey mudstones, bituminous black shales, and carbonates of the upper Assistência Member. The formation crops out from central to southern Brazil on the eastern border of the intracratonic Paraná Basin. Fossils of mesosaurid reptiles, pygocephalomorph crustaceans, and subordinate paleonisciform fish form dense concentrations within carbonate tempestites, interpreted as mass mortality events caused by storms. The present study describes the Passo do São Borja outcrop and five new locations, along with 11 drill cores of the complete Irati interval in the Rio Grande do Sul state, applying methods of facies analysis and sequence stratigraphy. Three fourth-order sequences within the Irati Formation were recognized, termed sequences 1, 2, and 3 (S1, S2, S3). S1 is broadly coincident with the Taquaral Member, and S2 and S3 with the Assistência Member. The upper two sequences are composed of a lowstand systems tract (LST), a transgressive systems tract (TST), and a highstand systems tract (HST), whereas the lower sequence lacks a LST. Sequence boundary SB2 was interpreted as coincident with a third-order sequence boundary. Mesosaurid and pygocephalomorph concentrations occur only in S3. Fossil occurrences and concentration were found to be strongly controlled by facies and sequence stratigraphy. Paleonisciform fish fossils are considerably more common at the early HST of S2 and S3, resulting from balanced sedimentation to accommodation rates. Pygocephalomorphs compose intraclasts concentrated in grainstone proximal tempestites of the LST in S3. They are the result of mass mortality events and background bioclastic input, enhanced by firmground formation (hiatal concentration) and subsequent storm reworking. Mesosaurids are also concentrated in grainstone tempestites of the LST, but in cores they were mostly found in distal tempestites of the TST, becoming more common towards the maximum transgressive surface (MTS). Their accumulation is also the result of mass mortality and background sedimentation, enhanced by sediment omission (hiatal concentration) of a severely sediment starved TST (culminating in a condensed section near the MTS), and subsequent storm reworking.

Formation phases of carbonate cements and sedimentary environments in lower Jurassic sandstones of the Lenghu V tectonic belt, North Qaidam Basin, China

Based on petrography and geochemistry, formation phases of carbonate cements and their sedimentary–diagenetic environments in Jurassic clastic rocks from the Lenghu V tectonic belt are determined. The results demonstrate that studied successions are mainly dark gray or black mudstone with interbedded thin gray siltstone and a few greywacke layers. Sandstones are lithic and feldspathic lithic greywacke with high kaolinite content. Calcite and ferrocalcite are the main carbonate cements. The carbon isotope values(δ13C) of the carbonate cements range from − 15.6 to 9.2‰ (average − 3.2‰) with a bimodal distribution. One peak is 4‰, which includes samples from the upper Xiaomeigou Formation (Fm) and the other one is − 12‰, which mainly represents the lower section. The oxygen isotope values(δ18O) have a wide range from − 18.5 to − 8.3‰ (average − 13.31‰). Combined with microscopic observations, two phases of carbonate cements are distinguished according to their isotopic characteristics. The earlier carbonate cements are mainly calcite and ferrocalcite, and they were precipitated in eodiagenesis stage. The carbon source of calcite was inorganic, and ferrocalcite was mixed with carbon from methanogenesis. This mixture led to a positive bias in the δ13C curve, which artificially inflated the paleosalinity. The later carbonate cements, formed in mesodiagenesis stage, were ferrocalcite. Decarboxylation of organic matters led to lower δ13C values. The major and trace elements data show that Sr, Ba, Fe and Mn have weak correlation with Al, Ti. So, they are effective to interpret the sedimentary environment. The Sr/Ba ratio < 1 indicates fresh water environment, Sr/Ca, Sr/Cu and Fe/Mn ratios suggest humid climate, and V/(V + Ni) ratio shows suboxic–anoxic environment. The carbon and oxygen isotopes, together with elemental geochemistry, show that the climate during the Early Jurassic was warm and wet and the studied successions were deposited in fresh water. The variations in elemental ratio curves indicate that climate became wetter and warmer later in the Early Jurassic.

The Trace Fossil Polykampton cabellae isp. nov. from the Pagliaro Formation (Paleocene), Northern Apennines, Italy: A Record of Nutritional Sediment Sequestration by a Deep Sea Invertebrate

ABSTRACTPolykampton cabellae isp. nov., a new ichnospecies of Polykampton Ooster, 1869, occurs in two localities of the Pagliaro Formation (Paleocene) in Liguria, Italy, 1.5–3.5 cm below the top of light grey or rose, thick-bedded turbiditic marlstones, which are capped by a thin layer of dark grey, non-calcareous mudstones being the background sediments. This is a ribbon-like, winding, rarely branched trace fossil that consists of 1) a passively-filled axial tunnel and 2) complex, partly imbricated, side lobes, which are composed mostly of dark grey mudstones, the same as in the background sediments. The lobes are produced by multiple probing. The producer, supposedly a polychaete, collected organic-rich, nutritional mud from the sea-floor surface, packed it in a deeper layer in the organic-poor marl, and reworked for feeding. This enabled a stable feeding during longer times of fluctuating supply of organic matter to the sea floor.

Chronostratigraphic Correlation of Lacustrine Deposits Using 87 SR/ 86 SR Ratios, Eocene Green River Formation, Wyoming, U.S.A.

Abstract: The reconstruction of detailed, basin-scale depositional histories from sedimentary rocks fundamentally depends on the availability of reliable time markers. Unlike marine strata, lacustrine strata typically lack rapidly evolving, cosmopolitan fauna or flora that might serve this purpose. Depending on their geologic context, lacustrine strata may also lack tephras that could provide isochronous markers or radioisotopic age. Variations in 87 Sr/ 86 Sr ratios could potentially provide an alternative means of chronostratigraphic correlation for carbonate-rich lake deposits, based on the hypothesis that Sr isotopes are well mixed in a lake and do not experience significant fractionation. To test this hypothesis we measured 87 Sr/ 86 Sr ratios in 114 samples from two drill cores of the upper Wilkins Peak Member from the Green River Formation that are located ∼ 23 km apart. These cores can be independently correlated using distinctive tephras and organic-carbon rich mudstone horizons. Measured 87 Sr/ 86 Sr ratios range from 0.71154 to 0.71504, and vary inversely with lake-water depth, as interpreted by sedimentary lithofacies characteristics. Lower ratios of 87 Sr/ 86 Sr are found in lithofacies deposited during lake highstands, which are marked by laminated dark-gray mudstone and elevated organic-carbon enrichment (as measured by Fischer Assay analysis). Higher 87 Sr/ 86 Sr ratios occur in lithofacies deposited during lake lowstands, which are marked by organic-lean gray-green mudstone. 87 Sr/ 86 Sr in approximately time-equivalent samples from the two cores show a strong positive correlation (r = 0.68), despite the likely presence of small temporal mismatches between approximately correlative samples. We conclude that lake-water was consistently well mixed with respect to Sr across distances of at least 23 km. These results suggest that 87 Sr/ 86 Sr can serve as a powerful tool to aid high-resolution chronostratigraphic correlation of lake deposits.