Corrosion Damage Research Articles

Study on Corrosion Damage Behavior of 300M Ultra-high Strength Steel in Marine Atmospheric Environment

Abstract The marine atmospheric environment exposure test of 300M ultra-high strength steel was carried out at Hainan test station. The corrosion damage behavior of 300M ultra-high strength steel in marine atmospheric environment was studied by macroscopic and microscopic corrosion morphology, tensile properties and stress corrosion. The results show that the comprehensive corrosion behavior of 300M ultra-high strength steel occurred in the marine atmospheric environment. The color of the corrosion products changed from red to reddish brown, dark brown and black, and the maximum corrosion depth in the three years was 400μm. The corrosion had a significant effect on the tensile properties during the test. The tensile strength and elongation of 300M ultra-high strength steel decreased by 13.3 % and 81.8 %, respectively, which indicated that the effect of corrosion on the plasticity of the material was much greater than that on the tensile strength. Corrosion also caused a decrease in fracture toughness, and the fracture toughness of 300M ultra-high strength steel decreased by 26% in 2 years. The results of stress corrosion show that the crack propagation of 300M ultra-high strength steel is very rapid in the initial stage of marine atmospheric environment test, and the crack propagation length reaches 10.836mm in 7 days. The stress corrosion threshold KISCC of 300M ultra-high strength steel is 24.48MPa•m1/2, and the relative index of stress corrosion cracking sensitivity is 0.31, which indicates that 300M ultra-high strength steel is very sensitive to stress corrosion in marine atmospheric environment. The results show that 300M ultra-high strength steel has poor adaptability to the marine environment. Therefore, it is necessary to adopt excellent surface treatment process and spray aging resistant coating to effectively protect 300M ultra-high strength steel to ensure its long-term reliable use in the marine environment.

Corrosion behavior of austenitic and ferritic steels in alkaline and water-salt solutions

The paper presents the results of studies of the corrosion behavior of austenitic and ferritic steels in alkaline, sulfide, and chloride environments. Structural changes on the surface when the steels are kept in solutions at room temperature are shown. The chemical composition of the steels was determined, and the exact phase-structural composition was theoretically predicted and metallographically determined. It was found that austenitic steel is almost not subject to sulfide corrosion at room temperature and chlorine-containing substances. At the same time, ferritic steel, under the same conditions, has significant corrosion damage on the surface, especially in places of mechanical damage.

Balancing Interfacial Toughness and Intrinsic Dissipation for High Adhesion and Thermal Conductivity of Polymer-Based Thermal Interface Materials.

In recent years, adhesive thermal interface materials have attracted much attention because of their reliable adhesion properties on most substrates, preventing moisture, vibration impact, or chemical corrosion damage to components and equipment, as well as solving the heat dissipation problem. However, thermal interface materials have a huge contradiction between strong adhesion and high thermal conductivity. Here, we report a polymer-based thermal interface material consisting of polydimethylsiloxane/spherical aluminum fillers, which possesses both adhesion properties (adhesion strength of 3.59 MPa and adhesion toughness of 1673 J m-2 and enhanced thermal conductivity of 3.90 W m-1 K-1). These excellent properties are attributed to the modified chain structure by introducing acrylate accelerators into the polydimethylsiloxane network, thereby striking a balance between interfacial toughness and intrinsic dissipation. The addition of thermally conductive aluminum fillers not only increases the thermal conductivity but also improves the bulk energy dissipation of the thermal interface material. This work provides a novel strategy for designing a novel thermal interface material, leading to new ideas in long-term applications in high-power electronics.

Investigation of the corrosion behavior of 29NC alloy in LiCl-KCl melt at 500 oC depending on the content of Li2O and LiOH from 0 to 2 mol. %

Molten chloride salt electrolytes are promising for use as a working medium for the implementation of high-temperature technologies. Alkali metal chlorides are an aggressive environment in relation to structural materials. One of the possible methods of reducing the corrosion damage of a structural material is the method of oxygen passivation of the surface of a metal or alloy by introducing a certain amount of oxygen-containing additives into the melt. The article considers the effect of oxygen-containing impurities (lithium oxide and lithium hydroxide) on the corrosive behavior of a metal material — an alloy of the composition iron–cobalt–nickel. To assess the corrosion resistance of materials, gravimetric analysis, micro-X-ray spectral analysis (XRSA) of the surface and cross-section sections, and X-ray phase analysis (XRF) of the sample surface were used. The dependences of the corrosion rate of the material on the concentration of oxygen-containing additives Li2O and LiOH are presented. Based on the data set of gravimetric, MRSA and XRF data, it was found that 29NC alloy samples in the LiCl–KCl–nLi2O salt melt are not susceptible to corrosion, but in the LiCl–KCl–nLiOH melt, the speed of the 29NC alloy increases significantly due to the interaction of the LiOH additive with the most electronegative component of the alloy — iron.

