Coupling Of Surface Plasmon Polaritons Research Articles

Surface plasmon polariton–enhanced upconversion luminescence for biosensing applications

Abstract Upconversion luminescence (UCL) has great potential for highly sensitive biosensing due to its unique wavelength shift properties. The main limitation of UCL is its low quantum efficiency, which is typically compensated using low-noise detectors and high-intensity excitation. In this work, we demonstrate surface plasmon polariton (SPP)-enhanced UCL for biosensing applications. SPPs are excited by using a gold grating. The gold grating is optimized to match the SPP resonance with the absorption wavelength of upconverting nanoparticles (UCNPs). Functionalized UCNPs conjugated with antibodies are immobilized on the surface of the fabricated gold grating. We achieve an UCL enhancement up to 65 times at low excitation power density. This enhancement results from the increase in the absorption cross section of UCNPs caused by the SPP coupling on the grating surface. Computationally, we investigated a slight quenching effect in the emission process with UCNPs near gold surfaces. The experimental observations were in good agreement with the simulation results. The work enables UCL-based assays with reduced excitation intensity that are needed, for example, in scanning-free imaging.

Near-field radiative heat transfer between graphene-covered Weyl semimetals

Polariton manipulations introduce novel approaches to modulate the near-field radiative heat transfer (NFRHT). Our theoretical investigation in this study centers on NFRHT in graphene-covered Weyl semimetals (WSMs). Our findings indicate variable heat flux enhancement or attenuation, contingent on chemical potential of graphene. Enhancement or attenuation mechanisms stem from the coupling or decoupling of surface plasmon polaritons (SPPs) in the graphene/WSM heterostructure. The graphene-covered WSM photon tunneling probabilities variation is demonstrated in detail. This research enhances our comprehension of SPPs within the graphene/WSM heterostructure and suggests methods for actively controlling NFRHT.

Polarization dependent exciton-plasmon coupling in PEA2PbI4/Al and its application to perovskite solar cell.

This paper reports the strong coupling between Al nanostructure and two-dimensional (2D) layered perovskite PEA2PbI4 (PEPI) films. The high exciton binding energy of 118 meV and long carrier lifetime of 216 ps are characterized from the 2D PEA2PbI4 film, which indicates that the excitons in perovskite are robust and can couple to metal plasmons. The ordinary and extraordinary optical dispersions are revealed from the anisotropic 2D perovskite. The transmission spectra of PEA2PbI4/Al nanoparticle arrays are simulated under different polarization excitations, and the typical anti-crossing behaviors originating from exciton-plasmon strong coupling are demonstrated. We found that compared with transverse magnetic (TM) polarization, transverse electric (TE) polarization excitation is more conducive to the realization of exciton-plasmon coupling with a larger Rabi splitting. Furthermore, the PEA2PbI4/Al nanoparticle arrays are proposed, which present polarization-dependent local electrical field enhancement due to the exciton-local surface plasmon polariton coupling. Additionally, it is noticed that the proposed plasmonic structure increases the photo-generation rate inside the active material with improved current density. Therefore, the 2D proposed plasmonic design increases the power conversion efficiency (PCE) with an enhancement of 3.3% and 1.3% relative to the planar structures for TE and TM polarizations, respectively. This study provides a deeper understanding of polarized exciton-plasmon coupling properties, promoting the development of the field of plasmon and providing guidance for the design and preparation of efficient optoelectronic devices.

Large-Area Near-Infrared Emission Enhancement on Single Upconversion Nanoparticles by Metal Nanohole Array.

Single lanthanide (Ln) ion doped upconversion nanoparticles (UCNPs) exhibit great potential for biomolecule sensing and counting. Plasmonic structures can improve the emission efficiency of single UCNPs by modulating the energy transferring process. Yet, achieving robust and large-area single UCNP emission modulation remains a challenge, which obstructs investigation and application of single UCNPs. Here, we present a strategy using metal nanohole arrays (NHAs) to achieve energy-transfer modulation on single UCNPs simultaneously within large-area plasmonic structures. By coupling surface plasmon polaritons (SPPs) with higher-intermediate state (1D2 → 3F3, 1D2 → 3H4) transitions, we achieved a remarkable up to 10-fold enhancement in 800 nm emission, surpassing the conventional approach of coupling SPPs with an intermediate ground state (3H4 → 3H6). We numerically simulate the electrical field distribution and reveal that luminescent enhancement is robust and insensitive to the exact location of particles. It is anticipated that the strategy provides a platform for widely exploring applications in single-particle quantitative biosensing.

