Craton Margin Research Articles

Post-Marinoan paleoredox and paleoproductivity record in Puga cap carbonate: Implication for coastal life colonization at the Amazon Craton marginal Sea

The geochemical signatures in cap carbonate successions are critical records of paleoceanographic conditions following Snowball Earth events. These deposits offer insight into the shifts in redox conditions and the re-establishment of biogeochemical cycles during postglacial periods, providing a window into the evolving marine environments and potential drivers of early oxygenation. To track redox changes during this transition, we present improved high-resolution analyses of redox proxies across Puga cap carbonate (~635 Ma) on the Southern Amazon Craton, Brazil, allowing for the identification of temporal redox transitions during the post-Marinoan transgression. The depletion of trace elements, particularly redox-sensitive elements (RSEs), such as Mo, U, V, Cr, and Ni in microbialites formed in basal cap dolostone, was deposited under oxic conditions. Following the initial melting of Marinoan glaciers, microbial mats flourished and grew in a semi-restricted shallow marine environment in the coastal paleoenvironment along the Amazon cratonic margin, where nutrient-rich surface waters fueled primary productivity. In contrast, the increase in RSEs in upper wave-dominated dolostone facies indicates predominantly dysoxic conditions in continuous sea level rise, resulting in the drowning of these early microbial environments and the precipitation of cap limestones. The sequential oxic-dysoxic redox marks the transition from shallow sea to deepening CaCO3-oversaturated platform conditions. These results demonstrate an unequivocal synchronous relationship between the initial oxygenation of the Amazon margin and the local microbial mat flourishment shortly after the Marinoan glaciation.

MICA COMPOSITION REFLECTING CONDITIONS OF AILLIKITE FORMATION IN ZIMA COMPLEX OF EASTERN SIBERIA

Four types of mica were identified in the macrocryst and fine porphyry aillikites from the Yarma zone of the Urik-Ija graben considering specific features of morphology, chemical composition, zonation and crystallization conditions. Mica of the first type was found in macrocryst aillikites. It is available as deformed phlogopite macrocrysts rich in TiO2 (2.5–5.7 wt. %) with varying content of Cr2O3 (from detection limit to 2.0 wt. %) and Mg# 0.87–0.89 and 0.79–0.81 in different dikes. In chemical composition this phlogopite corresponds to the secondary phlogopite from mantle xenoliths, and it was obviously captured by protoaillikite melt form the rocks of the lithosphere mantle. Mica of type 2 represents phlogopite from groundmass and infrequent phenocrysts in fine porphyry aillikites and groundmass of macrocryst aillikites. In this phlogopite, TiO2 content varies in different dikes from 0.7 to 6.0 wt. %, Mg# index varies from 0.70 to 0.90. Phlogopite crystallized within the upper crust at temperature ranging from 840 to 680 °С. Mica of type 3 represents biotite (Mg# 0.40–0.65), producing rims around phlogopite and independent grains in fine porphyry and in places in macrocryst aillikites. The rims crystallized from residual Fe-rich melt at moderately heightened fO2, the temperature of biotite formation reached 700‒760 °C. Mica of type 4 is available in macrocryst aillikites as biotite (Mg# 0.40‒0.67) with phlogopite rims. It was inferred, that this biotite crystallized in intermediate magmatic chambers in the upper crust from essentially carbonate melts, separated through crystallization differentiation from protoaillikite magmas and captured by new portions of less differentiated melts. Obtained data point to metasomatic transformation of the lithosphere mantle, preceding to protoaillikite melting, under the southern margin of the Siberian craton. Thus, we may assume existence in the upper crust of the sites composed of partially crystallized melt.

The role of an oxidized lithospheric mantle in gold mobilization.

Phanerozoic orogenic gold mineralization at craton margins is related to the metasomatism of the lithospheric mantle by crustal material. Slab subduction transfers Au from the crust to the metasomatized mantle and oxidizes the latter to facilitate the mobilization of Au into mantle melts. The role of volatiles in the mobilization of Au in the mantle is unclear because of the absence of direct geochemical evidence relating the mantle source of Au to Au mineralization in the overlying crust. This study uses lithium isotopes from a large suite of lamprophyres to characterize the mantle beneath the eastern North China Craton, which hosts giant Mesozoic gold deposits. Our results indicate a strong genetic link between carbonate metasomatism in the mantle and Au mineralization in the overlying crust. Although pre-enrichment of Au in the mantle is critical for forming giant Au provinces, the oxidation of the lithospheric mantle controls the mobilization of Au.

