Charge Coupling Research Articles

Design strategies and systematic analysis of GaN vertical MPS diodes with T-shaped shielding rings

Abstract We report gallium nitride (GaN) vertical merged pn-Schottky (MPS) diodes with T-shaped p-GaN shielding rings (SRs). The embedded T-shaped SR features an overlapped depletion region by the lateral and vertical p n junctions under reverse bias condition, which can effectively enhance the charge coupling effect and homogenize the 2-D electric field distribution. In the meantime, the incorporation of the T-shaped SRs can minimize unnecessary depletion of the vertical conduction channel and guarantee a decent current spreading through the drift region. The impact of the key design parameters on the reverse breakdown and forward conduction performance are investigated systematically. We found that the doping concentration and the geomatical shape of the T-shaped p-GaN SRs are closed related to the electric field distribution and forward current conduction behavior, which determines the reverse breakdown and forward conduction performance. With optimum design parameters of the T-shaped SRs, the breakdown voltage of the MPS diodes features a dramatic improvement to 2749 V from 1123 V in conventional MPS diodes. The results can provide a design strategy for high performance vertical GaN power diodes towards high-power and high-frequency applications.

Interface engineering by module customization of π-conjugated groups in hole transport materials for perovskite solar cells: Theoretical simulation and experimental characterization

Interface engineering is an effective approach to improve the power conversion efficiency (PCE) of perovskite solar cells (PSCs). To achieve the regulation of intermolecular and interfacial interactions from the point of view for the molecular design of hole transport materials (HTMs), the HTMs of CY9 and CY10 are designed by conjugate management on side-chain groups of carbazole-diphenylamine derivatives. Theoretical simulation demonstrates that the larger π-conjugate units in side-chain of CY10 improve the molecular planarity, thereby enhancing the potential for intermolecular π-π stacking and charge coupling. Molecular dynamics (MD) and first-principles simulations indicates that CY10 is uniformly distributed and compactly arranged on perovskite surface, which enhances intermolecular coupling strength, promotes hole transfer, and facilitates the interfacial interactions at perovskites/HTMs interface. The experimental results validated the reliability of the theoretical simulations, which demonstrated that CY10 as HTM exhibited tighter intermolecular π-π stacking, smooth film morphology, low interfacial defect density, and effective suppression of energy loss caused by interfacial non-radiative recombination. Consequently, the PSC devices based on CY10 exhibited a higher VOC than CY9. This work presents a strategy from the point of view for the molecular design of HTMs to enhance the interfacial interactions of the perovskite/HTM interface.

Impact of charge and non-minimal fluid-geometry coupling on anisotropic interiors

This paper explores the interior configuration of various charged anisotropic compact models within the framework of f(R,T,RληTλη) gravity. The chosen model in this theory is represented by R+γRληTλη , where γ is a real-valued parameter. We adopt a static spherical metric to describe the interior of compact strange stars and derive the corresponding field equations. The solution to these equations is then obtained using the Finch-Skea metric and a linear equation of state. Taking the radius and mass of the compact star model 4U 1820-30 as a case study, we investigate the impact of charge and modified corrections on its internal distribution. The stability of the resulting model is also determined within a specific range of γ. Additionally, we determine the values of the model parameter through the vanishing radial pressure constraint, aligning with the experimental data of eight different stars. Our findings indicate that the resulting model adheres to the conditions necessary for physically relevant interiors, particularly in the case of lower charge.

Efficient Charge Transfer in Graphene/CrOCl Heterostructures by van der Waals Interfacial Coupling.

Due to the large volume of exposed atoms and electrons at the surface of two-dimensional materials, interfacial charge coupling has been proven as an efficient strategy to engineer the electronic structures of two-dimensional materials assembled in van der Waals heterostructures. Recently, heterostructures formed by graphene stacked with CrOCl have demonstrated intriguing quantum states, including a distorted quantum Hall phase in the monolayer graphene and the unconventional correlated insulator in the bilayer graphene. Yet, the understanding of the interlayer charge coupling in the heterostructure remains challenging. Here, we demonstrate clear evidences of efficient hole doping in the interfacial-coupled graphene/CrOCl heterostructure by detailed Raman spectroscopy and electrical transport measurements. The observation of significant blue shifts and stiffness of graphene Raman modes quantitatively determines the concentration of hole injection of about 1.2 × 1013 cm-2 from CrOCl to graphene, which is highly consistent with the enhanced conductivity of graphene. First-principles calculations based on density functional theory reveal that due to the large work function difference and the electronegativity of Cl atoms in CrOCl, the electrons are efficiently transferred from graphene to CrOCl, leading to hole doping in graphene. Our findings provide clues for understanding the exotic physical properties of graphene/CrOCl heterostructures, paving the way for further engineering of quantum electronic states by efficient interfacial charge coupling in van der Waals heterostructures.

