δ13Corg Signature Research Articles

Overprinting of δ13Corg signatures in the sedimentary record linked to hydrocarbon migration: Evidence from Paleozoic drill cores from the Ordos Basin, China

Carbon isotopic compositions of organic matter (δ13Corg) provide critical information about changes in the global carbon cycle through Earth's history. However, several biotic and abiotic processes occurring after sediment deposition may overprint the original geochemical signals, complicating their paleoenvironmental interpretation. Here, we report multiple large and rapid δ13Corg swings (ranging from −30.8‰ to −23.3‰) from three Paleozoic drill cores in the Ordos Basin, Northwest China, which may reflect different organic contributions related to lithology. As a potentially important organic matter source, migrated hydrocarbons may substantially alter the original δ13Corg and total organic carbon contents (TOC), and their oxidation may contribute to forming 13C- and 18O-depelted carbonate cements in siliciclastic-dominated strata at depth. Cross-plots of δ13Corg and TOC from samples of the three drill cores all show similar hyperbolic trends that are well simulated using Rayleigh fractionation and a two-component mixing model, thus providing potential criteria for identifying the reservoir and the related hydrocarbon source in oil exploration. Our data call for a critical reassessment of the δ13Corg records of sedimentary rocks if hydrocarbon redistribution or mixing of organic sources is suspected to have occurred during the burial history.

Palaeoecology and palaeoclimate of an Early Cretaceous peat mire in East Laurasia (Hailar Basin, Inner Mongolia, China)

In this contribution, we report the palynology, organic petrography and carbon isotopes for the #16 Seam in the Lower Cretaceous Yimin Formation of the Hailar Basin, Inner Mongolia, China. Eighteen palynological samples were collected from the coal seam as well as from intraseam partings and the immediate roof. Microfloras comprise a diverse assemblage of ferns, conifers, horsetails, lycopsids, bryophytes, ginkgoes and cycads. Conifer pollen is common, especially representative of Pinaceae (Pinuspollenites) as well as Cheirolepidiaceae (Classopollis) and Araucariaceae (Araucariacites, Chasmatosporites); however, this material is interpreted as mostly derived from an upland source rather than from the mire-forming vegetation. An overrepresentation of conifer pollen may explain the relatively poor abundance and diversity of ginkgo and cycad pollen, compared to what is found in the macrofossil record. The palynological assemblage found in Seam #16 indicates a Barremian to Aptian age. Maceral composition, ash yields, and δ13Corg signature of the coal suggest peat accumulation was controlled by a rising water table from flooding of the mire, coupled with significant ground (peat) fires and/or surface wildfires. These conditions resulted in high levels of detrital mineral matter and charcoal input, the latter represented by inertodetrinite in the coals. The top of the coal seam is characterised by a higher ash yield, lower δ13Corg values and increased sphagnacean spores, which suggest the gradual drowning of the palaeomire. Although angiosperms were present in the Hailar Basin during the time that Seam #16 was accumulating, they are absent from the pollen found in this study. This may indicate that they were not yet adapted to the extreme conditions of the mire (e.g., acidity, anoxia), and unable to compete with the established mire vegetation.

Precipitation of Mn Oxides in Quaternary Microbially Induced Sedimentary Structures (MISS), Cape Vani Paleo-Hydrothermal Vent Field, Milos, Greece

Understanding microbial mediation in sediment-hosted Mn deposition has gained importance in low-temperature ore genesis research. Here we report Mn oxide ores dominated by todorokite, vernadite, hollandite, and manjiroite, which cement Quaternary microbially induced sedimentary structures (MISS) developed along bedding planes of shallow-marine to tidal-flat volcaniclastic sandstones/sandy tuffs, Cape Vani paleo-hydrothermal vent field, Milos, Greece. This work aims to decipher the link between biological Mn oxide formation, low-T hydrothermalism, and, growth and preservation of Mn-bearing MISS (MnMISS). Geobiological processes, identified by microtexture petrography, scanning and transmission electron microscopy, lipid biomarkers, bulk- and lipid-specific δ13Corganic composition, and field data, and, low-temperature hydrothermal venting of aqueous Mn2+ in sunlit shallow waters, cooperatively enabled microbially-mediated Mn (II) oxidation and biomineralization. The MnMISS biomarker content and δ13Corg signatures strongly resemble those of modern Mn-rich hydrothermal sediments, Milos coast. Biogenic and syngenetic Mn oxide precipitation established by electron paramagnetic resonance (EPR) spectroscopy and petrography, combined with hydrothermal fluid flow-induced pre-burial curing/diagenesis, may account for today’s crystalline Mn oxide resource. Our data suggests that MISS are not unique to cyanobacteria mats. Furthermore, microbial mats inhabited by aerobic methanotrophs may have contributed significantly to the formation of the MnMISS, thus widening the spectrum of environments responsible for marine Mn biometallogenesis.

