Cracking Products Research Articles

Determination of the Optimum Moisture Content for the Whole Kernel Recovery During the Cracking Process of Oil Palm Nuts

This study aimed to investigate the effect of moisture content on palm nut cracking and kernel production using a locally fabricated palm nut cracker. Palm nuts of mixed varieties (Dura, Tenera, and Pisifera) were manually cleaned and dried at different moisture content levels ranging from 8.53% to 26.82%. The palm nut cracker is designed with four major units: the in-feed unit, cracking unit, discharge unit and the driving unit. The cracking efficiency was determined by calculating the ratio of completely cracked nuts to the total nuts fed into the hopper. Results show that the whole kernel recovery varies considerably with moisture content and cracking speed. At the lowest moisture content of 8.58%, the whole kernel recovery is generally low across all the cracking speeds. As the moisture content increases, there is a significant improvement in whole kernel recovery at all the cracking speeds. The highest whole kernel recovery was obtained at intermediate moisture contents of around 14% to 18%, and the cracking speeds of 1000 rpm to 1400 rpm. The ANOVA table shows that both the cracking speed and moisture content have a significant effect on whole kernel recovery. Optimizing these parameters could lead to higher whole kernel recovery. However, it is important to note that other factors such as the cultivar of the nut and the equipment used may also affect the whole kernel recovery.

Coupling Conversion of CO2 and High‐Carbon Alkane to CO and Gasoline

AbstractCatalytic conversion of CO2 to valuable products is a promising way to reduce anthropogenic CO2 emission. Herein, a strategy for coupling conversion of CO2 and high‐carbon alkane to CO and gasoline is developed, which is a feasible choice for the combination of CO2 recycling and petroleum refining. The CO2 conversion reaches 2.6% under mild condition (270 °C), and the selectivity of gasoline in the cracking products exceeds 70 wt%. Additionally, the introduction of CO2 improves the selectivity of aromatic hydrocarbons and increases the octane number of gasoline. Mechanism studies indicate that synergistic effect between Brønsted acid centers and Ni sites on the Beta zeolite supported Ni (20 wt%) catalyst (20Ni/β) plays the key role in alkane cracking and CO2 reduction. Notably, 13CO2 isotopic experiments show that the hydrogen produced during the aromatization can be captured by CO2, inhibiting undesired hydrogen transfer pathways and enhanced the yield of aromatics, while CO2 is converted into valuable CO.

Functional ingredients in cracker production

Functional ingredients in cracker production

Compositon of Cracking Products of Resins and Asphaltenes and their Mixture in Case of Methane Crude Oil

Compositon of Cracking Products of Resins and Asphaltenes and their Mixture in Case of Methane Crude Oil

Influence of Mineral Components on the Composition of Oil Shale Organic Matter Cracking Products

Influence of Mineral Components on the Composition of Oil Shale Organic Matter Cracking Products

Effect of pre-oxidation on the rate of formation of sulfur-containing aromatic compounds during vacuum gas oil thermal cracking

It was shown that oxidation followed by heat treatment is an effective method for desulfurization of vacuum gas oil. Patterns of changes in the quantitative content of the thiophene series compounds in liquid cracking products of vacuum gas oil and liquid cracking products of pre-oxidized vacuum gas oil are described. A mixture of hydrogen peroxide and formic acid (molar ratio 3:4) was used as the oxidation system. The hypothetical mechanism for the formation of thiophene, benzo- and dibenzothiophene and their homologues from high-molecular weight components of the initial vacuum gas oil and its oxidation products is proposed. Presumably, main path of formation considerate compounds is thermal decomposition of high-molecular weight sulfur-containing components. On the basis of IR spectroscopy and structure-group analysis data, the averaged structures of such components were constructed. The influence of pre-oxidation and its conditions on the value of the rate constants for the formation of thiophene, benzo- and dibenzothiophene and their homologues during thermal cracking of initial and oxidized vacuum gas oils is studied.

