Epidote Crystals Research Articles

The mineral diversity of the Urdini Lakes and the glacial valley of the Urdina River (Rila Mountain) – an overview

An overview of different types of mineralization in the area of the Urdini Lakes and the glacial valley of the Urdina River (northwestern Rila Mountain) has been made. Currently, it is the only protected area for minerals in Bulgaria. In this area, mainly pegmatite, but also skarn and alpine-type mineralizations, have been found to date. Of particular interest are the hybrid desilicified type pegmatites containing emerald, aquamarine and chrysoberyl crystals and the extremely rare native aluminum. The skarn mineralizations from this area are characterized by wollastonite, diopside, garnet (grossular, andradite), zoisite, clinozoisite, scapolite, vesuvianite and others. In the alpine-type mineralizations, well-formed crystals of quartz, adular, epidote and pyrite, as well as nests of almandine with albite, were observed as recrystallization of the minerals previously formed in the cavities of the host rocks. These cavities may also occasionally contain zeolites.

Identification of Fe3+ content in Epidote from Varan, Urumieh-Dokhtar Magmatic Arc, Iran: using FTIR and Raman spectroscopy

This study is aimed to determine the Fe content in natural epidote from Varan area (Urumieh-Dokhtar Magmatic Arc, Iran) by using vibrational FTIR and Raman spectroscopy and EPMA analyses. Fe3+ concentration calculated from FTIR spectroscopic data is in the range of 0.96 to 1 apfu. The results are in complete agreement with EPMA data. The comparison between obtained Raman spectra of studied epidote grains and those from the RRUFF database suggest that epidote from Varan area is rich in Fe3+. High Fe3+ content might reflect moderate to high oxygen fugacity during the crystallization of epidote. This short paper demonstrates that the quantification of the Fe content in epidote via FTIR method is as good as EPMA, whereas the utilization of a low-cost Raman spectrometer helps in quickly distinguishing between Fe-rich and Fe-poor epidote, which even could be useful in the case of field studies.spectrometer helps in quickly distinguishing between Fe-rich and Fe-poor epidote, which even could be useful in the case of field studies.Key-words: Epidote, FTIR, Raman spectroscopy, Iron content, Urumieh-Dokhtar Magmatic Arc, Iran.

U − Pb geochronology of epidote by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) as a tool for dating hydrothermal-vein formation

Abstract. Epidote – here defined as minerals belonging to the epidote–clinozoisite solid solution – is a low-μ (μ=238U/204Pb) mineral occurring in a variety of geological environments and participating in many metamorphic reactions that is stable throughout a wide range of pressure–temperature conditions. Despite containing fair amounts of U, its use as a U−Pb geochronometer has been hindered by the commonly high contents of initial Pb, with isotopic compositions that cannot be assumed a priori. We present a U−Pb geochronology of hydrothermal-vein epidote spanning a wide range of Pb (3.9–190 µg g−1), Th (0.01–38 µg g−1), and U (2.6–530 µg g−1) contents and with μ values between 7 and 510 from the Albula area (eastern Swiss Alps), from the Grimsel area (central Swiss Alps), and from the Heyuan fault (Guangdong Province, China). The investigated epidote samples show appreciable fractions of initial Pb contents (f206=0.7–1.0) – i.e., relative to radiogenic Pb – that vary to different extents. A protocol has been developed for in situ U−Pb dating of epidote by spot-analysis laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) with a magmatic allanite as the primary reference material. The suitability of the protocol and the reliability of the measured isotopic ratios have been ascertained by independent measurements of 238U/206Pb and 207Pb/206Pb ratios, respectively, with quadrupole and multicollector ICP-MS applied to epidote micro-separates digested and diluted in acids. For age calculation, we used the Tera–Wasserburg (207Pb/206Pb versus 238U/206Pb) diagram, which does not require corrections for initial Pb and provides the initial 207Pb/206Pb ratio. Petrographic and microstructural data indicate that the calculated ages date the crystallization of vein epidote from a hydrothermal fluid and that the U−Pb system was not reset to younger ages by later events. Vein epidote from the Albula area formed in the Paleocene (62.7±3.0 Ma) and is related to Alpine greenschist-facies metamorphism. The Miocene (19.2±4.3 and 16.9±3.7 Ma) epidote veins from the Grimsel area formed during the Handegg deformation phase (22–17 Ma) of the Alpine evolution of the Aar Massif. Identical initial 207Pb/206Pb ratios reveal homogeneity in Pb isotopic compositions of the fluid across ca. 100 m. Vein epidote from the Heyuan fault is Cretaceous in age ( 107.2±8.9 Ma) and formed during the early movements of the fault. In situ U−Pb analyses of epidote returned reliable ages of otherwise undatable epidote–quartz veins. The Tera–Wasserburg approach has proven pivotal for in situ U−Pb dating of epidote, and the decisive aspect for low age uncertainties is the variability in intra-sample initial Pb fractions.

