Abstract In this paper, firstly, the conditions and existence region for the coexistence of the black hole and cosmological horizons in Non-linear charged dS (NLC-dS) spacetime are discussed, subsequently, the thermodynamic quantities for which the boundary conditions are satisfied in spacetime in the coexistence region of the two horizons are discussed, and the effective thermodynamic quantities in the NLC-dS spacetime in the coexistence region with two horizons are presented. Based on these, the heat capacity in the coexistence region with two horizons is addressed, the behavior of the heat capacity in the NLC-dS spacetime in the aforementioned region is found to exhibit the characteristics of Schottky specific heat. In order to investigate the intrinsic reason of the heat capacity in spacetime, regarding the two horizons in the NLC-dS spacetime as two distinct energy levels, consequently, the microscopic particles at different horizons exhibit disparate energies. Using the heat capacity relationship between the two-energy level in an ordinary thermodynamic system, the heat capacity in dS spacetime is discussed, it is observed that the behavior of the heat capacity is analogous to that of the two-energy levels in an ordinary thermodynamic system. The number of microscopic particles in the two-level system is approximated by comparing the maximum value of the heat capacity of the system with the maximum value obtained by treating the two horizons in the NLC-dS spacetime as a two-energy-level system of two distinct energies. This conclusion reflects the quantum properties of the coexistence region with two horizons in the NLC-dS spacetime. It provides a new avenue for further study of the thermodynamic properties of black holes and the quantum properties of de Sitter spacetime.