Latitudinal trends in stable isotope signatures and carbon-concentrating mechanisms of northeast Atlantic rhodoliths

Abstract. Rhodoliths are free-living calcifying red algae that form extensive beds in shallow marine benthic environments (<250 m), which provide important habitats and nurseries for marine organisms and contribute to carbonate sediment accumulation. There is growing concern that these organisms are sensitive to global climate change, yet little is known about their physiology. Considering their broad distribution along most continental coastlines, their potential sensitivity to global change could have important consequences for the productivity and diversity of benthic coastal environments. The goal of this study was to determine the plasticity of carbon-concentrating mechanisms (CCMs) of rhodoliths along a latitudinal gradient in the northeast Atlantic using natural stable isotope signatures. The δ13C signature of macroalgae can be used to provide an indication of the preferred inorganic carbon source (CO2 vs. HCO3-). Here we present the total (δ13CT) and organic (δ13Corg) δ13C signatures of northeast Atlantic rhodoliths with respect to changing environmental conditions along a latitudinal gradient from the Canary Islands to Spitsbergen. The δ13CT signatures (−11.9 to −0.89) of rhodoliths analyzed in this study were generally higher than the δ13Corg signatures, which ranged from −25.7 to −2.8. We observed a decreasing trend in δ13CT signatures with increasing latitude and temperature, while δ13Corg signatures were only significantly correlated to dissolved inorganic carbon. These data suggest that high-latitude rhodoliths rely more on CO2 as an inorganic carbon source, while low-latitude rhodoliths likely take up HCO3- directly, but none of our specimens had ∂13Corg signatures less than −30, suggesting that none of them relied solely on diffusive CO2 uptake. However, depth also has a significant effect on both skeletal and organic δ13C signatures, suggesting that both local and latitudinal trends influence the plasticity of rhodolith inorganic carbon acquisition and assimilation. Our results show that many species, particularly those at lower latitudes, have CCMs that facilitate HCO3- use for photosynthesis. This is an important adaptation for marine macroalgae, because HCO3- is available at higher concentrations than CO2 in seawater, and this becomes even more extreme with increasing temperature. The flexibility of CCMs in northeast Atlantic rhodoliths observed in our study may provide a key physiological mechanism for potential adaptation of rhodoliths to future global climate change.

Sedimentary mechanisms of a modern banded iron formation on Milos Island, Greece

Abstract. An early Quaternary shallow submarine hydrothermal iron formation (IF) in the Cape Vani sedimentary basin (CVSB) on Milos Island, Greece, displays banded rhythmicity similar to Precambrian banded iron formation (BIF). Field-wide stratigraphic and biogeochemical reconstructions show two temporal and spatially isolated iron deposits in the CVSB with distinct sedimentological character. Petrographic screening suggests the presence of a photoferrotrophic-like microfossil-rich IF (MFIF), accumulated on a basement consisting of andesites in a ∼ 150 m wide basin in the SW margin of the basin. A banded nonfossiliferous IF (NFIF) sits on top of the Mn-rich sandstones at the transition to the renowned Mn-rich formation, capping the NFIF unit. Geochemical data relate the origin of the NFIF to periodic submarine volcanism and water column oxidation of released Fe(II) in conditions predominated by anoxia, similar to the MFIF. Raman spectroscopy pairs hematite-rich grains in the NFIF with relics of a carbonaceous material carrying an average δ13Corg signature of ∼ −25‰. A similar δ13Corg signature in the MFIF could not be directly coupled to hematite by mineralogy. The NFIF, which postdates large-scale Mn deposition in the CVSB, is composed primarily of amorphous Si (opal-SiO2 ⋅ nH2O) while crystalline quartz (SiO2) predominates the MFIF. An intricate interaction between tectonic processes, changing redox, biological activity, and abiotic Si precipitation are proposed to have collectively formed the unmetamorphosed BIF-type deposits in a shallow submarine volcanic center. Despite the differences in Precambrian ocean–atmosphere chemistry and the present geologic time, these formation mechanisms coincide with those believed to have formed Algoma-type BIFs proximal to active seafloor volcanic centers.

