Cycling Performance Research Articles

Algae‐Derived Precursors for Sustainable Electrochemical Energy Storage

The simple production and harvesting of algae, along with its lower environmental impact and fewer geopolitical issues, make it a viable precursor for electrochemical energy storage devices. Algae represent a promising biomaterial for electrode materials in electrochemical energy storage devices, including hard carbon, sol–gel‐based anode batteries, sodium batteries, oxygen reduction reaction catalysts in zinc–air batteries, and cathode materials in zinc‐ion and lithium‐ion batteries. Algae‐based batteries are fabricated using methods like pyrolysis, hydrothermal processes, agar‐aided dissolution, electrolysis, annealing, and sol–gel methods. Among these, the sol–gel method using agar to construct refillable hydrogel batteries stands out. Agar's compatibility with acetylene black enhances electrochemical properties and offers the advantage of refill ability, which is challenging in metal‐ion batteries. Algae carbons have demonstrated enhanced specific capacity and cyclic performance, paving the way for their use in both medical and industrial applications. The article reviews the utilization of algae‐based batteries in different industrial and medical pacemaker applications as well as examines the feasibility of the operation of algae‐based batteries synthesized through various parameters and precursors.

Menstrual cycle performance barriers experienced by elite women football players and their management strategies applied: A semi-structured interview-based study

ABSTRACT The objective of this study was to investigate the barriers experienced by elite women football players due to their menstrual cycle, and coping strategies utilised against these barriers. Fifteen elite women footballers from two English Women’s Super League clubs (age: 25.2 years [18–33]) were interviewed using semi-structured interviews, developed using piloting and peer review. Data was audio recorded, transcribed verbatim and analysed thematically using NVivo. Analysis of 27,438 words unveiled key themes: internal barriers, external barriers, coping strategies, and player needs. Fear of leakage, associated with kit colour (n = 15) and lack of effective sanitary products (n = 12), and injury anxiety (n = 7), associated with ACL injury (n = 5), were the most common barriers. To combat these issues, players use internal (feeling fortunate n = 9) and external (support from teammates n = 6; support from club staff n = 4) coping strategies. The findings indicated that menstruation presents significant barriers to players. Increased awareness of menstruation-related barriers to performance and targeted intervention are achievable through staff and player involvement and by minimising concerns of visible leakage by kit interventions.

Polar Molecule Intercalation to Weaken P2─S Bonding in MnPS3 Toward Ultrahigh-Capacity Sodium Storage.

Layered transition metal trithiophosphates (TMPS3, TM = Mn, Fe, Co, etc.) with high theoretical capacity (>1300 mAh g-1) are potential anode materials for sodium-ion batteries (SIBs). However, the strong bonding between P2 dimers and S atoms in TMPS3 hinders the efficient alloying reaction between P2 dimers and Na+, resulting in practical capacities much lower than theoretical values. Herein, a polar molecule diisopropylamine (DIPA) is intercalated into MnPS3 for the first time to improve the sodium storage performance effectively. Theoretical calculations show that the electron transfer between DIPA and MnPS3 induces more delocalized S p states and weaker P─S bonds, significantly enhancing the electrochemical activity and sodiation/desodiation reaction kinetics. Moreover, the expanded interlayer spacing from 6.48 to 10.75 Å enables faster Na+ diffusion and more active sites for Na+ adsorption. As expected, the DIPA-MnPS3 exhibits an ultrahigh capacity of 1,023 mAh g-1 at 0.2 A g-1 and excellent cycling performance (≈100% capacity retention after 4200 cycles at 10 A g-1), far outperforming those metal thiophosphates anodes reported for SIBs. Interestingly, in situ and ex situ characterizations reveal a quasi-topological intercalation mechanism of DIPA-MnPS3. This work provides a novel strategy for the design of high-performance anode materials for SIBs.

Engineering Triple-Phase Interfaces with Hierarchical Carbon Nanocages for High-Areal-Capacity All-Solid-State Li-S Batteries.

