Cretaceous Bauxites Research Articles

Petrography and geochemistry of Cretaceous bauxites from Jajce, Bosnia and Herzegovina

The study presents petrographic and compositional data of Late Cretaceous bauxite deposits in the area of Jajce, Bosnia and Herzegovina. Results indicate that bauxites exhibit ooidic to pisodic textures enclosed within a pelitomorfic matrix. Most of the deposits are boehmitic but in some localities, a considerable quantity of diaspore is identified. Hematite is the dominant Fe-mineral, while kaolinite, goethite and calcite are minor. The accessory minerals are represented by anatase, rutile and zircon. Al2O3 content ranges between 54.32–61.05 wt % and is negatively correlated to Fe2O3. Rare earth elements (REE) show variable concentrations, reaching up to 1353 ppm. The chondrite normalized patterns reveal negative Eu anomaly in all and positive Ce anomaly in almost all samples. Ce anomaly shows negative correlation with REE. Bauxites from the Jajce area represent valuable mineral resource with potentially valuable quantities of REE and Sc. Mineralogy and geochemical signature indicate a complex petrogenetic history.

Geochemistry of Upper Cretaceous bauxite deposits, Zagros Fold Thrust Belt, SW Iran: Paleoenvironment and provenance constraints

Iranian's karst bauxites, as part of the Irano-Himalayan bauxite belt, are related to four structural zones, including the Zagros Fold-Thrust Belt (ZFTB). The ZFTB consists of 7–12 km of the Paleozoic to Pliocene carbonate sediments deposited on the Precambrian basement and Arabian continental margin. In the ZFTB occur several karst bauxite deposits between the Cenomanian-Turonian shallow-marine argillaceous of the Sarvak Formation and the Santonian-Campanian carbonates of the Ilam Formation. Compositional data of karst bauxite deposits may address paleogeographic restoration and record paleoclimate, and here we discuss a dataset including the Mombi, Bidgol, Tang-e Pirzal, and Bagoushi bauxite deposits in the ZFTB. Although the ZFTB karst bauxites show similar texture, they are different in composition, reflecting different paleoenvironmental formation conditions. In most of the studied bauxites, the composition of ooidal concretions indicates the occurrence of long periods of humid tropical climate followed by short and intermittent dry-to-wet conditions. In the Bidgol deposit, a different pattern is recognized, reflecting the predominance of dry climates and characterized by low aqueous silica activity and low water activity. The formation of iron oxyhydroxide minerals is likely due to a multistage process involving the circulation of Fe-rich solutions in micro-cracks or veins due to pyrite and chamosite dissolution and Fe2+ oxidization. In the ZFTB bauxites, two main trends of Ce/Ce* distribution with depth, a proxy of paleo-redox evolution during bauxitization, are recognized. In the Bidgol and Mombi deposits, Ce/Ce* is negative in the basal portion and increases upward. The positive Ce-anomalies in the upper parts of these deposits are due to ceranite formation under oxidizing environment near the surface. In the Bagoushi and Tang-e Pirzal deposits, Ce/Ce* is close to the unit with the notable exceptions of a few samples characterized by significant and positive Ce/Ce* anomalies. This feature suggests that cerianite, originally ubiquitous in these deposits, was affected by congruent dissolution through cerium reduction with Ce3+ transportation by acidic downward percolating solutions as fluoride complexes (REEF2+ and REEF2+), carbonate complexes (REECO3+) and carbonate–fluoride complexes (REECO3F) followed by fluorocarbonate minerals' precipitation. This process has been repeated several times with maximum distribution throughout the profile due to environmental changes, including periodic fluctuations in the groundwater level. Finally, the Sm/Nd, Nb/Ta, and Eu/Eu* provenance proxies indicate that the protolith(s) from which the ZFTB bauxite deposits are derived is UCC-like, thus excluding supply of mafic material and pointing toward a source material primarily derived from the bedrock argillaceous sediments. In addition, several samples record provenance from siliciclastic craton-derived sediment, suggesting that the ZFTB was connected with a continental margin during the Jurassic-early Cretaceous.