Current-induced nonreciprocal transmittance in graphene-embedded photonic multilayers comprising the Octonacci sequence

In this work, we have studied the nonreciprocal properties of quasi-periodic Octonacci multilayer incorporating current-induced drifted graphene monolayers at the interfaces. We have analyzed the transmittance of the structure and compared it with that of regular periodic photonic crystals. Our investigation has revealed that the transmission of light is significantly improved through configurations comprising dielectric layers and graphene monolayers. The proposed structures exhibit nonreciprocal optical responses across a broad range of frequencies. The coupling of surface plasmon polaritons in the quasi-periodic structure exceeds that of periodic structures. We have examined nonreciprocal behaviors versus the drift velocity of electrons and the Fermi energy of graphene layers. It has been demonstrated that the reciprocity of the system can be adjusted by manipulating the Fermi energy and the drift velocity of the graphene layers. Moreover, the direction of nonreciprocity is dictated by the sign of the drift velocity. Nonreciprocal behavior is absent under zero DC bias and can be tuned up to 4.5 THz with bias. These distinctive properties suggest potential applications of these structures in optoelectronic devices.

Near-field coupling of interlayer excitons in MoSe2/WSe2 heterobilayers to surface plasmon polaritons.

Two-dimensional (2D) transition metal dichalcogenides have emerged as promising quantum functional blocks benefitting from their unique combination of spin, valley, and layer degrees of freedom, particularly for the tremendous flexibility of moiré superlattices formed by van der Waals stacking. These degrees of freedom coupled with the enhanced Coulomb interaction in 2D structures allow excitons to serve as on-chip information carriers. However, excitons are spatially circumscribed due to their low mobility and limited lifetime. One way to overcome these limitations is through the coupling of excitons with surface plasmon polaritons (SPPs), which facilitates an interaction between remote quantum states. Here, we showcase the successful coupling of SPPs with interlayer excitons in molybdenum diselenide/tungsten diselenide heterobilayers. Our results indicate that the valley polarization can be efficiently transferred to SPPs, enabling preservation of polarization information even after propagating tens of micrometers.

Hydrogen sensor based on surface plasmon polaritons in palladium layer structure

We design a new hydrogen (H2) sensor composed of palladium (Pd) layer structure. Pd can absorb H2 and turns to Pd-H. The dielectric constant of Pd is totally different from the one of Pd-H. By calculating the propagation length of the layer structure, we find that the difference of the propagation lengths between the structure with Pd and the structure with Pd-H reaches ten times the wavelength in a certain condition. With the number of the layers increasing, another new mode appears and the dissipation of our proposed structure also linearly increases. There is a worst number of the layers that make the difference of the propagation lengths shortest. This shows the competition between the dissipation of the structure and the coupling of surface plasmon polaritons among the layers. In order to achieve the function of H2 detecting, we set the length of the structure at minimum of L Pd and at a certain working wavelength. By adding the concentration of H2, light will emit or not emit L_{Pd\ ext {-}H})$ ?> . Our proposed technique has a large difference of propagation lengths and is quite sensitive to H2, which can be used as a hydrogen sensor.

Small attenuation negative group delay of spoof surface plasmon polaritons

Spoof surface plasmon polariton (SSPP) waveguides can be used to effectively construct on-chip microwave systems due to the single-side conductor structure. SSPP waveguides usually exhibit normal dispersion, which can introduce large group delays to transmission signal and impair waveform shapes. However, the negative group velocity (NGV) effect may occur in the split modes of coupled surface plasmon polariton waveguides. In this regard, the synthesis wave model of forward and backward transmission waves is applied, which generates a quadrupole vortex wave transmission. In this paper, the SSPP unit structure with folded multi-split rings is proposed to achieve anomalous dispersion with NGV feature in the fundamental mode. The SSPP unit can be equivalent to an epsilon-negative medium, and a maximum negative group delay (NGD) can be reached at the frequency where the NGV begins to appear. For the corresponding SSPP waveguide, a NGD band with lower attenuation can be achieved at the stopband edge. While the SSPP unit structures are loaded as dispersive materials in a microstip line, the similar NGD performance can be obtained. Clearly, the SSPP NGD with lower attenuation provides a new delay equalization method for ultra reliable and low latency communications (URLLC), and can also be used as an effective dispersion compensation means.

