Coupled Quantum Research Articles

Theoretical Study on Singlet Fission Dynamics and Triplet Migration Process in Symmetric Heterotrimer Models.

Singlet fission (SF) is a photophysical process where one singlet exciton splits into two triplet excitons. To construct design guidelines for engineering directional triplet exciton migration, we investigated the SF dynamics in symmetric linear heterotrimer systems consisting of different unsubstituted or 6,13-disubstituted pentacene derivatives denoted as X/Y (X, Y: terminal and center monomer species). Time-dependent density functional theory (TDDFT) calculations clarified that the induction effects of the substituents, represented as Hammett's para-substitution coefficients σp, correlated with both the excitation energies of S1 and T1 states, in addition to the energies of the highest occupied and lowest unoccupied molecular orbitals (HOMO and LUMO). Electronic coupling calculations and quantum dynamics simulations revealed that the selectivity of spatially separated TT states for heterotrimers increased over 70%, superior to that in the homotrimer: an optimal region of the difference in σp between the substituents of X and Y for the increase in SF rate was found. The origin of the rise in SF rate is explained by considering the quantum interference effect: reduction in structural symmetry opens new interaction paths, allowing the S1-TT mixing, which contributes to accelerating the hetero-fission between the terminal and center molecules.

Ultrastrong coupling limit to quantum mean force Gibbs state for anharmonic environment.

The equilibrium state of a quantum system can deviate from the Gibbs state if the system-environment (SE) coupling is not weak. An analytical expression for this mean force Gibbs state (MFGS) is known in the ultrastrong coupling (USC) regime for the Caldeira-Leggett (CL) model that assumes a harmonic environment. Here, we derive analytical expressions for the MFGS in the USC regime for more general SEmodels. For all the generalized models considered here, we find the USC state to be diagonal in the basis set by the SEinteraction, just like in the CL case. While for the generic model considered, the corresponding USC-MFGS is found to alter from the CL result, we do identify a class of models more general than the CL model for which the CL-USC result remains unchanged. We also provide numerical verification for our results. These results provide key tools for the study of strong coupling quantum thermodynamics and several quantum chemistry and biology problems under more realistic SEmodels, going beyond the CL model.

Qubit-qubit quantum coherence mediated by an epsilon-near-zero waveguide

Quantum coherence, as a more general quantum resource compared to quantum entanglement, has attracted increasing attention over recent years. Establishing stable quantum coherence is crucial for implementing reliable quantum information tasks. In this study, we propose a scheme to generate stable quantum coherence of two qubits via an epsilon-near-zero (ENZ) waveguide. We find that employing Si3N4 rather than SiO2 results in stronger qubit-qubit coupling and maximal quantum coherence in a certain range. We derive analytical expressions for both quantum coherence and quantum entanglement, allowing for direct comparison within a unified framework. To achieve stable quantum coherence, classical field driving is introduced. We find that stable coherence is much larger and easier mediated than that of stable entanglement. Our work contributes to the creation of a new stable quantum resource via an ENZ waveguide.

Rotational excitation of methyl mercaptan (CH3SH) in collisions with molecular hydrogen

ABSTRACT This paper presents the calculation of rate coefficients for transitions between rotational levels of the A-type and E-type levels of methyl mercaptan (CH$_3$SH), resulting from collisions with molecular hydrogen. Radiative transfer modelling requires both radiative and collisional rates to describe the rotational populations under the usual conditions in interstellar clouds where local thermodynamic equilibrium conditions do not apply. To compute the intermolecular interaction between CH$_3$SH and H$_2$, the explicitly correlated CCSD(T)-F12a coupled-cluster method that utilized a correlation-consistent aug-cc-pVTZ basis was employed. The computed energies were fit to a functional form suitable for use in scattering calculations. Rate coefficients were calculated over the temperature range from 5 to 100 K for transitions between the 110 lowest CH$_3$SH rotational levels (having energies less than 107 cm$^{-1}$ (ca. 150 K) within both the A-type and E-type manifolds caused by collisions with para- and ortho-H$_2$. The rate coefficients were obtained through time-independent quantum close coupling quantum scattering calculations utilizing the calculated potential energy surface.

