Coupled Quantum Dots Research Articles

Quantum dot based Kitaev chains: Majorana quality measures and scaling with increasing chain length

Realizing Majorana bound states (MBSs) in short, well-controllable chains of coupled quantum dots sidesteps the problem of disorder but requires finetuning and does not give the true topological protection inherent to long chains. Here, we introduce a quality measure that is also applicable in the presence of strong electron-electron interactions and that quantifies the closeness to topological protection of finetuned MBSs in short quantum dot chains. We call this measure local distinguishability (LD) because it puts a bound to the degree an arbitrary local measurement can distinguish between two states. We study the LD for quantum dot chains of different length. The three-dot chain is studied in detail, and we find that it may not always be an improvement over the two-dot case, a fact that can be understood within an effective model derived from perturbation theory. For longer chains, the LD vanishes exponentially, signaling a transition to a topological phase with two ground states that cannot be distinguished by any local measurement. Published by the American Physical Society 2024

Floquet nonequilibrium Green's functions with fluctuation-exchange approximation: Application to periodically driven capacitively coupled quantum dots

Floquet nonequilibrium Green's functions with fluctuation-exchange approximation: Application to periodically driven capacitively coupled quantum dots

Electrostatically Interacting Wannier Qubits in Curved Space

A derivation of a tight-binding model from Schrödinger formalism for various topologies of position-based semiconductor qubits is presented in the case of static and time-dependent electric fields. The simplistic tight-binding model enables the description of single-electron devices at a large integration scale. The case of two electrostatically Wannier qubits (also known as position-based qubits) in a Schrödinger model is presented with omission of spin degrees of freedom. The concept of programmable quantum matter can be implemented in the chain of coupled semiconductor quantum dots. Highly integrated and developed cryogenic CMOS nanostructures can be mapped to coupled quantum dots, the connectivity of which can be controlled by a voltage applied across the transistor gates as well as using an external magnetic field. Using the anti-correlation principle arising from the Coulomb repulsion interaction between electrons, one can implement classical and quantum inverters (Classical/Quantum Swap Gate) and many other logical gates. The anti-correlation will be weakened due to the fact that the quantumness of the physical process brings about the coexistence of correlation and anti-correlation at the same time. One of the central results presented in this work relies on the appearance of dissipation-like processes and effective potential renormalization building effective barriers in both semiconductors and in superconductors between not bended nanowire regions both in classical and in quantum regimes. The presence of non-straight wire regions is also expressed by the geometrical dissipative quantum Aharonov–Bohm effect in superconductors/semiconductors when one obtains a complex value vector potential-like field. The existence of a Coulomb interaction provides a base for the physical description of an electrostatic Q-Swap gate with any topology using open-loop nanowires, with programmable functionality. We observe strong localization of the wavepacket due to nanowire bending. Therefore, it is not always necessary to build a barrier between two nanowires to obtain two quantum dot systems. On the other hand, the results can be mapped to the problem of an electron in curved space, so they can be expressed with a programmable position-dependent metric embedded in Schrödinger’s equation. The semiconductor quantum dot system is capable of mimicking curved space, providing a bridge between fundamental and applied science in the implementation of single-electron devices.

Peptide-mediated targeting of Quantum Dots in a 3D model of head and neck cancer

BackgroundOral squamous cell carcinoma (OSCC) treatment mainly relies on surgery. The status of surgical margin is a major prognostic factor for patients as positive margins are associated with lower survival. However, the anatomical particularities of this area complicate margin establishment. Fluorescence guided surgery (FGS) could be employed as an intraoperative technique to improve tumor resection and margin investigation. Quantum dots (QDs) serve as ideal contrast agents in this technique due to their brightness and stability. Since αVβ6 integrin is overexpressed in OSCC, coupling QDs with A20FMDV2 peptide (QDs-A20) targeting the αVβ6 integrin constitute a real opportunity. This study investigates the accumulation of QDs-A20 in 2D and 3D tongue cancer models, as well as QDs coupled to a scrambled version of this peptide (QDs-Scr) or without peptide (QDs-SPP), for imaging purposes. MethodsCdSeCdS/ZnS quantum dots were coated with sulfobetaine polymers (QDs-SPP) and conjugated to A20FMDV2 peptide (QDs-A20) or its scrambled version (QDs-Scr). Two-dimensional (2D) and three-dimensional (3D) tongue cancer cells HSC-3 were employed to test the effectiveness of intracellular accumulation of all types of QDs. Targeting ability of each QDs was assessed by flow cytometry, while the depth of penetration into cancerous spheroids was assessed by fluorescence microscopy. ResultsQDs coating with sulfobetaines polymers (QDs-SPP) completely prevented their internalization by HSC-3 cells in 2D and 3D models, making QDs stealthy and preventing their non-specific accumulation. Conversely, peptides conjugated QDs (QDs-A20 & QDs-Scr) labeled HSC-3 monolayers and managed to label spheroid periphery up to 23 µm deep. However, no difference in accumulation was found between these two QDs whereas only A20 peptide could potentially target αVβ6 integrin. It appears that peptide conjugation increased QDs zeta potential, promoting their adsorption and subsequent endocytosis by cells, independently from αVβ6 integrin. ConclusionsThe present study highlighted the impact of peptide conjugation on QDs internalization in 2D and 3D tongue cancer cell models. QDs-SPP were stealthy and did not accumulate in cells. Peptides conjugated QDs could be used as contrast agents, but in a passive targeting approach. Modifications to surface chemistry are required to target αVβ6 integrin through active targeting. This study also highlights the need for controls such as scrambled peptides, the absence of which can lead to misinterpretation of results.