Tectonostratigraphic framework and provenance of a Mesoproterozoic rift succession: An example from the Espinhaço Supergroup, SE Brazil

During the Mesoproterozoic era, the amalgamation of the Rodinia supercontinent witnessed numerous intraplate rifting events far-field induced by “Grenvillian-type age” orogenic systems. The intimate connection between tectonics and sedimentation enables the reconstruction of these intraplate rifting cycles, linking them to accretionary events along craton margins. This is essential for understanding the paleotectonic history of continents during the Mesoproterozoic era. In southeastern Brazil, the Espinhaço Supergroup documents long-lasting superimposed rifting events that extended to the eastern border of the São Francisco paleocontinent from the Paleoproterozoic to the Mesoproterozoic era. Three unconformity-bound rift sequences (∼1.77–1.7 Ga; ∼1.57–1.5 Ga; and ∼ 1.19 Ga) have been identified within the Espinhaço Supergroup, terminated by sag-marine deposits of the Conselheiro Mata Group. In the southern extension of the southern Espinhaço range (Cipó range), a detailed sedimentological and stratigraphic study was conducted on a rift-related sequence with unknown stratigraphic positioning. This sequence is bounded at the base by eolian sediments of the Galho do Miguel Formation of the Southern Espinhaço Supergroup and at the top by Ediacaran-Cambrian carbonates and pelites of the Bambuí Group. Examination of the tectonically-induced depositional controls in the provenance signatures involved stratigraphic surveys coupled with U-Pb geochronological data of detrital zircons. The lower section of the rift-related sequence transitions eastward into marine sediments of the Conselheiro Mata Group within the Santa Rita Formation, now identified as the Lower Member. With a maximum depositional age of 1660 ± 32 Ma, this section directly overlies the Galho do Miguel Formation by an erosive unconformity, comprising syn-rift coarse-grained deposits from alluvial and fluvial systems within an inverted half-graben structure. The Lower Member of the Santa Rita Formation provides evidence of the Mesoproterozoic rifting event associated with the Conselheiro Mata Group. The marine sediments of the Undefined sequence have a maximum depositional age of 1462 ± 19 Ma, overlying the Lower Member of the Santa Rita Formation with an erosive unconformity. The stratigraphic position of this sequence remains speculative, possibly linked to a later extensional phase of the Mesoproterozoic Conselheiro Mata rifting event or one of the two continental rifting stages leading to the Neoproterozoic Macaúbas Group.

The tectonic development of the Central African Plateau: evidence from shear-wave splitting

SUMMARY The Central African Plateau comprises a mosaic of numerous Archean terranes—the Congo, Bangweulu and Kalahari Cratons—sutured in a series of Proterozoic to early Cambrian orogenic events. Major upper-crustal deformation and complex craton margin fault zones reflect the region’s diverse tectonic history: rifting during the Neoproterozoic, collision during the Pan-African orogeny, and more recently, Permo-Triassic Karoo rifting and the Pliocene development of the Southwestern branch of the East African Rift. The tectonic evolution and extent to which the lithospheric mantle has been re-worked by each tectonic event is poorly understood. New seismograph networks across the Plateau provide fresh opportunity to place constraints on the plate-scale Precambrian-to-Phanerozoic processes that have acted across the region. Utilizing data from seismograph deployments across the Central African Plateau, including the new Copper Basin Exploration Science network—a NW–SE-trending, 750-km-long profile of 35 broad-band stations—we explore lithospheric deformation fabrics associated with past and present tectonic events via a shear-wave splitting study of mantle seismic anisotropy. Results reveal short length-scale variations in splitting parameters (fast direction: $\phi$, delay time: $\delta$t), suggestive of a fossil lithospheric fabric cause for the observed anisotropy. A lack of fault-parallel $\phi$ across the Mwembeshi shear zone, suggests it may be too narrow at mantle depths, a thin-skinned, crustal-scale feature, and/or did not experience sufficient fault parallel shear-strain during its last active phase to form a lithospheric deformation fabric discernible via teleseismic shear-wave splitting. In the heart of the Lufilian Arc, we observe abrupt changes in splitting parameters with NE–SW, N–S and NW–SE $\phi$ and 0.5 s $< $$\delta$t$< $ 1.2 s evident at short length-scales: no single, uniform, anisotropic lattice preferred orientation (LPO) fabric defines the entire region. This is consistent with the view that multiple episodes of deformation shaped the Lufilian Arc, or perhaps that pre-existing fabrics, relating to Neoproterozoic Katangan Basin development, have failed to be completely overprinted by the Pan-African orogeny. Near the Domes, where most intense crustal re-working is thought to have taken place during the Pan-African orogeny, there is a cluster of null and low $\delta$t splits which likely reflects the lack of organized LPO fabrics, perhaps due to the presence of depth-dependent anisotropy. The neighbouring Congo Craton margin is marked by consistently weak anisotropy ($\delta$t$\lt $ 0.7 s) indicating a weak horizontal alignment of olivine at mantle lithospheric depths, typical of several Archean terranes worldwide.