Hairy black holes in extended Einstein-Maxwell-scalar theories with magnetic charge and kinetic couplings

Hairy black holes in extended Einstein-Maxwell-scalar theories with magnetic charge and kinetic couplings

Non-universality Relationships for Charged Higgs Boson Yukawa Couplings in the Two Higgs Doublet Model Type III

In the context of the two Higgs doublet model type III with flavor-changing neutral currents at the tree level, I obtain non-universality relationships of charged Higgs boson Yukawa coupling constants by calculating the widths of the pure leptonic decays of the tau lepton τ→eν¯eντ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ au \\rightarrow e \\bar{\ u }_e \ u _\ au$$\\end{document} and τ→μν¯μντ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ au \\rightarrow \\mu \\bar{\ u }_\\mu \ u _\ au$$\\end{document}. To this end, I first calculate these total widths by including the effects of the exchanges of the Higgs boson H-\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$H^-$$\\end{document} and the gauge boson W-\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$W^-$$\\end{document}, with the purpose to obtain the flavor-violating contribution ΔlH-\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Delta _l^{H^-}$$\\end{document} and then to calculate the fraction ΔμH-/ΔeH-\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Delta _\\mu ^{H^-}/\\Delta _e^{H^-}$$\\end{document}. By writing this fraction in terms of the experimental and electroweak standard model branching ratios of these decays and assuming that flavors of neutrino and antineutrino in the final state are defined but unknown, I obtain fractions of charged Higgs boson Yukawa coupling constants that differ from one. These fractions establish non-universality relationships associated with the scalar interaction in contrast to the universality relationships associated with the electroweak interaction.

Two-Dimensional-Like Phonons in Three-Dimensional-Structured Rhombohedral GeSe-Based Compounds with Excellent Thermoelectric Performance.

The coupling of charge and phonon transport in solids is a long-standing issue for thermoelectric performance enhancement. Herein, two new narrow-gap semiconductors with the same chemical formula of GeSe0.65Te0.35 (GST) are rationally designed and synthesized: one with a layered hexagonal structure (H-GST) and the other with a non-layered rhombohedral structure (R-GST). Thanks to the three-dimensional (3D) network structure, R-GST possesses a significantly larger weighted mobility than H-GST. Surprisingly, 3D-structured R-GST displays an extremely low lattice thermal conductivity of ∼0.5 W m-1 K-1 at 523 K, which is comparable to that of layered H-GST. The two-dimensional (2D)-like phonon transport in R-GST stems from the unique off-centering Ge atoms that induce ferroelectric instability, yielding soft polar phonons, as demonstrated by the Boson peak detected by the low-temperature specific heat and calculated phonon spectra. Furthermore, 1 mol % doping of Sb is utilized to successfully suppress the undesired phase transition of R-GST toward H-GST at elevated temperatures. Consequently, a peak ZT of 1.1 at 623 K is attained in the rhombohedral Ge0.99Sb0.01Se0.65Te0.35 sample, which is 1 order of magnitude larger than that of GeSe. This work demonstrates the feasibility of exploring high-performance thermoelectric materials with decoupled charge and phonon transport in off-centering compounds.