Spin Transport Through Asymmetric Coupled Quantum Dots Between Ferromagnetic Leads

Spin Transport Through Asymmetric Coupled Quantum Dots Between Ferromagnetic Leads

Coupling of a hole double quantum dot in planar germanium to a microwave cavity

Coupling of a hole double quantum dot in planar germanium to a microwave cavity

Surface Engineering Enables Efficient AgBiS2 Quantum Dot Solar Cells.

Surface ligand chemistry is vital to control the synthesis, diminish surface defects, and improve the electronic coupling of quantum dots (QDs) toward emerging applications in optoelectronic devices. Here, we successfully develop highly homogeneous and dispersed AgBiS2 QDs, focus on the control of interdot spacing, and substitute the long-chain ligands with ammonium iodide in solution. This results in improved electronic coupling of AgBiS2 QDs with excellent surface passivation, which greatly facilitates carrier transport within the QD films. Based on the stable AgBiS2 QD dispersion with the optimal ligand state, a homogeneous and densely packed QD film is prepared by a facile one-step coating process, delivering a champion power conversion efficiency of approximately 8% in the QD solar cells with outstanding shelf life stability. The proposed surface engineering strategy holds the potential to become a universal preprocessing step in the realm of high-performance QD optoelectronic devices.

Many-Body Quantum Interference Route to the Two-Channel Kondo Effect: Inverse Design for Molecular Junctions and Quantum Dot Devices.

Molecular junctions-whether actual single molecules in nanowire break junctions or artificial molecules realized in coupled quantum dot devices-offer unique functionality due to their orbital complexity, strong electron interactions, gate control, and many-body effects from hybridization with the external electronic circuit. Inverse design involves finding candidate structures that perform a desired function optimally. Here we develop an inverse design strategy for generalized quantum impurity models describing molecular junctions, and as an example, use it to demonstrate that many-body quantum interference can be leveraged to realize the two-channel Kondo critical point in simple 4- or 5-site molecular moieties. We show that remarkably high Kondo temperatures can be achieved, meaning that entropy and transport signatures should be experimentally accessible.

Plasmon Mediated Single Photon Emission from a Nanocrystal Ensemble.

Quantum photonic devices require robust sources of single photons to perform basic computational and communication protocols. Thus, developing scalable, integrable, and efficient quantum light sources has become crucial for the realization of quantum photonic devices. Single quantum dots are promising sources of quantum light due to their tunable emission wavelength. Here, we show the emergence of quantum-emitter-like antibunched emission behavior when multiple quantum dots are located in the vicinity of plasmonic particles. To evaluate the robustness of this phenomenon, we consider both monometallic and bimetallic particles. We find that the photoluminescence intensity of the plasmon coupled quantum dots fits well to a single sublinear power law exponent that is distinct from the behavior of CQD aggregates. Significantly, we find that plasmon coupling results in reduced flickering, thus enabling the realization of a more stable and reliable single photon source. Possible roles of emergent excitonic interactions in the coupled system are discussed.