Study of Bragg scattering in the presence of dipole-dipole interaction in plasmonic nanohybrids

We have developed a theory of the Bragg scattering for metallic nanohybrid made of an ensemble of metallic nanorods doped in a substrate. The substrate can gas, liquid or solid. An external laser field is applied to study the Bragg scattered light. The photons from the incident laser interact with the surface plasmons od nanorods and produce surface plasmon polaritons (SPPs). The incident laser field also induced dipoles in the ensemble of nanorods and they interact with each other via the dipole-dipole interaction (DDI). We have developed a theory for Bragg scattering for metallic nanohybrids using the coupled-mode formulism based on Maxwell’s equation in the presence of SPP and DDI fields. It is found that the theory of Bragg scattered depends on the susceptibility induced by the SPP and DDI fields. We used the quantum mechanical density matrix method to calculate the susceptibility. An analytical expression of the Bragg scattered light intensity is obtained. These expressions can be useful for experimental scientists and engineers who can used them to compare their experiments and make new types of plasmonic devices. Next, we have compared our theory with the experiment data for a nanohybrid made of ensemble of Au-nanoris doped in water. We found a good agreement between theory and experiments. We have also performed the numerical simulations to study the effect of SPP and DDI fields on the Bragg intensity. We have predicted an enhancement the Brag intensity due to the SPP and DDI couplings. The enhancement is due to the two extra scattering mechanisms of the SPP and DDI polaritons with acoustic phonons. We have also found that the one peak in the Bragg intensity can be split int many peaks due the SPP coupling, DDI coupling and phase factor. The splitting is due the Bragg factor appearing in the theory, and it includes the coupling of the incident laser, SPP and DDI electric fields with of acoustic phonons. The enhancement effect can be used to fabricate new types of nanosensors. Similarity, splitting phenomenon can be used to fabricate new types nanoswitches where one peak can be considered as the OFF position and many peaks can be considered as the ON position.

Coupling polaritons in near-field radiative heat transfer between multilayer graphene/vacuum/α-MoO3/vacuum heterostructures.

Both materials and structures can significantly affect radiative heat transfer, which is more pronounced in the near-field regime of two-dimensional and hyperbolic materials, and has promising prospects in thermophotovoltaics, radiative cooling, and nanoscale metrology. Hence, it is important to investigate the near-field radiative heat transfer (NFRHT) in complicated heterostructures consisting of two-dimensional and hyperbolic materials. Recent studies have reported that adding vacuum layers to multilayer structures can effectively enhance the NFRHT. Take the case of multilayer graphene/α-MoO3 heterostructures: the effect of vacuum layers on these heterostructures has not been studied, and hence investigations on adding vacuum layers between graphene and α-MoO3 layers should be emphasized. In this work, we conduct an investigation of the NFRHT between multilayer graphene/vacuum/α-MoO3/vacuum heterostructures. Compared to unit graphene/α-MoO3 heterostructures without vacuum layers, it is found that NFRHT between the heterostructures with vacuum layers can be suppressed to 49.1% when the gap distance is 10 nm, and can be enhanced to 16.3% when the gap distance is 100 nm. These phenomena are thoroughly explained by the coupling of surface plasmon polaritons and hyperbolic phonon polaritons. Energy transmission coefficients and spectral heat flux are analysed during the calculations changing chemical potentials of graphene, thicknesses of vacuum layers, and α-MoO3 layers. This study is expected to provide guidance in implementing the thermal management of reasonable NFRHT devices based on graphene/α-MoO3 heterostructures.

The demultiplexing and broadband focusing on a gold nanoarray of in-plane propagating surface plasmons

An analytical approach is presented to comprehensively describe a meticulously designed gold nanoarray situated on a silicon waveguide(length (L) and width(W) are 12 µm and 3 µm). The incorporation of a glass substrate with an L and W of 12 µm is proposed as a means to achieve broadband focusing. At the same time, a demultiplexing element utilizing surface plasmon polariton (SPP) waves is introduced, employing a novel phase modulation method that uses in-plane diffraction processes. The analytical calculations are focused on the sublattice arrays, which are currently under investigation to enhance the performance of demultiplexers and confocal SPP beams. The suggested method exhibits various functionalities that make it a promising approach. Its planar construction ensures a streamlined and integrated design, and the absence of SPP coupling processes adds to its practicality for implementation in photonic integrations. By leveraging the unique properties of the gold nanoarray on the silicon waveguide, combined with the glass substrate for broadband focusing and the novel phase modulation method for demultiplexing SPP waves, this approach holds great potential for advancing the field of photonics.

Plasmonic red-light-emission enhancement by honeycomb-latticed InGaN/GaN ordered fine nanocolumn arrays

By using ordered fine nanocolumns suitable for high-efficiency red-emission, emission enhancement based on surface plasmon polariton (SPP) coupling was successfully obtained for the honeycomb lattice. This lattice enables us to obtain a longer SPP resonant wavelength in the red region, which could not be attained for the triangular lattice. A 4.8-fold red-emission enhancement was achieved for the honeycomb lattice, demonstrating effective synergy between plasmonic and nanocrystalline effects within the red-emission nanocolumn system. Additionally, a 3.2-fold light-extraction enhancement was attained by changing the emission directionality by introducing plasmonic crystals (PlCs) in addition to metal reflection.

