In recent years, CO2 geological sequestration has gained significant traction as a viable solution for mitigating global emissions. However, assessing such processes has been challenging due to its inherent complexity. Given the extensive temporal and spatial scales, numerical modeling has emerged as the most efficient and cost-effective means of evaluating them. At present, most existing models are tailored for CO2 sequestration in saline aquifers. There are relatively few models available for depleted gas reservoirs, and only a fraction of them possess the capability to account for geomechanical coupling or complex natural gas compositions.CO2 sequestration in depleted gas reservoirs is considered a promising technique for combating global warming. The use of depleted gas reservoirs has several advantages over saline aquifers, such as the availability of existing facilities and the proven capacity and stability of gas storage. It is believed that CO2 storage in depleted petroleum reservoirs can provide intermediate-scale storage until large-scale storage in saline aquifers becomes mature.Here we propose an Equation of State (EOS) module for CO2 sequestration in depleted gas reservoirs or CO2-enhanced gas recovery. It takes into consideration the mutual solubilities in the CO2-hydrocarbon gas-brine system based on the equality of the chemical potentials of the aqueous and non-aqueous phases. In such a way, it can properly address CO2 dissolution into brine when hydrocarbon gas is present. Hydrocarbon gas includes methane, ethane, and propane. It employs well-recognized approaches to calculate the thermodynamic properties of the gaseous and aqueous phases. This EOS module has been applied to our in-house simulator, TOUGH2-CSM, to enable thermo-hydrological-mechanical modeling. Our research could fill the gap and provide a reference for future studies in this regard.
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