Tectonic evolution of the Early Paleozoic proto-East Asian continental margin: Inference from Paleozoic metamorphic rocks in the South Kitakami belt, northeast Japan

To constrain the incipient Pacific-type orogeny and tectonic processes in the Early Paleozoic proto-East Asian continental margin, the Motai–Matsugadaira–Yamagami (MMY) metamorphic rocks in the South Kitakami belt, northeast Japan were investigated. They are divided into two different types: amphibolite-facies rocks associated with serpentinite and blueschist-facies rocks associated with pelitic and psammitic schists. Three geochemical groups are identified from the MMY metamorphic rocks. Groups 1 and 2 resemble geochemical characteristics of mid-ocean ridge basalt and continental arc rocks, respectively. Group 3 exhibits considerable depletion of highly incompatible elements, which is caused by the high degree of partial melting of a hot mantle plume. The zircon U–Pb ages of Group 1 indicate that the protoliths experienced amphibolite-facies metamorphism soon after their formation in the Early Ordovician. Group 2 exhibits a coeval zircon U–Pb age with Group 1. The age distribution of detrital zircons in the MMY psammitic schists shows a peak of 500–400 Ma, the presence of Archean to Neoproterozoic zircons, and the youngest Late Devonian zircon. The following model is proposed for the tectonic evolution of the proto-East Asian continental margin: (1) the formation of an arc in the eastern margin of the South China craton in the Cambrian to Ordovician; (2) the subduction of a spreading axis and an oceanic plateau at the same time as the continental arc formation; (3) the consumption and subduction of arc materials by tectonic erosion; and (4) the formation of the Carboniferous accretionary complex and high-pressure metamorphic rocks under steady oceanic plate subduction. The proposed tectonic evolution model may also be applicable to equivalent Early Paleozoic rocks in southwest Japan.

Audio magnetotelluric view of the giant carbonatite-hosted Bayan Obo REE deposit, Inner Mongolia, northern China

As critical minerals in low-carbon economies, rare-earth elements (REEs) are crucial for modern industry, technology, and medicine. The largest known REE resource in the world is the Bayan Obo (BO) deposit in northern China. However, BO features as complicated mineral compositions and has experienced several geological events. As a reuslt, controversy remains about the BO REE genesis and enrichment mechanism, and debates are also ongoing about the controlling structure of this giant deposit. We carried out an multiscale electromagnetism study on BO mineral deposits. The multiscale study consists a microscale on samples, a small scale targeting mineral deposits and a mid scale concerning the mine field. The small and mid scale study were conducted using audio-magnetotelluric (AMT). This study revealed the controlling structure using geoelectrical characteristics. AMT data were acquired from more than 590 stations, and the petro-electromagnetism of several samples was analyzed to understand the geoelectrical features of the ore deposits and their surrounding rocks. The data were interpreted using Bostick transformation and generalized least-squares inversions. We obtained the geoelectrical structure of the BO complex down to a maximum depth of 3500 m, and we present two-dimensional imaging based on the AMT conversion results. The results show that the BO deposit developed at the transition of the high- and low-resistivity geoelectrical structure from south to north. Our AMT results indicate that the tectonic setting of the BO deposit is the transition zone between the rift edge and craton margin slope. The ore geology is presently controlled by the complex slope and the rift remnant, the ore-bearing dolostone in the profiles is Y-shaped. It goes downward from south to north and potentially features a great mineral prospect deep in the BO deposit.

The Early Neoproterozoic Andean-Type Orogenic and Within-Plate Magmatic Events in the Northern Margin of the Yangtze Craton during the Convergence of the Rodinia Supercontinent

Although considered a crucial component of the Rodinia supercontinent, it remains uncertain how the Yangtze craton relates to the accretion and breakup of Rodinia. Here, the Huanglingmiao granitic complex (HGC), an intermediate-acid rock series that intruded on the southern Kongling terrane of the northern Yangtze craton margin, is investigated to help resolve this conundrum. Our analysis indicates that these rocks consist of tonalite, trondhjemite, granodiorite, oligoporphyritic granodiorite, porphyric biotite granodiorite, and fine- to medium-grained granodiorite dyke compositions. Collectively, this assemblage is further subdivided into two categories by their temporal, spatial, and geochemical features into early TTG-like and later granitic–dioritic units, which are composed of tonalite, trondhjemite, granodiorite, porphyritic granodiorite, and the fine- to medium-grained granodiorite dykes, respectively. Zircon U-Pb dating yields ages of 865~850 Ma for the TTG-like rocks, 844~825 Ma for the porphyritic granodiorites, and ~800 Ma for the granodiorite dykes. Combined with geochemical evidence, the data suggest that the early- and late-series rocks were formed by a partial melting of Mesoproterozoic and Paleoproterozoic crustal materials, respectively, suggesting that the vertical layering of the crust controlled the composition of the independent units. In addition, isotopic evidence points to different sources for the various rocks in the Kongling terrane and that mantle-derived materials influenced the early-series lithologies. Combined with previous studies on the northern margin of the Yangtze craton, it is inferred that the early-series rocks formed in an active continental margin environment, while the late-series rocks display within-plate boundary formation characteristics. The multiple magmatic activities revealed by this study record sequential partial melting with tectonic transition characteristics from an Andean-type to within-plate magmatism in the northern margin of the Yangtze craton. Taken together, these observations point to a strong association between these rocks, convergence, and incorporation of the northern Yangtze craton margin into the Rodinia supercontinent during the Tonian Period.