Dynamics of carbon sources supporting burial in seagrass sediments under increasing anthropogenic pressure

AbstractSeagrass meadows are strong coastal carbon sinks of autochthonous and allochthonous carbon. The aim of this study was to assess the effect of coastal anthropogenic pressure on the variability of carbon sources in seagrass carbon sinks during the last 150 yr. We did so by examining the composition of the sediment organic carbon (Corg) stocks by measuring the δ13Corg signature and C : N ratio in 210Pb dated sediments of 11 Posidonia oceanica seagrass meadows around the Balearic Islands (Spain, Western Mediterranean) under different levels of human pressure. On average, the top meter sediment carbon deposits were mainly (59% ± 12%) composed by P. oceanica derived carbon whereas seston contribution was generally lower (41% ± 8%). The contribution of P. oceanica to the total sediment carbon stock was the highest (∼ 80%) in the most pristine sites whereas the sestonic contribution was the highest (∼ 40–80%) in the meadows located in areas under moderate to very high human pressure. Furthermore, an increase in the contribution of sestonic carbon and a decrease in that of seagrass derived carbon toward present was observed in most of the meadows examined, coincident with the onset of the tourism industry development and coastal urbanization in the region. Our results demonstrate a general increase of total carbon accumulation rate in P. oceanica sediments during the last century, mainly driven by the increase in sestonic Corg carbon burial, which may have important implications in the long‐term carbon sink capacity of the seagrass meadows in the region examined.

Organic matter compositions and loadings in soils and sediments along the Fly River, Papua New Guinea

The compositions and loadings of organic matter in soils and sediments from a diverse range of environments along the Fly River system were determined to investigate carbon transport and sequestration in this region. Soil horizons from highland sites representative of upland sources have organic carbon contents (%OC) that range from 0.3 to 25wt%, carbon:nitrogen ratios (OC/N) that range from 7 to 25mol/mol, highly negative stable carbon isotopic compositions (δ13Corg<−26‰) and variable concentrations of lignin phenols (1<LP<5mg/100mgOC). These compositions reflect inputs from local vegetation, with contributions from bedrock carbon in the deeper mineral horizons. Soils developed on the levees of active floodplains receive inputs of allochthonous materials by overbank deposition as well as autochthonous inputs from local vegetation. In the forested upper floodplain reaches, %OC contents are lower than upland soils (0.8–1.5wt%) as are OC/N ratios (9–15mol/mol) while δ13Corg (−25 to −28‰) and LP (2–6mg/100mgOC) values are comparable to upland soils. These results indicate that organic matter present in these active floodplain soils reflect local (primarily C3) vegetation inputs mixed with allochthonous organic matter derived from eroded bedrock. In the lower reaches of the floodplain, which are dominated by swamp grass vegetation, isotopic compositions were less negative (δ13Corg>−25‰) and non-woody vegetation biomarkers (cinnamyl phenols and cutin acids) more abundant relative to upper floodplain sites. Soils developed on relict Pleistocene floodplain terraces, which are typically not flooded and receive little sediment from the river, were characterized by low %OC contents (<0.6wt%), low OC/N ratios (<9mol/mol), more positive δ13Corg signatures (>−21‰) and low LP concentrations (∼3mg/100mgOC). These relict floodplain soils contain modern carbon that reflects primarily local (C3 or C4) vegetation sources. Total suspended solids collected along the river varied widely in overall concentrations (1<TSS<9000mg/L), %OC contents (0.1–60wt%), OC/N ratios (7–17mol/mol) and δ13Corg signatures (−26 to −32‰). These compositions reflect a mixture of C3 vascular plants and freshwater algae. However, little of this algal production appears to be preserved in floodplain soils. A comparison of organic carbon loadings of active floodplain soils (0.2 and 0.5mgC/m2) with previous studies of actively depositing sediments in the adjacent delta–clinoform system (0.4–0.7mgC/m2) indicates that Fly River floodplain sediments are less effective at sequestering organic carbon than deltaic sediments. Furthermore, relict Pleistocene floodplain sites with low or negligible modern sediment accumulation rates display significantly lower loadings (0.1–0.2mgC/m2). This deficit in organic carbon likely reflects mineralization of sedimentary organic carbon during long term oxidative weathering, further reducing floodplain carbon storage.