Stent coating containing a charged silane coupling agent that regulates protein adsorption to confer antithrombotic and cell-adhesion properties

The evolution of endovascular therapies, particularly in the field of intracranial aneurysm treatment, has been truly remarkable and is characterized by the development of various stents. However, ischemic complications related to thrombosis or downstream emboli pose a challenge for the broader clinical application of such stents. Despite advancements in surface modification technologies, an ideal coating that fulfills all the desired requirements, including anti-thrombogenicity and swift endothelialization, has not been available. To address these issues, we investigated a new coating comprising 3-aminopropyltriethoxysilane (APTES) with both anti-thrombogenic and cell-adhesion properties. We assessed the anti-thrombogenic property of the coating using an in vitro blood loop model by evaluating the platelet count and the level of the thrombin–antithrombin (TAT) complex, and investigating thrombus formation on the surface using scanning electron microscopy (SEM). We then assessed endothelial cell adhesion on the metal surfaces. In vitro blood tests revealed that, compared to a bare stent, the coating significantly inhibited platelet reduction and thrombus formation; more human serum albumin spontaneously adhered to the coated surface to block thrombogenic activation in the blood. Cell adhesion tests also indicated a significant increase in the number of cells adhering to the APTES-coated surfaces compared to the numbers adhering to either the bare stent or the stent coated with an anti-fouling phospholipid polymer. Finally, we performed an in vivo safety test by implanting coated stents into the internal thoracic arteries and ascending pharyngeal arteries of minipigs, and subsequently assessing the health status and vessel patency of the arteries by angiography over the course of 1 week. We found that there were no adverse effects on the pigs and the vascular lumens of their vessels were well maintained in the group with APTES-coated stents. Therefore, our new coating exhibited both high anti-thrombogenicity and cell-adhesion properties, which fulfill the requirements of an implantable stent.

Relativistic head-on collisions of U(1) gauged Q -balls

We investigate the collision dynamics of U(1) gauged Q-balls by performing high-resolution numerical simulations in axisymmetry. Focusing on the case of relativistic head-on collisions, we consider the effects of the initial velocity, relative phase, relative charge, and electromagnetic coupling strength on the outcome of the collision. We find that the collision dynamics can depend strongly on these parameters; most notably, electromagnetic effects can significantly alter the outcome of the collision when the gauge coupling is large. When the gauge coupling is small, we find that the dynamics generally resemble those of ordinary (nongauged) Q-balls. Published by the American Physical Society 2024

Binding Angle Robustness of Plasmonic Nanorod Dimer Resonances

AbstractNarrow gaps between coupled plasmonic nano‐particles show strong optical field enhancements and spectrally adjustable resonance positions, making them attractive for surface enhanced spectroscopies. Gold nanorod dimers formed from nanorod solutions with narrow size distributions are intensely investigated in this context. However, the binding angle of rods coupled at their end faces is usually not controllable. Surprisingly, it is observed that this has only little effect on field enhancement and resonance energies. In this work, gold nanorod dimers are investigated by mapping their plasmon resonances using electron energy‐loss spectroscopy in a scanning transmission electron microscope. For a wide range of dimer orientations, a negligible influence of the angle between the two rods on the bonding and antibonding longitudinal dipole resonances is confirmed, in good agreement with numerical simulations. The results are interpreted via the predominant end‐coupling of the individual nanorod's plasmonic modes, as illustrated by an analytical charge coupling model. In addition, the simulations emphasize that conclusions from experimental data on the gap morphology on the size range of one nanometer can be ambiguous. In any case, the full understanding of the angle‐invariant resonances of nano‐rod dimers can further promote their controlled application in surface enhanced spectroscopy or ‐sensing.

High‐sensitive and fast MXene/silicon photodetector for single‐pixel X‐ray imaging

AbstractThe demand for high‐performance X‐ray detectors leads to material innovation for efficient photoelectric conversion and carrier transfer. However, current X‐ray detectors are often susceptible to chemical and irradiation instability, complex fabrication processes, hazardous components, and difficult compatibility. Here, we investigate a two‐dimensional (2D) material with a relatively low atomic number, Ti3C2Tx MXenes, and single crystal silicon for X‐ray detection and single‐pixel imaging (SPI). We fabricate a Ti3C2Tx MXene/Si X‐ray detector demonstrating remarkable optoelectronic performance. This detector exhibits a sensitivity of 1.2 × 107 μC Gyair−1 cm−2, a fast response speed with a rise time of 31 μs, and an incredibly low detection limit of 2.85 nGyair s−1. These superior performances are attributed to the unique charge coupling behavior under X‐ray irradiation via intrinsic polaron formation. The device remains stable even after 50 continuous hours of high‐dose X‐ray irradiation. Our device fabrication process is compatible with silicon‐based semiconductor technology. Our work suggests new directions for eco‐friendly X‐ray detectors and low‐radiation imaging system.image

Invoking Interfacial Engineering Boosts Structural Stability Empowering Exceptional Cyclability of Ni-Rich Cathode.