Coevolution of craton margins and interiors during continental break-up

Many cratonic continental fragments dispersed during the rifting and break-up of Gondwana are bound by steep topographic landforms known as ‘great escarpments’1–4, which rim elevated plateaus in the craton interior5,6. In terms of formation, escarpments and plateaus are traditionally considered distinct owing to their spatial separation, occasionally spanning more than a thousand kilometres. Here we integrate geological observations, statistical analysis, geodynamic simulations and landscape-evolution models to develop a physical model that mechanistically links both phenomena to continental rifting. Escarpments primarily initiate at rift-border faults and slowly retreat at about 1 km Myr−1 through headward erosion. Simultaneously, rifting generates convective instabilities in the mantle7–10 that migrate cratonward at a faster rate of about 15–20 km Myr−1 along the lithospheric root, progressively removing cratonic keels11, driving isostatic uplift of craton interiors and forming a stable, elevated plateau. This process forces a synchronized wave of denudation, documented in thermochronology studies, which persists for tens of millions of years and migrates across the craton at a comparable or slower pace. We interpret the observed sequence of rifting, escarpment formation and exhumation of craton interiors as an evolving record of geodynamic mantle processes tied to continental break-up, upending the prevailing notion of cratons as geologically stable terrains.

Helium resource and play classification systems, effective reservoir control elements, and enrichment patterns in China

The classification system, effective reservoir control elements, and major enrichment and exploration modes of helium resources in China are analyzed based on the source of helium, carrier, geological background, and anatomy of typical helium-rich fields. Firstly, based on the special characteristics of helium and the correlation analysis of natural gas accumulation and reservoir formation, we analyzed and sorted out the helium resource and play type classification scheme and classification system in China from nine aspects, namely, the source of helium parental sources, helium type diversities, the storage and carrier types, the technically and economically recoverable characteristics of carrier gases, the carrier gas genesis, the main components of carrier gases, the matching combination of helium sources and reservoirs, background of prototype basin structure, and helium content, to lay the foundation for the subsequent targeted and detailed studies and evaluation programs in different categories. Secondly, the analysis points out the characteristics of helium resource types in the east, middle, and west of China in terms of longitudinal and transverse distribution, tectonic dynamics, geological and geochemical characteristics, and key conditions for the formation of helium deposits. Thirdly, from the perspective of the helium “generation-migration-accumulation” system and the controlling elements and effectiveness of helium-rich reservoir formation, we analyze the effective controlling elements of helium accumulation and the related problems that deserve attention in geological evaluation and point out the misunderstandings in helium reservoir formation and exploration evaluation. Last but not least, from the perspective of basin tectonic background, helium enrichment controlling mechanism and exploration direction, the exploration and evaluation direction and classification scheme for the four element combination zones of “original basin–structure–lithology–carrier gas” helium accumulation in China have been proposed, based on which, four types of basins and eight types of helium-rich zones in China have been sorted out. In these eight types of helium-rich zones, eight typical helium-rich field enrichment and exploration patterns, including the ancient uplift type of China's craton, fracture-fold variant of the craton margin, fracture-rise type of depression basin, slope bulge and uplift type of foreland basin, fracture-convex type of fracture basin, and U/Th-rich basement type of basin were analyzed, and the main controlling factors of the formation of different types of helium-rich deposits were analyzed, which will provide a reference for the subsequent exploration and discovery of similar helium-rich areas and exploration target evaluation.

Magmatic underplating associated with Proterozoic basin formation: insights from gravity study over the southern margin of the Bundelkhand Craton, India

Abstract. Extension tectonics responsible for intracratonic rift basin formation are often the consequences of active or passive tectonic regimes. The present work puts forth a plume-related rifting mechanism for the creation and evolution of two Proterozoic sedimentary basins outlining the Bundelkhand Craton, namely the Bijawar and Vindhyan basins. Using global gravity data, a regional-scale study is performed over the region encompassing the southern boundary of the Bundelkhand Craton consisting of the Bijawar Basin, Vindhyan Basin, and Deccan basalt outcrops. The gravity highs in the central part of the complete Bouguer anomaly and the upward-continued regional anomaly, derived from global gravity grid data, suggest that the Vindhyan sedimentary basin overlies a deeper high-density crustal source. The deepest interface as obtained from the radially averaged power spectrum analysis is observed to occur at a depth of ∼30.3 km, indicating that the sources responsible for the observed gravity signatures occur at larger depths. The 3D inversion of complete Bouguer anomaly data based on Parker–Oldenburg's algorithm revealed the Moho depth of ∼32 km below the Vindhyan Basin, i.e., south of the craton. The 2D crustal models along two selected profiles showcase a thick underplated layer with a maximum thickness of ∼12 km beneath the southern part of the Bundelkhand Craton. The inferred large E–W-trending underplating and deciphered shallower Moho beneath the regions south of the exposed Bundelkhand Craton point to crustal thinning compensated for magmatic emplacement due to a Paleoproterozoic plume activity below the craton margin.