All-solid-state lithium-sulfur batteries (ASSLSBs) have garnered widespread attention due to their advantages of high energy density and enhanced safety. However, the typical composite structure composed of solid-state electrolyte (SE), discrete conducting carbon black, and microsized sulfur (μ-S) with long-range Li+/e- conducting path and huge volume changes, suffers from sluggish charge transport and severe electrochemical-mechanical failure. In this work, a unique hierarchical carbon nanocage (hCNC) is applied as a continuous conducting network where nanosized sulfur are confined. Due to the synergistic effects of multi-dimensional (particle, interface, and electrode) structural engineering, this new sulfur-carbon composite cathode (S@hCNC39) can achieve uniform distribution of sulfur and carbon, and efficiently constructs triple-phase interfaces, showing enhanced charge-carrier transport and improved electrochemical-mechanical stability. Remarkable cycling performance of 89% after 300 cycles at 0.2C at 30°C is realized in ASSLSBs assembled with S@hCNC39. Notably, ASSLSBs achieve an ultrahigh areal capacity of 9.95 mAh cm-2 with stable cycling at 60°C with high sulfur contents of 40% and high sulfur loadings of 6mg cm-2. These results provide critical insights into the design of rational sulfur-carbon composites and offer a viable approach to enhance the overall performance of ASSLSBs.

Nucleophilic Sn Seeding and Interface Engineering for Highly Stable Sodium Metal Batteries.

Sodium metal is a promising anode material for energy storage beyond lithium-ion batteries due to its abundance and low cost. However, the uncontrolled growth of dendrites and associated safety concerns have limited the practical application of sodium metal batteries (SMBs). By embedding nucleophilic tin seeds in a free-standing carbon film (FSF), here, an effective solution is developed to stabilize the sodium metal anode. The highly conductive and porous carbon matrix, intimately embedded with abundant Sn seeds (C@Sn), enables remarkably uniform sodium plating, and provides long-term stability for SMBs. Mechanistic studies confirm the formation of an Na─Sn alloy on interface which helps to lower the nucleation barrier for sodium plating. Hence, symmetric sodium cells equipped with C@Sn FSFs can sustain uninterrupted sodium plating and stripping for almost 2600h at a high areal capacity of 4mAhcm-2, achieving an average Coulombic efficiency (CE) of 99.88%. In addition, full cells prepared with commercial Na3V2(PO4)3 cathode and C@Sn-FSFs anode deliver remarkable cycling (90mAhg-1 beyond 1300 cycles at 1C) and excellent rate performance. This ingenious strategy of embedding Sn particles within a carbon matrix offers an overall compelling solution to enhance the longevity of sodium anodes.

Enhancing High‐Voltage LNMO Cathode Performance in Li‐Metal Batteries Via Anionic Electrolyte Additive‐Integrated CEI Engineering

AbstractAn anionic‐additive electrolyte system is introduced by incorporating Lithium tetrafluoroborate (LiBF4) into a conventional base electrolyte for high‐voltage LiNi₀.₅Mn₁.₅O₄ (LNMO) cathodes in lithium‐metal batteries. At high voltages, the sacrificial oxidation of LiBF4 mitigates electrolyte degradation and forms a robust cathode electrolyte interface (CEI) enriched with boron and fluorine‐based components, which protects against active material corrosion. Density Functional Theory (DFT) studies reveal that BF₄⁻ is more readily oxidized, while MD simulations validate the CEI's inorganic composition. Initial cycling with a specialized charge‐discharge protocol ensures optimal use of the additive, resulting in a uniform, thin (4–6 nm) CEI on the LNMO cathode. The CEI formed in anionic‐additive electrolyte system effectively suppresses transition metal dissolution and surface degradation, enhancing long‐term cycling performance. The LiBF4‐enhanced electrolyte also lowers overpotential and promotes more uniform Li deposition compared to the base electrolyte. At a 1 C‐rate, the LNMO cathode with a Li metal anode and optimized electrolyte achieves a discharge capacity of 115 mA h g⁻¹ and an energy density of 540 Wh kg⁻¹ over 500 cycles. These findings underscore LiBF4’s dual role in protecting LNMO cathodes and Li metal anodes, highlighting the critical role of additives in CEI development for advanced lithium‐metal batteries.

Rice-pigeon pea biochar influences nutrient cycling, microbial dynamics, and onion performance in organic production system: insights from Alfisols of the Eastern Plateau and Hill Region of India

Rice-pigeon pea biochar influences nutrient cycling, microbial dynamics, and onion performance in organic production system: insights from Alfisols of the Eastern Plateau and Hill Region of India

Crystalline Electrolyte Boosts High Performance of All-Solid-State Lithium-Ion Batteries.