Coupled cylindrical quantum well wires in broken symmetry: effects of intense laser field on the harmonic generations

Coupled cylindrical quantum well wires in broken symmetry: effects of intense laser field on the harmonic generations

Spatial electron-photon entanglement

Free electron beams and their quantum coupling with photons are attracting a rising interest due to the basic questions they address and the innovative technology these particles are involved in, such as microscopy, spectroscopy, and quantum computation. This work proposes spatially encoded coupling, where a dual-rail-like electron (e−) state is entangled to a dual-rail photonic qubit. Thus, it complements the leading current concept of the coupling, which links photonic Fock states with the e− energy. Importantly, we show that a spatial electron-photon pair can reach maximal entanglement and propose mutually unbiased bases for verifying the entanglement in a realistic experimental apparatus. Although the energy-level coupling of an e− beam with photonic excitations is well understood, we show that a naïve approach for extending such interaction from a single to a double path results in a retrocausal paradox. In the future, the atomic scale precision of electron microscopes can harness such position-encoded free-e− entangled qubits for novel quantum sensing and quantum transduction. Published by the American Physical Society 2024

Exploring the inorganic perovskite materials Mg3SbX3 (Where, X=I, Br, Cl and F) through the perspective of density functional theory: Adjustment of physical characteristics as consequence of strain

The solar technology industry has lately given inorganic perovskite materials an abundance of thought because of their unique optical, electrical and structural characteristics. Issues pertaining to lead (Pb) toxicity and instability require being referred to promptly, making lead-free atomically designed metal halide perovskites of foremost importance to the photovoltaic and optoelectronic industries. Perovskites, a class of inorganic metal halide semiconductors, have variant similarities with Mg3SbX3 (X = I, Br, Cl and F). According to the space group Pm-3m Mg3SbX3 (X = I, Br, Cl and F) has a cubic perovskite crystal structure. Utilizing first-principles density-functional theory (FPDFT), The intention of this investigation is to analyze how strain and spin-orbit coupling (SOC) impact the structural, electrical, optical and mechanical features of the inorganic cubic perovskite of Mg3SbX3 (X = I, Br, Cl and F). At the point between R and Γ, the Mg3SbI3,Mg3SbBr3,Mg3SbCl3 molecule displays an indirect bandgap of 0.105 eV, 0.957 eV, 1.728 eV. At the Γ point, the Mg3SbF3 molecule displays a direct bandgap of 3.184 eV. The bandgaps of the Mg3SbI3,Mg3SbBr3,Mg3SbCl3 and Mg3SbF3 perovskites are 0.198 eV, 1.203 eV, 1.901 eV and 3.723 eV respectively, when considering the spin-orbital coupling (SOC) quantum influence. A wider bandgap is investigated for increasing compressive strain while a smaller bandgap is observed for increasing tensile strain. Apart from the elastic constants and anisotropic factors, other factors that are anticipated include Pugh's ratio, Poisson's ratio, bulk modulus and others. Isotropic, ductile and mechanically stable are the words that best describe these materials, according to the elastic property evaluations. In the photon energy range that is appropriate for solar cells, the dielectric constant spikes of Mg3SbX3 are found to be visible. Therefore, Mg3SbX3 (X = I, Br, Cl and F) perovskite is a good material to use in solar cells for managing light and producing electricity.

Different Optical Behaviors Revealed by Electroluminescence and Photoluminescence of InGaN/GaN Coupled Quantum Wells.

The optical properties of wurtzite violet InGaN/GaN coupled quantum well (QW) structures are experimentally studied using photoluminescence (PL) and electroluminescence (EL) spectroscopy. Two emission peaks, referred to as Peak H and Peak L, are observed in both PL and EL spectra, due to the ground state splitting induced by the well coupling. Experimental PL and EL results reveal that coupled QWs show different optical responses due to the different variation in the electric field inside the QW structure. Since the direction of the polarization electric field of the as-grown well/barrier layers is different, the external electric field applied by electrodes can change the energy band alignment between the well and the barrier layers, thus adjusting the coupling between the wells. Our results provide relevant information to improve our understanding of the optical properties of InGaN/GaN QWs and to develop novel optoelectronic devices.

Exploring Fractal Quantum Field Theory in Higher-Order Dimensions Using the McGinty Equation

This hypothesis investigates the application of the McGinty Equation to quantum fields in higher-order dimensions, proposing that these fields exhibit self-similar fractal properties. The primary objective is to understand the implications of fractal geometry on quantum field interactions, coupling constants, and particle scattering processes, offering new insights into the fundamental forces and the structure of spacetime.