Analisis Pengurangan Produk Cacat pada Produksi Kerupuk Bawang dengan Metode Six Sigma pada UD. Rukun Jaya Pasuruan

Failed products are a challenge for business people in doing business. UD. Rukun Jaya produces food products, namely onion crackers. The problem encountered in this business is product defects resulting from the onion cracker production process which causes the average percentage of defective products for the period January - April 2024 to be 4.22% with a sigma value of 4.59. The type of defect that dominates is onion crackers, namely crushed onion crackers, unsold products, hard texture, and damaged packaging. This failure is actually trivial, but it can disappoint customers. This research aims to provide a solution in the hope of reducing the number of product defects produced using the six sigma and FMEA methods. This research produces information on the causes of defective product problems, dominated by the type of defect in broken or crushed crackers and unsold crackers. The type of defect in crushed keupuk products is dominated by suppliers and employees who are not careful when frying and shipping. Meanwhile, the product did not sell because the employees were not good at marketing and what was more, there was no good marketing strategy and the crackers sold were not diverse enough.

Effects of the depth of hydro desulfurization of raw materials on the yields of catalytic cracking products

The article is devoted to the problem of complex processing of oil feedstock and increasing the output of light petroleum products, in particular, catalytic cracking gasoline. Currently, the oil refining industry of Kazakhstan is faced with the task of complex processing of hydrocarbon raw materials, increasing the depth of processing and output of light petroleum products. In this connection it is urgent to solve the problem of lack of raw materials for oil refineries of the Republic of Kazakhstan. The complexity of solving the problem of processing residues of oils, fuel oil and intermediates of secondary processes lies in the fact that they contain a large amount of various sulfur compounds. This problem concerns not only domestic refineries, for example, oil from Uzbekistan fields contains a relatively large amount of SO2 compounds, which in turn contains about 1.28% sulphur. The high content of sulfur compounds in oil not only negatively affects the quality and environmental friendliness of manufactured products, but also reduces the service life of equipment and oil refineries. In this regard, the preparation and hydrodesulfurization of raw materials is one of the main issues of intensifying the process of catalytic cracking of petroleum raw materials of "PKOP" LLP. The issues of possibility of modernisation of catalytic cracking process units by including the process of hydrodesulphurisation of feedstock in order to improve the quality and yield of light products when using fuel oil and secondary intermediates having a large volume of various sulphur compounds in their composition have been considered by the authors. To evaluate the influence of the depth of hydrodesulfurisation of feedstock on the yields and composition of catalytic cracking products, the cracking of crude and hydrotreated hydrogenated vacuum gas oil mixed with fuel oil was carried out on a laboratory unit. The experiments were carried out on a fluidised catalyst bed at mass feed rates of 2h-1 and 4h-1, catalyst to feed ratio of 3:1 and temperature equal to 5100 C. The analysis of the experimental data obtained showed that preliminary hydrotreating of a mixture of vacuum gas oil and sulfur fuel oil followed by catalytic cracking increases the depth of oil refining and helps to increase the yield of catalytic distillate, improves its quality, which ultimately leads to a decrease in environmental pollution with sulfur compounds.

Evaluation of the nutritional and chemical composition of crackers developed from blends of wheat, unripe plantain, and mushroom flour

Crackers are considered a healthier substitute for other types of biscuits that are more calorie-dense. Novel ingredients are therefore being searched for in the formulation of crackers. This study evaluated crackers' nutritional and chemical composition from blends of wheat, unripe plantain, and mushroom flours. Compared to wheat flour, the functional properties of the blends showed high water absorption capacity (WAC), and bulk density, while swelling capacity was not significantly affected. The moisture (4.98–8.51 %), protein (10.47–21.31 %), fat (7.17–11.46 %), fiber (0.20–0.60 %), and ash (1.61–3.47 %), contents of the composite crackers were higher, while carbohydrate content (51.81–72.07 %) was lower than the control. The soluble and insoluble dietary fiber increased from 5.13 % to 9.00 %, and 3.49 % to 7.08 % respectively. K and Na were the principal minerals in the crackers based on the mineral analysis results, which increased upon 10 % replacement of mushroom flour. The oxalate and phytate contents of the crackers ranged between 0.05–0.07 mg/g and 7.78–14.98 mg/g respectively. The crackers with 10 % replacement of mushroom flour were accepted by panelists. The study revealed the feasibility of cracker production with enhanced nutritional composition using wheat, unripe plantain, and mushroom flour blends.