T-t Evolution of the Early Proterozoic Rocks in the Northern Ladoga Region from the Data on U-Pb, Rb-Sr and Sm-Nd Systems in Minerals

This paper presents the results of a study of isotopic systems in minerals and rocks in southern margin of the epi-Archean Karelian craton in the zone of its junction with the Svecofennian mobile belt. U-Pb, Sm-Nd and Rb-Sr mineral ages of metamorphic rocks allowed reconstructing a T-t trend during ~1.88–1.61 Ga, which reflects a wide-ranging cooling history of metamorphic rocks from the peak values of about 650–700 °C at 1.88–1.79 Ga (U-Pb age of monazites and apparent oldest Sm-Nd age of amphiboles) to 300–400 °C at 1.61 Ga (model Rb-Sr age of biotites) in zones of low- and medium-temperature metamorphism. The specificity of removal of deep-seated rocks to the present-day erosion surface and the reconstructed T-t trend comply with the development of thrust-nappe structures during the exhumation of the Svecofennids. It is also assumed that differential vertical block movements played a significant role during the post-orogenic extensional collapse and neorifting.

The distribution and generation of carbonatites

The physio-chemical framework that generates carbonatites and, ultimately, the associated rare earth element deposits remains contentious. This primarily reflects the diverse tectonic settings in which carbonatites occur: large igneous provinces, continental rifts and major extensional terranes, syn- to post-collisional settings, or ocean islands. There is, however, a broad consensus that carbonatites (or their parental melts) originate in the mantle. These exotic melts have small volumes that make them ideal probes of conditions in their underlying source regions. We combine the carbonatite locations with global maps of lithospheric thickness, derived from seismic tomography, and show that post-Neoproterozoic carbonatites occur preferentially above the margins of thick cratonic lithosphere (e.g., adjacent to the South Atlantic and Indian Oceans or in North America, Greenland, and Asia) and where once thick lithosphere has undergone stretching (e.g., eastern Asia). Our thermal modeling reveals that lateral and vertical heat conduction on rifted craton margins, or rapid stretching of cratonic lithosphere, can mobilize carbonated peridotite at the temperatures (950−1250 °C) and pressures (2−3 GPa) required to form primary carbonatites or their parental alkali silicate melts. Importantly, our models show that heat conduction from upwelling mantle plumes or ambient mantle on rifted cratonic margins may sufficiently modify the temperature of the lithospheric mantle to cause melting of carbonated peridotite, settling the long-standing debate on the role of rifting and heating in the generation of carbonatites.

The electrical structure of the lithosphere in the southeastern margin of the Amazonian craton: Contribution to West Gondwana tectonics

A high electrical conductivity belt near the southeastern margin of the Amazonian craton, known as Paraguay-Araguaia Conductivity Anomaly (PACA), has been discovered and mapped over a distance of more than 1,000 km by a large array of magnetometer measurements. To precisely determine the location and structure of the conductive anomaly, we conducted a 200-km-long magnetotelluric (MT) profile with typical site spacing of 8 km over the northern part of PACA and crossing the Goiás magmatic arc and Araguaia belt in Central Brazil. Three-dimensional resistivity models derived from this data indicate that the PACA is not a single conductor but comprises at least two contiguous bodies at the upper to middle crust. The enhanced conductivity of the northern part of PACA is likely due to sulfide minerals deposited in an inter-arc or back-arc basin that were deformed and subsequently emplaced tectonically beneath the western Goiás magmatic arc. The PACA is truncated to the west by a prominent sub-vertical resistor, attributed to the Transbrasiliano lineament (TBL), a continental-scale structural feature interpreted here as a mylonitic shear zone developed late in the Neoproterozoic to Cambrian tectonic history involving the collision between Amazonian craton and proto-West Gondwana. We cannot confirm the prevailing view of an east-dip subduction of oceanic lithosphere from the Amazonian plate under the Goiás arc terranes. Instead, our results probably represent the record of an oblique continental collision. Regardless of its origin, the PACA may serve as a proxy for the paleo border of the Amazonian plate. Therefore, additional geophysical mapping, especially in areas covered by thick Phanerozoic sediments, is essential to constrain the tectonic evolution of West Gondwana.