Uranium mineralization associated with late magmatic ductile to brittle deformation and Na–Ca metasomatism of the Pan-African A-type Zabili syntectonic pluton (Mayo-Kebbi massif, SW Chad)

The Mayo-Kebbi massif (Chad) exposes a Neoproterozoic juvenile crustal segment that has been tectonically accreted in the Central African Orogenic Belt and reworked during the Pan-African orogeny. It comprises a syntectonic high-K magmatic suite including the Zabili A-type granitic pluton. The Zabili pluton is made of a highly differentiated granite generated by fractional crystallization of a magma formed by partial melting of a Neoproterozoic juvenile protolith. Syn- to post-magmatic ductile to brittle deformation of the Zabili pluton is associated with metasomatism and deposition of uranium. Primary magmatic U-bearing minerals are zircon, monazite, and uranothorite. Late-magmatic deformation and Na-metasomatism are marked by the development of R’ antithetic shear zones with high-temperature dynamic recrystallization of K-feldspar and Ca-plagioclase phenocrysts coeval with crystallization of albite along deformation bands and grain boundaries, and crystallization of interstitial amphibole, calcite epidote and albite also affected by intracrystalline deformation. At this stage, U-bearing minerals are monazite, uraninite, brannerite (pseudomorphosed in ekanite). This late-magmatic event is dated by U–Th–Pb on monazite at 599 ± 4 Ma. Brittle deformation and Ca-metasomatism are marked by cataclastic zones and veins containing albite, epidote, calcite, chlorite, apatite, metamict zircon, pitchblende, U-silicates, and iron oxides. U-bearing minerals are altered and/or remobilized in ekanite, kasolite, and uranophane. These data suggest that the uranium mineralization hosted by the Zabili pluton records a superposition of processes and traces extreme crustal differentiation of a Neoproterozoic juvenile crustal segment reworked during the Pan-African orogeny.

Bohseit z beryl-columbitového pegmatitu D6e v Maršíkově (silezikum, Česká republika)

Bohseite was found in a lenticular body of D6e beryl-columbite granitic pegmatite near Maršíkov, which is hosted by amphibole gneisses of the Sobotín Amphibolite Massif (Silesicum, northeastern part of Czech Republic). Bohseite forms chalky white aggregates up to 1 cm in size, which are hosted by small vugs in the coarse-grained pegmatite. It is associated with small crystals of quartz, adularia, albite, muscovite and epidote. Bohseite is orthorhombic, space group Cmcm with following unit-cell parameters refined from X-ray powder diffraction data: a 23.210(2), b 4.955(2), c 19.428(3) Å and V 2234.5(1.0) Å3. The electron microprobe compositional data of bohseite are presented. Bohseite from Maršíkov contains 14.3 - 42.5 mol. % of bavenite component, up to 0.06 apfu Na and 0.13 - 0.36 apfu F. The association with other beryllium-rich phases (milarite, bertrandite) points to variable activities of Be and Al during hydrothermal stage of evolution of the pegmatite body. The likely source of Be was beryl, which is sometimes completely dissolved and vugs after its crystals are lined by small crystals of above mentioned hydrothermal phases.

Metallotectic Context of the Mineralization of the Tondabo Gold Prospect (Brobo, Center of Côte d’Ivoire, West Africa)

The gold mineralization of the Tondabo prospect, located in the northern part of the Oumé-Toumodi-Fettêkro greenstone belt, is mainly hosted in the rhyodacite and to a lesser extent in the mafic volcanics (volcanic lavas and volcanoclastites). These rocks were affected by a hydrothermal alteration marked by quartz veins and veinlets associated with crystals of carbonates, sericite, epidote and sulfides. This hydrothermal alteration induced a pervasive alteration of the surrounding bodies with silicification, chloritization, carbonation and sericitization of the feldspars. The metalliferous paragenesis contains an abundant pyrite, with rare pyrrhotite and chalcopyrite. This mineralization indicates that the Tondabo gold prospect exhibits lithological control. The mineralized deposits are generally affected by a S1 schistosity oriented mainly N000-010° and minority N040-050° with a general dip of 60°-80°to the West; however with rare N-S orientations with a dip of 60°-80° to the East. The drilling intervals show that the highest gold contents are linked to the quartz-carbonates veins and veinlets, which are located in the highly deformed zones, characterizing local shear zones.