Enhanced superhydrophobicity of acrylic polyurethane coatings by femtosecond laser ablation

In recent years, superhydrophobic coatings on aircraft surfaces have garnered significant attention due to their ability to protect the surface from corrosive source like raindrops, sand, and gasoline, etc. However, to date, research on enhancing the hydrophobicity of commercial aviation coatings on aircraft Al surface is still insufficient. In the present study, the femtosecond laser ablation technique is used to texture acrylic polyurethane coatings (denoted as APU) which has been used in the aviation field to achieve a superhydrophobic surface. The relationship between micro-/nanostructures fabricated on the coatings under different laser processing parameters and the corresponding hydrophobicity was studied. The microcone-structured superhydrophobic APU surface prepared under the optimal parameters exhibited a contact angle of 151.2° and a sliding angle of 4.2°. Durability test results show that the APU surface remains at a contact angle of more than 150° after a 140° high-temperature test and 6 h acid-base solution immersion, indicating good chemical and thermal stability. The adopted femtosecond laser fabrication technology and the resultant superhydrophobic coating in the present study may have potential applications to protect aircraft parts from corrosion damage.

Cellular Automata-Based Experimental Study on the Evolution of Corrosion Damage in Bridge Cable Steel Wire

Cable-stayed bridges have become the preferred bridge type for large-span bridges due to their unique advantages, and the long-term performance of the cable under the extreme conditions has been facing great challenges. An accelerated corrosion test was carried out using in-service cable, and the evolution model of the etch pit was established based on cellular automata to study the evolution law of corrosion damage to steel wire. This study showed that with the increase in the number of dry-wet cycles in the electrified accelerated corrosion, the macro- and micromorphology of the steel wire showed more serious corrosion damage, the tensile strength decreased, the ductility index decreased, and the tensile strength of the steel wire after corrosion decreased by nearly 5%; the geometric dimension of the steel wire etch pits all met a right-skewed distribution with a broader range of etch pit depth, mainly consisting of shallow spherical etch pits and deep ellipsoidal etch pits. The length, width, and depth sizes were mainly distributed in the range of 0.005 mm to 0.015 mm, 0.005 mm to 0.02 mm, and 0 mm to 0.04 mm; at the early stage of corrosion, the etch pits were first developed along the longitudinal direction. As the corrosion process progressed, the iron matrix participated in the electrochemical reaction, leading to the rapid expansion of the etch pits’ dimensions. The stress concentration effect at the bottom of the etch pit caused the maximum stress to approach 1800 MPa, with a stress concentration coefficient of more than 3.0; when the cable anchorage system was located in the connecting sleeve and the threaded splice seam, where corrosion protection was prone to failure, the outer steel wire bore most of the corrosive effects, and the internal cable was less eroded by the corrosive medium.

Assessment of the influence of glycol and alcohol on the morphology and protective properties of iron carbonate in carbon dioxide corrosion of gas pipelines