Spin Transport Through Asymmetric Coupled Quantum Dots Between Ferromagnetic Leads

Spin Transport Through Asymmetric Coupled Quantum Dots Between Ferromagnetic Leads

Unraveling how hydrogen-bonding networks affect the capture of amphetamine-type stimulants by polymerized deep eutectic solvent modified magnetic biochar: Coupling quantum chemical calculations with experiment

The abuse of amphetamine-type stimulants (ATSs) has caused irreversible harm to public safety and ecosystems. A novel polymerized deep eutectic solvent modified magnetic pomelo peel biochar (PMBC) was prepared, and the differences in adsorption of four abused amphetamine-type stimulants (ATSs: AMP, MAMP, MDA and MDMA) were due to varying hydrogen bonds quantities and strengths. PMBC showed excellent chemical reactivity to MDMA, with a maximum adsorption capacity of 926.13 μg g−1, which was 3.25, 2.52 and 1.15 times higher than that of AMP, MAMP and MDA, respectively. Modern spectral analysis showed that there were a series of active centers (-COOH, -NH2 and -OH) on the PMBC, which could form hydrogen bond networks with the nitrogen and oxygen functional groups of ATSs. In various chemical environments: pH level (4–11), inorganic ion and organic matter (humic acid), PMBC maintained high activity towards four ATSs. Additionally, the quantum chemical calculations revealed that the methylenedioxy bridge of ATSs can increase the active sites, and the -NH- and -NH2 groups had different hydrogen bond formation capabilities, which together resulted in the adsorption order of PMBC on the four ATSs: MDMA > MDA > MAMP > AMP. Moreover, the hydrogen-bonding binding energies of several common hydrogen-bonding types were compared, including O-H····O, N-H····O/O-H····N and N-H···N. This study laid an empirical and theoretical foundation for the efficient capture of ATSs in water and contributed to the innovative design of materials.

Quantum coupling and self-heating impacts on threshold voltages of GaN metal–insulator-semiconductor high-electron-mobility transistors

A transient heat conduction equation has been proposed to describe the cooling process of a hot two-dimensional electron gas layer in a GaN-based transistor. This equation serves as the basis for a physical analytical model that explains the impacts of hot electrons in the hot two-dimensional electron gas layer via quantum coupling on the threshold voltage of GaN-based transistors. The temperature of the two-dimensional electron gas layer decreases to ambient temperature as time increases, and the threshold voltage shifts caused by such a temperature will recover with time. The proposed model accurately reflects the observed recovery of threshold voltage over time in experiments. At the same time, it offers insight into how the gate voltage, the source-drain voltage, and the ambient temperature can shift the threshold voltage in these transistors. The simplicity and analytic nature of this proposed model not only provide a physical origin of the threshold voltage instability in GaN-based devices but also offer the possibility for improving device reliability by selecting appropriate device physical parameters.

Geometry-Tuned Optical Absorption Spectra of the Coupled Quantum Dot-Double Quantum Ring Structure.

We investigate the energy spectra and optical absorption of a 3D quantum dot-double quantum ring structure of GaAs/Al0.3Ga0.7As with adjustable geometrical parameters. In the effective mass approximation, we perform 3D numerical computations using as height profile a superposition of three Gaussian functions. Independent variations of height and width of the dot and of the rings and also of the dot-rings distance determine particular responses, useful in practical applications. We consider that a suitable manipulation of the geometrical parameters of this type of quantum coupling offer a variety of responses and, more important, the possibility of a fine adjusting in energy spectra and in the opportunity of choosing definite absorption domains, properties required for the improvement of the performances of optoelectronic devices.

The combined effects of quantum and strong coupling on the nonlinear collective excitation in quantum dusty plasmas

The quantum hydrodynamic model for electrons and ions and the generalized hydrodynamic model for the strongly coupled dust particles are proposed in the strongly coupled quantum dusty plasma, where the combined quantum effects of quantum diffraction, quantum statistic pressure, as well as electron exchange and correlation effects are all considered in the quantum hydrodynamic model. The shear and bulk viscosity effects are included in the viscoelastic relaxation, which leads to the decay of the dust-ion-acoustic waves. The approximate time-dependent solitary solution is obtained by the momentum conservation law in the presence of viscosity.