The cycling stability of LiNi0.8Co0.1Mn0.1O2 under high voltages is hindered by the occurrence of hybrid anion- and cation-redox processes, leading to oxygen escape and uncontrolled phase collapse. In this study, an interfacial engineering strategy involving a straightforward mechanical ball milling and low-temperature calcination, employing a Se-doped and FeSe2&Fe2O3-modified approach is proposed to design a stable Ni-rich cathode. Se2- are selectively adsorbed within oxygen vacancies to form O─TM─Se bond, effectively stabilizing lattice oxygen, and preventing structural distortion. Simultaneously, the Se-NCM811//FeSe2//Fe2O3 self-assembled electric field is activated, improving interfacial charge transfer and coupling. Furthermore, FeSe2 accelerates Li+ diffusion and reacts with oxygen to form Fe2O3 and SeO2. The Fe2O3 coating mitigates hydrofluoric acid erosion and acts as an electrostatic shield layer, limiting the outward migration of oxygen anions. Impressively, the modified materials exhibit significantly improved electrochemical performance, with a capacity retention of 79.7% after 500 cycles at 1C under 4.5V. Furthermore, it provides an extraordinary capacity retention of 94.6% in 3-4.25V after 550 cycles in pouch-type full battery. This dual-modification approach demonstrates its feasibility and opens new perspective for the development of stable lithium-ion batteries operating at high voltages.

Solvent effects on the ESIPT emission of salicylaldehyde Schiff base derivative: A theoretical reconsideration

Salicylaldehyde Schiff base derivatives have potential applications in bioimaging, chemical sensors and organic luminescence materials because of their high fluorescence quantum yield with the excited-state intramolecular proton transfer (ESIPT) process. Recently, Shu et al. studied the luminescent mechanism of the Et2N-substituted salicylaldehyde Schiff base compound (DDHAC) in solvents [Dyes and Pigments 195 (2021) 109708]. It showed double-peaked bands in an n-hexane solvent but a single-peaked band in an acetonitrile solvent. They suggested that the open-enol in the acetonitrile solvent was the dominant species. They considered that open-enol fluorescence and ESIPT fluorescence constituted a dual fluorescent phenomenon in the n-hexane solvent. However, because acetonitrile is a non-protonic solvent, DDHAC molecules in acetonitrile mainly existed as the lower-energy hydrogen-bonded enol form rather than the open-enol form alone. In addition, the open-enol did not undergo the ESIPT process in n-hexane. Therefore, the luminescence mechanism of the DDHAC molecules in n-hexane and acetonitrile solvents needs to be reconsidered. In this study, we investigated the DDHAC molecules in n-hexane and acetonitrile solvents using the density functional theory and time-dependent density functional theory. The potential energy surfaces and optimisation of structures elucidated that the DDHAC molecules in n-hexane and acetonitrile solvents underwent the ESIPT process. The calculated fluorescence peaks demonstrated that the single-peaked broad emission band in the acetonitrile solvent was formed by the combination of the hydrogen-bonded enol* and keto* forms rather than open-enol*. Moreover, the dual fluorescence peaks in the n-hexane solvent were reattributed to the open-enol* form and hydrogen-bonded enol* form. The lack of keto* fluorescence in the n-hexane solvent was attributed to diminished charge coupling in comparison to the enol* form. Our results revise the mechanism of the DDHAC molecules in n-hexane and acetonitrile solvents, providing guidance for designing efficient organic fluorescence probes.

