Pitted impact deposits (PIDs) on Vesta have been shown to exhibit distinct spectral characteristics with respect to their surrounding host deposits and other typical Vestan areas regarding the first major pyroxene absorption near 0.9 μm. The PIDs, especially those in the ejecta blanket of the large crater Marcia, show higher reflectance and pyroxene band strength with respect to their impact deposit surroundings. This study complements the spectral characterization of the PIDs on Vesta with Visible and Infrared Spectrometer observations obtained by NASA’s Dawn mission. In particular, we focus on the second major pyroxene absorption near 1.9 μm. We analyze nine PIDs in the ejecta blanket of the crater Marcia, as well as PIDs within the crater-fill deposits of the craters Marcia, Cornelia, and Licinia. We find that the second pyroxene absorption behaves in similar ways as the first major pyroxene absorption. The PIDs in Marcia’s ejecta blanket show higher reflectance and pyroxene band strength with respect to their immediate impact deposit surroundings. The PIDs present in the crater-fill deposits of Marcia, Cornelia, and Licinia, however, do not show such spectral characteristics. This is also consistent with previous observations of the first pyroxene absorption band. Based on the experimental results of other studies, we speculate that the observed spectral distinctness arises from an oxidation process in the interior of impact deposits, where Fe cations migrate within their host pyroxene grains. Thus, the surfaces of (melt-bearing) impact deposits might be different from their interiors, apart from space-weathering effects.