The potential effect of hydrate formation inhibitors (glycols, alcohols) — components of the liquid phase of gas pipeline operating media — on carbon dioxide corrosion during the transport of aggressive gas has not been sufficiently studied. The paper presents the results of a study of the corrosive effect of glycol (alcohol) present in the liquid phase on the composition and properties of corrosion products on steel when modeling the main aggressive factors under conditions of transport of CO2-containing gas. On a corrosion stand, the aggressive conditions of alternating wetting of gas pipeline walls with water were reproduced. The fluid circulation characteristic of a partially filled pipeline can have an effect on preventing the formation or destruction of films of corrosion products (iron carbonate, siderite) on the steel surface. In places of cracking and peeling of siderite formed in the presence of CO2, conditions will be created for the formation of general and local corrosion damage. During simulation tests, monoethylene glycol and isopropanol, as well as their aqueous solutions of different concentrations, were used. For the first time, data on the formation and composition of non-stoichiometric siderite in water-glycol and water-alcohol media at CO2 partial pressures and temperature were obtained. By processing diffraction patterns obtained by X-ray diffraction, the degree of substitution of iron ions in non-stoichiometric siderites by other cations was determined. The dependence of the degree of substitution on the concentration of alcohol (glycol) in their aqueous solutions was analyzed. It was revealed that with an increase in glycol concentration, a decrease in the rate of local corrosion is observed. With a high glycol content, internal corrosion is completely suppressed in the presence of CO2. It has been established that in aqueous-alcoholic media at elevated temperatures, local carbon dioxide corrosion does not occur. This is apparently due to the uneven distribution of water and alcohol in the mixture. The results obtained can be used in assessing internal carbon dioxide corrosion in the presence of glycol (alcohol), used at gas facilities as an inhibitor of hydrate formation.

Study on Multi-Crack Damage Evolution and Fatigue Life of Corroded Steel Wires Inside In-Service Bridge Suspenders

The parallel steel wires used in arch bridge suspenders experience random corrosion damage on their surfaces during service. Corrosion damage, including micro-cracks, pitting, and a combination of both, leads to significant stress concentration under axial loading, which affects the performance of the steel wires. The change in the stress field caused by surface damage alters the stress intensity factor at the crack tip, and the presence of adjacent crack tips significantly amplifies the stress intensity factor, thereby accelerating crack propagation. The development of small surface damages in the steel wires is difficult to control and observe through experiments. By utilizing finite element methods for simulation, it is possible to intuitively analyze the crack propagation process, the trend of stress changes at the crack tip, and the interaction between damages. Numerical simulation results based on Paris’ law indicate that corrosion pits have a certain impact on the stress intensity factor at the crack tip. The propagation process of coplanar double cracks is highly sensitive to the initial crack size and the distance between adjacent crack tips. When the crack spacing is less than the crack depth, the stress intensity factor at the adjacent crack tips exhibits significant amplification. Based on this phenomenon, the coplanar double-crack system can be simplified to a complete single crack for analysis. By comparing the fatigue life of the double-crack system with that of the equivalent single crack, the effectiveness of the simplification rule has been validated.

The activity of hydrolytic enzymes and antibiotics against biofilms of bacteria isolated from industrial-scale cooling towers

BackgroundCooling towers (CTs) are crucial to myriad industrial processes, supporting thermal exchange between fluids in heat exchangers using water from lakes and rivers as coolant. However, CT water can sometimes introduce microbial contaminants that adhere to and colonize various surfaces within the CT system. These microorganisms can form biofilms, significantly hindering the system’s thermal exchange efficiency. Current treatment strategies employ oxidizing biocides to prevent microbial growth. However, despite their affordability, they do not eliminate biofilms effectively and can lead to corrosive damage within the system. Herein, we aim to devise an anti-biofilm strategy utilizing hydrolytic enzymes (such as α-amylase, glucoamylase, pectin-lyase, cellulase, protease, and DNase) alongside antibiotics (including meropenem, ciprofloxacin, gentamicin, erythromycin, chloramphenicol, and ceftriaxone) to combat microbial growth and biofilm formation in cooling systems.ResultsAll enzymes reduced the development of the biofilms significantly compared to controls (p < 0.05). The polysaccharidases exhibited biomass reduction of 90%, except for pectin-lyase (80%), followed by DNAse and protease at 43% and 49%, respectively. The antibiotics reduced the biofilms of 70% of isolates in concentration of > 2 mg/mL. The minimal biofilm eradication concentration (MBEC) lower than 1 mg/mL was detected for some 7-day-old sessile isolates. The enzymes and antibiotics were also used in combination against biofilms using the modified Chequerboard method. We found six synergistic combinations, with Fractional inhibitory concentrations (FIC) < 0.5, out of the ten tested. In the presence of the enzymatic mixture, MBECs presented a significant decrease (p < 0.05), at least 4-fold for antibiotics and 32-fold for enzymes. Moreover, we characterized high molecular weight (> 12 kDa) exopolysaccharides (EPS) from biofilms of ten isolates, and glycosyl composition analysis indicated a high frequency of glucose, mannose, erythrose, arabinose, and idose across isolates EPS contrasting with rhamnose, allose, and those carbohydrates, which were detected in only one isolate.ConclusionThe synergistic approach of combining enzymes with antibiotics emerges as a highly effective and innovative strategy for anti-biofilm intervention, highlighting its potential to enhance biofilm management practices.