Variation in carbon isotopic composition over the past ca. 46,000 yr in the loess–paleosol sequence in central Kazakhstan and paleoclimatic significance

We present a high resolution record of δ13Corg variation from two loess sequences in central Kazakhstan. The variation shows that the vegetation was persistently dominated by C3 plants over the past ca. 46,000yr. The δ13Corg signature was most likely an indicator of moisture and the moisture variation in central Kazakhstan was associated with the precipitation in Western Europe. The δ13Corg indicated that moisture variation exhibited five stages: decreasing during stage 1 (ca. 46,000–ca. 31,500yr BP), increasing during stage 2 (ca. 31,500–ca. 25,500yr BP), again decreasing during stage 3 (ca. 25,500–ca. 19,000yr BP), fluctuating along a constant line during stage 4 (ca. 19,000–ca. 5000yr BP) and increasing during stage 5 (last ca. 5000yr). Our comparison demonstrated a general similarity between the δ13Corg-indicated moisture variation in central Kazakhstan and the reconstructed precipitation variation in Western Europe. The similarity implies that the moisture of the past ca. 46,000yr in central Kazakhstan has been controlled or modulated by westerlies that brought water vapor from the North Atlantic not only to Western Europe but also to central Kazakhstan.

Particulate organic matter sinks and sources in high Arctic fjord

The main aim of this paper is to present results on concentrations, fluxes and isotopic composition (δ13Corg) of particulate and sedimentary organic carbon (measures of particulate and sedimentary organic matter, respectively) in Kongsfjorden, Spitsbergen. The terrestrial particulate organic carbon (POC) input to the Kongsfjorden reached 760·106±145·106gCorgy−1, forced mostly by the glaciers' activity. This constituted 5–10% of the bulk POC supplied to the system. Marine primary production was the main source of the remaining 90–95% of POC. Organic carbon burial rates amounted to 9±1gCorgm−2y−1 in the central and 13±1gCorgm−2y−1 in the outer part of the fjord. Two terrestrial POM δ13Corg end members were identified: the ancient organic matter (OM) supplied by glaciers and rivers fed by water discharged from the glaciers (from −25.4‰ to −25.1‰), and the fresh terrestrial POM (from −26.7‰ to −26.6‰). Marine OM was characterized by a wide range of δ13Corg signatures: from ≤−26.1‰ for the phytoplankton depleted in 13Corg to ca. −15.8‰ for debris of marine phytobenthos. The lack of distinct marine δ13Corg end member and the resemblance of phytoplankton δ13Corg signatures to the terrestrial POM δ13Corg end member precluded the use of the two δ13Corg end member mixing model to trace the terrestrial OM in Kongsfjorden, which is also very likely to happen in other Arctic regions.

Palynology and geochemistry of channel-margin sediments across the tidal–fluvial transition, lower Fraser River, Canada: Implications for the rock record

In the tidally influenced Fraser River, Canada, palynological and carbon isotope (δ13Corg) signatures of channel-margin sediments are compared to environmental parameters (e.g., grain size, water salinity) to establish how the signatures vary across the tidal–fluvial transition. Palynological assemblages in the Fraser River are dominated by tree pollen, which constitutes between 85% and 95% of all assemblages. Dinocyst abundances do not exceed 2% of the total palynological assemblage, and the number and diversity of dinocysts gradually decreases landward. The calculated landward limit for dinocysts is at approximately 83 river km, which is relatively close to the upstream limit of the tidal backwater (at ∼100 km). δ13Corg values show minimal variability across the tidal–fluvial transition, and the average value is approximately −26‰. The δ13Corg signature of river sediments indicates a dominance of terrestrially sourced organic matter regardless of brackish-water and tidal influence on sediment deposition.Six palynological and geochemical trends are identified as relevant to the rock record. 1) In deltaic environments, palynological and geochemical characteristics are less useful than sedimentological and ichnological characteristics for establishing depositional conditions. 2) In marginal-marine settings, low abundances and low species diversities of dinocysts, coupled with a “terrestrial” geochemical signature (δ13Corg < −25‰) do not necessarily indicate deposition in a terrestrial environment. 3) Dinocyst abundances above 1% of the total palynomorph population can indicate a significant marine influence on sediment deposition. 4) Mud beds, preferably bioturbated, should be preferentially sampled in order to maximize palynomorph recovery. 5) Marine palynomorphs can occur, albeit in very low concentrations, to the landward limit of the tidal–backwater zone. 6) Palynological and geochemical data should be compared across the paleo-depositional environment in order to establish general trends and remove local variations caused by biases such as grain size.