Design of high power evanescent quantum dot distributed feedback lasers on Si

Great advancements in III–V/Si epitaxy have pushed quantum dot lasers to the forefront of silicon photonics. In this work, we designed the structures of evanescent coupled quantum dot distributed feedback lasers with asymmetric gratings, which made significant improvement in on-chip output power while maintaining single-longitudinal-mode stability. The optimal λ/4 phase-shift position (the ratio of the grating length from the rear-end of λ/4 phase-shift to the total grating length) from conventional position of 0.50 to 0.64 allows the ratio of the output power at both sides of silicon waveguide to be increased from 1.0 to 5.9. Moreover, the optimal duty cycle at one side of the phase-shift from 0.50 to 0.8 allows the ratio to be increased from 1.0 to 3.7. Meanwhile, the ratio could be dramatically improved from 1.0 to 9.2 by changed the duty cycle at one side of phase-shift to 0.7 while maintaining the phase-shift position of 0.64. With those designed structures, evanescent coupled quantum dot lasers could challenge the state-of-the-art bonded quantum well lasers and may eventually become ubiquitous and affordable for future commercial production.

Majorana-Free Bound State in the Continuum in the Double-Channel Fano–Anderson Structure

Abstract We investigate the electron transport through a double-channel Fano–Anderson structure, by considering the side-coupling of Majorana bound states (MBSs). It is found that the bound state in the continuum (BIC) phenomenon can be induced when interchannel dot–lead couplings are identical to the intrachannel dot–lead couplings, whose signature is manifested as a halved quantum transmission ability. If the balance between the dot–lead couplings is broken, the BIC phenomenon will also be destroyed, leading to further suppression of the transmission ability. Next, when MBSs are introduced to this system, the BIC phenomenon can be modified efficiently. For the case of two MBSs side-coupled to the quantum dots in a symmetric way, level degeneracy causes a new BIC phenomenon. As only one MBS is incorporated, it suppresses the electron transmission by inducing new transmission dips. When the interdot Coulomb interaction is considered, the BIC phenomena are still robust despite the complicated changes of the transmission ability spectra. One can then understand the realization of BICs in coupled quantum dots and their variation due to the presence of side-coupled MBSs.

SI/GE Quantum Dot Channel FETs for Multi-Bit Computing

This paper presents quantum dot channel (QDC) FETs in quantum wire and coupled quantum dot configurations for cryogenic operation with multi-state operation. It also describes gate-all-around (GAA) quantum dot channel (QDC) FETs that exhibit potential multi-state characteristics at room temperature. FETs with cladded Si and Ge quantum dot layers as a transport channel have been fabricated. The formation of a quantum dot superlattice (QDSL) when SiOx-cladded Si and/or GeOx-cladded Ge quantum dots (QD) are assembled results in mini-energy sub-bands in the conduction and valence band. The intra-mini-energy band transitions results in significant changes in the drain current when gate and/or drain voltages are varied. This novel feature provides a pathway for 16-/32-state logic in CMOS-X configuration. The gate-defined Si quantum dot FETs, comprising of tunnel barrier coupled, have been reported for quantum computing at cryogenic temperatures.

Coupled vertical double quantum dots at single-hole occupancy

Gate-defined quantum dots define an attractive platform for quantum computation and have been used to confine individual charges in a planar array. Here, we demonstrate control over vertical double quantum dots confined in a strained germanium double quantum well. We sense individual charge transitions with a single-hole transistor. The vertical separation between the quantum wells provides a sufficient difference in capacitive coupling to distinguish quantum dots located in the top and bottom quantum wells. Tuning the vertical double quantum dot to the (1,1) charge state confines a single-hole in each quantum well beneath a single plunger gate. By simultaneously accumulating holes under two neighboring plunger gates, we are able to tune to the (1,1,1,1) charge state. These results motivate quantum dot systems that exploit the third dimension, opening new opportunities for quantum simulation and quantum computing.

Slow Hot-Exciton Cooling and Enhanced Interparticle Excitonic Coupling in HgTe Quantum Dots.

Rapid hot-carrier/exciton cooling constitutes a major loss channel for photovoltaic efficiency. How to decelerate the hot-carrier/exciton relaxation remains a crux for achieving high-performance photovoltaic devices. Here, we demonstrate slow hot-exciton cooling that can be extended to hundreds of picoseconds in colloidal HgTe quantum dots (QDs). The energy loss rate is 1 order of magnitude smaller than bulk inorganic semiconductors, mediated by phonon bottleneck and interband biexciton Auger recombination (BAR) effects, which are both augmented at reduced QD sizes. The two effects are competitive with the emergence of multiple exciton generation. Intriguingly, BAR dominates even under low excitation fluences with a decrease in interparticle distance. Both experimental evidence and numerical evidence reveal that such efficient BAR derives from the tunneling-mediated interparticle excitonic coupling induced by wave function overlap between neighboring HgTe QDs in films. Thus, our study unveils the potential for realizing efficient hot-carrier/exciton solar cells based on HgTe QDs. Fundamentally, we reveal that the delocalized nature of quantum-confined wave function intensifies BAR. The interparticle excitonic coupling may cast light on the development of next-generation photoelectronic materials, which can retain the size-tunable confinement of colloidal semiconductor QDs while simultaneously maintaining high mobilities and conductivities typical for bulk semiconductor materials.