Placing constraints on the age and origin of basaltic dykes on the Ghaap Plateau, Griqualand West, South Africa

Abstract Well-preserved strata of the Ghaap Plateau along the western margin of the proto-Kalahari Craton have been intruded by a large number of mafic dykes. Owing to the scarcity of outcrops, these dykes are generally not well documented and intrusion ages remain poorly understood. In order to address this lack of knowledge, a total of seventeen Ghaap Plateau dykes that included seven north-northeast to northeast-trending dykes, eight northwest-trending dykes and two east to east-northeast-trending dykes were sampled for this study. Here, we report on the petrography and whole rock geochemistry of these dykes. We also report three new U-Pb baddeleyite ages along with some palaeomagnetic data. The mineralogy of the dykes is dominated by clinopyroxene and plagioclase showing varying degrees of alteration. Whole rock geochemical data identify the dykes as basalts with MORB, E-MORB or within plate-like signatures, suggesting an asthenospheric magma source. Our study indicates that the Ghaap Plateau dykes represent several magmatic events of markedly different age. Based on their whole rock geochemical composition, all but one of the dyke samples are tentatively arranged into four distinct groups (Groups A to D). Group A dykes (four dykes) are compositionally similar to the Umkondo Large Igneous Province (LIP). Two north-northeast-trending dykes of this Group yielded overlapping U-Pb baddeleyite ages of 1 103 ± 84 Ma and 1 112 ± 55 Ma, thereby adding to the known footprint of the Umkondo LIP along the western margin of the proto-Kalahari craton. In Group B (four dykes), one northeast-trending dyke yielded a U-Pb baddeleyite age of 1 929 ± 17 Ma. Its palaeomagnetic signature (Lat. 24.5°, Long. 317.6°, A95= 14.20°) is supported by a positive baked contact test and agrees well with the ~1.93 Ga Hartley LIP palaeopole. Group B dykes are thus interpreted to be related to the Hartley LIP, with our new 1 929 ± 17 Ma age supporting a wider extent for the Hartley magmatism than previously known. A new palaeopole for the Hartley LIP (Lat. 22.3°, Long. 327.4°, A 95 = 9.25°) was calculated by combining the data of our 1 929 Ma dyke with data reported previously from other sites. Whole rock geochemical data for the remaining dykes are consistent with the Karoo magmatism (two east to east-northeast-trending dykes of Group D) or the ~2.4 Ga Ongeluk LIP (north-trending dyke). The final four dykes (Group C) are difficult to match with other known mafic units. Precise geochronology is needed to confirm the exact age of these unassigned dykes.

Age and composition of perovskite in ultramafic lamprophyres from the Zima alkaline-ultramafic carbonatite complex, the southern margin of the Siberian craton: Petrogenetic implications

This paper presents data on the age and trace element composition of perovskites from dykes of ultramafic lamprophyres (aillikites) of the Zima alkaline-ultramafic carbonatite complex (Bolshaya Tagna and Bushkanay) located within the Urik-Iya graben, Eastern Sayan region, southern margin of the Siberian craton. The studied samples exhibit similar textural and structural features but differ slightly in the mineral composition of the groundmass. They have a porphyritic structure, a massive texture, and consist of olivine macrocrystals embedded in a fully crystallized groundmass composed of perovskite, apatite, spinel, phlogopite, garnet, carbonates, clinopyroxene and other minerals. The macrocrystals quantity varies between 40 and 50 vol%. With the exception of a single sample from the Bushkanay dyke, olivine is entirely replaced by serpentine and/or talc.Perovskites from aillikites of the Bolshaya Tagna intrusion exhibit crystals with normal zoning showing a decrease in Na, REE, and Nb contents with center-to-rim increasing Ca content. In contrast, minerals from the aillikites of the Bushkanay dyke demonstrate reverse zoning, with an increase in Na, REE, and Sr and decrease in Ca contents from the center to the rim. We suggest that during crystallization of perovskites, the magma parental to the aillikites of the Bolshaya Tagna intrusion and the Bushkanay dyke had nearly similar trace element composition, but after crystallization of the cores of perovskite crystals each melt portion evolved independently. The samples from the Bushkanay dyke show an increase in fO2 and the residual magma enrichment in REE, Na, and Sr as evidenced by their elevated contents at the rims of perovskite grains. In the Bolshaya Tagna aillikites after crystallization of perovskite cores, the melt was depleted in REE, Na, and Nb.Based on U-Pb dating of perovskites, the age of aillikites from the Bolshaya Tagna intrusion is 583–654 Ma. Perovskite from aillikites of the Bushkanay dyke is relatively young, with an age of 575 ± 39 Ma. The obtained ages are consistent with the age of formation of Neoproterozoic alkaline-ultramafic carbonatite complexes of the Siberian craton and other occurrences of aillikites in a response to extension of the Rodinia lithosphere.

