Abstract In the present work, the Fischer–Tropsch synthesis (FTS) is carried out through simulation. This reaction uses a gas mixture, called synthesis gas, composed of carbon monoxide rich in hydrogen (H2/CO > 2.5), to form medium and long chain hydrocarbons (C5 +). For the modeling of this system, a packed bed reactor with a cobalt-based catalyst has been considered, which promotes the polymerization of methylene species, selective to linear paraffins and 1-olefins. The objective of this work is evaluating the impact of operation variables, such as feed flows and temperature, coolant flow, system pressure, on the chain length distribution of the products. Current operating policies does not promote selectivity to the production of synthetic gasolines (C5–C12), because of the drastic increase in the temperature inside the reactor as consequence of the high exothermicity of the reactions (ΔH = −170 kJ mol−1). It has been impossible to maintain these reactions within the appropriate temperature range (475–520 K) without the presence of an external agent that manages the available heat, for this project molten sales have been proposed as a cooling medium (KNO3–NaNO3), based on its favorable heat transfer characteristics. By analyzing the system responses, the open loop model has allowed us to explore multiple hydrocarbon production scenarios, specifically highlighting the increasing of the yield of synthetic gasoline (48 wt%) in the products, from a defined molten salts (coolant) countercurrent flow range (7.05E-2 at 2.50E-1 m/h). It was noticed that this heat management allowed us to obtain a specific range of hydrocarbons, representing the opportunity to control the growth of the chain length. In conclusion, this analysis will lay the foundations for the design control policies, which help to increase current yields of synthetic gasoline, making it possible to achieve the desired quality for the immediate future.
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