Multivariate benthic ecosystem functioning in the Arctic – benthic fluxes explained by environmental parameters in the southeastern Beaufort Sea

Abstract. The effects of climate change on Arctic marine ecosystems and their biogeochemical cycles are difficult to predict given the complex physical, biological and chemical interactions among the ecosystem components. We studied benthic biogeochemical fluxes in the Arctic and the influence of short-term (seasonal to annual), long-term (annual to decadal) and other environmental variability on their spatial distribution to provide a baseline for estimates of the impact of future changes. In summer 2009, we measured fluxes of dissolved oxygen, nitrate, nitrite, ammonia, soluble reactive phosphate and silicic acid at the sediment–water interface at eight sites in the southeastern Beaufort Sea at water depths from 45 to 580 m. The spatial pattern of the measured benthic boundary fluxes was heterogeneous. Multivariate analysis of flux data showed that no single or reduced combination of fluxes could explain the majority of spatial variation, indicating that oxygen flux is not representative of other nutrient sink–source dynamics. We tested the influence of eight environmental parameters on single benthic fluxes. Short-term environmental parameters (sinking flux of particulate organic carbon above the bottom, sediment surface Chl a) were most important for explaining oxygen, ammonium and nitrate fluxes. Long-term parameters (porosity, surface manganese and iron concentration, bottom water oxygen concentrations) together with δ13Corg signature explained most of the spatial variation in phosphate, nitrate and nitrite fluxes. Variation in pigments at the sediment surface was most important to explain variation in fluxes of silicic acid. In a model including all fluxes synchronously, the overall spatial distribution could be best explained (57%) by the combination of sediment Chl a, phaeopigments, δ13Corg, surficial manganese and bottom water oxygen concentration. We conclude that it is necessary to consider long-term environmental variability along with rapidly ongoing environmental changes to predict the flux of oxygen and nutrients across Arctic sediments even at short timescales. Our results contribute to improve ecological models predicting the impact of climate change on the functioning of marine ecosystems.

A Novel Approach for Inferring the Proportion of Terrestrial Organic Matter Input to Marine Sediments on the Basis of TOC:TN and δ&amp;lt;sup&amp;gt;13&amp;lt;/sup&amp;gt;C&amp;lt;sub&amp;gt;org&amp;lt;/sub&amp;gt; Signatures

The ratio of total organic carbon to total nitrogen (TOC:TN) and the stable carbon isotope ratio of organic matter (δ13Corg) are widely applied for inferring the origin of organic matter (OM) in Quaternary marine sediments. A plot of TOC:TN vs. δ13Corg is useful for such studies but is strongly based on qualitative constraints. This study is based on the qualitative characterization of the source of Quaternary OM via analysis of TOC:TN and δ13Corg signatures, but also proposes a probability parameter, which combines both signatures, to infer the amount of Terrestrial OM Input (TOMI). This index provides a method for quantifying the proportion of terrestrial OM vs. marine OMin a more comprehensive manner. The TOMI index concept was applied to a study area in theJoetsuBasin, eastern margin of theJapanSea, where previous studies have characterized theOMfrom the Last Glacial Maximum (LGM) to the present. The upwards increase in TOC indicates thatOMproduction during the Holocene was higher than during the LGM. The enriched δ13Corg signature upwards and decrease in TOC:TN suggest predominantly marine phytoplankton OM during the Holocene. Throughout the LGM, low OM production with depleted δ13Corg values and high TOC:TN values in the sediments suggest a predominantly C3 terrestrial plant source for the OM. Using these data, it was possible to calculate a proxy for a sea level variation curve during that period and to investigate the influence of the proximity of the coastal line to the continental slope on the input of terrestrial material to the basin. The proposal provides information for the application of sequence stratigraphic concepts. The TOMI index could confirm that the proximity to the shoreline and shelf break has a strong influence on the input of terrestrial material during lowstand periods.