Geochemistry and Geometrical Features of the Upper Cretaceous Vitulano Para-Autochthonous Karst Bauxites (Campania Region, Southern Italy): Constraints on Genesis and Deposition

In the Vitulano area, Upper Cretaceous bauxite bodies fill small depressions and karst cavities within Cretaceous shallow-water limestones. These bauxites were studied to understand the processes that led to their formation. Geochemical, mineralogical, and petrographic analyses were carried out on the bauxite samples, together with image analysis providing geometric parameters. The texture of Vitulano bauxite consists of ooids and sub-circular aggregates dispersed in a predominantly Ca-rich matrix. Ooids are generally formed by a single large core, often surrounded by an alternation of different aggregates of boehmite and Al-hematite reflecting different climate periods. The composition is dominated by the major elements Al2O3 and CaO with lower concentrations of Fe2O3 and SiO2. Boehmite, calcite, hematite, and anatase are the main mineralogical phases identified. Image analysis provided values of fractal dimension D that gives information on carbonate platform exposure times since it is linked to long-lasting sub-aerial events and diffusion-limited cluster aggregation processes. The tectonic evolution of the area played an important role in the genesis of the Vitulano bauxites since it favored the erosion, transport, and re-deposition of pre-existing bauxite material from the surrounding Campania bauxites. Based on this hypothesis, Vitulano bauxites are defined and classified as para-autochthonous, and this was supported by Eu/Eu* vs. Sm/Nd and Eu/Eu* vs. TiO2 Al2O3 indices displaying a similarity between Vitulano and the other Campania bauxites.

U-Pb detrital zircon ages and Hf isotope from Sardinia and Adria Cretaceous bauxite (Italy): Constraints on the Alpine Tethys paleogeography and tectonic evolution

Bauxite deposits in Italy mainly distribute in Sardinia and Adria regions within Cretaceous carbonate sequences. Parental affinity of Italian bauxite deposits has long been a controversial problem. At least four potential sources have been proposed: (1) Cretaceous debris and autochthonous marlstones; (2) alluvial sheets from the weathered Variscan basement; (3) weathering materials from North Africa and (4) Cretaceous bimodal volcanism in the Dinaric and Carpatho-Balkan orogenic belts. In this study, a total of 374 detrital zircon U-Pb ages and 86 Hf isotope values have been acquired from Cretaceous bauxites of Sardinia and Adria regions. Combining with the published geochemical data, provenances of Cretaceous bauxite deposits in Sardinia and Adria regions have been discussed. In bauxite deposits of Sardinia, dominant Early Paleozoic aged zircon grains (main age peaks at 291 – 295 Ma, 454 – 465 Ma, and 582 – 639 Ma) and their various Hf isotope compositions (εHf(t) = +9.61 to −5.66) indicate a parental affinity of Variscan metasedimentary basement. As a contrast, bauxite deposits in Adria show abundant Jurassic – Cretaceous (93 – 178 Ma) zircon grains with negative εHf(t) values (-13.75 to −4.61), demonstrating significant supply from coeval volcanic materials. Cretaceous bauxite samples from Sardinia and Adria shed light on paleogeographic restoration and tectonic evolution of Alpine Tethys. Began in Early Cretaceous, Sardinia was affected by uplift due to the subduction between Ligurian oceanic crust and the Iberia plate. The Mesozoic carbonate sequence were eroded and the underlying Variscan basement was exposed in the area from Sardinia to the Massif Meridional, provided weathering materials for bauxitization. Late Cretaceous witnessed the further NNE-trending subduction of the Adria Plate to the West Vardar oceanic plate, where calcalkaline igneous rocks and volcanic ashes from Dinarides supplied windborne weathering materials to carbonate platforms in Adria. Particularly, provenance difference between the bauxite of central-southern Apennine and Sardinian reveals that the hosting carbonate sequence in Apennine was not located on the Sardinia shelf before the Cenozoic tectonism in the south Mediterranean realm. Diversity of provenances in bauxite deposits from Sardinia and Adria may cause differences in geochemical composition and further influence qualities of bauxite ore in two regions.