Epidote spherulites and radial euhedral epidote aggregates in a greenschist facies metavolcanic breccia hosting an UHP eclogite in Dabieshan (China): Implication for dynamic metamorphism

AbstractEpidote spherulites are identified in a greenschist facies metavolcanic breccia enclosing a body of coesite-bearing eclogite at Ganghe in the Dabie ultrahigh-pressure metamorphic belt, east-central China. The epidote spherulites are formed by fibrous, radially arranged, and rare earth element (REE)-rich epidote crystals (ΣREE = 0.13–0.36 (or slightly higher) cations per formula unit, cpfu) and interfibrillar REE-poor epidote (ΣREE ≤ 0.10 cpfu). Some of the epidote spherulites are overgrown by radially arranged euhedral epidote crystals, which also form aggregates around preexisting quartz, plagioclase, and/or epidote. The epidote grains in such aggregates display oscillatory zoning, with REE content varying from a negligible amount to about 0.44 cpfu. Epidote also occurs as REE-poor individual euhedral crystals about the radial epidote aggregates or form loose clusters of randomly oriented crystals. Thermodynamic modeling of the mineral assemblages in the plagioclase pseudomorphs and in the matrix shows that they formed at greenschist facies metamorphic conditions (435–515 °C and 5–7 kbar). The epidote spherulites and radial euhedral epidote aggregates, however, do not belong to these assemblages and are non-equilibrium textures. They imply crystal growth under large degrees of supersaturation, with relatively low ratios of the diffusion rate (D) to the crystal growth rate (G). At low D/G ratios, spiky interfaces are favorable for diffusion-controlled growth and the resultant texture is a collection of spikes around a growth center, forming a spherulite. The change of epidote texture from spherulite to radial euhedral crystal aggregate implies a decrease of supersaturation and an increase of D/G, such that the crystal morphology was controlled by its crystallographic structure. The crystallization of the individual epidote grains corresponds to a further drop of supersaturation and a further increase of the D/G ratio, approaching to the equilibrium conditions. Transiently higher P-T conditions are inferred from the spherulite-forming reactions, relative to the P-T estimates for the equilibrium assemblages. The fibrous crystals in the spherulites having relatively large interfacial energies would inevitably adjust their shapes to equilibrium ones with low interfacial energies if the P-T-H2O conditions were maintained for a sufficiently long period of time. The non-equilibrium epidote aggregates likely formed in response to P-T and fluid pulses, possibly related to seismicity.

New data on REE and rare-metal mineralization in pegmatites of the Slyudyanogorsk muscovite deposit in the Southern Urals

The Slyudyangorsk muscovite deposit in the southern Urals was explored and mined in 1926–1957. By the mid-1950s, 104 veins of quartz–feldspar pegmatites including 21 muscovite-bearing veins have been found. Pegmatites with giant black Y-bearing epidote crystals are crosscut by veins with giant muscovite crystals, which, in turn, are intersected by veins of two-mica–quartz–two-feldspar pegmatites with rare-metal and REE mineralization. Microprobe data on compositions of complex Ti–Ta–Nb oxides [fergusonite-(Y), samarskite-(Y), euxenite-(Y), polycrase-(Y), columbite-(Fe), pyrochlore supergroup] are characterized, as well as of uraninite, ilmenorutile, scheelite, Y-bearing epidote, certain sulfides and rock-forming minerals from the Slyudyanogorsk deposit. The morphology and interrelation of minerals indicate that they are the result of crystal growth in cavities rather than of metasomatic replacement of gneisses, as has been suggested earlier. Thus, it is more promising for rare-metal and REE minerals in the Slyudorudnik area to be found in igneous rocks (granitic muscovite–quartz–feldspar pegmatites with the Nb–Ta–Ti–Y–U–W–Mo mineralization) than in metasomatic rocks.