Geochemical Analysis as a Complementary Tool to Estimate the Uplift of Sediments Caused by Shallow Gas Hydrates in Mounds at the Seafloor of Joetsu Basin, Eastern Margin of the Japan Sea

The Holocene sediments of the eastern margin of the Japan Sea are characterized by high total organic carbon (TOC) and total nitrogen (TN) contents, low TOC/TN and TS/TOC values with enriched δ13Corg signatures, as a result of high marine productivity during present oxic highstand. On the other hand, the LGM sediments are characterized by low TOC and TN contents, high TOC/TN and TS/TOC values with depleted δ13Corg signatures, characteristic of C3-derived terrestrial organic matter input during that anoxic lowstand. However, at the top of mounds at the seafloor, where gas hydrate and authigenic carbonate nodules occur, the host sediments have a mixture of both Holocene and LGM geochemical signatures. Both gas hydrate and authigenic carbonate, formed by the anaerobic oxidation of methane, increased the sedimentary volume and caused an uplift of older sediments, inducing mound formation. The thickness of the Holocene sediments over mounds is very small or absent exposing the last glacial maximum (LGM) sediments to the seafloor. The uplift of the LGM sediments within mounds is estimated to be &gt;2 m. We conducted geochemical analysis to detect such sediment movement, using samples collected by shallow cores in the Joetsu Basin, eastern margin of the Japan Sea.

Origin of the organic matter in the Late Quaternary sediments of the eastern margin of Japan Sea

This study was carried out on sediment samples collected by piston-coring in two areas of the eastern margin of the Japan Sea. One area is located at open sea conditions in the Oki Trough, offshore Kanazawa city, and the other is located in the enclosed bay conditions of the Joetsu Basin, offshore Joetsu city. Using these samples it was possible to differentiate the source of the organic matter in the sediments of Holocene and late Pleistocene time on the basis of δ13Corg and TOC/TN ratios coupled with palynofacies analysis. The Holocene sediments are characterized by high TOC and TN contents, low TOC/TN ratio, and heavier δ13Corg values, which indicate a predominant marine organic matter production, probably due to warming and inflow of warm ocean currents and coastal currents along the East China Sea. These currents carried abundant phytoplankton from the Pacific Ocean as a result of the sea level rise. Occurrence of particulate organic matter shows abundant primary productivity during the Holocene under marine conditions. On the other hand, the LGM sediments are characterized by low TOC and TN contents, high TOC/TN ratio, and lighter δ13Corg signatures, which are characteristic of terrestrial organic matter, probably due to seaward migration of shorelines and strong input of freshwater with terrestrial materials. This terrestrial influence decreased gradually from the LGM to the Holocene because of the sea level rise and consequent increase in the marine organic matter.

Late-Quaternary supply of terrigenous organic matter to the Congo deep-sea fan (ODP site 1075): implications for equatorial African paleoclimate

Late-Quaternary sections (about 1 Ma) from the Congo deep-sea fan (ODP Leg 175, site 1075) were used to reconstruct the terrigenous organic matter supply to the easternmost equatorial Atlantic Ocean. Variations in quantity and quality of the riverine organic matter reflect the interaction between the paleoclimatic development within the continental catchment area and the paleoceanographic conditions in the Congo river plume. To characterize the delivery of organic matter from terrigenous and marine sources, we used elemental and bulk carbon isotopic analyses, Rock-Eval pyrolysis, lignin chemistry, and organic petrology. High-amplitude fluctuations occurring about every 15–25 ka reveal a mainly precessional control on organic sedimentation. Results from Rock-Eval pyrolysis indicate a mixed kerogen type III/II, as would be anticipated in front of a major river. Fluctuations in Tmax from Rock-Eval pyrolysis demonstrate pronounced cyclic changes in the delivery of low- and high-mature organic matter. Contribution of the low-mature organic fraction was strongest during warm climates supporting enhanced marine production offshore of the Congo. Organic petrological observations confirm the existence of abundant terrigenous plant tissues, both non-oxidized (vitrinite) and oxidized (inertinite). Charcoal-like organic matter (fusinite) is attributed to periods of increased bush fires in the continental hinterland, and implies more arid climatic conditions. Results from ratios of specific phenolic lignin components suggest that terrigenous organic matter in Late-Quaternary sections of site 1075 mainly derives from non-woody angiosperm tissue, i.e., grasses and leaves. Correlation between the amount of specific lignin phenols and the bulk δ13Corg signature fosters the conclusion that an appreciable amount of the terrigenous organic fraction derives from C4 plant matter. This may cause an underestimation of the terrigenous proportion of bulk organic matter when assessments are based on bulk carbon isotopic signatures alone.