SummaryIn the context of Reconfigurable Intelligent Surface (RIS) assisted millimeter wave communications within the Multiple Input Multiple Output (MIMO) system, Channel Estimation (CE) poses a significant challenge due to signal sparsity and blockages between transmitters and receivers. Consequently, communication faces difficulties without a direct line‐of‐sight path, leading to increased pilot overhead. To address these obstacles, this research introduces a channel estimation approach for RIS‐aided millimeter wave communication employing the Multidimensional Runge Kutta Orthogonal Matching Pursuit (MRKOMP) algorithm in MIMO systems. The proposed method aims to enhance network coverage and channel capacity for efficient data transmission. By utilizing the multiscale cumulative residual distribution entropy function, the method establishes an indirect path when the line‐of‐sight is obstructed. Furthermore, the multidimensional orthogonal matching pursuit methodology calculates sparsity levels and facilitates sparse recovery. Optimization of the weight parameter through the Runge Kutta optimizer effectively eliminates sparsity, resulting in improved spectral efficiency and RIS gain. Simulation results demonstrate a significant 99.9% enhancement in network capacity and spectral efficiency compared to existing methods.