Possible new Ca-REE-Bi phosphate minerals from a tungsten-rich calcsilicate skarn, Sierra Nevada Mountains, California

Scanning electron microscope and electron microprobe analyses of 3 to 15 μm diameter grains present within a garnet-quartz granofels from a tungsten skarn reveal the possible existence of at least two new rare earth element (REE)-bearing phosphate phases: Ca(Ce,La,Bi,Nd) 2 [(P,As)O 4 ] 2 (OH) 2 and Ca(La,Ce,Nd,Pr,Bi) 2 [(P,As)O 4 ] 2 (OH) 2 . The analyzed REEs constitute up to 50 wt% of the phases; bismuth oxide contents range from 4.1 to 16.1 wt%. Structural data has proved impossible to obtain from these tiny grains, presumably due to radiation damage by thorium decay. These potentially new phosphate minerals are present within alteration assemblages of REE-rich epidote crystals, as well as along grain boundaries and cracks cross-cutting the quartz-garnet host rock. Association with the zeolite brewsterite-Ba suggests that these hydroxyl phosphates formed during water-rich, low-temperature, retrograde mineralization in the skarn environment.

Natural radioactivity distribution and gamma radiation exposure of beach sands from Sithonia Peninsula

Abstract This study aims to evaluate the activity concentrations of 238U, 226Ra, 232Th, 228Th and 40K along the beaches of Sithonia Peninsula which are adjacent to the rock-types of the Sithonia Plutonic Complex. These range from 6–673, 5–767, 5–1750, 6–1760 and 185–875 Bq/kg respectively. The (% wt.) heavy magnetic (HM) fraction (epidote, allanite, hornblende, biotite and garnet), the heavy non-magnetic (HNM) fraction (monazite, zircon, titanite and apatite) and the total heavy (TH) fraction, were correlated with the concentrations of the measured radionuclides in the bulk samples. The HNM fraction seems to control the activity concentrations of 238U in all samples, while the HM fraction, at least for the heavy mineral rich samples bearing high amounts of epidote crystals with allanite cores, controls their 232Th content. The measured radionuclides in beach sands were normalized to the respective values measured in the granitic rocks, which are their most probable parent rocks, in order to provide data on their enrichment or depletion. The annual effective dose varies from 0.013 to 0.688 mSv y−1 for local people working on the beach, while for tourists the annual external effective dose ranges between 0.003 and 0.165 mSv y−1.

In situ Sr isotopic analyses of epidote: tracing the sources of multi-stage fluids in ultrahigh-pressure eclogite (Ganghe, Dabie terrane)

This study presents in situ strontium (Sr) isotope and Sr content data on multi-stage epidote crystals from ultrahigh-pressure (UHP) eclogites and omphacite–epidote veins therein at Ganghe (Dabie terrane, China), determined using LA-MC-ICP-MS. The Ganghe eclogites occur as lenses in mainly leucocratic UHP gneisses, and therefore, our data provide insights into the origin, composition, and transport scale of the discrete multi-stage fluids in UHP eclogites during the subduction and exhumation of a continental crust. Four textural types of epidote that record compositional and isotopic signatures of fluid at various metamorphic P–T conditions have been distinguished based on petrographic observations and compositional analyses. They are (1) fine-grained high-pressure (HP) epidote inclusions (Ep-In) in omphacite that define the earliest stage of epidote formation in the eclogite; (2) coarse-grained UHP epidote porphyroblasts (Ep-P) that contain omphacite with Ep-In inclusions in the eclogite; (3) fine-grained HP epidote in omphacite–epidote veins (Ep-V) as well as (4) the latest-stage epidote in disseminated amphibolite-facies veinlets (Ep-A), which crosscut the Ep-P or matrix minerals in the eclogite and HP vein. Both Ep-P and Ep-V crystals exhibit significant and complex chemical zonations with respect to the XFe (= Fe/(Fe + Al)) ratio and Sr content. In contrast to the varying Sr contents, Ep-In, Ep-P, and Ep-V have similar and narrow ranges of initial 87Sr/86Sr ratios (from 0.70692 to 0.70720 for Ep-In, from 0.70698 to 0.70721 for Ep-P, and from 0.70668 to 0.70723 for Ep-V), which are significantly different from those in Ep-A (from 0.70894 to 0.71172). The initial 87Sr/86Sr ratio of Ep-A is closer in value to the initial Sr isotopic composition of the gneisses (from 0.710790 to 0.712069) which enclose the UHP eclogite. These data indicate different sources of the eclogite-facies fluids and retrograde amphibolite-facies fluid in the Ganghe eclogites. The HP–UHP fluids responsible for the large amounts of hydrous minerals in the eclogites were internally derived and buffered. The omphacite–epidote veins were precipitated from the channelized solute-rich HP–UHP fluids released from the host eclogite. However, hydrated amphibolite-facies metamorphism during exhumation was mainly initiated by the low-Sr and high-87Sr/86Sr external fluid, which infiltrated into the eclogite from the surrounding gneisses. The eclogite-facies fluids in the Ganghe eclogites were locally derived, whereas the infiltration of the retrograde amphibolite-facies fluid from the gneisses required a long transport, most likely longer than 80 m. This study highlights that the in situ Sr isotopic analysis of multi-stage epidote can be employed as a powerful geochemical tracer to provide key information regarding the origin and behavior of various-stage subduction-zone metamorphic fluids.