Corrosion-life prediction model for 316L stainless steel under electronic special gases containing trace moisture employed in semiconductor manufacturing industry

Special gases with trace moisture cause the formation of dynamic acidic microdroplets (DMD), which results in corrosion of semiconductor manufacturing devices. In this study, a predictive model for corrosion damage in 316L stainless steel (SS) was developed by combining the DMD process and the pitting initiation model. The DMD process was modeled using the BET model to describe the moisture-to-solution conversion. The pitting initiation model was reconstructed by incorporating the Sridhar model, temporal corrosion model, and Macdonald model. Finally, the predicted results were validated by various experimental data, indicating that the prediction model was accurate and highly reliable.

The impact fretting corrosion behavior and damage mechanism of Inconel 690TT under different impact forces in high temperature pressurized water

The impact fretting corrosion of Inconel 690TT under different impact forces was investigated. The results indicated that there was a competitive relationship between formation of third body layer (TBL) and fragmentation of TBL caused by impact force. With the increase of impact forces, damage mechanism changed from adhesive wear to delamination wear, and crack initiation sites gradually shifted from TBL to internal oxidation zone in tribologically transformed structure (TTS) layer. Nanocrystalline boundaries and defects induced by impact force provided channels for internal oxidation. The formation mechanism of TTS was the combined effect of continuous dynamic recrystallization (cDRX) and twin-assisted cDRX.

Corrosion-resistant titanium-based electrodes synergistically stabilized with polymer for hydrogen evolution reaction

The economic and reasonable design of highly stable and corrosion-resistant electrodes is fundamental to achieving the industrial-scale hydrogen productions via water electrolysis, but electrodes’ premature failures are often caused by corrosion and stress damage. Therefore, these challenges are successfully solved by utilizing conductive and crack-resistant polyaniline “stabilizer” with a mild chemical plating process to construct the catalytic electrode on a titanium substrate (15 %PANI-NiB@Ti) in the present work. The 15 %PANI-NiB@Ti catalytic electrodes have been in continuous operation for 350 h at the current density of 200 mA cm−2 with the high efficiency of 98.4 % in a 323.15 K environment. With the high economy and universality, the catalytic electrodes have good catalytic performance and reliability in the extreme industrial environments, such as high temperature, air, and high current density. Except for the above advantages, the 15 %PANI-NiB@Ti catalytic electrodes also have good cracking resistance, which provides a novel and feasible approach to the industrial application of transition metal catalytic electrodes.

Deep Learning-Based Decision Support System for Automatic Detection and Grading of Surface Corrosion on Galvanized Steel Sheets

Corrosion in the sheets produced leads to significant material losses, including the loss of resources, capital, labor, energy and knowledge. Corrosion control is significant for sheets produced and sent to customers in iron and steel factories. Surface corrosion testing of produced sheets and the accurate detection of corrosion levels are of great importance. The corrosion detection process for sheets in steel factories is performed visually with the naked eye. This is a subjective and time-consuming method. Identifying corrosion damage by visual detection and accurately determining the type and extent of corrosion requires expertise. Wrong decisions at this stage lead to losses during the production phase. Therefore, there is a need for systems that can automate this process and make it human-independent. In this study, a decision support system was designed to automatically detect the level of corrosion in galvanized sheets using convolutional neural networks. The average accuracy of the system is 97.5%, the average precision is 0.98, the average recall is 1 and the average F1 score is 0.99. The results we obtained indicate that a successful system has been developed for the detection and determination of corrosion levels. The high performance of the convolutional neural network models used for corrosion detection supports the practical applicability of the developed system. This system will increase the reliability and efficiency of industrial processes by enabling the accurate and automatic classification of corrosion. This system, which meets a significant need in this area for industrial organizations, reduces production costs and also makes the corrosion detection process more consistent and faster.