Cracking behavior of brittle materials under eccentric decoupled charge blasting

The decoupled charge structure is often used in controlled blasting. However, in actual engineering scenarios, boreholes are typically horizontal or inclined. The explosive is close to the borehole wall because of gravity action, resulting in an eccentric charge structure. In this study, concentric and eccentric decoupled charge blasting tests were conducted on 250 mm × 250 mm × 150 mm cuboid concrete specimens. The blast-induced fracture propagation behavior was evaluated using digital image correlation (DIC) technology, and surface fracture networks were extracted by image processing to investigate the fractal characteristics. A three-dimensional finite element model was established and verified using experimental data to reveal the influencing mechanism of the coupling medium and eccentricity coefficient on concrete fractures from the energy perspective. Finally, the borehole wall pressure (BWP) and displacement distribution with different charge structures and coupling media are analyzed theoretically, and the application of an eccentric charge structure in smooth blasting is discussed. The results reveal that nonequivalent BWP and displacement are produced in eccentric charge blasting, with a more evident crushed zone appearing on the coupled side owing to the higher energy utilization efficiency of the explosive. Sand had the largest fracture volume fraction ratio between the coupled and decoupled sides, effectively controlling the damage level on the decoupled side. The proposed eccentric decoupled charge-blasting scheme produced directional damage effects in the field test, maximizing the failure of the excavation rock while reducing the damage level to the reserved rock.

In Situ Surface-Enhanced Raman Spectroscopy on Organic Mixed Ionic-Electronic Conductors: Tracking Dynamic Doping in Light-Emitting Electrochemical Cells.

In the domain of organic mixed ionic-electronic conductors (OMIECs), simultaneous transport and coupling of ionic and electronic charges are crucial for the function of electrochemical devices in organic electronics. Understanding conduction mechanisms and chemical reactions in operational devices is pivotal for performance enhancement and is necessary for the informed and systematic development of more promising materials. Surface-enhanced Raman spectroscopy (SERS) is a potent tool for monitoring electrochemical evolution and dynamic doping in operational devices, offering enhanced sensitivity to subtle spectral changes. We demonstrate the utility of SERS for in situ tracking of doping in OMIECs in an organic light-emitting electrochemical cell (LEC) containing a conjugated polymer (poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]; MEH-PPV), a molecular anion (lithium triflate), and an electrolyte network (poly(ethylene oxide); PEO). SERS enhancement is achieved via an interleaved layer of gold particles formed by spontaneous breakup of a deposited thin gold film. The results successfully highlight the ability of SERS to unveil time-resolved MEH-PPV doping and polaron formation, elucidating the effects of triflate ion transfer in the operating device and validating the electrochemical doping model in LECs.

A novel MOSFET with lateral–vertical charge coupling for extremely low C gd

A novel MOSFET with lateral–vertical charge coupling (LVCC-MOSFET) is proposed in this paper. Lateral charge coupling is enabled by a metal field plate, lightly doped drain and P-Epi layer to reduce the C gd. Vertical charge coupling is enabled by a shield gate, sinker and P-Epi layer to support a high breakdown voltage (BV) and further reduce the C gd. By combining both lateral charge coupling and vertical charge coupling, which is first proposed in low-voltage power MOSFETs, the trade-off relationship between BV, R on and C gd can be significantly improved. It is verified by both small-signal analysis and transient capacitance simulation that the gate-to-drain capacitance of the proposed LVCC-MOSFET can be reduced by more than 99% without deterioration of BV and R on. The LVCC-MOSFET achieves 93.7% reduction in Q gd, and R on × Q gd is only 0.81 mΩ·nC, which is reduced by 93.9%. Furthermore, E on and E off can be reduced by 73.6% and 53.8%, respectively. The hot carrier injection reliability can be enhanced by reducing the electric field and the impact ionization generation rate near the drain-side gate oxide. Moreover, the LVCC-MOSFET can be feasibly manufactured with compatible fabrication process flow, and only three extra steps are needed.

Spectroscopic clarifications, topological insights, Hirshfeld interactions, and quantum chemical computational analysis of antibacterial agent benzimidazolium picrate

The distribution of density at the B3LYP level with a 6–311++G(d,p) basis set for Benzoimidazolium Picrate was presumably assessed to comprehend additional information regarding its molecular shape, harmonic emission, and complex kinetic spectra. Leveraging VEDA software, spectral investigations were conducted for each system which enabled us to gain both qualitative and quantitative assessments of the Raman and IR spectra. Simulations were additionally implemented for net Mulliken charge, Fukui inquiry, RDG review, and intact coupling orbital analyses. The likelihood of shifting charges in the molecule's structure is foretold by the FMO potential gap of 3.9719 eV. Conceptual and feasible computations were employed to evaluate the UV–vis optical properties of BP. The dimensions, design, charge concentration dispersion, and the chemical activity region of the components were established with the electrostatic potential layer (ESP). The morphological attributes of BP were further depicted via ELF and LOL charts. The hyperpolarizability ratings of the drug demonstrate an appropriate level of reliability, and found to be 24 times than urea. To identify the target molecule's appropriate bonding energy with amino acids, a docking virtual reality was conducted.

