We report a comprehensive study on low-lying parity doublet states of 224Rn by mixing both quadrupole- and octupole-shaped configurations in multireference covariant density functional theory, in which broken symmetries in configurations are restored using projection techniques. The low-lying energy spectrum is reasonably reproduced when the shape fluctuations in both the quadrupole and octupole shapes are considered. Electric octupole transition strength in 224Rn is found to be B(E3;31-→01+)=43\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B(E3; 3^-_1 \\rightarrow 0^+_1)=43$$\\end{document} W.u., comparable to that in 224Ra, whose data are 42(3) W.u.. Our results indicate that 224Rn shares similar low-energy structure with 224Ra despite the excitation energy of first 3-\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$3^-$$\\end{document} state of the former nucleus is higher than that of the latter. This study suggests 224Rn is a candidate for the search for permanent electric dipole moment.
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