The rigid solid-solid contact at the interface between the solid electrolyte and electrodes in full-solid-state lithium-ion batteries (ASSBs) presents a considerable challenge to lithium ion transport. To address this, we propose using Li-concentrated succinonitrile (Li-SN45) as an efficient bilateral interface modifier in ASSBs. This material boasts exceptional ionic conductivity of 3.38 mS cm-1 and excellent corrosion resistance to the Li metal anode. The assembled ASSBs using layered cathodes and Li metal demonstrate outstanding discharge capacity (170 mAh g-1 @ 20 mA g-1) and superior long-term cycling performance (97% capacity retention after 100 cycles). MALDI-TOF results suggest the formation of a crystalline structure in Li-SN45, which facilitates smooth "anion-free" Li+ hopping paths assisted by the oxygen atoms, as revealed by the solved crystal structure. Our findings enriched the understanding of Li transport dynamics in electrolytes of ASSBs, paving the way to designing superior next-generation ASSBs with fast Li transport.

Ferrocene‐Based Nickel Metal–Organic Framework Nanosheets as Efficient, Long‐Cycle Cathode Catalyst for Li‐CO2 Battery

AbstractLi‐CO2 batteries, as a novel type of secondary battery, show great potential for energy conversion and storage. However, challenges such as large electrode polarization and poor cycling performance, stemming from difficulties in decomposing discharge products, limit their practical application. Here, Ferrocene‐based nickel metal–organic framework (Ni‐Fc) nanosheets structure to act as cathode catalysts, prepared via a one‐pot solvothermal reaction. X‐ray absorption fine structure (XAFS) analysis shows that Ni metal forms abundant catalytic active centers with O coordination of carboxylic acid groups in ferrocene units. The Ni‐Fc‐based battery demonstrates a high discharge capacity of 18636 mAh g−1 and exhibits a cycle life exceeding 2000 h at a current of 200 mA g−1. Density functional theory (DFT) calculations indicate that the stronger interaction of Ni‐Fc with discharge intermediates and enhanced Li adsorption accelerate battery reaction kinetics. This study introduces novel catalyst design concepts aimed at achieving high‐performance CO2 reduction and oxidation, thereby advancing Li‐CO2 batteries toward practical application.

Remarkably Boosted High‐Temperature Electrostatic Energy Storage of Polyetherimide Film Induced by TiO2@Au@AlOx@Au Core‐shell Nanofibers

AbstractPolymer dielectrics have broad applications in advanced electronics and power systems. However, they suffer from low energy density and poor breakdown performance at high temperatures, limiting their applications in high‐temperature environments. Herein, TiO2@Au@AlOx@Au nanofibers with double coulomb blockade nanolayers are obtained via a physical sputtering strategy to improve the high‐temperature energy storage performance of polyetherimide composites. Experimental studies and finite elemenet phase‐field simulations demonstrate that the double‐layer coulomb blockade effect and micro‐capacitor effect of Au nanoparticles synergistically enhance the breakdown strength and dielectric permittivity of polyetherimide composite at high temperatures. Notably, the composite exhibits ultra‐high discharged energy densities of 11.33 and 9.70 J cm−3 at 150 and 200 °C, respectively, along with high charge–discharge efficiencies of 93.4% and 84%, which far exceed that of the polymer nanocomposites reported so far. Furthermore, the composite exhibits excellent charge–discharge cycling performance (>50000 cycles at 400 MV m−1) and high‐power density (1.16 MW cm−3) at 200 °C, making it an ideal candidate for high‐temperature capacitors. Hopefully, these nanofibers not only serve as excellent nanofillers for high‐temperature energy storage dielectric composites but also holds tremendous potential and inspirational significance for other applications such as electronics, biomedical fields, optics, and catalysis.