SPP excitation and coupling mechanism based onmicro/nano fibers.

A hot trend in the development of optoelectronic devices is how to use the principle of surface plasmon resonance to enhance the performance of integrated photonics devices and achieve miniaturization. This paper proposes an accompanying waveguide coupling structure of micro/nano fibers, which consists of two parallel-placed micro/nano fibers (MNFs) coated with a silver film in the waist region and infused with a refractive index matching oil. In the overlapping region, there exists a segment of surface plasmon polaritons (SPPs) coupling area. The excitation and coupling characteristics of SPPs are studied through numerical simulation. Optimal coupling enhancement configuration is obtained by studying variables such as spacing distance, coupling length, and metal film thickness. A comparison is made with the SPP intensity of a single MNF, showing a 220% increase in electric field intensity, demonstrating its excellent coupling effect. By using this coupling structure, exploration of SPPs excitation and coupling mechanisms is enhanced, and structures resembling interferometric devices can be designed, providing new insights for high-performance miniaturized devices.

Regulation of Near-Field Radiative Heat Transfer between Multilayer BP/hBN Heterostructures.

As an allotrope of phosphorus and a promising 2D semiconductor, black phosphorus (BP) exhibits in-plane anisotropy along its armchair and zigzag crystal directions, allowing for efficient regulation of near-field radiative heat transfer (NFRHT). In this work, we investigate the NFRHT between two multilayer BP/hBN heterostructures and theoretically demonstrate that thermal regulation can be realized by tuning the electron density and rotation angle of BP. Results show that a larger electron density leads to the coupling of anisotropic surface plasmon polaritons (SPPs) of BP with hyperbolic modes of hBN, and rotation of BP changes the anisotropic characteristic of coupled SPPs on both sides, whereby a regulation ratio of 5.8 can be obtained. We also analyze the effects of period number, hBN layer thickness, and topmost-layer material on the NFRHT. This work may be beneficial for efficient nanoscale thermal management and physical understanding of radiative heat transfer based on anisotropic SPPs.

Tunable narrowband and broadband coexisting absorber enabled by a simple all-metal grating for sensing applications

We realize a tunable narrowband and broadband coexisting absorber based on a simple step-shaped all-metal grating structure. The absorber presents an ultra-narrow absorption band of 1.5 nm and a relatively broad absorption band of 29.8 nm, both with nearly 100% absorption in the infrared region. The mechanism underlying the dual-band perfect absorption is the interaction between two diffraction coupled surface plasmon polariton (SPP) modes with one of them modulated by a cavity resonance. Influences of structure parameters on the absorption performance are numerically investigated. It is found that the positions of the two perfect absorption peaks can be easily tuned both independently and together by changing the structural parameters. In addition, the designed grating structure presents excellent sensing performance with sensitivity and figure of merit as high as 2,514 nm/RIU and 1,600 RIU−1, respectively. The excellent sensing performance, flexible tenability and simple structure design endow this grating absorber with great potential in high-precision biochemical sensing applications.

Narrow bandwidth perfect absorber based on composite hybrid plasmonics

Surface plasmon polaritons (SPPs) have shown unprecedented potential for miniaturizing photonic devices beyond the optical diffraction limit. However, their high intrinsic loss from metal material has been a major barrier to practical applications. One effective approach to reducing their effective loss is to engineer SPPs coupling by designing hybrid plasmonic waveguides (HPWs). In this work, we first theoretically calculate and analyze the coupling modes in a composite HPW (CHPW), demonstrating that the long-range and short-range supermodes in CHPW correspond to two different SPPs at two metal layer interfaces. Next, we propose and demonstrate a narrow bandwidth perfect absorber based on CHPW structure. The absorber’s bandwidth is only 12.9 nm in the visible range and 6.67 nm in the near-infrared range. Our simulation results demonstrate that the CHPW’s SPPs coupling mechanism can be extended to localized surface plasmons (LSPs) in the proposed perfect absorber, enabling a low-loss mode that contributes to the narrow bandwidth. This suggests that the CHPW configuration could facilitate the development of more advanced low-loss, high-performance plasmonic devices.