New U-Pb zircon tuff ages and revised stratigraphic correlations in the Superior craton during the Great Oxidation Episode

Major environmental changes during the Great Oxidation Episode are recorded in 2.5–2.0 Ga sedimentary successions across the world. In North America, the Huronian Supergroup is the most complete succession, preserving three glacial intervals with possible equivalents in the Lake Superior region. The third and youngest glacial unit (Gowganda Formation, Cobalt Group) of the Huronian Supergroup has been correlated with glacial deposits of the Chocolay Group in the Lake Superior region. Here we present the results of in situ SHRIMP U-Pb geochronology of zircon in thin tuff layers from the basal Wewe Slate, Chocolay Group, from drill-core in the Marquette Range area, upper Michigan. Zircon U-Pb data from two intervals ∼16 m apart yielded weighted mean 207Pb/206Pb ages of 2174 ± 9 Ma and 2172 ± 6 Ma, which define the depositional ages of the Wewe Slate and the conformably underlying Kona Dolomite. In the Huronian Supergroup, SHRIMP U-Pb dating of zircon in a tuff bed from the Gordon Lake Formation, Cobalt Group, yielded a weighted mean 207Pb/206Pb age of 2318 ± 8 Ma, interpreted to be the age of deposition. Re-examination of previously published U-Pb zircon data from the Gordon Lake Formation (Rasmussen et al., 2013) yields a slightly older weighted mean 207Pb/206Pb age of 2310 ± 5 Ma. Our results show that the Wewe Slate, and probably the Kona Dolomite, are ∼150 million years younger than the ∼2.32 Ga Gordon Lake Formation, with which they were previously correlated. Our results suggest that the glacial deposits in the Lake Superior region represent a fourth Paleoproterozoic glaciation in North America, whose age range corresponds to that of the fourth and final early Paleoproterozoic glaciation in southern Africa. We propose that the Chocolay Group was deposited after the Huronian Supergroup and is broadly coeval with the rift-passive margin succession (Cycle 1 of the Kaniapiskau Supergroup) in the New Québec Orogen, Canada, whose deposition has been linked to rifting and breakup along the eastern margin of the Superior craton at ∼2.22 Ga.

Insights into the Phanerozoic evolution of the São Francisco Craton based on detrital zircon thermochronology and U-Pb-Hf geochronology

Basins within cratonic environments offer valuable insights into the fragmentation, dispersion, and agglutination of the lithosphere within supercontinents. The southern São Francisco Craton is home to sedimentary basins that formed in both intraplate tectonic settings (late Paleoproterozoic to Neoproterozoic and Mesozoic) and convergent tectonic settings (Ediacaran to Cambrian). To elucidate the Phanerozoic thermal history of the craton and the long-term depositional history of the southern São Francisco Craton’s cover, a comprehensive study was conducted utilizing detrital zircons through zircon fission-track (ZFT) thermochronology and U-Pb-Hf geochronology. This study analyzed samples from the following units: (1) the intracratonic basin—Lower and Upper Espinhaço Supergroup, with depositional age intervals ranging 1800−1600 Ma and 1200−920 Ma, respectively; (2) the rift-related passive margin basin—Lower Macaúbas Group (720 Ma and 640 Ma) and Jequitaí Formation, which is likely of Cryogenian age (650−635 Ma); (3) and the foreland basin—Bambui Group and Três Marias Formation, with ages of ca. 600−520 Ma and 520−480 Ma, respectively. U-Pb-Hf detrital zircon geochronology revealed the complex depositional history of the southern São Francisco Craton, and indicated changing source rocks over time. Conversely, the ZFT analysis of Precambrian to Cambrian samples allowed for the identification and characterization of Phanerozoic events in the southern São Francisco Craton. These events include: (1) the exhumation and late orogenic uplift of the foreland at ca. 500−480 Ma (mean age of 499 ± 5.5 Ma) during the late stages of the Brasiliano−Pan-African Cycle, which was associated with the Araçuaí Belt and lithospheric rebound of the peripheral cratonic margin of the southern São Francisco Craton; and (2) an age of 330−280 Ma (mean age of 306.6 ± 4.8 Ma) that possibly resulted from ice retreat and isostatic rebound interior of the Gondwana Paleocontinent. Additionally, analysis of detrital zircons from the Areado Group shows a later tectonic event recorded at 128.1 ± 9.4 Ma, which indicates Mesozoic intracontinental rifting. Based on these results and interpretations, the timing and exhumation of the southern São Francisco Craton during the Phanerozoic can be attributed to the final stages of the continental collision of the southern São Francisco Craton and Congo Craton and large-scale continental uplift during the Permo-Carboniferous late Paleozoic Ice Age of Gondwana. Overall, the findings demonstrate a direct correlation between known tectonic events at the plate margins of Western Gondwana and periods of cratonic basin formation.