EFFECT OF DIDODECANOYL PEROXIDE ON TRANSFORMATIONS OF HIGH-SULFUR VACUUM RESIDUE COMPONENTS IN THE PROCESS OF INITIATED CRACKING

This paper presents the results of the study of the composition of cracking products of high-sulfur tar obtained from oil of Zyuzeyevskoye field in the presence of radical-forming additive – didodecanoyl peroxide. Thermal treatment of the mixture of vacuum residue with different amounts of didodecanoyl peroxide was carried out at a temperature of 500 °C. The duration of the process was 15 min. Characteristic features of changes in the material balance of the process, group composition of liquid cracking products, qualitative and quantitative composition of newly formed sulfur compounds were established. The use of additive in the amount of 0.5 – 0.75%wt. allows to reduce thermal stability of high-molecular components of tar (resins and asphaltenes), and also promotes change in direction of reactions. Processes of condensation of resins and asphaltenes into solid coke-like products are slowed down, and cracking reactions are initiated with formation of low-molecular components, which fall into the composition of oils, as a result of which it is possible to obtain additional amounts of distillate fractions. It is shown that thiophene, benzo- and dibenzothiophene derivatives, which are absent in the initial tar, are intensively formed and accumulated in the composition of liquid cracking products, which worsens the quality of the obtained distillate fractions. Among the identified sulfur compounds benzothiophene homologs prevail. It was found that cracking of tar in the presence of additive didodecanoyl peroxide promotes deep destruction of sulfur-containing fragments of vacuum residue and asphaltene molecules. Sulfur compounds formed under these conditions not only get into the composition of oils, but also participate in condensation reactions with the formation of solid products, which leads to an increase in the degree of sulfur removal from the composition of liquid cracking products. For citation: Goncharov A.V., Krivtsov E.B. Effect of didodecanoyl peroxide on transformations of high-sulfur vacuum residue components in the process of initiated cracking. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2024. V. 67. N 8. P. 121-128. DOI: 10.6060/ivkkt.20246708.15t.

STUDY OF THE EFFECT OF SUPERCRITICAL WATER ON SOLID PRODUCTS OBTAINED AFTER CRACKING

One of the possible applications of supercritical water is the conversion of heavy hydrocarbon feedstocks with a high content of resins and asphaltenes. The use of supercritical water makes it possible to reduce the yield of solid products and increase the yield of light fractions. In this work, a comparative analysis of the cracking processes of petroleum residue, asphaltenes and resins isolated from it was carried out in an environment of supercritical water and without water. The experiments were carried out in an autoclave at a temperature of 450 °С and a pressure of up to 47 MPa. Cracking duration – 60 min. Cracking of petroleum residue, as well as its individual components - resins and asphaltenes, in a supercritical water environment - showed a positive effect on conversion; in all experiments, the yield of solid products decreased and the yield of maltenes increased. Solid products were studied using X-ray diffraction and thermogravimetric analysis and scanning electron microscopy. Using X-ray diffraction analysis, the influence of supercritical water on the parameters of the macrostructure was studied. It was determined that cracking with water affects the increase in the distance between saturated fragments of molecules (dr) in the structure of solid cracking products in comparison with products obtained without water. Using scanning electron microscopy, the surface of particles of insoluble cracking products was characterized. Solid products obtained in a supercritical water environment have a porous surface. According to thermal analysis data, it is shown that solid products obtained by cracking in water are characterized by more intense dynamics of sample weight loss and a smaller residue at the final temperature. For citation: Nalgieva Kh.V., Kopytov M.A. Study of the effect of supercritical water on solid products obtained after cracking. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2024. V. 67. N 8. P. 113-120. DOI: 10.6060/ivkkt.20246708.14t.