Effect of grain size on high-temperature corrosion performance of laser cladding inconel 625 coating

As the calorific value of waste-to-energy incineration continues to rise, the corrosion damage to boilers becomes increasingly severe. The impact of the grain size on the high-temperature corrosion resistance of Inconel 625 coating was investigated. The results indicated that the corrosion performance of the coating in 1:1 NaCl–KCl salts at 700 °C for 120 h was highly dependent on the grain size of the coating. The coating fabricated with a laser power of 1800 W and an overlapping distance of 1.5 mm had an average grain size of 13.7 μm and highest hardness, exhibiting the best corrosion performance, with a corrosion weight loss of 1.4 mg/cm2. Coatings processed under different conditions all formed a three-layered structure, with a NiO outermost layer, a Cr2O3 intermediate layer, and an innermost Cr-depletion zone. Coatings with finer grains formed a continuous and dense protective oxide layer of NiO and Cr2O3 due to the rapid diffusion of alloy elements, effectively preventing the invasion of corrosive media and protecting the substrate from corrosion.

An Experimental Assessment Using Acoustic Emission Sensors to Effectively Detect Surface Deterioration on Steel Plates

Acoustic emission (AE) testing is used for the continuous evaluation of structural integrity and the monitoring of damage evolution in structural components and materials. During operation, the environmental and loading conditions of metal structures can result in corrosion and surface wear damage. The early detection of surface degradation flaws is crucial, as they can serve as local stress concentration points, leading to crack initiation and failure. In this work, the effectiveness of AE in monitoring corrosion and surface wear flaw formation was experimentally evaluated. AE sensors were installed on steel test plates during the artificial induction of corrosion and surface wear in order to detect and record the generated AE signals. Corrosion-related AE signals typically exhibit low amplitude, count, and energy values. The direct detection of active corrosion can be challenging in noisy environments, but it can be carried out under certain conditions using dedicated AE sensor groups. Surface-wear-related AE signals exhibit high amplitude, energy, and count values, with long duration values that are associated with wear and grinding conditions. It was found that AE sensors can be utilised to detect corrosion and surface degradation events. The effectiveness of the AE method in detecting surface degradation in noisy environments can be improved by implementing a filtering methodology. This will limit the recording of noise-related signals that can mask out actual surface degradation AE events.

Fatigue Life Assessment of Corroded AlSi10MgMn Specimens

This study investigates the influence of pre-corrosion damage on the fatigue behavior of AlSi10MgMn high-pressure die-cast specimens, using the statistical distribution of corrosion depths. The analysis is conducted on two different surface conditions: an unmachined rough surface (Ra=5.05μm) and a machined, polished surface (Ra=0.25μm). For the unmachined specimens, the corrosive damage manifests as homogeneously spread localized corrosion, whereas the polished specimens exhibit less uniform but deeper corrosion. The average corrosion depth of the polished specimens is found to be slightly higher (313 μm compared to 267 μm) with a broader depth distribution. Specimens are tested under a constant bending load amplitude in laboratory conditions at a stress ratio of R=0 until fracture. A fracture mechanics-based methodology is developed to assess the remaining fatigue life of corroded specimens, utilizing short and long crack fracture mechanical parameters derived from SENB specimens. This model incorporates a thickness reduction of the critical specimen cross-section based on the corrosion depth distribution and combines it with a small initial crack of the intrinsic defect size (aeff=14μm). Regardless of the surface condition, using the most frequent corrosion depth for thickness reduction provides a good estimate of the long-life fatigue strength, while using the 90th percentile depth allows for a conservative assessment.

Ultimate strength assessment of randomly pitted stiffened panels considering stiffener corrosion

Stiffened panels are renowned for their exceptional load-bearing capabilities due to their high strength-to-weight ratio and are extensively utilized in ship and marine structures. Nevertheless, they are susceptible to failure under compression, particularly in marine environments where corrosion leads to material and structural degradation. Stiffener corrosion was not involved adequately in current studies, with an unclear synergistic effect of corrosion damage with structural configurations. This paper introduces a numerical modeling approach to develop finite element (FE) models of panels with random pitting corrosion, considering both corrosion on the plating and stiffeners. These FE models are validated against existing experiments and empirical formulae and employed to investigate the effect of random pitting damage on the ultimate strength of panels. The study examines the impact of various structural parameters, such as plate aspect ratio, plate slenderness ratio, stiffener slenderness ratio, and the height-to-thickness ratio of stiffener web, on ultimate strength under different levels of pitting damage. Additionally, the load-bearing behavior and failure modes of damaged panels are analyzed. An artificial neural network (ANN) is developed to predict the ultimate strength of pitted panels. The findings indicate that the ultimate strength of panels with stiffener corrosion in the form of random pitting corrosion leads to a more significant reduction by about 17.7% than that without stiffener corrosion, potentially altering the failure mode. The proposed ANN model accurately predicts the ultimate strength of pitted panels with and without stiffener corrosion, with a mean relative error of approximately 1.1% compared to FE analysis results.