Mineralogical and Geochemical Features of Cretaceous Bauxite from San Giovanni Rotondo (Apulia, Southern Italy): A Provenance Tool

In this study, the mineralogical and chemical compositions of bauxite from San Giovanni Rotondo (SGR) on the Gargano Promontory (northern Apulia, Italy) are presented and discussed with the aim of assessing the nature of its source material. Bauxite from the SGR, which is known as the “Montecatini mine”, was exploited intensively until the 1970s to recover alumina. As with most of the autochthonous peri-Mediterranean bauxites, the studied deposit is a karst bauxite with a massive, matrix-supported texture and an oolitic structure. Boehmite and hematite are the main mineral phases, and anatase, rutile, and kaolinite are present in lesser amounts along with detrital zircons and monazite grains. Calcite is abundant only in the deposit’s lower portion, triggering a significant dilution effect on trace element concentrations. However, with respect to the average crust and chondrite compositions, strong enrichments of trace metals (up to 10X Upper Continental Crust’s (UCC)) and rare earth elements (REEs, up to 800X chondrite) exist throughout the studied deposit. The distribution of REEs, the (La/Yb)N and Eu/Eu* ratios, and an Eu/Eu* versus Sm/Nd diagram have been used for determining the bauxite’s provenance. These geochemical proxies point to a parental material consisting of a mixture of distant magmatic and siliciclastic components.

Austrian versus Hungarian bauxites in an Alpine tectonic context: a tribute to Prof. Andrea Mindszenty

The correlation between the Cretaceous bauxites of Austria and Hungary was first highlighted by the pioneering work of Andrea Mindszenty in the 1980s. The physical distance today between these bauxite occurrences, located in the Northern Calcareous Alps and the Transdanubian Central Range, is on the order of hundred of kilometers. However, a semi-quantitative palinspastic reconstruction of their relative positions at the time of bauxite deposition during the Late Cretaceous (Turonian to early Santonian) shows their much closer proximity. Still, the important differences between these Upper Cretaceous bauxites are due to their different paleogeographic settings during their deposition on a subaerially exposed Eo-Alpine nappe substratum. Some other differences, such as porosity, are attributed to the subsequent tectonic overprint in the Alpine edifice. The Austrian and Hungarian bauxites not only record important information about of the syn-depositional geologic landscape but also provide clues about the pre- and post-depositional regional tectonic context of the areas where they developed. The typical setting for many of the Cretaceous bauxites in the broader Alpine region was uplift and karstification associated with the formation of various flexural basin systems. Therefore bauxites, in general, may contain important geologic information about the regional geodynamic processes, as it was pointed by Andrea Mindszenty, in a pioneering manner, already in the early 1990s.

Tracing multiple resedimentation on an isolated karstified plateau: The bauxite-bearing Miocene red clay of the Southern Bakony Mountains, Hungary

The Vöröstó (=Red Lake) Formation, located in the Southern Bakony Mountains and the Balaton Highlands (Hungary), is a red, clayey continental assemblage containing hard, up to fist-sized bauxite pebbles, occurring in a large apparent stratigraphic gap between underlying karstified Triassic carbonates and mid’ Miocene to Quaternary cover. The origin and the exact stratigraphic position of the assemblage have been controversial for a long time. In this study, petrographic observations on the bauxite pebbles revealed common features with Cretaceous bauxite deposits known in the region, whereas heavy mineral composition of the red clay matrix is similar to those known from the Eocene bauxite horizon of the region. Single grain zircon U–Pb ages obtained from the bauxite pebbles and their red clayey matrix show similar late Archean to Jurassic age components. Additionally, Cenozoic U–Pb ages are well represented in the mostly euhedral zircon crystals separated from the red clays, whereas this volcanogenic contribution completely missing from the bauxite pebbles. SEM morphology and related EDX chemical analysis of clay minerals indicate polygenetic, detrital origin for the red clays. The main source material of the bauxite bearing Vöröstó Formation is most probably local Cretaceous and Eocene bauxite deposits exposed during the middle-late Miocene. These tropical weathering products were partly decomposed and degraded, but dilution by siliciclastic contribution is negligible. We suggest a transport mechanism dominated by local redeposition of mostly pelitic and allitic material through seasonal muddy debris flows within a karstic landscape.