THERMAL TRANSFORMATIONS OF MALTENES AND OILS FROM HEAVY METHANE BASE CRUDES

The paper considers changes of composition of oils and maltenes during thermal cracking process. The oils and maltenes (mixture Oils+Resins) were isolated from crudes from two oil fields: Zyuzeevskoye (Republic of Tatarstan) and Zuunbayanskoye (Mongolia). Both crudes relate to methane type, but differ by content of saturated, aromatic hydrocarbons, resins, asphaltenes and sulfur. Cracking of oils and (O+R) mixtures was carried out at 450 °С for 120 min in isothermal mode. Data on the mass balance of process, composition of gaseous and liquid cracking products were obtained. It was shown the С1-С5 hydrocarbons are predominate in the composition of gaseous cracking products of oils and (O+R) mixtures. Independent of cracking object their content changes in a series: C1 > C2 > C3 > С4-С5. The dynamics of group hydrocarbon composition changes in thermolysates was studied. It was shown the thermal transformations of hydrocarbons steer in the direction of destruction reactions during cracking of oils with high content of saturated hydrocarbons, as it indicated by gaseous products yield. Condensation reactions are dominated during cracking of oils, in composition of which aromatic hydrocarbons are prevail. It was shown the addition of resins into the complex multicomponent mixture of hydrocarbons leads to directivity change of cracking free radical reaction behavior. Differences in structural-group characteristics of average resins molecules reflect not only on the yield of solid and gaseous cracking products of (O+R) mixture, but also affect on the directivity of hydrocarbons thermal transformations. Moreover it is impossible to exclude the effect of differences in the content of saturated and aromatic hydrocarbons in the composition of oils on the components thermal transformations during cracking process of (O+R) mixtures. For citation: Voronetskaya N.G., Pevneva G.S. Thermal transformations of maltenes and oils from heavy methane base crudes. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2024. V. 67. N 8. P. 59-67. DOI: 10.6060/ivkkt.20246708.4t.

THE EFFECT OF ASPHALTENES QUANTITY ON THERMAL AND CATALYTIC CRACKING PRODUCT YIELD OF HEAVY OIL FROM KARMALSKOYE FIELD

The study investigated the composition of products resulting from thermal and catalytic cracking of mixtures of deasphaltenized oil from the Karmalskoye field with asphaltenes content of 0.0, 5.2, and 10.4wt.%. The experiments were conducted at a temperature of 450 °C for a duration of 100 min. The catalyst used was a mixture of tungsten carbide and nichrome powders (NiCrWC), in an amount of 0.1%wt. The presence of the NiCrWC additive during cracking of mixtures of deasphaltenized oil with different asphaltenes content has been shown to increase the yield of oils, gasoline, and diesel fractions while reducing the yield of coke and asphaltenes compared to thermal cracking. During the catalytic cracking of all the mixtures studied, the combined yield of gasoline and diesel fractions exceeds 70%wt. It is important to note that an increase in asphaltenes content during catalytic cracking results in a decrease in the yield of gasoline fractions and an increase in the yield of diesel fractions. Studies have demonstrated that the thermal cracking of heavy oil mixtures with different asphaltene contents results in a decrease in the contents of saturated and monoaromatic hydrocarbons, while the contents of biaromatic and triaromatic hydrocarbons increase. Additionally, the presence of asphaltenes has been found to impact the formation of polyaromatic hydrocarbons. During catalytic cracking, the content of saturated, monoaromatic, and biaromatic hydrocarbons increases, while the content of triaromatic and polyaromatic hydrocarbons decreases. During catalytic cracking, the average structure of asphaltene molecules undergoes significant changes. The molecules become smaller, more aromatic, and monoblock, with fewer carbon atoms in the saturated moieties. This catalyst also helps reduce the amount of heteroatoms in the resulting asphaltenes. For citation: Sviridenko N.N., Urazov Kh.Kh., Sergeyev N.S. The effect of asphaltenes quantity on thermal and catalytic cracking product yield of heavy oil from Karmalskoye field. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2024. V. 67. N 8. P. 76-84. DOI: 10.6060/ivkkt.20246708.6t.