Experimental investigation of the seismic performance of corroded reinforced concrete coupling beams

In this study, a seismic performance assessment of six reinforced concrete (RC) coupling beam specimens with accelerated corrosion is conducted by combining accelerated corrosion methods with quasistatic loading tests. A detailed comparison of the corrosion damage, failure modes, and mechanical performance differences of the coupling beam specimens under different corrosion levels is presented. The degradation patterns of the coupling beam seismic performance are revealed through analyses of the hysteresis behavior, stiffness degradation, energy dissipation capacity, and proportions of bending, shear, and slip deformations in relation to the corrosion level. The experimental results indicate that with increasing corrosion level, the load-carrying, deformation, and energy dissipation capacities of the coupling beams continuously decrease. The cracking pattern of corrosion-induced cracks is influenced by the reinforcement arrangement, with diagonal reinforcement causing cracks to propagate diagonally. The nonuniform distribution of corrosion leads to asymmetric loading in coupling beam specimens with higher corrosion ratios, significantly weakening the load-carrying and energy dissipation capacities and making the specimens more prone to sudden brittle shear failure without warning. Corrosion-induced damage degrades the shear capacity of the coupling beams, increasing the proportion of shear deformation.

In-situ monitoring of changes in temperature and microstrain during the chemical corrosion of stone cultural relics

Temperature changes during the chemical corrosion of stone cultural relics affect the condensation and evaporation of water and chemical reactions between soluble substances and corrosive solutions. This ultimately leads to changes in the internal structure and composition of the artifacts, which in turn lead to changes in the microstrain of cultural relics. To obtain in-situ real-time information on changes in the temperature and microstrain of stone cultural relics during chemical corrosion damage, a fiber Bragg grating (FBG) detection system was developed. The detection principle for the temperature and microstrain of sandstone was provided. Thermal field emission scanning electron microscopy, X-ray diffraction, and mercury intrusion porosimetry were used to characterize the surface morphology, composition, and pore structure of the sandstone samples, respectively. The temperature and microstrain changes of the sandstone samples under deionized water with different acidic/alkaline and salt solutions and at different temperatures were examined online in situ using the FBG measurement system. The results indicate that the dissolution of sandstone in the acidic solution (H2SO4 and NaHSO4) resulted in an exothermic chemical reaction as well as the dissolution of sandstone in the neutral salt solution (Na2SO4) and alkaline solution (NaOH and Na2CO3) led to material conversion and exothermic chemical reaction; the deionization reaction belongs to the dissolution reaction. The NaHSO4 solution caused the most serious corrosive disease on the sandstone surface. When the temperature of the NaHSO4 solution was 60 °C, the temperature and microstrain of the sandstone reached 63.9 °C and 253.6 με, respectively. The results of this study can support the research of revealing the corrosion mechanism of sandstone in different environments.

Corrosion and conductivity damage of AgNW transparent conductive thin films under a simulated sulfur-containing atmosphere and mechanical force

Silver nanowire (AgNW) transparent conductive thin films possess high flexibility, high conductivity, high light transmittance and etc., demonstrating significant advantages in flexible electronics applications. However, in the service occasions, the coupled effect of corrosion and mechanical force easily makes the electrical conductivity of AgNW films deteriorate or even fail, which seriously affects the service reliability of AgNW films. In this work, scanning vibrating electrode technique was firstly used to confirm the existence of electrochemical corrosion on AgNW films. Furthermore, electrochemical measurements (including OCP, PDP and EIS) were carried out for researching the electrochemical corrosion process on AgNW films under different environmental factors and mechanical forces. Their surface morphologies and electrical conductivity were characterized and evaluated by the Scanning Electron Microscopy and square resistance tester respectively. Experimental results indicate that the corrosion-mechanics interaction effect aggravates the damage process of electrical conductivity of AgNW films.