Mineralogical and geochemical investigations of the Mombi bauxite deposit, Zagros Mountains, Iran

The Mombi bauxite deposit is located in 165km northwest of Dehdasht city, southwestern Iran. The deposit is situated in the Zagros Simply Fold Belt and developed as discontinuous stratified layers in Upper Cretaceous carbonates (Sarvak Formation). Outcrops of the bauxitic horizons occur in NW-SE trending Bangestan anticline and are situated between the marine neritic limestones of the Ilam and Sarvak Formations. From the bottom to top, the deposit is generally consisting of brown, gray, pink, pisolitic, red, and yellow bauxite horizons. Boehmite, diaspore, kaolinite, and hematite are the major mineral components, while gibbsite, goethite, anatase, rutile, pyrite, chlorite, quartz, as well as feldspar occur to a lesser extent. The Eh–pH conditions during bauxitization in the Mombi bauxite deposit show oxidizing to reducing conditions during the Upper Cretaceous. This feature seems to be general and had a significant effect on the mineral composition of Cretaceous bauxite deposits in the Zagros fold belt. Geochemical data show that Al2O3, SiO2, Fe2O3 and TiO2 are the main components in the bauxite ores at Mombi and immobile elements like Al, Ti, Nb, Zr, Hf, Cr, Ta, Y, and Th were enriched while Rb, Ba, K, Sr, and P were depleted during the bauxitization process. Chondrite-normalized REE pattern in the bauxite ores indicate REE enrichment (ΣREE=162.8–755.28ppm, ave. ∼399.36ppm) relative to argillic limestone (ΣREE=76.26–84.03ppm, ave. ∼80.145ppm) and Sarvak Formation (ΣREE=40.15ppm). The REE patterns also reflect enrichment in LREE relative to HREE. Both positive and negative Ce anomalies (0.48–2.0) are observed in the Mombi bauxite horizons. These anomalies are related to the change of oxidation state of Ce (from Ce3+ to Ce4+), ionic potential, and complexation of Ce4+ with carbonate compounds in the studied horizons. It seems that the variations in the chemistry of ore-forming solutions (e.g., Eh and pH), function of carbonate host rock as a geochemical barrier, and leaching degree of lanthanide-bearing minerals are the most important controlling factors in the distribution and concentration of REEs. Several lines of evidences such as Zr/Hf and Nb/Ta ratios as well as similarity in REE patterns indicate that the underlying marly limestone (Sarvak Formation) could be considered as the source of bauxite horizons. Based on mineralogical and geochemical data, it could be inferred that the Mombi deposit has been formed in a karstic environment during karstification and weathering of the Sarvak limy Formation.

Bauxite provinces of the world

Phanerozoic bauxite provinces are contoured and characterized. The relations to large tectonic units—ancient and young platforms, island arcs and foldbelts, active continental margins, etc.—are chosen as the major criterion for the recognition of bauxite provinces; 19 provinces of different age and conditions of bauxite deposition are described. Single- and multistage as well as single- and multilevel provinces are distinguished depending on the type of tectonic and geomorphic structure. The most productive bauxite provinces are located in the present-day tropical zone within ancient Gondwanan platforms. Three-level provinces with Cretaceous bauxite at the highest and oldest (post-Gondwanan) surface and Cenozoic deposits at lower and younger planation surfaces are predominant. The most complex, two- and three-stage and multilevel provinces are related to ancient fold regions. The single-level provinces are localized in young island arcs and oceanic islands. The prevalent genetic types of bauxite deposits—lateritic, sedimentary, and karst—are shown in the map of bauxite provinces.

Sur un 'sol tropical' a base d'argilites ferrugineuses, sous-jacent a l'Oligocene varoise, et sur son extension

Abstract Laterization, Ludian, clay mineralogy, DTA, x-ray diffraction analysis, similarity of infra-Oligocene argillites and Cretaceous bauxites, France