ZnxMnO2/PPy Nanowires Composite as Cathode Material for Aqueous Zinc‐Ion Hybrid Supercapacitors

ABSTRACTOver the past decade, the extensive consumption of finite energy resources has caused severe environmental pollution. Meanwhile, the promotion of renewable energy sources is limited by their intermittent and regional nature. Thus, developing effective energy storage and conversion technologies and devices holds considerable importance. Zinc‐ion hybrid supercapacitors (ZISCs) merge the beneficial aspects of both supercapacitors and batteries, rendering them an exceptionally promising energy storage method. As an important cathode material for ZISCs, the tunnel structure MnO2 has poor conductivity and structural stability. Herein, the ZnxMnO2/PPy (ZMOP) electrode materials are prepared by hydrothermal method. Doping with Zn2+ is used to enhance its structural stability, while adding polypyrrole to improve its conductivity. Therefore, the fabricated ZMOP cathode presents superb specific capacity (0.1 A g−1, 156.4 mAh g−1) and remarkable cycle performance (82.6%, 5000 cycles, 0.2 A g−1). Furthermore, the assembled aqueous ZISCs with ZMOP cathode and PPy‐derived porous carbon nanotube anode obtain a superb capacity of 109 F g−1 at 0.1 A g−1. Meanwhile, at a power density of 867 W kg−1, the corresponding energy density can achieve 20 Wh kg−1. And over 5000 cycles at 0.2 A g−1, the cycle performance of ZISCs maintains at 86.4%, which exhibits excellent cycle stability. This suggests that ZMOP nanowires are potential cathode materials for superior‐performance aqueous ZISCs.

Synergistic effect of molybdenum dioxide wrapped nitrogen doped carbon nanotubes in binder-free anodes for enhanced lithium storage properties

Molybdenum dioxide (MoO2) is regarded as a potential anode for lithium-ion batteries due to its highly theoretical specific capacity. However, its further application in lithium-ion battery is largely limited by insufficient practical discharge capacity and cyclic performance. Here, MoO2nanoparticles are in-situ grown on three-dimensional nitrogen doped carbon nanotubes (NCNTs) on nickel foam substrate homogeneously using a simple electro-deposition method. The unique structural features are favorable for lithium ions insertion and extraction and charge transfer dynamics at electrode/electrolyte interface. As a proof of concept, the as-synthesized nanocomposites have been employed as anode for lithium-ion battery, exhibiting a reversible and significantly improved discharge capacity of ∼517 mA h g-1at the current density of 150 mA g-1as well as superior cycle and rate performance. The first-principle calculations based on density functional theory and electrochemical impedance spectroscopy results demonstrate a reduced energy barrier of lithium ions diffusion, improved lithium storage behavior, reduced structure collapse, and significantly enhanced charge transfer kinetics in MoO2/NCNTs nanocomposites with respect to MoO2powder. The excellent performance makes as-prepared MoO2/NCNTs nanocomposites promising binder-free anode for high performance lithium-ion batteries. This work also provides important theoretical insights for other state-of-the-art batteries design.

Inhomogeneous Coordination in High‐Entropy O3‐Type Cathodes Enables Suppressed Slab Gliding and Durable Sodium Storage

AbstractO3‐type layered oxides are highly promising cathodes for sodium‐ion batteries (SIBs), however they undergo complex phase transitions and exhibit high sensibility to air, leading to subpar cycling performance and commercial viability. In this work, we report a layered cathode material (NaNi0.29Cu0.1Mg0.05Li0.05Mn0.2Ti0.2Sn0.11O2) with a sate‐of‐the‐art high‐entropy compositional design. We unveil that such a configuration featuring inhomogeneous coordination environment of transition metal (TM) elements, can enable enhanced gliding energy (−0.38 vs −0.58 eV) of TMO2 slabs upon desodiation both theoretically and experimentally, which underlies the fundamental origin of the outstanding structural stability of HEO materials. As a consequence, the complex phase transitions (O3−O′3−P3−P′3−P3′−O3′) of conventional O3‐type cathode have been eliminated, and the as‐obtained material demonstrates exceptional structural robustness and integrity with an ultra‐long cycle life in a quasi‐solid‐state cell (maintaining 73.2 % capacity after 1000 cycles at 2 C). Moreover, the material presents satisfactory air stability, with minimal structural and electrochemical degradation when directly exposed to the air. An Ah‐scale pouch cell based on the cathode material is constructed, demonstrating a capacity retention of 83.6 % after 500 cycles, signaling substantial promise for commercial applications.

Inhomogeneous Coordination in High-Entropy O3-Type Cathodes Enables Suppressed Slab Gliding and Durable Sodium Storage.