Multiple growth mechanisms of jadeite in Cuban metabasite

Samples of rocks reported in the literature to be jadeite jade from the subduction-zone complex of the Escambray Massif in central Cuba have been studied by optical and transmission electron microscopy, electron microprobe and hot-cathode cathodoluminescence (CL) microscopy. Although these rocks are indeed rich in jadeite, the bulk rock composition generally conforms to MORB, with Na2O enriched by . 3 wt% and CaO depleted by .2 wt%. Al2O3 contents are unchanged. These changes are attributed to early pre-subduction spilitization of the ocean-floor protolith. Relics of magmatic augite preserving an ophitic texture are common. Disequilibrium textures are the rule. Extensively recrystallized rocks show fine, felty intergrowths of predominantly Al-rich glaucophane and jadeite, the latter with rims and patches of omphacite. TEM observations indicate extensive replacement of pyroxene by amphibole. Glaucophane developed rims of magnesiokatophorite and edenite. Chlorite and epidote are also present. Late development of actinolite, chlorite, epidote and albite is observed. Quartz is present. Less recrystallized samples with numerous large (.1.5 mm) grains of augite show several types of sodic and sodic-calcic clinopyroxene development: (1) Topotactic replacement of magmatic pyroxene by jadeite and omphacite along a broad front encroaching upon the augite grain from the rock matrix. Jadeite dominates where presumably plagioclase was formerly present. Omphacite dominates where augite is internally replaced along cleavage and fractures. Late chlorite, taramite and ferropargasite replace these pseudomorphs. (2) Former plagioclase laths of the ophitic fabric are replaced by jadeite together with lesser omphacite in epitactic relationship with the enclosing augite. Former plagioclase-augite grain boundaries remain preserved. Late pumpellyite is associated with the omphacite. (3) Jadeite þ omphacite þ pumpellyite þ chlorite with irregular grain boundaries dominate in the rock matrix between the augite relics, with idiomorphic crystals of epidote scattered throughout and in chlorite–epidote clusters. Pumpellyite is interpreted to be a late retrograde product. Quartz is present. (4) Jadeite þ omphacite þ chlorite assemblages, in which monomineralic sheaf-like jadeite aggregates are common, fill very thin (500–1500 mm) fractures criss-crossing the sample, including ophitic augite remnants. Cathodoluminescence microscopy shows that jadeite in the veins is distinctly different from CL in the other types of jadeite, showing features like oscillatory growth zoning indicative of crystallization from a fluid. Generally omphacite develops irregularly along jadeite rims, but recrystallization may lead to pairs with straight grain boundaries suggestive of phase equilibration. Comparison with published solvus relationships suggests temperatures of 425–500 C. This unusual occurrence of different types of jadeite in a metabasic rock suggests two contrasting sources. The first – in the rock matrix, as topotactic alteration of igneous pyroxene and as plagioclase replacement epitactically growing on augite – can be explained as due to local domain equilibration in a rapidly subducted ‘‘spilitized’’ gabbroic rock. The second, in very thin fracture fillings, conforms to an origin as a crystallization product from a pervasive fluid. Conceivably, ‘‘pooling’’ of the fluids flowing through the fractures in larger cavities could lead to larger masses of jadeitite. These have not yet been conclusively documented in the Escambray Massif.

Quartz-albite-microcline metasomatic rocks in the Main Sayan Fault Zone: Evolution of metasomatism and composition of accessory minerals