A quantum otto heat engine driven by three quantum dots

A quantum heat engine composed of three coupled quantum dots as a working substance is proposed. Since quantum dots naturally obey the Fermi Hubbard Hamiltonian, the strong coupling interaction regime allows the working substance to be evaluated under an effective Heisenberg Hamiltonian. Indeed, the influence of the strength coupling, between the three dots, on quantum machine efficiency and work in the presence of a homogeneous magnetic field is also examined. Furthermore, the influence of entanglement on the efficiency & work of the quantum dot Otto heat engine is well analyzed. As a tripartite working substance, we are interested in analyzing the local work and efficiency associated with each single and pair of quantum dots. The results show that the local efficiency associated with a pair of quantum dots achieves a maximum value, unlike the global efficiency. Indeed, the entanglement impact on Global/local work is studied.

Elucidating the Mechanisms of the Large Stokes Shift in Isolated and Coupled PbS Quantum Dots

Elucidating the Mechanisms of the Large Stokes Shift in Isolated and Coupled PbS Quantum Dots

Gate-tunable Josephson diode effect in Rashba spin-orbit coupled quantum dot junctions

Gate-tunable Josephson diode effect in Rashba spin-orbit coupled quantum dot junctions

Stronger Coupling of Quantum Dots in Hole Transport Layer Through Intermediate Ligand Exchange to Enhance the Efficiency of PbS Quantum Dot Solar Cells.

Nowadays, the extensively used lead sulfide (PbS) quantum dot (QD) hole transport layer (HTL) relies on layer-by-layer method to replace long chain oleic acid (OA) ligands with short 1,2-ethanedithiol (EDT) ligands for preparation. However, the inevitable significant volume shrinkage caused by this traditional method will result in undesired cracks and disordered QD arrangement in the film, along with adverse increased defect density and inhomogeneous energy landscape. To solve the problem, a novel method for EDT passivated PbS QD (PbS-EDT) HTL preparation using small-sized benzoic acid (BA) as intermediate ligands is proposed in this work. BA is substituted for OA ligands in solution followed by ligand exchange with EDT layer by layer. With the new method, smoother PbS-EDT films with more ordered and closer QD packing are gained. It is demonstrated stronger coupling between QDs and reduced defects in the QD HTL owing to the intermediate BA ligand exchange. As a result, the suppressed nonradiative recombination and enhanced carrier mobility are achieved, contributing to ≈20% growth in short circuit current density (Jsc) and a 23.4% higher power conversion efficiency (PCE) of 13.2%. This work provides a general framework for layer-by-layer QD film manufacturing optimization.

Quantifying Förster Resonance Energy Transfer from Single Perovskite Quantum Dots to Organic Dyes.

Colloidal quantum dots (QDs) are promising regenerable photoredox catalysts offering broadly tunable redox potentials along with high absorption coefficients. QDs have thus far been examined for various organic transformations, water splitting, and CO2 reduction. Vast opportunities emerge from coupling QDs with other homogeneous catalysts, such as transition metal complexes or organic dyes, into hybrid nanoassemblies exploiting energy transfer (ET), leveraging a large absorption cross-section of QDs and long-lived triplet states of cocatalysts. However, a thorough understanding and further engineering of the complex operational mechanisms of hybrid nanoassemblies require simultaneously controlling the surface chemistry of the QDs and probing dynamics at sufficient spatiotemporal resolution. Here, we probe the ET from single lead halide perovskite QDs, capped by alkylphospholipid ligands, to organic dye molecules employing single-particle photoluminescence spectroscopy with single-photon resolution. We identify a Förster-type ET by spatial, temporal, and photon-photon correlations in the QD and dye emission. Discrete quenching steps in the acceptor emission reveal stochastic photobleaching events of individual organic dyes, allowing a precise quantification of the transfer efficiency, which is >70% for QD-dye complexes with strong donor-acceptor spectral overlap. Our work explores the processes occurring at the QD/molecule interface and demonstrates the feasibility of sensitizing organic photocatalysts with QDs.

Time evolution of entangled Bell states in coupled quantum dots in the presence of fluctuations

Time evolution of entangled Bell states in coupled quantum dots in the presence of fluctuations