O3-type layered oxides are highly promising cathodes for sodium-ion batteries (SIBs), however they undergo complex phase transitions and exhibit high sensibility to air, leading to subpar cycling performance and commercial viability. In this work, we report a layered cathode material (NaNi0.29Cu0.1Mg0.05Li0.05Mn0.2Ti0.2Sn0.11O2) with a sate-of-the-art high-entropy compositional design. We unveil that such a configuration featuring inhomogeneous coordination environment of transition metal (TM) elements, can enable enhanced gliding energy (-0.38 vs -0.58 eV) of TMO2 slabs upon desodiation both theoretically and experimentally, which underlies the fundamental origin of the outstanding structural stability of HEO materials. As a consequence, the complex phase transitions (O3-O'3-P3-P'3-P3'-O3') of conventional O3-type cathode have been eliminated, and the as-obtained material demonstrates exceptional structural robustness and integrity with an ultra-long cycle life in a quasi-solid-state cell (maintaining 73.2 % capacity after 1000 cycles at 2 C). Moreover, the material presents satisfactory air stability, with minimal structural and electrochemical degradation when directly exposed to the air. An Ah-scale pouch cell based on the cathode material is constructed, demonstrating a capacity retention of 83.6 % after 500 cycles, signaling substantial promise for commercial applications.

Strength Training Among Male Master Cyclists—Practices, Challenges, and Rationales

Background: Cycling performance declines with age due to reduced aerobic capacity, along with reductions in muscle mass and bone density. Strength training can help counter these effects. This study aims to explore the strength training practices, challenges, and decision-making rationale of male master cyclists to optimize performance and health as they age. Methods: A total of 555 male master cyclists aged 35 and above completed an online questionnaire, distributed via social media platforms, that included Likert-type, single- and multiple-selection, and open-ended questions. Participants were then divided into two age groups: 35–49 years (n = 359) and ≥50 years (n = 196). Analyses involved descriptive statistics, Wilcoxon signed-rank tests, Mann–Whitney U-tests, and chi-square tests, with qualitative data analyzed using content analysis. Results: More cyclists engaged in strength training during the off-/pre-season, with a significant reduction in both frequency and the number of cyclists engaging in strength training during the race season. The strength training practice was focused mainly on core and lower body, employing hypertrophy and maximal strength training methods. Key challenges included fatigue induced by strength training and limited time to perform strength training. The main rationale for the strength training revolved around improving cycling performance, reducing injury risk, and the health benefits of strength training. Both age categories, but the older group in particular, reported bone health as a primary rationale for strength training. Conclusions: While strength training offers performance and health benefits, issues of fatigue and time constraints remain substantial, suggesting the need for tailored training programs to improve adherence and effectiveness.

Electrolyte Design via Cation-Anion Association Regulation for High-Rate and Dendrite-Free Zinc Metal Batteries at Low Temperature.

Low-temperature zinc metal batteries (ZMBs) are highly challenged by Zn dendrite growth, especially at high current density. Here, starting from the intermolecular insights, we report a cation-anion association modulation strategy by matching different dielectric constant solvents and unveil the relationship between cation-anion association strength and Zn plating/stripping performance at low temperatures. The combination of comprehensive characterizations and theoretical calculations indicates that moderate ion association electrolytes with high ionic conductivity (12.09 mS cm-1 at -40 °C) and a stable anion-derived solid electrolyte interphase (SEI) jointly account for highly reversible and dendrite-free Zn plating/stripping behavior, resulting in high-rate and ultrastable cycle performance at low temperature. As a result, at -40 °C, Zn//Zn cells can stably cycle over 400 h at 5 mA cm-2 and 10 mAh cm-2 and Zn//Cu cells exhibit an exceptional average Coulombic efficiency (CE) of 99.91% for 1800 cycles at 1 mA cm-2 and 1 mAh cm-2. Benefiting from enhanced low-temperature Zn plating/stripping performance, Zn//PANI full cells stably operate for 12,000 cycles at 0.5A g-1 and 35,000 cycles at 5 A g-1. Impressively, at -60 °C, Zn//Cu cells still display a high average CE of 99.68% for 2000 cycles. This work underscores the crucial effect of cation-anion association regulation for high-rate and dendrite-free Zn metal anodes, deepening the understanding of intermolecular interaction insights for low-temperature electrolyte design.

Phosphorylated Covalent Organic Framework Membranes Toward Ultrafast Single Lithium-Ion Transport.