Coupled vertical double quantum dots at single-hole occupancy

Gate-defined quantum dots define an attractive platform for quantum computation and have been used to confine individual charges in a planar array. Here, we demonstrate control over vertical double quantum dots confined in a strained germanium double quantum well. We sense individual charge transitions with a single-hole transistor. The vertical separation between the quantum wells provides a sufficient difference in capacitive coupling to distinguish quantum dots located in the top and bottom quantum wells. Tuning the vertical double quantum dot to the (1,1) charge state confines a single-hole in each quantum well beneath a single plunger gate. By simultaneously accumulating holes under two neighboring plunger gates, we are able to tune to the (1,1,1,1) charge state. These results motivate quantum dot systems that exploit the third dimension, opening new opportunities for quantum simulation and quantum computing.

Advanced Analytical and Numerical Studies on Coupled Schrödinger Equations with Fractional Order Damping

This paper embarks on a thorough analytical and numerical exploration of coupled Schrödinger equations under the influence of fractional order damping mechanisms. By integrating fractional damping, which introduces memory effects and non-local dissipative interactions, into the coupled Schrödinger framework, we aim to dissect and understand the nuanced dynamics that govern these complex quantum systems. The research delves into the mathematical underpinnings, stability characteristics, and the dynamical behaviors that emerge from the intricate balance between quantum coupling and fractional damping effects. Through a blend of analytical rigor and sophisticated numerical simulations, this study unveils new insights into the complex interplay among quantum entanglement, dissipation, and non-linear dynamics, offering potential implications for quantum computing, optical systems, and beyond.

Physical Modeling of Threshold Voltage Instability in GaN High‐Electron‐Mobility Transistors

The transient heat conduction equation for the 2D electron gas layer in GaN high‐electron‐mobility transistors is developed. The Schottky barrier height and the conduction band offset seen by electrons in the 2D electron gas layer will be reduced due to self‐heating in the 2D electron gas of GaN high‐electron‐mobility transistors via quantum coupling. Such a reduction will lead to a shift in the threshold voltage. To address this issue, an analytical physical model of self‐heating in the 2D electron gas of a GaN high‐electron‐mobility transistor via quantum coupling impacts on its threshold voltage instability is proposed. The proposed model forecasts that the threshold voltage can have an exponentially dependent relation with the reciprocal of the recovery time after the stress voltage is released, as well as dependencies on the square of the drift velocity, the gate voltage, and the surrounding temperature. The experimentally observed threshold voltage shifts of GaN high‐electron‐mobility transistors confirm such dependent relationships predicted by the proposed physical model. This article provides evidence that the combination of self‐heating in the 2D electron gas layer and quantum coupling may be a possible physical origin of the threshold voltage instability in GaN high‐electron‐mobility transistors.

Wideband coherent microwave conversion via magnon nonlinearity in a hybrid quantum system

Frequency conversion is a widely realized physical process in nonlinear systems of optics and electronics. As an emerging nonlinear platform, spintronic devices have the potential to achieve stronger frequency conversion. Here, we demonstrated a microwave frequency conversion method in a hybrid quantum system, integrating nitrogen-vacancy centers in diamond with magnetic thin film CoFeB. We achieve a conversion bandwidth ranging from 0.1 to 12 GHz, presenting an up to 25th order frequency conversion and further display the application of this method for frequency detection and qubits coherent control. Distinct from traditional frequency conversion techniques based on nonlinear electric response, our approach employs nonlinear magnetic response in spintronic devices. The nonlinearity, originating from the symmetry breaking such as domain walls in magnetic films, presents that our method can be adapted to hybrid systems of other spintronic devices and spin qubits, expanding the application scope of spintronic devices and providing a promising on-chip platform for coupling quantum systems.

Exceptional Nexus in Bose-Einstein Condensates with Collective Dissipation.

In multistate non-Hermitian systems, higher-order exceptional points and exotic phenomena with no analogues in two-level systems arise. A paradigm is the exceptional nexus (EX), a third-order EP as the cusp singularity of exceptional arcs (EAs), that has a hybrid topological nature. Using atomic Bose-Einstein condensates to implement a dissipative three-state system, we experimentally realize an EX within a two-parameter space, despite the absence of symmetry. The engineered dissipation exhibits density dependence due to the collective atomic response to resonant light. Based on extensive analysis of the system's decay dynamics, we demonstrate the formation of an EX from the coalescence of two EAs with distinct geometries. These structures arise from the different roles played by dissipation in the strong coupling limit and quantum Zeno regime. Our Letter paves the way for exploring higher-order exceptional physics in the many-body setting of ultracold atoms.

Susceptibility in a Coupled Double Quantum Dot-Metal Nanoparticle System under Standing Wave Field

Susceptibility in a Coupled Double Quantum Dot-Metal Nanoparticle System under Standing Wave Field