Quartz-albite-microcline metasomatic rocks (qualmites) localized in the Main Sayan Fault Zone at the boundary of Irkutsk oblast and Buryatia (Eastern Sayan, middle reaches of the Kitoi River) were formed after dynamometamorphic biotite and biotite-amphibole granite gneisses. The zone of alkaline metasomatism up to 250–300 m thick extends for about 12 km along the Main Sayan Fault. Riebeckite-aegirine and hornblende-clinopyroxene qualmites were formed during the early alkaline stage of metasomatism. Biotite-magnetite qualmites, which are occasionally superimposed on riebeckite-aegirine rocks, are products of the following stage of increasing acidity. The 40Ar/39Ar age of amphibole from metasomatic rocks is 321 ± 5 Ma. The metasomatic rocks are enriched by 2–4 times in Zr, Nb, Y, REE, Be, Th, and U relative to unaltered granite gneisses and contain rare-metal mineralization (fergusonite-(Y), betafite, Nb- and Y- bearing titanites, gadolinite-(Y), zircon, thorite, allanite-(Ce), chevkinite-(Ce), etc.). The composition of accessory minerals was studied on a LEO-1430VP SEM. Their composition and mineral assemblages show that meta-somatic alteration and Ti-Nb-Zr-REE mineralization were formed synchronously. The stage of acid solution neutralization was characterized by crystallization of epidote and andradite and by replacement of chevkinite with allanite and titanite in metasomatic rocks. Hydro- and fluorcarbonates of LREE, phosphates (monazite-(Ce)), and fluorides (F-bearing thorianite?) were formed during the final low-temperature stage.

Static stress drop associated with brittle slip events on exhumed faults

We estimate the static stress drop on small exhumed strike‐slip faults in the Lake Edison granodiorite of the central Sierra Nevada (California). The subvertical strike‐slip faults were exhumed from 4 to 15 km depth and were chosen because they are exposed in outcrop along their entire tip‐to‐tip lengths of 8–12 m. Slip nucleated on joints and accumulated by crystal‐plastic shearing (forming quartz mylonites from early quartz vein filling in joints) and successive brittle faulting (forming epidote‐bearing cataclasites). The occurrence of thin, ≤300 μm wide, pseudotachylytes along some small faults throughout the study area suggests that some, if not all, of the brittle slip on the study area faults may have been seismic. We suggest that the contribution of brittle, cataclastic slip to the total slip along the studied cataclasite‐bearing small faults may be estimated by the length of epidote‐filled, rhombohedral dilatational jogs (rhombochasms) distributed quasi‐periodically along the length of the faults. The interpretation that slip recorded by rhombochasms occurred in single events is based on evidence that (1) epidote crystals are randomly oriented and undeformed within the rhombochasm; (2) cataclasite in principal slip zones does not include clasts of previous cataclasite, and (3) rhombochasm lengths vary systematically along the length of the faults with slip maximum occurring near the fault center, tapering to the fault tips. We thereby constrain both the rupture length and slip. On the basis of these measurements, we calculate stress drops ranging over 90–250 MPa, i.e., one to two orders of magnitude larger than typical seismological estimates for earthquakes, but similar in magnitude to seismological estimates of small (<M2) earthquakes from the San Andreas Fault Observatory at Depth (SAFOD). The slip events described in the present study occurred along small, deep‐seated faults, and, given the calculated stress drops and observations that brittle faults exploited joints sealed by quartz‐bearing mylonite, we conclude that these were “strong” faults.

Mesoarchean sanukitoid rocks of the Rio Maria Granite-Greenstone Terrane, Amazonian craton, Brazil

The Archean sanukitoid Rio Maria Granodiorite yielded zircon ages of ∼2.87 Ga and is exposed in large domains of the Rio Maria Granite-Greenstone Terrane, southeastern Amazonian craton. It is intrusive in the greenstone belts of the Andorinhas Supergroup, in the Arco Verde Tonalite and Caracol Tonalitic Complex (older TTGs). Archean potassic leucogranites, younger TTGs and the Paleoproterozoic granites of Jamon Suite are intrusive in the Rio Maria Granodiorite. The more abundant rocks of the Rio Maria Granodiorite have granodioritic composition and display medium to coarse even-grained textures. These rocks show generally a gray color with greenish shades due to strongly saussuritized plagioclase, and weak WNW-ESE striking foliation. The significant geochemical contrasts between the occurrences of Rio Maria Granodiorite in different areas suggest that this unit corresponds in fact to a granodioritic suite of rocks derived from similar but distinct magmas. Mingling processes involving the Rio Maria Granodiorite and similar mafic to intermediate magmas are able to explain the constant occurrence of mafic enclaves in the granodiorite. The associated intermediate rocks occur mainly near Bannach, where mostly quartz diorite and quartz monzodiorite are exposed. The dominant rocks are mesocratic, dark-green rocks, with fine to coarse even-grained texture. The Rio Maria Granodiorite and associated intermediate rocks show similar textural and mineralogical aspects. They follow the calc-alkaline series trend in some diagrams. However, they have high-Mg#, Cr, and Ni conjugate with high contents of large ion lithophile elements (LILEs), typical of sanukitoids series. The patterns of rare earth elements of different rocks are similar, with pronounced enrichment in light rare earth elements (LREEs) and strong to moderate fractionation of heavy rare earth elements (HREEs). Field aspects and petrographic and geochemical characteristics denote that the granodiorites and intermediate rocks have sanukitoid affinity. However, geochemical data suggest that the intermediate rocks and the granodiorites are not related by a fractional crystallization process. It is concluded that the intermediate rocks derived from similar sources to the granodiorites, but probably result from a higher degree of melting, being both cogenetic, but not comagmatic rocks. Mineralogical aspects associated with experimental evidence suggest that the Rio Maria Granodiorite magma was relatively water-enriched (>4 wt.%), explaining the presence of hornblende at the liquidus and the absence of clinopyroxene and orthopyroxene in the studied rocks. The occurrence of well-preserved magmatic epidote crystals, admitting that the Rio Maria Granodiorite was emplaced at shallow crustal levels, points to a rapid ascent of the Rio Maria Granodiorite magma.