Developing all-solid-state electrolytes, the chips for lithium-metal batteries, with superior electrochemical and mechanical properties awaitsthe disruptive materials. Herein, ionic covalent organic framework membranes are explored as solid-state electrolytes for single Li+ conduction. In the membrane, the anion groups act as Li+ transporter, determining Li+ binding capacity and releasing ability, whereas the oxygen-containing groups act as Li+ co-transporter, creating relay sites between adjacent Li+ transporters for rapid hopping. The membrane exhibits an unprecedented Li+ conductivity of 1.7 mS cm-1 with a Li+-transference number close to unity at room temperature. Additionally, the membrane possesses high flexibility, low interfacial resistance, and excellent cycling performance at room temperature. This work paves an unprecedented path for the advancement of next-generation Li+ conductors in solid-state electrolytes.

Redox-Bipolar Covalent Organic Framework Cathode for Advanced Sodium-Organic Batteries.

Redox-active covalent organic frameworks (COFs) are promising candidates for sodium-ion batteries (SIBs). However, the construction of redox-bipolar COFs with the anions and cations co-storage feature for SIBs is rarely reported. Herein, redox-bipolar COF constructed from aniline-fused quinonoid units (TPAD-COF)is developed as the cathode material in SIBs for the first time. The unique integration of conductive aniline skeletons and quinone redox centers endows TPAD-COF with high ionic/electrical conductivity, abundant redox-active sites, and fascinating bipolar features. Consequently, the elaborately tailored TPAD-COF cathode exhibits higher specific capacity (186.4mAhg-1 at 0.05Ag-1) and superior cycling performance (over 2000 cycles at 1.0Ag-1 with 0.015% decay rate per cycle). Impressively, TPAD-COF also displays a high specific capacity of 101mAhg-1 even at -20°C. As a proof of concept, all-organic SIBs (AOSIBs) are assembled using TPAD-COF cathode and disodium terephthalate anode, which also show impressive electrochemical properties, indicating the potential application of TPAD-COF cathode in AOSIBs. The work will pave the avenue toward advanced COFs cathode for rechargeable batteries through rational molecular design.

Basics and Advances of Manganese-Based Cathode Materials for Aqueous Zinc-Ion Batteries.

It is greatly crucial to develop low-cost energy storage candidates with high safety and stability to replace alkali metal systems for a sustainable future. Recently, aqueous zinc-ion batteries (ZIBs) have received tremendous interest owing to their low cost, high safety, wide oxidation states, and sophisticated fabrication process. Nanostructured manganese (Mn)-based oxides in different polymorphs are the potential cathode materials for the widespread application of ZIBs. However, Mn-based oxide materials suffer from several drawbacks, such as low electronic/ionic conductivity and poor cycling performance. To overcome these issues, various structural modification strategies have been adopted to enhance their electrochemical activity, including phase/defect engineering, doping with foreign atoms (e.g., metal and/or nonmetal atoms), and coupling with carbon materials or conducting polymers. Herein, this review targets to summarize the advantages and disadvantages of the above-mentioned strategies to improve the electrochemical performance of the cathodic part of ZIBs. The challenges and suggestions for the development of manganese oxides for ZIBs are put forward.

An Ultrafast and Ultralow‐Temperature 3D‐Printed All‐Organic Proton Pseudocapacitor

AbstractA critical challenge for pseudocapacitors applications is the rapid capacitance fading under extreme environments, which originates from sluggish diffusion kinetics of inorganic materials and tortuous ionic channels in conventional bulk electrodes. Herein, a novel 3D‐printed all‐organic proton pseudocapacitor (composed of 2,6‐diaminoanthraquinone (DQ)‐based anode and polyaniline‐based cathode) with chemical and structural stability is developed, which exhibits an extraordinary rate performance and cycle stability under ultralow temperature. The DQ molecules are anchored on reduced graphene oxide, which enhances the electronic conductivity and structural stability. Theoretical calculation and spectroscopic characterization reveal that the two‐electron transfer process involves quinone/hydroquinone transition. Exploiting the synergy of fast reaction kinetics of organic and the efficient ion diffusion paths of the 3D architecture, the 3D‐printed anode achieves an impressive areal capacitance of 10.14 F cm−2 at high mass loading (28.73 mg cm−2). The 3D‐printed all‐organic proton pseudocapacitor shows stable cycling performance at −80 °C and releases a high energy density of 0.76 mWh cm−2 at −60 °C. This work is instructive for the development of competitive ultra‐low temperature energy storage devices via integrating organic materials and 3D architectural electrode designs.