Preparation of Financial Statements in Accordance with SAK EMKM in the UD Restu Jaya Cracker Business, Puger District, Jember Regency

This study aims to analyze the application of financial accounting standards for micro, small and medium entities (SAK EMKM) at UD Restu Jaya Puger. This research was conducted on MSMEs engaged in production, namely cracker production. This research uses a qualitative method with a type of descriptive approach. This research was carried out by obtaining data through observation, interviews and documentation. The results of this study show that UD Restu Jaya in its financial records is still manual and simple, because the owner has not understood how to prepare financial statements in accordance with SAK EMKM and there has been no socialization received related to the SAK EMKM that has been determined. This research is expected to provide information for MSME owners in implementing financial statements in accordance with SAK EMKM.

Research on the formation and evolution mechanism of cracks in laser stealth dicing of silicon carbide crystals

In this study, to enhance the cutting efficiency and precision of the chip while minimizing waste from cutting damage, molecular dynamics simulation is used to investigate the formation mechanism of defects and cracks of silicon carbide crystals during the laser stealth dicing. The results showed that the high thermal stress generated by the laser scanning induced the production and expansion of cracks. Thus, the crack propagates in the direction of [100], and subsequently forms branches in the directions of [101] and [101‾]. It also can be found that the silicon carbide crystals produced dislocation slip, and the dislocation lines moved along the slip surface, which impeded the crack extension in the directions of [101‾] and [1‾01‾]. In addition, atomic phase transformation and loss is occurred under the high-temperature environment of the laser heating process. Cubic diamond crystal structure atoms are partially transformed into amorphous structure, while a small portion transformed into hexagonal diamond structure. The crystal structural arranged orderliness temporarily increased and then rapidly decreased due to prefabrication defects, and new unknown crystal structures are produced.

Sustainable Business Development Strategy In Cassava Cracker Production Business

Cassava is a plant originating from Central and South America, as a type of tuber plant that has high carbohydrates. As many people know, food made from cassava will give a feeling of satiety, so in some regions in Indonesia cassava is used as a staple food as a substitute for rice. As a root crop that cannot last long, some people take the initiative to process cassava into dry food that can be stored for several months but still has a good taste as a snack or food accompaniment. Several groups of housewives took the initiative to process cassava into savory and crispy crackers, and can increase family income. As a cassava cracker processor in the countryside, it still uses a chopper for raw materials that are still simple to produce cassava crackers. The purpose of this study is to find out the level of effectiveness of cassava cracker processing so that it has more selling value and export quality, with a strategy that can develop a sustainable business, so that it becomes one of the products that is competitive and exported abroad. In terms of production, cassava cracker orders are quite promising, but are still constrained by several conditions that result in not fulfilling all orders. This makes the researcher intend to help producers to be able to increase the production of cassava crackers that have characteristics and can be competitive until they are exported abroad. The strategies offered will have an impact on improving business results and sustainable and competitive cracker production processes, testing the quality of cassava crackers, packaging and branding, and marketing strategies. The expected output is that researchers can contribute to sustainable business development for producers and can be published in international journals.

The effect of starch types on extensional, linear and nonlinear rheological properties of starch cracker dough

Cracker is a popular snack, and their quality depends on the rheological properties of the dough during production. This study focused on the impact of different starch types (tapioca, corn, and potato) used in the same amount (30 g) on the rheology of starch cracker dough. Various rheological tests were conducted to assess the dough's properties. Linear viscoelastic properties were determined using oscillatory frequency and temperature sweep tests, while the nonlinear viscoelastic behavior was characterized through stress relaxation and creep recovery tests. Extensional rheological behavior was also examined. Additionally, the textural and thermal properties of the dough were monitored to understand starch gelatinization and its interactions with other components. In the linear viscoelastic region, no significant differences were found between different dough formulations. However, in the nonlinear viscoelastic region, the potato starch-containing formulation exhibited different viscoelastic and textural properties. Biaxial extensional rheological behaviors showed no significant variations between formulations. The temperature sweep test data from differential scanning calorimetry measurements were consistent with temperature sweep data. In summary, this study provides valuable insights into how different starches influence the rheological behavior of starch cracker dough, considering various degrees of deformation and temperature. These findings have implications for cracker production parameters.