High Sensitivity Surface Plasmon Resonance Magnetic Field Sensor Based on Au/Gold Nanoparticles/Magnetic Fluid in the Hollow Core Fiber

A type of surface plasmon resonance (SPR) magnetic field sensor based on Au/gold nanoparticles/magnetic fluid (MF)-processed hollow core fiber is proposed in this work, which fully utilizes SPR’s high sensitivity to RI and the magnetron refractive index characteristic of MF. The metal material Au excites SPR and gold nanoparticles excite the localized surface plasmon resonance (LSPR). The coupling of surface plasmon polariton (SPP) with localized surface plasmon (LSP) increases the local electric field strength, thus improving the sensor’s sensitivity. Both the theoretical analysis on the sensing mechanism and the experimental findings demonstrate that this novel SPR magnetic field sensor has a wide measurement range and high sensitivity. In the range of magnetic field strength from 0 to 603 Gs, the sensitivity can reach up to 156 pm/Gs, and the linearity is good (the coefficient of determination is 0.996). Compared with other optical fiber magnetic field sensors, the sensor proposed in this paper has the benefits of easy fabrication, excellent sensitivity, simple structure, strong anti-interference ability, and wide measurement range, exhibiting significant application potentials in the fields of military drills, aerospace, etc.

Thermosensitive Plasmonic Color Enabled by Sodium Metasurface

AbstractActive plasmonic nanostructures have attracted tremendous interest in nanophotonics and metamaterials owing to the dynamically switchable capabilities of plasmonic resonances. In this study, tunable hybrid plasmon resonances (HPR) of sodium metasurfaces through heat‐initiated structural transformation is experimentally demonstrated. A HPR is formed by coupling surface plasmon polaritons (SPP) and gap plasmon resonances (GPR), whose resonant wavelengths are highly sensitive to gaseous nanogaps. By carefully manipulating the thermo‐assisted spin‐coating process and post‐thermal treatment, tuning of the HPR is achieved because of the phase transition between the antidome and nanodome structural profiles of liquid sodium inside the patterned fused silica substrates. Furthermore, the figure of merit of the heat initiated variable structure‐spectrum is demonstrated that is highly dependent on the size of the substrate patterns, based on which temperature‐sensitive plasmonic color and “invisible ink” of sodium metasurfaces are demonstrated. These findings can lead to new solutions for manipulating low‐cost and high‐performance active plasmonic devices.

LSP-SPP Coupling Structure Based on Three-Dimensional Patterned Sapphire Substrate for Surface Enhanced Raman Scattering Sensing.

Although the fabrication of controllable three-dimensional (3D) microstructures on substrates has been proposed as an effective solution for SERS, there remains a gap in the detection and manufacturability of 3D substrates with high performance. In this study, photolithography is adopted to obtain a pyramid-like array on a patterned sapphire substrate (PSS), with Al2O3 as the dielectric layer. In addition, silver nanoparticles (AgNPs) are used to decorate Au films to obtain mass-producible 3D SRES substrates. In the case of low fluorescence, the substrate realizes the coupling of localized surface plasmon polaritons (LSPs) and surface plasmon polaritons (SPPs), which is consistent with the simulation results obtained using the finite element method. The performance of the SERS substrate is evaluated using rhodamine 6G (R6G) and toluidine blue (TB) as probe molecules with detection limits of 10-11 M and 10-9 M, respectively. The substrate exhibits high hydrophobicity and excellent light-capturing capability. Moreover, it shows self-cleaning ability and long-term stability in practical applications. Allowing for the consistency of the composite substrate in the preparation process and the high reproducibility of the test results, it is considered to be promising for mass production.

Dual-Band Coupling of Phonon and Surface Plasmon Polaritons with Vibrational and Electronic Excitations in Molecules

Strong coupling (SC) between light and matter excitations bears intriguing potential for manipulating material properties. Typically, SC has been achieved between mid-infrared (mid-IR) light and molecular vibrations or between visible light and excitons. However, simultaneously achieving SC in both frequency bands remains unexplored. Here, we introduce polaritonic nanoresonators (formed by h-BN layers on Al ribbons) hosting surface plasmon polaritons (SPPs) at visible frequencies and phonon polaritons (PhPs) at mid-IR frequencies, which simultaneously couple to excitons and molecular vibrations in an adjacent layer of CoPc molecules, respectively. Employing near-field optical nanoscopy, we demonstrate the colocalization of near fields at both visible and mid-IR frequencies. Far-field transmission spectroscopy of the nanoresonator structure covered with a layer of CoPc molecules shows clear mode splittings in both frequency ranges, revealing simultaneous SPP-exciton and PhP-vibron coupling. Dual-band SC may offer potential for manipulating coupling between exciton and molecular vibration in future optoelectronics, nanophotonics, and quantum information applications.