Geology of southeast Alaska: rock and ice in motion

Geology of southeast Alaska: rock and ice in motion

Chromian epidote in omphacite rocks from the Sambagawa metamorphic belt, central Shikoku, Japan

Chromian epidote was found in pebbles of omphacite rock derived from the Sambagawa metamorphic rocks in central Shikoku, Japan. The pebbles consist of chromian epidote, omphacite, amphibole, muscovite, phlogopite, chromite, albite, and zircon. The chromian epidote crystals are dark yellow to brown. Microscopically, they are subhedral and are pleochroic from yellowish orange to pale yellow-colorless. Chromian epidote has a zonal structure. Typically, cores of Sr-rich epidote are overgrown with Ca-epidote; alternatively Ca-epidotes are rimmed by and/or intergrown with REE-rich epidote. However, Cr distribution is not related to the zonal structure caused by Ca ↔ Sr and Ca + M3+ ↔ REE3+ + M2+ substitution since regions of higher Cr-concentration generally occur around chromite grains. The chromium content of epidote reaches 5.7 wt% Cr2O3 (0.36 Cr apfu/12.5 oxygens). In contrast, the Fe3+ content of the chromian epidote varies in a narrow range (5.1 to 8.9 wt% Fe2O3) irrespective of the chromium content. Associated minerals surrounding chromite (omphacite, amphibole, muscovite, and phlogopite) also tend to have a high and variable chromium content caused by Al ↔ Cr substitution, but with a nearly constant Fe content in individual minerals. Chromite is considered to be the source material of the chromian epidote and the associated minerals. The heterogeneous distribution of chromium may be attributed to the immobility of chromium under metamorphic conditions. The maximum Cr content of the chromian epidote in the present study is less than that of Fe3+-poor chromian epidote from other localities, whereas the Fe3+ content is greater. The substitution of Cr3+ for Al in the M3 site of the studied chromian epidote may be limited by the ferric iron occupying the M3 site to the extent of 0.52 apfu.

Chromian epidote in omphacite rocks from the Sambagawa metamorphic belt, central Shikoku, Japan

Chromian epidote was found in pebbles of omphacite rock derived from the Sambagawa metamorphic rocks in central Shikoku, Japan. The pebbles consist of chromian epidote, omphacite, amphibole, muscovite, phlogopite, chromite, albite, and zircon. The chromian epidote crystals are dark yellow to brown. Microscopically, they are subhedral and are pleochroic from yellowish orange to pale yellow-colorless. Chromian epidote has a zonal structure. Typically, cores of Sr-rich epidote are overgrown with Ca-epidote; alternatively Ca-epidotes are rimmed by and/or intergrown with REE-rich epidote. However, Cr distribution is not related to the zonal structure caused by Ca ↔ Sr and Ca + M3+ ↔ REE3+ + M2+ substitution since regions of higher Cr-concentration generally occur around chromite grains. The chromium content of epidote reaches 5.7 wt% Cr2O3 (0.36 Cr apfu/12.5 oxygens). In contrast, the Fe3+ content of the chromian epidote varies in a narrow range (5.1 to 8.9 wt% Fe2O3) irrespective of the chromium content. Associated minerals surrounding chromite (omphacite, amphibole, muscovite, and phlogopite) also tend to have a high and variable chromium content caused by Al ↔ Cr substitution, but with a nearly constant Fe content in individual minerals. Chromite is considered to be the source material of the chromian epidote and the associated minerals. The heterogeneous distribution of chromium may be attributed to the immobility of chromium under metamorphic conditions. The maximum Cr content of the chromian epidote in the present study is less than that of Fe3+-poor chromian epidote from other localities, whereas the Fe3+ content is greater. The substitution of Cr3+ for Al in the M3 site of the studied chromian epidote may be limited by the ferric iron occupying the M3 site to the extent of 0.52 apfu.