Production risk management of prawn crackers using fuzzy FMEA and fuzzy AHP methods

Prawn crackers hold a significant position within Indonesia's agro-industrial product landscape. The industrial process involved in their production is fraught with potential risks that could result in substantial losses for companies. PT. XYZ, a prominent prawn cracker producer in Indonesia, grapples with various risks, including non-compliant raw material supplies, machinery and equipment breakdowns, product defects, and process failures. Hence, there is an imperative need for comprehensive risk management involving further analysis, identification of potential failure modes, and formulation of mitigation strategies to curb losses. This research aims to ascertain the priority of potential failure modes and their corresponding mitigation strategies in the prawn cracker production process at PT. XYZ. The study employs risk analysis through the Fuzzy Failure Mode and Effect Analysis (Fuzzy-FMEA) method and determines mitigation strategies using the Fuzzy Analytical Hierarchy Process (Fuzzy-AHP) method. The findings reveal 11 identified failure modes in PT. XYZ's prawn cracker production process, with machinery and equipment damage emerging as the top-priority failure mode, giving a Fuzzy Risk Priority Number (FRPN) value of 7.620. The recommended mitigation strategy involves intensifying inspections of production machinery and equipment, both before and after use by workers, with a weight of 0.368.

UTILIZATION OF BUSINESS INTELLIGENCE IN MARKETING STRATEGY FOR BALADO SHRIMP CRACKER PRODUCTS

This research explores the integration of business intelligence (BI) tools in the marketing strategy for Balado Shrimp Cracker products, aiming to enhance consumer insights and competitive advantage in the snack industry. Through qualitative research methods, the study investigates how BI facilitates the identification and analysis of consumer preferences, purchasing behaviors, and competitor dynamics. The findings emphasize the importance of leveraging BI for data-driven decision-making, personalized marketing initiatives, and proactive market intelligence. By harnessing BI, Balado can optimize its marketing strategies, drive growth, and foster brand loyalty amidst a competitive landscape.

Gluten-free crackers using chickpea and pumpkin seed press cake blend: Effects of gastrointestinal digestion

The use of a blend of chickpea and pumpkin seed press cake flours in the production of gluten-free crackers represents a promising strategy to address nutritional gaps and meet the growing demand for healthier gluten-free options. To test this assumption, an in vitro digestion method was employed to assess changes in total phenolic content, antioxidant activity, protein composition, electrophoretic patterns, and mineral content of gluten-free crackers formulated using these raw materials before and after digestion. The crackers were produced substituting 20% and 35% of chickpea flour by using two types of pumpkin seed press cake flour, one from virgin oil pressing (VFC) and the other from cold-pressed oil pressing (CFC). This approach aimed to assess how the treatment history of the pumpkin seed press cake flour affected the tested parameters. All samples displayed a 3- to 4-fold increase in total phenolic content after in vitro digestion. A noticeable enhancement in antioxidant activity is observed, where CFC samples showed higher values compared to VFC samples. The control sample and 35CFC sample present similar protein digestibility values (%), 76.97 and 77.05 respectively, while other crackers showed significantly lower digestibility. Incorporation of pumpkin seed press cake flours leads to a substantial increase in mineral content, notably zinc (up to 2-fold), iron (up to 40%), and magnesium (up to 2.5 fold). Overall, the study provides valuable insights into the utilization of pumpkin seed press cake as a potential source of bioactive compounds, emphasizing its significance beyond its traditional role as a by-product.