Multilayered BCST/PZT thin films on GaN substrate for ultraviolet photodetector applications

In the realm of photodetection, there has been growing interest in Ferroelectric/semiconductors heterostructures due to the interfacial charge coupling resulting from ferroelectric polarization. In this study, we created a thin film consisting of alternating layers of Ba0.86Ca0.14Ti0.9Sn0.1O3 and PbZr0.52Ti0.48O3 (referred to as BCST/PZT) using a sol-gel growth method on a (0001) GaN/c-sapphire template. Our objective was to examine the impact of these films on the optoelectronic properties of ferroelectric/GaN heterojunctions. Our findings indicate that the BCST/PZT multilayer films possess improved ferroelectric properties. Furthermore, the multilayer structure demonstrates outstanding optoelectronic performance compared to the individual BCST/GaN or PZT/GaN structures, particularly within the 1 V to 3 V bias range. Notably, the multilayer thin film/GaN devices exhibit a responsivity of 121.4 mA/W and a detectivity of 1.44 × 1011 Jones under a 1 V bias voltage. In contrast to other GaN-based materials documented in the literature, our straightforward sol-gel techniques yielded devices exhibiting UV photodetection characteristics that are either comparable to or superior than those reported.

Quantum computing using floating electrons on cryogenic substrates: Potential and challenges

In this review, we introduce a developing qubit platform: floating-electron-based qubits. Electrons floating in a vacuum above the surface of liquid helium or solid neon emerge as promising candidates for qubits, especially due to their expected long coherence times. Despite being in the early stages, a variety of recent experiments from different groups have shown substantial potential in this role. We survey a range of theoretical proposals and recent experiments, primarily focusing on the use of the spin state as the qubit state, wherein the spin and charge states are hybridized. Throughout these proposals and experiments, the charge state is coupled to an LC resonator, which facilitates both the control and readout mechanisms for the spin state via an artificially introduced spin–charge coupling.

Dielectric spectroscopy of ferroelectric nematic liquid crystals: Measuring the capacitance of insulating interfacial layers

Numerous measurements of the dielectric constant ɛ of the recently discovered ferroelectric nematic (NF) liquid crystal (LC) phase report extraordinarily large values of ɛ′ (up to ∼30 000) in the NF phase. We show that what is in fact being measured in such experiments is the high capacitance of the nonferroelectric, interfacial, insulating layers of nanoscale thickness that bound the NF material in typical cells. Polarization reorientation as a linear response to AC electric field drive renders the NF layer effectively electrically conductive, exhibiting low resistance that enables the charging of the interfacial capacitors. We analyze the commonly employed parallel-plate cell filled with NF material of high polarization , oriented parallel to the plates at zero applied voltage. Minimization of the dominant electrostatic energy renders spatially uniform and orients the polarization to make the electric field in the NF as small as possible, a condition under which the voltage applied to the cell appears almost entirely across the high-capacity interfacial layers. This coupling of orientation and charge creates a combined polarization-external capacitance (PCG) Goldstone reorientation mode requiring applied voltages orders of magnitude smaller than that of the NF layer alone to effectively transport charge across the NF layer. The NF layer acts as a low-value resistor, and the interfacial capacitors act as reversible energy storage reservoirs, lowering the restoring force (mass) of the PCG mode and producing strong reactive dielectric behavior. Analysis of data from a variety of experiments on ferroelectric LCs (chiral smectics C, bent-core smectics, and the NF phase) supports the PCG model, showing that deriving dielectric constants from electrical impedance measurements of high-polarization ferroelectric LCs, without properly accounting for the self-screening effects of polarization charge and the capacitive contributions of interfacial layers, can result in overestimation of the ɛ′ values of the LC by many orders of magnitude. Published by the American Physical Society 2024