Constraints on crustal compositional architecture across the North China-Altaids transition and implications for craton margin reworking

Abstract The phase of secular evolution of continents is manifested as the degree of compositional differentiation, modification, and maturation of continental crusts, which is vital in understanding the mechanism of continental evolution but is difficult to quantify. Here we use integrated passive- and active-source seismic profiling to conduct joint analysis and inversion and derive Vs and Vp/Vs section models across the North China craton (NCC) to southeastern Altaids boundary zone that bears a tectonic transition from a reworked ancient craton margin to a Phanerozoic accretionary orogen. We systematically exploited the imaged multiple physical properties as precise and delicate proxies to constrain the compositional architecture in the crust across this important tectonic transition subject to various crustal evolutional phases. Our Vs and Vp/Vs imaging, together with the existing isotopic data, characterizes the Yin Shan-Yan Shan belt as the northern NCC margin with layered homogeneous compositions that point to an evolved crust. However, the lower-crustal low-Vs/high-Vp/Vs signature that overlaps the shallowly dipping to horizontal reflective fabrics suggests the crust of the northern NCC margin has undergone considerable reworking through lower-crustal-stretching assisted melt migration and mixing since the late-Paleozoic to Mesozoic era. The process probably involved crust-mantle interaction and thus resulted in a compositionally modified ancient crustal basement. On the contrary, the southeastern Altaids domain manifests crustal complexity in compositions and structures inferred to be indicative of a juvenile crust of the Phanerozoic accretionary orogen. Our results provide deep physical-property constraints that shed new light on the crustal evolution of a complex craton margin.

Fluid–Melt–Rock Interaction during the Transition from Magmatism to HT-UHT-Granulite- and Amphibolite-Facies Metamorphism in the Ediacaran Adrar–Suttuf Metamafic Complex, NW Margin of the West African Craton (Southern Morocco)

Abstract Underplated mafic intrusions ponded at the base of the lower continental crust in extensional settings can experience ultra-high-temperature (UHT) granulite-facies metamorphism during tens of My due to slow cooling rates. These intrusions are also the source of heat and carbonic fluids for regional high-temperature (HT) granulite-facies metamorphism in the continental crust. This work analyses the fluid–melt–rock interaction processes that occurred during the magmatic to HT-UHT-granulite- and amphibolite-facies metamorphic evolution of high-grade mafic rocks from the Eastern Ediacaran Adrar–Suttuf Metamafic Complex (EASMC) of the Oulad Dlim Massif (West African Craton Margin, Southern Morocco). P–T conditions were determined using Ti-in-amphibole thermometry, two-pyroxene and amphibole–plagioclase thermobarometry, and phase diagram calculations. The thermobarometric study reveals the presence of tectonically juxtaposed lower- and mid-crustal blocks in EASMC that experienced decompression-cooling paths from, respectively, UHT and HT granulite-facies conditions at ca. 1.2 ± 0.28 GPa and 975 ± 50°C, and ca. 0.82 ± 0.15 GPa and 894 ± 50°C, to amphibole-facies conditions at ca. 0.28 ± 0.28 GPa and 787 ± 45°C (precision reported for the calibrations at 1 s level). An age for the magmatic to UHT granulite-facies metamorphic transition of 604 Ma was constrained from published SHRIMP Th–U–Pb zircon ages of the igneous protoliths. An amphibole 40Ar–39Ar cooling age of 499 ± 8 Ma (precision at 2 s level) was obtained for the lower-crustal blocks. Amphibole 40Ar–39Ar closure temperatures of 520–555°C were obtained for an age range of 604–499 Ma and an average constant cooling rate of 4.2°C/My, suggesting that the lower-crustal blocks cooled down to the greenschist–amphibolite facies transition in ca. 100 My. During the high-temperature stage, interstitial hydrous melts assisted textural maturation of the rock matrix and caused incongruent dissolution melting of olivine and pyroxenes, and, probably, development of An-rich spikes at the grain rims of plagioclase, and local segregation of pargasite into veins. Subsequent infiltration of reactive hydrous metamorphic fluids along mineral grain boundaries during cooling down to amphibolite-facies conditions promoted mineral replacements by coupled dissolution-precipitation mechanisms and metasomatism. Ubiquitous dolomite grains, with, in some cases, evidence for significant textural maturation, appear in the granoblastic aggregates of the high-grade mafic rocks. However, calculated phase relationships reveal that dolomite could not coexist with H2O–CO2 fluids at HT-UHT granulite- and low-medium P amphibolite-facies conditions. Therefore, it is proposed that it may have been generated from another CO2-bearing phase, such as an immiscible carbonatitic melt exsolved from the parental mafic magma, and preserved during cooling due to the prevalence of fluid-absent conditions in the granoblastic matrix containing dolomite. The lower-crustal mafic intrusions from EASMC can represent an example of a source of heat for granulitisation of the mid crust, but a sink for carbon due to the apparent stability of dolomite under fluid-absent conditions.