Emplacement, petrological and magnetic susceptibility characteristics of diverse magmatic epidote-bearing granitoid rocks in Brazil, Argentina and Chile

Magmatic epidote (mEp)-bearing granitoids from five Neoproterozoic tectonostratigraphic terranes in Northeastern (NE) Brazil, Early Palaeozoic calc-alkalic granitoids in Northwestern (NW) Argentina and from three batholiths in Chile have been studied. The elongated shape of some of these plutons suggests that magmas filled fractures and that dyking was probably the major mechanism of emplacement. Textures reveal that, in many cases, epidote underwent partial dissolution by host magma and, in these cases, may have survived dissolution by relatively rapid upward transport by the host magma. In plutons where such a mechanism is not evident, unevenly distributed epidote at outcrop scale is armoured by biotite or near-solidus K-feldspar aggregates, which probably grew much faster than epidote dissolution, preventing complete resorption of epidote by the melt. Al-in-hornblende barometry indicates that, in most cases, amphibole crystallized at P≥5 kbar. Kyanite-bearing thermal aureoles surrounding plutons that intruded low-grade metamorphic rocks in NE Brazil support pluton emplacement at intermediate to high pressure. mEp show overall chemical variation from 20 to 30 mol% (mole percent) pistacite (Ps) and can be grouped into two compositional ranges: Ps 20–24 and Ps 27–30. The highest Ps contents are in epidotes of plutons in which hornblende solidified under P<5 kbar. The percentage of corrosion of individual epidote crystals included in plagioclase in high-K calc-alkalic granitoids in NE Brazil, emplaced at 5–7 kbar pressure, yielded estimates of magma transport rate from 70 to 350 m year −1. Most of these plutons lack Fe–Ti oxide minerals and Fe +3 is mostly associated with the epidote structure. Consequently, magnetic susceptibility (MS) in the Neoproterozoic granitoids in NE Brazil, as well as Early Palaeozoic plutons in Argentina and Late Palaeozoic plutons in Chile, is usually low (<0.50×10 −3 SI), which is typical behavior of plutons which crystallized under low fO 2 (ilmenite-series granitoids), although Fe/(Fe+Mg) ratios in hornblende (0.40–0.65) indicate crystallization under high fO 2. Mesozoic to Tertiary calc-alkalic plutons in Chile, however, exhibit iron oxide minerals and MS values >3.0×10 −3 SI, typical of magnetite-series granitoids crystallized under higher oxygen fugacity. In NE Brazil, Argentina and Chile, it seems that mEp is more common in Precambrian to Palaeozoic ilmenite-series granitoids, while its occurrence in magnetite-series granitoids is more restricted to Mesozoic to Tertiary granitoids.

In situ oxygen isotope analysis with an excimer laser using F 2 and BrF 5 reagents and O 2 gas as analyte

In situ oxygen isotope analysis of silicate minerals has been validated by interlaboratory calibration using an excimer laser (KrF fill gas, 248 nm), F 2 gas fluorinating reagent, and O 2 gas as mass spectrometer analyte. A value of δ 18O SMOW = 5.82%. (±0.03, 4 analyses) was obtained for almandine UWG-2 compared to a recommended value of 5.8%0 (Valley et al., 1995). The interhalogen BrF5 was tested by comparing in situ analyses made alternatively with either BrF 5 or F 2 gas on crystals of almandine, epidote, forsterite, tourmaline, and zircon. Results for different pressures of BrF 5 (20 to 40 torr) in the reaction chamber show that δ 18O values decrease by 1 permil for an increase of 10 torr in BrF 5 pressure. In strong contrast, δ 18O values measured with purified F 2 gas are precise and accurate over a range of from 15 to 150 torr F 2 gas pressure. Use of F 2 gives higher yields of O 2 than with BrF 5. Values of δ 17O and δ 18O measured in situ on a variety of silicates all plot on the terrestrial mass fractionation line, provided that NF 3 contamination is eliminated from the O 2 gas analyte.